Rattling Phonon and Superconductivity
Project/Area Number |
18204030
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Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Condensed matter physics II
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Research Institution | Tohoku University |
Principal Investigator |
TANIGAKI Katsumi Tohoku University, 原子分子材料科学高等研究機構, 教授 (60305612)
|
Co-Investigator(Kenkyū-buntansha) |
RYOTARO Kumashiro 東北大学, 大学院・理学研究科, 助教 (00396417)
MATSUOKA Eiichi 東北大学, 高等教育開発推進センター, 助教 (20400228)
KIMURA Noriaki 東北大学, 大学院・理学研究科, 助教 (30292311)
|
Project Period (FY) |
2006 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
|
Budget Amount *help |
¥48,750,000 (Direct Cost: ¥37,500,000、Indirect Cost: ¥11,250,000)
Fiscal Year 2009: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2008: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2007: ¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2006: ¥23,790,000 (Direct Cost: ¥18,300,000、Indirect Cost: ¥5,490,000)
|
Keywords | クラスレート / ナノ材料 / フォノン / 電導 / 物性実験 / 熱伝導 / 超電導 / 分子性固体 / 有機導体 / 超伝導 |
Research Abstract |
The Effects of rattling phonons created by the anharmonic atomic motions accommodated in a nano cage structure are studied focusing on superconductivity via electron-phonon interactions. In the case of local Jahn Teller distortion in the Ge_<100> cage structure, a large reduction in the density of states at the Fermi level occurs to lower the superconducting transition temperature T_c, which cannot be observed in the Si_<100> structure. For the rigid cage structure of Ga16Ge30, the Jahn Teller distortion is suppressed and, instead, the rearrangement in crystal sites of the constituent atoms occurs leading to anharmonic potentials on the endohedral atoms. In such a situation enhanced electron-phonon interactions can be anticipated.
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Report
(6 results)
Research Products
(137 results)
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[Journal Article] Rotational Sub-level of Ortho-Hydrogen Molecule Encapsulated in Isotropic C60 Fullerene Cages2009
Author(s)
Yoshimitsu Kohama, Takeshi Rachi, Ju Jing, Zhaofei Li, Jun Tang, Ryotaro Kumashiro, Satoru Izumisawa, Hitoshi Kawaji, Tooru Atake, Hiroshi Sawa, Yasujiro Murata, Koichi Komatsu, Katsumi Tanigaki
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Journal Title
Phys.Rev.Lett. 102
Pages: 13001-13004
Related Report
Peer Reviewed
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[Journal Article] Soft x-ray photoelectron spectroscopy study of type-I clathrates2009
Author(s)
Jun Tang, Zhaofei Li, Jing Ju, Ryotaro Kumashiro, Marcos A. Avila, Kouichirou Suekuni, Toshiro Takabatake, FangZhun Guo, Keisuke Kobayashi, Koji Akai, Katsumi Tanigaki
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Journal Title
Sci.Technol.Adv.Mater. 9
Pages: 44207-44211
Related Report
Peer Reviewed
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[Journal Article] Soft x-ray photoelectron spectroscopy study of type-I clathrates2009
Author(s)
Jun Tang, Zhaofei Li, Jing Ju, Ryotaro Kumashiro, Mazcos A. Avila, Kouichirou Suekuni, Toshiro Takabatake2, FangZhun Guo, Keisake Kobayashi, Koji Akai, Katstuni Tanigaki
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Journal Title
Sci.Technol.Adv.Mater. 9
Pages: 44207-44211
Related Report
Peer Reviewed
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[Journal Article] Rotational Sub-level of Ortho-Hydrogen Molecule Encapsulated in Isotropic C_60 Fullerene Cages2009
Author(s)
Yoshimitsu Kohama, Takeshi Rachi, Ju Jing, Zhaofei Li, Jun Tang, Ryotaro Kumashiro, Satoru Izumisawa, Hitoshi Kawaji, Tooru Atake, Hiroshi Sawa, Yasujiro Murata, Koichi Komatsu, Katsumi Tanigaki
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Journal Title
Phys.Rev.Lett. 102
Pages: 13001-13004
Related Report
Peer Reviewed
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[Journal Article] Soft x-ray photoelectron spectroscopy study of type-I clathrates2009
Author(s)
J. Tang, Z. Li, J. Ju, R. Kumashiro, M. A. Avila, K. Suekuni, T. Takabatake2, F. Z. Guo, K. Kobayashi, K. Akai, K. Tanigaki
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Journal Title
Sci. Technol. Adv. Mater., 9
Pages: 44207-44211
Related Report
Peer Reviewed
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[Journal Article] Nanorods of Endohedral Metallofullerene Derivative2008
Author(s)
Takahiro Tsuchiya, Ryotaro Kumashiro, Katsumi Tanigaki, Yoichiro Matsunaga, Midori O.Ishitsuka, Takatsugu Wakahara, Yutaka Maeda, Yuta Takano, Motoki Aoyagi, Takeshi Akasaka, Michael T.H.Liu, Tatsuhisa Kato, Kazutomo Suenaga, Jong S.Jeong, Sumio Iijima, Fumiko Kimura, Tsunehisa Kimura, Shigeru Nagase
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Journal Title
J.Am.Chem.Soc. 130
Pages: 450-451
Related Report
Peer Reviewed
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[Journal Article] Soft x-ray photoelectron spectroscopy study of type-I clathrates2008
Author(s)
Jun Tang, Zhaofei Li, Jing Ju, Ryotaro Kumashiro, Marcos A. Avila, Kouichirou Suekuni, Toshiro Takabatake, FangZhun Guo, Keisuke Kobayashi, Koji Akai, Katsumi Tanigaki
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Journal Title
J.Sci and Tech.Advanced Mater 9
Pages: 44207-44207
Related Report
Peer Reviewed
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[Journal Article] Tanigaki, Energetics of endohedral atoms in type-I clathrates observed by soft x-ray spectroscopy2008
Author(s)
J. Tang, T. Rachi, R. Kumashiro, M. A. Avila, K. Suekuni, T. Takabatake, FZ. Guo, K. Kobayashi, K. Aoki, K.
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Journal Title
Phys. Rev. B 78
Pages: 85203-85206
Related Report
Peer Reviewed
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[Journal Article] Nanorods of endohedral metallofullerene derivative2008
Author(s)
T. Tsuchiya, R. Kumashiro, K. Tanigaki, Y. Matsunaga, M. O. Ishitsuka, T. Wakahara, Y. Maeda, Y. Takano, M. Aoyagi, T. Akasaka, M. T. H. Liu, T. Kato, K. Suenaga, J. S. Jeong, S. Iijima, F. Kimura, T. Kimura, S. Nagase
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Journal Title
J. Am. Chem. Soc 130
Pages: 450-451
Related Report
Peer Reviewed
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[Journal Article] Nanorods of Endohedral Metallofullerene Derivative2008
Author(s)
T. Tsuchiya, R. Kumashiro, K. Tanigaki, Y. Matsunaga, O. Ishitsuka, T. Wakahara, Y. Maeda, Y. Takano, M. Aoyagi, Takeshi Akasaka, M. T. H. Liu, T. Kato, K. Suenaga, J. S. Jeong, S. Iijima, F. Kimura, T. Kimura, and S. Nagase
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Journal Title
J. Am. Chem. Soc., Communication 130
Pages: 451-452
Related Report
Peer Reviewed
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[Journal Article] Switchable Semiconductive Property of the Polyhydroxylated Metallofulleren2007
Author(s)
Jun Tang, Gengmei Xing, Yuliang Zhao, Long Jing, Hui Yuan, Feng Zhao, Xueyun Gao, Haijie Qian, Run Su, Kurash Ibrahim, Weiguo Chu, Lina Zhang, Katsumi Tanigaki
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Journal Title
J.Phys.Chem.B 111(41)
Pages: 11929-34
Related Report
Peer Reviewed
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[Journal Article] Switchable Semiconductive Property of the Polyhydroxylated Metallofulleren2007
Author(s)
J. Tang, G. Xing, Y. Zhao, L. Jing, H. Yuan, F. Zhao, X. Gao, H. Qian, R. Su, K. Ibrahim, W. Chu, L. Zhang, and K. Tanigaki
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Journal Title
J. Phys. Chem.B 111 (41)
Pages: 11929-11934
Related Report
Peer Reviewed
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[Journal Article] Switchable Semiconductive Property of the Polyhydroxylated Metallofulleren2007
Author(s)
J. Tang, G. Xing, Y. Zhao, L. Jing, H. Yuan, F. Zhao, X. Gao, H. Qian, R. Su, K. Ibrahim, W. Chu, L. Zhang, and K. Tanigaki
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Journal Title
J. Phys. Chem. B 111
Pages: 11929-11934
Related Report
Peer Reviewed
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[Journal Article] Specific heat capacity and magnetic susceptibility of superconducting Ba24Si1002006
Author(s)
Takeshi Rachi , Katsumi Tanigaki, Ryotaro Kumashiro, Kensuke Kobayashi, Harukazu Yoshino, Keizo Murata, Hiroshi Fukuoka, Syoji Yamanaka, Hidekazu Shimotani, Taishi Takenobu , Yoshihiro Iwasa, Takahiko Sasaki, Norio Kobayashi, Yuji Miyazaki, Kazuya Saito
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Journal Title
J.Physics and Chemistry of Solids 67
Pages: 1334-1337
Related Report
Peer Reviewed
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[Journal Article] Ferromagnetic ordering in a new nickel polyborate NiB12O14(OH)102006
Author(s)
J. Ju, J. Sasaki, T. Yang, S. Kasamatsu, E. Negishi, G. Li, J. Lin, H. Nojiri, T. Rachi, K. Tanigaki, N. Toyota
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Journal Title
Dalton Trans
Pages: 1597-1601
Related Report
Peer Reviewed
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[Journal Article] Electric Transport and Modulated Density of States in Rotational Order and Disorder in Na2CsC602006
Author(s)
M. Akada, T. Yamamoto, R. Kumashiro, A. Hojyo, H. Matsui, N. Toyota, J. P. Lu, K. Tanigaki
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Journal Title
Multifunctional Conducting Molecular Materials(eds. G. Saito, et al.)(Royal Society of Chemistry, Cambride, U.K.)
Pages: 191-197
Related Report
Peer Reviewed
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[Journal Article] Ferromagnetic ordering in a new nickel polyborate NiB_<12>O_<14>(OH)_<10>2006
Author(s)
J.Ju, J.Sasaki, T.Yang, S.Kasamatsu, E.Negishi, G.Li, J.Lin, H.Nojiri, T.Rachi, K.Tanigaki, N.Toyota
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Journal Title
Dalton Trans. 7 S1
Pages: 1597-1601
Related Report
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[Journal Article] Electric Transport Properties of Doped C60 Nanowhiskers2006
Author(s)
R.Kumashiro, K.Tanigaki, N.Miyata, H.Ohashi, T.Fujiki, Y.Gao, Y.murata, K.Komasu, T.Akasaka, J.Minatao, K.Miyazawa
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Journal Title
Multifunctional Conducting Molecular Materials (Special Issue)
Pages: 216-219
Related Report
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[Journal Article] Properties of Chemically Modified Carbon Nanotubes2006
Author(s)
R.Kumashiro, H.Ohashi, T.Akasaka, Y.Maeda, S.Takaishi, M.Yamashita, S.Maruyama, T.Izumida, R.Hatakeyama, K.Tanigaki
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Journal Title
Mater. Res. Soc. Symp. Proc., Volume 901E
Pages: 21-25
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[Presentation] クラスレート化合物Ba_<24>Ge_<100>とAg_6O_8AgNO_3におけるNMR2008
Author(s)
金武史弥, 成輪啓史, 原田淳之, 椋田秀和, 北岡良雄, 長柄一誠, 草部浩一, 良知健, 谷垣勝己, 川島健司, 秋光純, 伊藤公平, E. E. Haller
Organizer
日本物理学会2008年春季大会
Place of Presentation
大阪府東大阪市
Year and Date
2008-03-23
Related Report
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[Presentation] TmAg_2Inの低温物性2008
Author(s)
原口崇, 高木滋, 鈴木博之, 谷田博司, 神永潤弥, 松岡英一, 小野寺秀也, 谷垣勝己
Organizer
日本物理学会2008年春季大会
Place of Presentation
大阪府東大阪市
Year and Date
2008-03-22
Related Report
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[Presentation] 表面修飾したSWCNTsのFET特性2008
Author(s)
熊代良太郎, 小松直也, 齋藤達也, 赤阪健, 前田優, 小林長夫, 谷垣勝己
Organizer
第34回フラーレン・ナノチューブ総合シンポジウム
Place of Presentation
愛知県船橋市
Year and Date
2008-03-03
Related Report
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[Presentation] 73Ge-NMRと第一原理計算によるクラスレート化合物Ba_<24>Ge_<100>の圧力誘起転移の解析2007
Author(s)
金武史弥, 原田淳之, 椋田秀和, 北岡良雄, 長柄一誠, 草部浩一, 鈴木直, 良知健, 谷垣勝己, 伊藤公平, E.E. Haller
Organizer
日本物理学会2007年秋季大会
Place of Presentation
北海道札幌市
Year and Date
2007-09-21
Related Report
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[Presentation] Structural, Thermal, Spectroscopic, Specific Heat, and Magnetic Studies of a New Nickel Polyborate NiB12O14(OH)10 and Its Dehydration Product2007
Author(s)
J. Ju(Sp), J. Sasaki, T. Rachi, K. Tanigaki, N. Toyota
Organizer
Euromat 2007 Euromat 2007
Place of Presentation
Nurunberg, Germany,
Year and Date
2007-09-10
Related Report
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[Presentation] FET Properties of Chemically Modified Carbon Nanotubes2007
Author(s)
R. Kumashiro, N. Hiroshiba, N. Komatsu, T. Akasaka, Y. Maeda, S. Suzuki, Y. Achiba, S. Minami, R. Hatakeyama and K. Tanigaki
Organizer
14th International Symposium on Intercalation Compounds
Place of Presentation
Seoul, Korea,
Year and Date
2007-06-15
Related Report
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[Presentation] Rattling Motions in Superconducting Clathrates Ba_<24>IV_<100>(IV=Si, Ge)2007
Author(s)
T. Rachi, R. Kumashiro, Y. Miyazaki, K. Saito, F. Z. Guo, K. Kobayashi, H. Fukuoka, S. Yamanaka, K. Tanigaki
Organizer
14th International Symposium on Intercalation Compounds
Place of Presentation
Seoul, Korea,
Year and Date
2007-06-15
Related Report
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[Presentation] Physical Properties of H_2 Endohedral C_<60>2007
Author(s)
K. Tanigaki, T. Rachi, R. Kumashiro, Y. Murata, K. Komatsu, T. Kakiuchi, H. Sawa, Y. Kohama, S. Izumisawa, H. Kawaji and T. Atake
Organizer
211th Electrochemical Society Meeting
Place of Presentation
Chicago, USA,
Year and Date
2007-05-11
Related Report
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[Presentation] Physical Properties of H2@C602007
Author(s)
K. Tanigaki, T. Rachi, R. Kumashiro,Y. Murata, K. Komatsu, T. Kakiuchi, H. Sawa, Y. Kohama, S. Izumisawa, H. Kawaji, T. Atake
Organizer
211^<th> Electrochemical Society Meeting
Place of Presentation
Chicago, USA
Year and Date
2007-05-10
Related Report
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