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Atomic-scale study of lattice defect formation due to electronic excitation in spinel-type oxide

Research Project

Project/Area Number 18206068
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionKyushu University

Principal Investigator

MATSUMURA Syo  Kyushu University, 工学研究院, 教授 (60150520)

Co-Investigator(Kenkyū-buntansha) 安田 和弘  九州大学, 工学研究院, 准教授 (80253491)
椎山 謙一  九州大学, 工学研究院, 助教 (30243900)
波多 聡  九州大学, 総合理工学研究院, 准教授 (60264107)
Co-Investigator(Renkei-kenkyūsha) YASUDA Kazuhiro  九州大学, 大学院・工学研究院, 准教授 (80253491)
SHIIYAMA Kenichi  九州大学, 大学院・工学研究院, 助教 (30243900)
HATA Satoshi  九州大学, 大学院・総合理工学研究院, 准教授 (60264107)
Project Period (FY) 2006 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥48,360,000 (Direct Cost: ¥37,200,000、Indirect Cost: ¥11,160,000)
Fiscal Year 2009: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2008: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2007: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2006: ¥33,410,000 (Direct Cost: ¥25,700,000、Indirect Cost: ¥7,710,000)
Keywordsイオン照射 / イオントラック / 高分解能電子顕微鏡 / 電子チャンネリングX線分光 / 分子動力学計算 / 規則-不規則相転移 / 格子欠陥形成エネルギー / 格子欠陥移動エネルギー / スピネル化合物 / 電子チャンネリング分光 / 規則-不規則転移 / 酸化セリウム / 球面収差補正 / 格子欠陥移動工ネルギー
Research Abstract

Structural disordering in magnesium aluminate spinel compounds MgAl_2O_4 induced by strong electronic excitation due to irradiation with swift heavy ions were investigated by means of advanced transmission electron microscopy and molecular dynamics simulations, in connection to their application as inert matrix material in nuclear engineering. The results have clearly revealed the atomistic structure inside ion-tracks as well as the induced disordering behavior quantitatively. The atomistic mechanism for transformation into defective rock-salt structure has been also demonstrated.

Report

(6 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (47 results)

All 2010 2009 2008 2007 2006

All Journal Article (21 results) (of which Peer Reviewed: 17 results) Presentation (26 results)

  • [Journal Article] Accumulation of disordered zone in MgAl_2O_4 irradiated with swift heavy ions2010

    • Author(s)
      K.Yasuda, M.Etoh, S, Kawasoe, T.Yamamoto, S.Matsumura
    • Journal Title

      Nuclear Instruments and Method in Physics Reserach B (印刷中)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Dynamics Simulations of Oxygen Frenkel Pairs in Cerium Dioxide2010

    • Author(s)
      K.Shiiyama, T.Yamamoto, T.Takahashi, A.Guglielmetti, A.Chartier, K Yasuda, S.Matsumura, K.Yausnaga, C.Meis
    • Journal Title

      Nuclear Instruments and Method in Physics Reserach B (印刷中)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recovery and Restructuring induced by Fission Energy Ion in High Burnup Nuclear Fuel2009

    • Author(s)
      M.Kinoshita, K.Yasunaga, T.Sonoda, A.Iwase, N.Ishikawa, M.Sataka, K.Yasuda, S.Matsumura, H.Y.Geng, T.Ichinomiya, Y.Chen, Y.Kaneta, M.Iwasawa, T.Ohnuma, Y.Nishiura, J.Nakamura, Hj Matzke
    • Journal Title

      Nuclear Instruments and Method in Physics Reserach B 267

      Pages: 960-963

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Frenkel pair accumulation induced crystallization of amorphous MgAl2O42008

    • Author(s)
      A. Chartier, T. Yamamoto, K. Yasuda, C. Meis, S. Matsumura
    • Journal Title

      Journal of Nuclear Materials 378

      Pages: 188-192

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular dynamics simulation of point defect accumulation in MgAl2O42008

    • Author(s)
      T. Yamamoto, A. Chartier, K. Yasuda, C. Meis, K. Shiiyama, S. Matsumura
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B 266

      Pages: 2676-2682

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Frenkel pair accumulation induced crystallization of amorphous MgAl_2O_42008

    • Author(s)
      A. Chartier, T. Yamamoto, K. Yasuda, C. Meis, S. Matsumura
    • Journal Title

      Journal of Nuclear Materials 378

      Pages: 188-192

    • Related Report
      2008 Annual Research Report 2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Molecular dynamics simulation of point defect accumulation in MgAl_2O_42008

    • Author(s)
      T. Yamamoto, A. Chartier, K. Yasuda, C. Meis, K. Shiiyama, S. Matsumura
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B 266

      Pages: 2676-2682

    • Related Report
      2008 Annual Research Report 2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Production and stability of radiation-induced defects in MgAl_2O_4 under electronic excitation2008

    • Author(s)
      K. Yasuda, T. Yamamoto, S. Seki, K. Shiiyama, S. Matsumura
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B 266

      Pages: 2834-2841

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular dynamics simulation of irradiation induced phase transition in MgAl_2O_42008

    • Author(s)
      A. Chartier, T. Yamamoto, K. Yasuda, C. Meis, S. Matsumura
    • Journal Title

      Proc. the Fouth Int'l. Conf. on Multiscale Materials Modeling

      Pages: 583-588

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular dynamics simulation of point defect accumulation in MgAl_2O_42008

    • Author(s)
      T.Yamamoto, A.Chartier, K.Yasuda, C.Meis, K.Shiiyama, S.Matsumura
    • Journal Title

      Nuclear Instruments and Methods in Physics Research B (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Production and stability of radiation-induced defects in MgAl_2O_4 under electronic excitation2008

    • Author(s)
      K.Yasuda, T.Yamamoto, S.Seki, K.Shiiyama, S.Matsumura
    • Journal Title

      Nuclear Instruments and Methods in Physics Research B (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The atomic structure of disordered ion tracks in magnesium aluminate spinel2007

    • Author(s)
      K. Yasuda, T. Yamamoto, S. Matsumura
    • Journal Title

      JOM 59

      Pages: 27-30

    • NAID

      10018791195

    • Related Report
      2009 Final Research Report 2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] The atomic structure of disordered ion tracks in magnesium aluminate spinel2007

    • Author(s)
      K.Yasuda, T.Yamamoto, S.Matsumura
    • Journal Title

      JOM 59

      Pages: 27-30

    • NAID

      10018791195

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructure and Ion Configuration of Spinel Irradiated with Swift Heavy Ions2007

    • Author(s)
      K.Yasuda, T.Yamamoto, S.Kawasoe, S.Matsumura, N.Ishikawa
    • Journal Title

      JAEA Review 2007 46

      Pages: 91-92

    • Related Report
      2007 Annual Research Report
  • [Journal Article] Radiation damage effects in insulators for fusion reactors: Microstructure evolution in MgO-Al2O3 system oxide crystal2006

    • Author(s)
      K. Yasuda, S. Matsumura
    • Journal Title

      Advances in Science and Technology 45

      Pages: 1961-1968

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atomic structure and disordering induced by 350 MeV Au ions in MgAl2O42006

    • Author(s)
      K. Yasuda, T. Yamamoto, M. Shimada, S. Matsumura, Y. Chimi, N. Ishikawa
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B 250

      Pages: 238-244

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Radiation damage effects in insulators for fusion reactors : Microstructure evolution in MgO-Al_2O_3 system oxide crystal2006

    • Author(s)
      K. Yasuda, S. Matsumura
    • Journal Title

      Advances in Science and Technology 45

      Pages: 1961-1968

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Atomic structure and disordering induced by 350 MeV Au ions in MgAl_2O_42006

    • Author(s)
      K. Yasuda, T. Yamamoto, M. Shimada, S. Matsumura, Y. Chimi and N. Ishikawa
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section B 250

      Pages: 238-244

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Microstructure and atomic disordering of magnesium aluminate spinel irradiated with swift heavy ions2006

    • Author(s)
      M.Shimada, T.Yamamoto, K.Yasuda, S.Matsumura, Y.Chimi, N.Ishikawa
    • Journal Title

      Nuclear Instruments and Methods in Physics Research B 245巻・1号

      Pages: 235-238

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Atomic structure and disordering induced by 350 MeV Au ions in MgAl_2O_42006

    • Author(s)
      K.Yasuda, T.Yamamoto, M.Shimada, S.Matsumura, Y.Chimi, N.Ishikawa
    • Journal Title

      Nuclear Instruments and Methods in Physics Research B 250巻

      Pages: 238-244

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Radiation damage effects in insulators for fusion reactors : Microstru cture evolution in MgO-Al_2O_3 system oxide crystal2006

    • Author(s)
      K.Yasuda, S.Matsumura
    • Journal Title

      Advances in Science and Technology 45巻

      Pages: 1961-1968

    • Related Report
      2006 Annual Research Report
  • [Presentation] Sub-divided grain formation and recovery of dislocation structure in CeO_2 induced by swift heavy ions2009

    • Author(s)
      K.Yasuda, K.Yasunaga, S.Matsumura, T.Sonoda, M.Kinoshita
    • Organizer
      MRS 2009 Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2009-12-03
    • Related Report
      2009 Annual Research Report
  • [Presentation] Atomic-scale analysis of irradiation-induced structural change in magnesium aluminate spinel compound2009

    • Author(s)
      S. Matsumura, T. Yamamoto, K. Yasuda
    • Organizer
      MRS 2009 Fall Meeting
    • Place of Presentation
      Boston, MA, USA
    • Year and Date
      2009-11-30
    • Related Report
      2009 Final Research Report
  • [Presentation] Atomic-scale Analysis of Irradiation-induced Structural Change in Magnesium Aluminate Spinel Compound2009

    • Author(s)
      S.Matsumura, T.Yamamoto, K.Yasuda
    • Organizer
      MRS 2009 Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2009-11-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高速重イオン照射したCeO_2の転位組織の回復と微細粒形成2009

    • Author(s)
      安田和弘, 江藤基稀, 山田隆雄, 安永和史, 松村晶
    • Organizer
      日本金属学会第145回大会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 酸化セリウム中の酸素イオンフレンケル対挙動に関する分子動力学計算2009

    • Author(s)
      椎山謙一, 高橋達郎, 山本知一, 安田和弘, 松村晶, A.Chartier, C.Meis
    • Organizer
      日本金属学会第145回大会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Accumulation of disordered zone in MgAl2O4 irradiated with swift heavy ions2009

    • Author(s)
      K. Yasuda, M. Etoh, S, Kawasoe, T. Yamamoto, S. Matsumura
    • Organizer
      Radiation Effects in Insulators-15
    • Place of Presentation
      Padova, Italy
    • Year and Date
      2009-08-31
    • Related Report
      2009 Final Research Report
  • [Presentation] Accumulation of disordered zone in MgAl_2O_4 irradiated with swift heavy ions2009

    • Author(s)
      K.Yasuda, M.Etoh, S, Kawasoe, T.Yamamoto, S.Matsumura
    • Organizer
      Radiation Effects in Insulators-15
    • Place of Presentation
      Padova, Italy
    • Year and Date
      2009-08-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] Molecular Dynamics Simulations of Oxygen Frenkel Pairs in Cerium Dioxide2009

    • Author(s)
      K.Shiiyama, T.Yamamoto, T.Takahashi, A.Guglielmetti, A.Chartier, K.Yasuda, S.Matsumura, K.YAusnaga, C.Meis
    • Organizer
      Radiation Effects in Insulators-15
    • Place of Presentation
      Padova, Italy
    • Year and Date
      2009-08-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] Small grain formation by swift heavy ions in CeO_22009

    • Author(s)
      K.Yasunaga, T.Sonoda, K.Yasuda, S.Matsumura
    • Organizer
      The 12th Frontiers of Electron Microscopy in Materials Science
    • Place of Presentation
      Sasebo
    • Related Report
      2009 Annual Research Report
  • [Presentation] Molecular dynamics simulation of irradiation induced phase transition in MgAl2O42008

    • Author(s)
      A. Chartier, T. Yamamoto, K. Yasuda, C. Meis, S. Matsumura
    • Organizer
      Fouth International Conference on Multiscale Materials Modeling (MMM2008)
    • Place of Presentation
      Tallahassee, Florida, USA
    • Year and Date
      2008-10-28
    • Related Report
      2009 Final Research Report
  • [Presentation] Molecular dynamics simulation of irradiation induced phase transition in MgAl_2O_42008

    • Author(s)
      A. Chartier, T. Yamamoto, K. Yasuda, C. Meis, S. Matsumura
    • Organizer
      Fouth International Conference on Multiscale Materials Modeling (MMM2008)
    • Place of Presentation
      Tallahassee, Florida, USA.
    • Year and Date
      2008-10-28
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Molecular dynamics simulation of irradiation induced phase transition in MgAl_2O_42008

    • Author(s)
      A. Chartier, T. Yamamoto, K. Yasuda, C. Meis, S. Matsumura
    • Organizer
      Fouth International Conference on Multiscale Materials Modeling (MMM2008)
    • Place of Presentation
      Tallahassee, Florida, USA
    • Year and Date
      2008-10-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] A. Chartier,C.Meis, MgAl_2O_4中のフレンケル対再結合・蓄積過程のMDシミュレーション2008

    • Author(s)
      山本知一, 安田和弘, 椎山謙一, 松村晶
    • Organizer
      日本金属学会2008年秋期(第143回)大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] MgAl_2O_4中のフレンケル対再結合・蓄積過程のMDシミュレーション2008

    • Author(s)
      山本知一, 安田和弘, 椎山謙一, 松村 晶, A. Chartier, C. Meis
    • Organizer
      日本金属学会2008年秋期(第143回)大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] Molecular dynamics study of irradiation-induced structural change in magnesium aluminate spinel compound2008

    • Author(s)
      S. Matsumura, T. Yamamoto, K. Yasuda, K. Shiiyama, A. Chartier, , C. Meis
    • Organizer
      ECI conference on Innovative Dynamics Studies of Materials at the Nanoscale
    • Place of Presentation
      Gyeong-ju, Korea
    • Year and Date
      2008-06-30
    • Related Report
      2009 Final Research Report 2008 Annual Research Report 2008 Self-evaluation Report
  • [Presentation] 電子照射に伴うセラミックス中の照射欠陥形成とその安定性2008

    • Author(s)
      松村 晶, 安田和弘, 安永和史
    • Organizer
      日本顕微鏡学会第64回学術講演会
    • Place of Presentation
      京都国際会議場
    • Year and Date
      2008-05-22
    • Related Report
      2008 Annual Research Report
  • [Presentation] Production and stability of radiation-induced defects in MgO/Al2O3 under electronic excitation2007

    • Author(s)
      K. Yasuda, S. Matsumura
    • Organizer
      14th International Conference on Radiation Effects in Insulators
    • Place of Presentation
      Caen, France
    • Year and Date
      2007-08-29
    • Related Report
      2009 Final Research Report
  • [Presentation] Production and stability of radiation-induced defects in MgO/Al_2O_3 under electronic excitation2007

    • Author(s)
      K. Yasuda, S. Matsumura
    • Organizer
      14th International Conference on Radiation Effects in Insulators
    • Place of Presentation
      Caen, France.
    • Year and Date
      2007-08-29
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] Molecular dynamics simulation of point defect accumulation in MgAl_2O_42007

    • Author(s)
      T.Yamamoto, A.Chartier, K.Yasuda, C.Meis, K.Shiiyama, S.Matsumura
    • Organizer
      14^<th> International Conference on Radiation Effects in Insulators
    • Place of Presentation
      Caen,France
    • Related Report
      2007 Annual Research Report
  • [Presentation] Production and stability of radiation-induced defects in MgO/Al_2O_3 under electronic excitation2007

    • Author(s)
      K.Yasuda, S.Matsumura
    • Organizer
      14^<th> International Conference on Radiation Effects in Insulators
    • Place of Presentation
      Caen,France
    • Related Report
      2007 Annual Research Report
  • [Presentation]2007

    • Author(s)
      椎山 謙一, 山本 知一, 安田 和弘 松村 晶, A.Chartier, C.Meis
    • Organizer
      日本原子力学会2007年秋の大会
    • Place of Presentation
      北九州市
    • Related Report
      2007 Annual Research Report
  • [Presentation] MgAl_2O_4中の点欠陥に関する分子動力学計算:(2)フレンケル対蓄積過程2007

    • Author(s)
      山本 知一, 椎山 謙一, 安田 和弘 松村 晶, A.Chartier, C.Meis
    • Organizer
      日本原子力学会2007年秋の大会
    • Place of Presentation
      北九州市
    • Related Report
      2007 Annual Research Report
  • [Presentation] 電子励起下におけるマグネシア・スピネル中の転位ループ成長・収縮過程2007

    • Author(s)
      安田 和弘、関真 一郎、山本 知一、松村 晶
    • Organizer
      日本原子力学会2007年秋の大会
    • Place of Presentation
      北九州市
    • Related Report
      2007 Annual Research Report
  • [Presentation]2007

    • Author(s)
      A.Chartier, T.Yamamoto, K.Yasuda, C.Meis, K.Shiiyama, S.Matsumura
    • Organizer
      2007 MRS Fall Meeting
    • Place of Presentation
      Boston,USA
    • Related Report
      2007 Annual Research Report
  • [Presentation] Atomic resolution transmission electron microscope analysis of disordered ion tracks formed in magnesium aluminate spinel by swift heavy ions2006

    • Author(s)
      S. Matsumura, T. Yamamoto, K. Yasuda, Y. Chimi, N. Ishikawa
    • Organizer
      Materials Science & Technology 2006 Conference and Exhibition
    • Place of Presentation
      Cincinnati, OH, USA
    • Year and Date
      2006-10-18
    • Related Report
      2009 Final Research Report
  • [Presentation] Atomic resolution transmission electron microscope analysis of disordered ion tracks formed in magnesium aluminate spinel by swift heavy ions2006

    • Author(s)
      S. Matsumura, T. Yamamoto, K. Yasuda, Y. Chimi, N. Ishikawa
    • Organizer
      Materials Science &amp; Technology 2006 Conference and Exhibition
    • Place of Presentation
      Cincinnati, OH, USA.
    • Year and Date
      2006-10-18
    • Related Report
      2008 Self-evaluation Report

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Published: 2006-04-01   Modified: 2016-04-21  

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