Synthesis of functional mesoporous material-nanogate material-using hydrothermal reaction (low environmental load process)

• Project/Area Number: 18201014
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Environmental technology/Environmental materials
• Research Institution: Tohoku University
• Principal Investigator: ISHIDA Hideki Tohoku University, 大学院・環境科学研究科, 教授 (10396468)
• Co-Investigator(Kenkyū-buntansha): IOKU Kouji 東北大学, 大学院・環境科学研究科, 教授 (60212726) ; MAEDA Hirotaka 東北大学, 大学院・環境科学研究科, 助教 (20431538)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥38,480,000 (Direct Cost: ¥29,600,000、Indirect Cost: ¥8,880,000); Fiscal Year 2008: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000); Fiscal Year 2007: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000); Fiscal Year 2006: ¥21,970,000 (Direct Cost: ¥16,900,000、Indirect Cost: ¥5,070,000)
• Keywords: 環境材料 / ナノ材料 / 人間生活環境 / 二酸化炭素排出削減 / 多孔体

Research Abstract

本研究では、地球内部で起こっている続成作用のメカニズムを工学的に応用した200℃程度の水熱合成法を用いて、低環境負荷合成による高機能環境親和材料の合成と応用方法の検討を行った。これまでに報告のほとんどなかったAlを多量に含む粘土鉱物を用いた水熱固化に成功した。水熱合成により作製した固化体には、3-20nmの範囲にブロ-ドなナノサイズの細孔が多数存在した。これらのナノ細孔を利用することで、高い水蒸気の吸放出特性や、VOCガスのような有害ガスの吸着特性を有する材料であることを見出し、安全で安心して、快適に過ごせる住空間の創出に寄与できる材料設計を可能にした。

Research Products

• [Journal Article] Water vapor adsorption and desorption of mesoporous materials derived form metakaolinite by hydrothermal treatment (2009)
  • Author(s): H. Maeda and E. H. Ishida
  • Journal Title: Ceramic International Vol.35 Pages: 987-990
  • Peer Reviewed
• [Journal Article] Solidification mechanism of allophone by hydrothermal reaction (2009)
  • Author(s): H. Maeda, Y. Hashimoto and E. H. Ishida
  • Journal Title: Applied Clay Science Vol.44 Pages: 71-74
  • Peer Reviewed
• [Journal Article] Hydrothermal solidification of zeolite/tobermorite composites (2009)
  • Author(s): H. Maeda, T. Okada and E. H. Ishida
  • Journal Title: Journal of the Ceramics Society of Japan Vol.117 Pages: 147-151
  • NAID: 110007044064
• [Journal Article] Water vapor adsorption and desiorption of mesoporous materials derived form metakaolinite by hydrothermal treatment (2009)
  • Author(s): H. Maeda and E. H. Ishida
  • Journal Title: Ceramic International Vol.35 Pages: 987-990
  • Peer Reviewed
• [Journal Article] Water vapor adsorption and desorption of mesoporous materials derived from metakaolinite by hydrothermal treatment (2009)
  • Author(s): H. Maeda and E. H. Ishida
  • Journal Title: Ceramics International 35 Pages: 987-990
  • Peer Reviewed
• [Journal Article] Solidification mechanism of allophane by hydrothermal reaction (2009)
  • Author(s): H. Maeda, Y. Hashimoto, and E. H. Ishida
  • Journal Title: Applied Clay Science 44 Pages: 71-74
  • Peer Reviewed
• [Journal Article] Hydrothermal solidification of zeolite/tobermorite composites (2009)
  • Author(s): H. Maeda, T. Okada, and E. H. Ishida
  • Journal Title: Journal of the Ceramic Society of Japan 117 Pages: 147-151
  • NAID: 110007044064
  • Peer Reviewed
• [Journal Article] Hydrothermal synthesis of mesoporous materials from diatomaceous earth (2007)
  • Author(s): Z. Jing, H. Maeda, K. Ioku and E. H. Ishida
  • Journal Title: AICHE Journal Vol.53 Pages: 2114-2122
  • Peer Reviewed
• [Journal Article] Hydrothermal preparation of solidified materials from metakaolinite, quartz and slaked lime (2007)
  • Author(s): H. Maeda, T. Yamazaki, K. Ioku and E. H. Ishida
  • Journal Title: Journal of the Ceramics Society of Japan Vol.115 Pages: 447-449
  • Peer Reviewed
• [Journal Article] Hydrothermal synthesis of a novel tobermorite-based porous materials from municipal incineration bottom ach (2007)
  • Author(s): Z. Jing, F. Jin, N. Yamasaki and E.H. Ishida
  • Journal Title: Industrial and Engineering Chemistry Research Vol.46 Pages: 2657-2660
  • Peer Reviewed
• [Journal Article] Hydrothermal solidification of blast furnace slag by formation of tobermorite (2007)
  • Author(s): Z. Jing, F. Jin, T. Hashida, N. Yamasaki and E.H. Ishida
  • Journal Title: Journal of Materials Science Vol.46 Pages: 2657-2660
  • Peer Reviewed
• [Journal Article] Hydrothermal solidification of blast furnace slag by formation of tobermorite (2007)
  • Author(s): Jing Z, Jin F, Hashida T, Yamasaki T, Ishida H
  • Journal Title: Journal of Materials Scince 42 Pages: 8236-8241
  • Peer Reviewed
• [Journal Article] Hydrothermal synthesis of mesoporous materials from diatomaceous earth (2007)
  • Author(s): Jing Z, Maeda H, Ioku K, Ishida H
  • Journal Title: AICHE Journal 53 Pages: 2114-2122
  • Peer Reviewed
• [Journal Article] Hydrothermal synthesis of a novel tobermorite-based porous materials from municipal incineration bottom ash (2007)
  • Author(s): Jing Z, Jin F, Yamasaki T, Ishida H
  • Journal Title: Industrial & Engineering Chemistry Research 46 Pages: 2657-2660
  • Peer Reviewed
• [Journal Article] Hydrothermal preparation of solidified materials form metakaolinite, quartz and slaked lime (2007)
  • Author(s): Maeda H, Yamazaki T, Ioku K, Ishida H
  • Journal Title: Journal of the Ceramic Society of Japan 115 Pages: 447-449
  • NAID: 110006317677
  • Peer Reviewed
• [Journal Article] ネイチャー・テクノロジー-2030年に向けた産業構造と生活価値のイノベーションに向けて- (2006)
  • Author(s): 石田 秀輝
  • Journal Title: Journal o the Society of Inorganic Materials, Japan 13 Pages: 428-435
  • NAID: 10018107934
• [Journal Article] Influence of Quartz Particle Size on Hydrothermal Solidification on Blast Furnace Slag (2006)
  • Author(s): Zhenji Jing
  • Journal Title: Industrial and Engineering Chemistry Research 45 Pages: 7470-7474
• [Journal Article] Hydrothermal preparation of tailored hydroxyapatite (2006)
  • Author(s): Koji Ioku
  • Journal Title: Journal of Materials Science 41 Pages: 1341-1344
• [Journal Article] リン酸カルシウムセラミックスキャホールドの設計 (2006)
  • Author(s): 井奥洪二
  • Journal Title: 腎と骨代謝 19 Pages: 313-318
• [Journal Article] Hydrothermal Solidification of Mesoporous Materials from Metakaolin (2006)
  • Author(s): Hirotaka Maeda
  • Journal Title: Proceedings of the 23^<rd> International Korea-Japan Seminar on Ceramics Pages: 495-498
• [Journal Article] Water vapor adsorption and desorption on materials hydrothermally solidified from clay minerals
  • Author(s): H. Maeda and E. H. Ishida
  • Journal Title: Journal of the American Ceramic Society (in press)
  • Peer Reviewed
• [Presentation] Investigation of water vapor adsorption on humidity controlling materials (2008)
  • Author(s): H. Maeda
  • Organizer: IUMRS-ICA2008
  • Place of Presentation: Nagoya
  • Year and Date: 2008-12-09
• [Presentation] Investigation of water vapor adsorption on humidity controlling materials (2008)
  • Author(s): H. Maeda and E. H. Ishida
  • Organizer: IUMRS-ICA 2008
  • Place of Presentation: Nagoya
  • Year and Date: 2008-12-09
• [Presentation] Hydrothermal synthesis of mesoporous materials derived from metakaolinite (2007)
  • Author(s): H. Maeda
  • Organizer: International symposium on ecotopia science
  • Place of Presentation: Nagoya
  • Year and Date: 2007-11-24
• [Presentation] Hydrothermal synthesis of mesoporous materials derived from metakaolinite (2007)
  • Author(s): Maeda H
  • Organizer: International Symposium on Ecotopia Science
  • Place of Presentation: Nagoya
  • Year and Date: 2007-11-24
• [Presentation] Preparation of hydrothermally solidified materials with humidity control properrties (2007)
  • Author(s): H. Maeda
  • Organizer: 7^<th> pacific rim conference on ceramic and glass technology
  • Place of Presentation: Shanghai, China
  • Year and Date: 2007-11-13
• [Presentation] Preparation of hydrothermal solidified materials with humidity control properties (2007)
  • Author(s): Maeda H
  • Organizer: 7th Pacific Rim Conference on Ceramic and Glass Technology
  • Place of Presentation: Shanghai, China
  • Year and Date: 2007-11-13
• [Book] 環境対応型セラミックスの技術と応用-第5章 建材- (2007)
  • Author(s): 石田 秀輝
  • Total Pages: 292
  • Publisher: シーエムシー出版
• [Patent(Industrial Property Rights)] 無機水熱固化体およびその製造方法ならびに水熱固化体を使用したもの (2008)
  • Inventor(s): 石田秀輝, 景鎮子, 前田浩孝, 古川柳蔵, 岡田大邦, 鈴木浩一
  • Industrial Property Rights Holder: 鈴木浩一
  • Industrial Property Number: 2008-074333
  • Filing Date: 2008-03-21