Structural control of atoms and molecules encapsulated in nanotubes and investigation of their physical properties

• Project/Area Number: 18201017
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanostructural science
• Research Institution: National Institute of Advanced Industrial Science and Technology
• Principal Investigator: KATAURA Hiromichi National Institute of Advanced Industrial Science and Technology, ナノテクノロジー研究部門, 研究グループ長 (30194757)
• Co-Investigator(Kenkyū-buntansha): OKADA Susumu 筑波大学, 数理物質科学研究科, 岡田 晋 (70302388) ; 真庭 豊 首都大学東京, 都市教養学部, 教授 (70173937)
• Co-Investigator(Renkei-kenkyūsha): MANIWA Yutaka 首都大学東京, 都市教養学部, 教授 (70173937)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥52,520,000 (Direct Cost: ¥40,400,000、Indirect Cost: ¥12,120,000); Fiscal Year 2008: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000); Fiscal Year 2007: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000); Fiscal Year 2006: ¥34,320,000 (Direct Cost: ¥26,400,000、Indirect Cost: ¥7,920,000)
• Keywords: ナノ構造物性 / カーボンナノチューブ / 分子内包 / ラマン散乱 / 光吸収 / TEM / 単層カーボンナノチューブ / ピーポッド / フォトルミネッセンス / エネルギー移動

Research Abstract

SWCNT内部に、塩化鉄や色素分子、レチナール-C60複合体、βカロテン分子、水分子等を挿入し、その構造や電子状態の変化を調べた。色素分子の場合、フォトルミネッセンスの測定から、内部の色素が吸収した光のエネルギーがSWCNTに移動し、そのエネルギーでSWCNTが発光するという興味深い現象を見いだした。また、レチナール分子のシスートランス変位の電子顕微鏡による直接観察、内包された水分子によるナノバルブの効果等、これまで実現できなかった観測、新たな物理現象の発見に成功した。

Research Products

• [Journal Article] Screening of the missing electron (2009)
  • Author(s): Hidetsugu Shiozawa, Thomas Pichler, Christian Kramberger, Mark Rummeli, DavidBatchelor, Zheng Liu, Kazu Suenaga, Hiromichi Kataura, and S. Ravi P. Silva
  • Journal Title: Nanochemistry in action Phys. Rev. Lett. 102
  • Peer Reviewed
• [Journal Article] Raman spectral features of longer polyynes HC_<2n>H (n=4-8) in SWNTs (2009)
  • Author(s): T. Wakabayashi
  • Journal Title: Eur. Phys. J. D 52 Pages: 79-82
  • Peer Reviewed
• [Journal Article] Tuning of Electronic Properties of Single-Walled Carbon Nanotubes under Homogenous Conditions (2009)
  • Author(s): Yutaka Maeda
  • Journal Title: Chem. Phys. Chem. 10 Pages: 926-930
  • Peer Reviewed
• [Journal Article] Screening of the missing electron : Nanochemistry in action (2009)
  • Author(s): Hidetsugu Shiozawa
  • Journal Title: Phys. Rev. Lett. 102
  • Peer Reviewed
• [Journal Article] Phase Control of Graphene Nanoribbon by Means of Carrier Doping : Antiferromagnetic, Noncollinear-Magnetic, and Ferromagnetic Phases (2009)
  • Author(s): Keisuke Sawada
  • Journal Title: Nano Letters 9 Pages: 269-272
  • Peer Reviewed
• [Journal Article] Electronic Structure of Carbon Nanotubes in Field-Effect Transistor : A First-Principle Study (2009)
  • Author(s): Kazuyuki Uchida, Susumu Okada
  • Journal Title: Physical Review B 79
  • Peer Reviewed
• [Journal Article] Capillary filling of single-walled carbon nanotubes with ferrocene in an organic solvent (2008)
  • Author(s): Hidetsugu Shiozawa
  • Journal Title: Phys. Status Solidi B 245 Pages: 1983-1985
  • Peer Reviewed
• [Journal Article] Energetics of Carbon Peapods ; Radial deformation of nanotubes and aggregation of encapsulated C_<60> (2008)
  • Author(s): Susumu Okada
  • Journal Title: Physical Review B 77
  • Peer Reviewed
• [Journal Article] Energetics of nanoscale graphene ribbons : Edge geometries and electronic structures (2008)
  • Author(s): Susumu Okada
  • Journal Title: Physical Review B 77
  • Peer Reviewed
• [Journal Article] Structural support of the external tubes in double-wall carbon nanotubes (2008)
  • Author(s): J. Arvanitidis
  • Journal Title: High Pressure Research 28 Pages: 591-595
  • Peer Reviewed
• [Journal Article] Phase-relaxation processes of excitons in semiconducting single-walled carbon nanotubes (2008)
  • Author(s): Masao Ichida
  • Journal Title: Phys. Status Solidi B 245 Pages: 2712-2715
  • Peer Reviewed
• [Journal Article] All-polarization-maintaining Er-doped ultrashort-pulse fiber laser using carbon nanotube saturable absorber (2008)
  • Author(s): N. Nishizawa
  • Journal Title: Opt. Express 16 Pages: 9429-9435
  • Peer Reviewed
• [Journal Article] Logic circuits using solution-processed single-walled carbon nanotube transistors (2008)
  • Author(s): Ryo Nouchi
  • Journal Title: Appl. Phys. Lett. 92
  • Peer Reviewed
• [Journal Article] Optical Characterization of Double-wall Carbon Nanotubes : Evidence for Inner Tube Shielding (2008)
  • Author(s): Konstantin Iakoubovskii
  • Journal Title: J. Phys. Chem. C 112 Pages: 11194-11198
  • Peer Reviewed
• [Journal Article] Diameter-dependent relaxation dynamics of 1D excitons in single-walled Carbon nanotubes (2008)
  • Author(s): Masao Ichida
  • Journal Title: Journal of Luminescence 128 Pages: 952-955
  • Peer Reviewed
• [Journal Article] Fine tuning the charge transfer in carbon nanotubes via the interconversion of encapsulated molecules (2008)
  • Author(s): H.Shiozawa
  • Journal Title: Phys.Rev.B 77
  • Peer Reviewed
• [Journal Article] Highly-Stabilized Conductivity of Metallic Single Wall Carbon Napotube Thin Films (2008)
  • Author(s): Y.Miyata
  • Journal Title: J.Phys.Chem.C 112 Pages: 3591-3596
  • Peer Reviewed
• [Journal Article] Catalytic reaction inside a single-wall carbon nanotube (2008)
  • Author(s): Hidetsugu Shiozawa
  • Journal Title: Advanced Materials 20 Pages: 1443-1449
  • Peer Reviewed
• [Journal Article] Imaging the dynamic behaviour of individual retinal chromophores confined inside carbon nanotubes (2007)
  • Author(s): Zheng Liu, Kazuhiro Yanagi, Kazu Suenaga, Hiromichi Kataura and Sumio Iijima
  • Journal Title: Nature Nanotechnology 2 Pages: 422-425
  • Peer Reviewed
• [Journal Article] Water-filled single-wall carbon nanotubes as molecular nanovalves (2007)
  • Author(s): Yutaka Maniwa, Kazuyuki Matsuda, Haruka Kyakuno, Syunsuke Ogasawara, Toshihide Hibi, Hiroaki Kadowaki, Shinzo Suzuki, Yohji Achiba and Hiromichi Kataura
  • Journal Title: Nature Materials 6 Pages: 135-141
  • Peer Reviewed
• [Journal Article] Photosensitive Function of Encapsulated Dye in Carbon Nanotubes (2007)
  • Author(s): Kazuhiro Yanagi, Konstantin Iakoubovskii, Hiroyuki Matsui, Hiroyuki Matsuzaki, Hiroshi Okamoto, Yasumitsu Miyata, Yutaka Maniwa,Said Kazaoui, Nobutsugu Minami, and Hiromichi Kataura
  • Journal Title: J. Am. Chem. Soc 129 Pages: 4992-4997
  • Peer Reviewed
• [Journal Article] Magnetic field dependence of the spin-1/2 and spin-1 Kondo effects in a quantum dot (2007)
  • Author(s): C.H.L.Quay
  • Journal Title: Phys.Rev.B 76
  • Peer Reviewed
• [Journal Article] Structural Study of Single-Walled Carbon Nanotube Films Doped by a Solution Method (2007)
  • Author(s): T.Takenobu
  • Journal Title: Journal of Nanoscience and Nanotechnology 7 Pages: 3533-3536
  • Peer Reviewed
• [Journal Article] High pressure Raman study of the second-order vibrational modes of single-and double-walled carbon nanotubes (2007)
  • Author(s): K.Papagelis
  • Journal Title: Phys.Stat.Sol.(b) 244 Pages: 4069-4073
  • Peer Reviewed
• [Journal Article] Tube encapsulation effects in various carbon nanotube systems (2007)
  • Author(s): D.Christofilos
  • Journal Title: Phys.Stat.Sol.(b) 244 Pages: 4082-4085
  • Peer Reviewed
• [Journal Article] Growth mechanisms of inner-shell tubes in double-wall carbon nanotubes (2007)
  • Author(s): R.Pfeiffer
  • Journal Title: Phys.Stat.Sol.(b) 244 Pages: 4097-4101
  • Peer Reviewed
• [Journal Article] Ferrocene encapsulated in single-wall carbon nanotubes:a precursor to secondary tubes (2007)
  • Author(s): Hidetsugu Shiozawa
  • Journal Title: Phys. Stat. Sol.(b) 244 Pages: 4102-4105
  • Peer Reviewed
• [Journal Article] Bond-curvature effect on burning of single-wall carbon nanotubes (2007)
  • Author(s): Y.Miyata
  • Journal Title: Phys.Stat.Sol.(b) 244 Pages: 4035-4039
  • Peer Reviewed
• [Journal Article] Identification of jnnner and outer shells of double-wall carbon nanotubesusing high-pressure Raman spectroscopy (2007)
  • Author(s): D.Christofilos
  • Journal Title: Phys.Rev.B 76
  • Peer Reviewed
• [Journal Article] Imaging of Aromatic Amide Molecules in Motion (2007)
  • Author(s): Niclas Solin
  • Journal Title: Chem.Lett 36 Pages: 1208-1209
  • Peer Reviewed
• [Journal Article] Transport properties of carbon nanotube C60 peapods (2007)
  • Author(s): C.H.L.Quay
  • Journal Title: Phys.Rev.B 76
  • Peer Reviewed
• [Journal Article] Unrraveling van Hove singularities in x-ray absorption response of single-wall carbon nanotubes (2007)
  • Author(s): C.Kramberger
  • Journal Title: Phys.Rev.B 75
  • Peer Reviewed
• [Journal Article] Dynamics of Carbon Nanotube Growth from Fullerenes (2007)
  • Author(s): Rudolf Pfeiffer
  • Journal Title: Nano Lett 7 Pages: 2428-2434
  • Peer Reviewed
• [Journal Article] Imaging the dynamic behaviour of individual retinal chromophores confined inside carbon nanotubes (2007)
  • Author(s): Zheng Liu
  • Journal Title: Nature Nanotechnology 2 Pages: 422-425
  • Peer Reviewed
• [Journal Article] Effective,fast,and low temperature encapsulation of fullerene derivatives in Single wall Carbon nanotubes (2007)
  • Author(s): A.Mrzel
  • Journal Title: Surface Science 601 Pages: 5116-5120
  • Peer Reviewed
• [Journal Article] Chirality-Dependent Combustion of Single-Walled Carbon Nanotubes (2007)
  • Author(s): Yasumitsu Miyata
  • Journal Title: J.Phys.Chem.C 111 Pages: 9671-9677
  • Peer Reviewed
• [Journal Article] Photosensitive Function of Encapsulated Dye in Carbon Nanotubes (2007)
  • Author(s): Kazuhiro Yanagi
  • Journal Title: J.Am.Chem.Soc 129 Pages: 4992-4997
  • Peer Reviewed
• [Journal Article] Raman Spectroscopy of Size-Selected Linear Polyyne Molecules C2nH2 (n=4-6) Encapsulated in Single-Wall Carbon Nanotubes (2007)
  • Author(s): Daisuke Nishida
  • Journal Title: The Journal of Physical Chemistry C 111 Pages: 5178-5178
• [Journal Article] Water-filled single-wall carbon nanotubes as molecular nanowaves (2007)
  • Author(s): Yutaka Maniwa
  • Journal Title: Nature Materials 6 Pages: 135-135
• [Journal Article] Second-order Raman study of double-wall carbon nanotubes under high pressure (2007)
  • Author(s): K.Papagelis
  • Journal Title: Physica Status Solidi (b) 244 Pages: 116-116
• [Journal Article] Orientation Dependence of Magnetic Moment of Carbon Nanotubes with Topological Line Defect (2007)
  • Author(s): Susumu Okuda
  • Journal Title: Applied Physics Letters 90 Pages: 103120-103120
• [Journal Article] Radical-breathing mode frequencies for nanotubes encapsulating fullerenes (2007)
  • Author(s): Susumu Okuda
  • Journal Title: Chemical Physics Letters 438 Pages: 59-59
• [Journal Article] Formation of Titanium-carbide in nanospace of C78 fullerenes (2007)
  • Author(s): Minoru Otani
  • Journal Title: Chemical Physics Letters, 438 Pages: 274-274
• [Journal Article] Photosensitive Function of Encapsulated Dye in Carbon Nanotubes (2007)
  • Author(s): Kazuhiro Yanagi
  • Journal Title: Journal of the American Chemical Society 129 Pages: 4992-4992
• [Journal Article] Vibration Analysis of Organic Molecules Encapsulated in Carbon Nanotubes by Tip-Enhanced Raman Spectroscopy (2006)
  • Author(s): Yuika Saito
  • Journal Title: Japanese Journal of Applied Physics 45 Pages: 9286-9286
• [Journal Article] Structural properties of carbon peapods under extreme conditions studies using in situ x-ray diffraction (2006)
  • Author(s): M.Chorro
  • Journal Title: Physical Review B 74 Pages: 205425-205425
• [Journal Article] Light-harvesting function of β-carotene inside carbon nanotubes (2006)
  • Author(s): Kazuhiro Yanagi
  • Journal Title: Physical Review B 74 Pages: 155420-155420
• [Journal Article] Water dynamics inside single-wall carbon nanotubes : NMR observations (2006)
  • Author(s): Kazuyuki Matusda
  • Journal Title: Physical Review B 74 Pages: 73415-73415
• [Journal Article] Ferromagnetic Spin Ordering on Carbon Nanotubes with Topological Line Defects (2006)
  • Author(s): Susumu Okuda
  • Journal Title: Physical Review B 74 Pages: 121412-121412
• [Presentation] Kaman study of double-walled carbon nanotubes under high hydrostatic pressure (2009)
  • Author(s): M. Grennvall
  • Organizer: IWEPNM2009
  • Place of Presentation: オーストリア、キルヒベルグ
  • Year and Date: 2009-03-12
• [Presentation] Excitement of nano-test tube chemistry inside single-walled carbon nanotubes (2009)
  • Author(s): Hidetsugu Shiozawa, Thomas Pichler, Christian Kramberger, Mark Rummeli, DavidBatchelor, Zheng Liu, Kazu Suenaga, Hiromichi Kataura, and S. Ravi P. Silva
  • Organizer: IWEPNM2009
  • Place of Presentation: Kirchberg, Austria
  • Year and Date: 2009-03-08
• [Presentation] Excitement of nano-test tube chemistry inside single-walled carbon nanotubes (2009)
  • Author(s): Hidetsugu Shiozawa
  • Organizer: IWEPNM2009
  • Place of Presentation: オーストリア、キルヒベルグ
  • Year and Date: 2009-03-08
• [Presentation] Evaluation of single wall carbon nanotubes by UV-Raman spectroscopy (2007)
  • Author(s): 片浦弘道
  • Organizer: 第33回フラーレンナノチューブ総合シンポジウム
  • Place of Presentation: 九州大学
  • Year and Date: 2007-07-11
• [Book] 2007インクジェット技術大全 第3編2章5節 CNTインクジェット技術によるnm配線の可能性 (2007)
  • Author(s): 片浦弘道
  • Publisher: 電子ジャーナル
• [Book] 2007インクジェット技術大全第3編2章5節CNTインクジェット技術によるnm配線の可能性 (2007)
  • Author(s): 片浦 弘道
  • Total Pages: 4
  • Publisher: 電子ジャーナル
• [Remarks] 成果発表webページ http://staff.aist.go.jp/h-kataura/kataura.html
• [Remarks]
  • URL: http://staff.aist.go.jp/h-kataura/kataura.html
• [Remarks]
  • URL: http://staff.aist.go.jp/h-kataura/kataura.html
• [Patent(Industrial Property Rights)] カーボンナノチューブ薄膜 (2024)
  • Inventor(s): 片浦 弘道, 柳 和宏, 宮田 耕充
  • Industrial Property Rights Holder: 独立行政法人産業技術総合研究所
  • Industrial Property Rights Type: 特許
  • Acquisition Date: 2024-03-23