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Synthesis of nanophotocrystals via novel green process using water : Solubilization of non-water-soluble metals into water based upon complexation

Research Project

Project/Area Number 18206069
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

KAKIHANA Masato  Tohoku University, 多元物質科学研究所, 教授 (50233664)

Co-Investigator(Kenkyū-buntansha) TOMITA Koji  東海大学, 理学部, 講師 (00419235)
PETRYKIN Valery  東北大学, 多元物質科学研究所, 准教授 (20375166)
Project Period (FY) 2006 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥49,920,000 (Direct Cost: ¥38,400,000、Indirect Cost: ¥11,520,000)
Fiscal Year 2009: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2008: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2007: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2006: ¥23,660,000 (Direct Cost: ¥18,200,000、Indirect Cost: ¥5,460,000)
Keywords水 / グリーンプロセス / ナノ光結晶 / 水溶性金属錯体 / フォトセラミックス / グループプロセス
Research Abstract

In this study we developed new water-soluble compounds as precursors for photo-functional ceramics and synthesized high-performanced photoceramics using water as a processing solvent. We succeeded in development of new Si, Nb, and Ta water-soluble compounds through chemical complexation techniques. Our newly developed aqueous solution method using these compounds enabled us not only to prepare materials having properties superior to those for materials synthesized by the conventional method but also to provide highly morphologically controlled particles. Another important achievement in this study includes establishment of the new parallel synthetic scheme using water-soluble Si compound, which made possible to find quickly optimal compositions of high-brightness phosphors.

Report

(6 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (99 results)

All 2010 2009 2008 2007 2006 Other

All Journal Article (47 results) (of which Peer Reviewed: 42 results) Presentation (37 results) Book (5 results) Remarks (3 results) Patent(Industrial Property Rights) (7 results)

  • [Journal Article] Preparation of Water Soluble Silicon Compound and its Application for Synthesis of (Y,Ce,Gd)_2SiO_5 Blue Emission Phosphor2009

    • Author(s)
      Y. Suzuki, M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 330-334

    • NAID

      110007123878

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] New water soluble and handy silicon precursor for synthesis of (Y, Ce, Gd)_2SiO_5 phosphor2009

    • Author(s)
      Y. Suzuki, M. Kakihana
    • Journal Title

      J.Phys. : Conf.Seri. : Mater.Sci.Eng. 1

      Pages: 12012-12012

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of K_3Ta_3B_2O_<12> photocatalyst by solution based method and effect of co-catalyst and phase purity to water splitting activity2009

    • Author(s)
      Matsumoto, K. Ueda, K. Tomita, Y. Sekine, Y. Miura, N. Yamatani, M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 1191-1194

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of high-performance ceramics based on polymerizable complex method2009

    • Author(s)
      M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 857-862

    • NAID

      130006980170

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Patterning using Nano-Colloidal Anatase in Aqueous Solution Process2009

    • Author(s)
      K. Tomita, K. Yamamoto, K. Fujita, V. Petrykin, M. Kakihana
    • Journal Title

      Trans.Mater.Res.Soc.Jpn. 34

      Pages: 279-281

    • NAID

      130005003976

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of TiO_2(B) using glycolato titanium complex and post-synthetic hydrothermal crystal growth of TiO_2(B)2009

    • Author(s)
      K. Yamamoto, K. Tomita, K. Fujita, M. Kobayashi, V. Petrykin, M. Kakihana
    • Journal Title

      J.Cryst.Grow 311

      Pages: 619-622

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nano- crystalline YVO_4 : Eu Red Emission Phosphor with High Fluorescence Intensity by Hydrothermal Method using Original Vanadium-Peroxo- Citrate Complex2009

    • Author(s)
      S. Kaowphong, V. Petrykin, S. Thongtem, M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 273-276

    • NAID

      110007123912

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis and Photocatalytic Activity of Whisker-Like Rutile-Type Titanium Dioxide2009

    • Author(s)
      M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita
    • Journal Title

      J.Am.Ceram.Soc. 92

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Water Soluble Silicon Compound and its Applicati on for Synthesis of(Y, Ce, Gd)_2SiO_5 Blue Emission Phosphor2009

    • Author(s)
      Y.Suzuki, M.Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn 117

      Pages: 330-334

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New water soluble and handy silicon precursor for synthesis of(Y, Ce, Gd)_2SiO_5 phosphor2009

    • Author(s)
      Y.Suzuki, M.Kakihana
    • Journal Title

      J.Phys.: Conf Seri.: Mater.Sci.Eng. 1

      Pages: 12012-12012

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of K_3Ta_3B_2O_<12> photocatalyst by solution based method and effect of co-catalyst and phase purity to water splitting activity2009

    • Author(s)
      Y.Matsumoto, K.Ueda, K.Tomita, Y.Sekine, Y.Miura, N.Yamatani, M.Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 1191-1194

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of high- performance ceramics based on polymerizable complex method2009

    • Author(s)
      M.Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 857-862

    • NAID

      130006980170

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Patterning using Nano-Colloidal Anatase in Aqueous Solution Process2009

    • Author(s)
      K.Tomita, K.Yamamoto, K.Fujita, V.Petrykin, M.Kakihana
    • Journal Title

      Trans.Mater.Res.Soc.Jpn. 34

      Pages: 279-281

    • NAID

      130005003976

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of TiO_2(B)using glycolato titanium complex and post-synthetic hydrothermal crystal growth of TiO_2(B)2009

    • Author(s)
      K.Yamamoto, K.Tomita, K.Fujita, M.Kobayashi, V.Petrykin, M.Kakihana
    • Journal Title

      J.Cryst.Grow. 311

      Pages: 619-622

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nano- crystalline YVO_4 : Eu Red Emission Phosphor with High Fluorescence Intensity by Hydrothermal Method using Original Vanadium-Peroxo-Citrate Complex2009

    • Author(s)
      S.Kaowphong, V.Petrykin, S.Thongtem, M.Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 273-276

    • NAID

      110007123912

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis and Photocatalytic Activity of Whisker-Like Rutile-Type Titanium Dioxide2009

    • Author(s)
      M.Kobayashi, V.Petrykin, M.Kakihana, K.Tomita
    • Journal Title

      J Am.Ceram.Soc. 92

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of TiO_2(B) using glycolato titanium complex and post-synthetic hydrothermal crystal growth of TiO_2(B)2009

    • Author(s)
      K. Yamamoto, K. Tomita, K. Fujita, M. Kobayashi, V. Petrykin, M. Kakihana
    • Journal Title

      J. Cryst. Grow. 311

      Pages: 619-622

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis and Photocatalytic Activity of Whisker-Like Rutile-Type Titanium Dioxide2009

    • Author(s)
      M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita
    • Journal Title

      1Am. Cera. Soc. 92

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis of TiO_2 (B) using glycolato titanium complex and post-synthetic hydrothermal crystal growth of TiO_2 (B)2009

    • Author(s)
      Kazuhiro Yamamoto, et.al.
    • Journal Title

      Journal of Crystal Growth 311(3)

      Pages: 619-622

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes2008

    • Author(s)
      M. Kobayashi, K. Tomita, V. Petrykin, M. Yoshimura, M. Kakihana
    • Journal Title

      J.Mat.Sci. 43

      Pages: 2158-2162

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes2008

    • Author(s)
      M. Kobayashi, K. Tomita, V. Petrykin, M. Yoshimura, M. Kakihana
    • Journal Title

      J. Mat. Sci. 43

      Pages: 2158-2162

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Direct synthesis of brookite-type titanium oxide by hydrotherm al method using water-soluble titanium complexes2008

    • Author(s)
      Makoto Kobayashi, et.al.
    • Journal Title

      Journal of Materials Science 43(7)

      Pages: 2158-2162

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal synthesis of TiO2 nano-particles using novel water-soluble titanium complexes2008

    • Author(s)
      Koji Tomita, et.al.
    • Journal Title

      Journal of Materials Science 43(7)

      Pages: 2217-2221

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New water-soluble complexes of titanium with amino acids and their application for synthesis of TiO2 nanoparticles2008

    • Author(s)
      Makoto Kobayashi, et.al.
    • Journal Title

      Journal of the Ceramic Society of Japan 116(4)

      Pages: 578-583

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes2008

    • Author(s)
      M. Kobayashi, et. al.
    • Journal Title

      Journal of Materials Science 43

      Pages: 2158-2162

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal synthesis of TiO_2 nano-particles using novel water-soluble titanium complexes2008

    • Author(s)
      K. Tomita, et. al.
    • Journal Title

      Journal of Materials Science 43

      Pages: 2217-2221

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New water-soluble complexes of titanium with amino acids and their application for synthesis of TiO_2 nanoparticles2008

    • Author(s)
      Makoto Kobayashi, et. al.
    • Journal Title

      Journal of the Ceramic Society of Japan 116(4)

      Pages: 578-583

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-step synthesis of TiO_2(B) nanoparticles from a Water-Soluble titanium complex2007

    • Author(s)
      M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita, M. Yoshimura
    • Journal Title

      Chem.Mat. 19

      Pages: 5373-5376

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microwave-assisted hydrothermal synthesis of brookite nanoparticles from a water-soluble titanium complex and their photocatalytic activity2007

    • Author(s)
      Y. Morishinia, M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita
    • Journal Title

      J.Ceram.Soc.Jpn 115

      Pages: 826-830

    • NAID

      110006546362

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-step synthesis of TiO_2(B) nanoparticles from a Water-Soluble titanium complex2007

    • Author(s)
      M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita, M. Yoshimura
    • Journal Title

      Chem. Mat. 19

      Pages: 5373-5376

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Microwave-assisted hydrothermal synthesis of brookite nanoparticles from a water-soluble titanium complex and their photocatalytic activity2007

    • Author(s)
      Y. Morishinia, M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita
    • Journal Title

      1 Ceram. Soc. Jpn. 115

      Pages: 826-830

    • NAID

      110006546362

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] The Chemistry of The Processes Involved in The Production of Lanthanide Titanates by The Polymerized Complex Method2007

    • Author(s)
      Dimitr Todorovsky, et. al.
    • Journal Title

      Canadian Journal of Chemistry 85

      Pages: 547-559

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-Step Synthesis of TiO_2(B) Nanoparticles from a Water-Soluble Titanium Complex2007

    • Author(s)
      M. Kobayashi, et. al.
    • Journal Title

      Chemistry of Materials 19

      Pages: 5373-5376

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Properties of HCa_2Nb_3O_10 Prepared by Polymerizable Complex Method2007

    • Author(s)
      Yohichi Yamashita, et. al.
    • Journal Title

      Journal of the Ceramic Society of Japan 115(8)

      Pages: 511-513

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water Soluble Na[Nb(O_2)_3]-2H_2O as a New Molecular Precursor for Synthesis of Sodium Niobate2007

    • Author(s)
      Deepa Dey, et. al.
    • Journal Title

      Journal of the Ceramic Society of Japan 115(12)

      Pages: 808-812

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microwave-assisted hydrothemal synthesis of brookite nanoparticles from a water-soluble titanium complex and their photocatalytic activity2007

    • Author(s)
      Yusuke Morishima, et. al.
    • Journal Title

      Journal of the Ceramic Society of Japan 115(12)

      Pages: 826-830

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphology control of rutile nanoparticles in a hydrothermal synthesis from water-soluble titanium complex aqueous solution2007

    • Author(s)
      Makoto Kobayashi, et. al.
    • Journal Title

      Journal of the Ceramic Society of Japan 115(12)

      Pages: 835-839

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高輝度発光を有する水溶性金属錯体への挑戦2007

    • Author(s)
      中島光一, 他
    • Journal Title

      化学 62

      Pages: 66-67

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ソフトプロセスによる水分解光触媒の合成2007

    • Author(s)
      冨田恒之, 他
    • Journal Title

      会報光触媒 22

      Pages: 40-45

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A water-soluble titanium complex for the selective synthesis of nanocrystalline brookite, rutile, and anatase by a hydrothermal method2006

    • Author(s)
      K. Tomita, V. Petrykin, M. Kobayashi, M. Shiro, M. Yoshimura, M. Kakihana
    • Journal Title

      Ang.Chem.Int.Ed. 45

      Pages: 2378-2381

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and structure of new water-soluble and stable tantalum compound : Ammonium tetralactatodiperoxo-μ-oxo-ditantalate(V)2006

    • Author(s)
      V. Petrykin, M. Kakihana, K. Yoshioka, S. Sasaki, Y. Ueda, K. Tomita, Y. Nakamura, M. Shiro, A. Kudo
    • Journal Title

      Inorg.Chem. 45

      Pages: 9251-9256

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] A water-soluble titanium complex for the selective synthesis of nanocrystalline brookite, rutile, and anatase by a hydrothermal method2006

    • Author(s)
      K. Tomita, V. Petrykin, M. Kobayashi, M. Shiro, M. Yoshimura, M. Kakihana
    • Journal Title

      Ang. Chem. Int. Ed. 45

      Pages: 2378-2381

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Synthesis and structure of new water-soluble and stable tantalum compound : Ammonium tetralactatodiperoxo- μ-oxo- ditantalate(V)2006

    • Author(s)
      V. Petrykin, M. Kakihana, K. Yoshioka, S. Sasaki, Y. Ueda, K. Tomita, Y. Nakamura, M. Shiro, A. Kudo
    • Journal Title

      Inorg. Chem. 45

      Pages: 9251-9256

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] A Water-Soluble Titanium Complex for the Selective Synthesis of Nanocrystalline Brookite, Rutile, and Anatase by a Hydrothermal Method"2006

    • Author(s)
      Koji Tomita, et al.
    • Journal Title

      Angewandte Chemie, Int. Ed. 45

      Pages: 2378-2381

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis and Structure of New Water Soluble and Stable Tantalum Compound : Ammonium Tetralactatodiperoxo-μ-oxo-ditantalate (V)2006

    • Author(s)
      V.Petrykin, et al.
    • Journal Title

      Inorganic Chemistry 45

      Pages: 9251-9256

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Hydrothermal synthesis of nanosized titania photocatalysts using novel water-soluble titanium complexes2006

    • Author(s)
      Makoto Kobayashi, et al.
    • Journal Title

      Solid State Phenomena 124-126

      Pages: 723-726

    • Related Report
      2006 Annual Research Report
  • [Journal Article] ゾルゲルコーティング材料としての新規水溶性チタン錯体2006

    • Author(s)
      垣花眞人, 他
    • Journal Title

      化学工業 57

      Pages: 901-907

    • Related Report
      2006 Annual Research Report
  • [Presentation] 水からつくるナノセラミックス2010

    • Author(s)
      垣花眞人
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      小金井市
    • Year and Date
      2010-03-22
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Synthesis of sulfide-based phosphors by multiply combined methods based upon inorganic chemistry2009

    • Author(s)
      M. Kakihana, V. Petrykin
    • Organizer
      The 9th International Meeting on Information Display (IMID 2009)
    • Place of Presentation
      KINTEX, Seoul, Korea
    • Year and Date
      2009-10-12
    • Related Report
      2009 Final Research Report
  • [Presentation] Synthesis of sulfide based phosphors by multiply combined methods based upon inorganic chemistry2009

    • Author(s)
      M.Kakihana, V.Petrykin
    • Organizer
      The 9th International Meeting on Information Display(IMID 2009)
    • Place of Presentation
      韓国ソウル
    • Year and Date
      2009-10-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis of high performance phosphor materials by advanced solution methods2009

    • Author(s)
      M . Kakihana
    • Organizer
      Sungkyunkwan University (SKKU) Advanced Institute of Nanotechnology (SAINT) seminar
    • Place of Presentation
      Sungkyunkwan University, Korea
    • Year and Date
      2009-10-01
    • Related Report
      2009 Final Research Report
  • [Presentation] Synthesis of high performance phosphor materials by advanced solution methods2009

    • Author(s)
      垣花眞人
    • Organizer
      Sungkyunkwan University(SKKU)Advanced Institute of Nanotechnology(SAINT)seminar
    • Place of Presentation
      韓国水源市
    • Year and Date
      2009-10-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] 水溶性金属錯体を活用した水溶液からの無機機能材料の合成-難水溶性金属の親水錯体技術2009

    • Author(s)
      垣花眞人
    • Organizer
      錯体化学若手の会北海道・東北支部勉強会
    • Place of Presentation
      山形市
    • Year and Date
      2009-07-04
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 高分子前駆体法によるセラミックス合成2009

    • Author(s)
      垣花眞人
    • Organizer
      第28回無機高分子シンポジウム
    • Place of Presentation
      東京都
    • Year and Date
      2009-06-26
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] New generation of Si, Ti, Nb and Ta precursors for aqueous solution synthesis of advanced nanophotoceramicsi2009

    • Author(s)
      M. Kakihana, M. Kobayashi, Y. Suzuki, V. Petrykin, S. Tezuka, K.Tomita
    • Organizer
      The third international conference on the science and technology for advanced ceramics
    • Place of Presentation
      横浜市
    • Year and Date
      2009-06-16
    • Related Report
      2009 Final Research Report
  • [Presentation] New generation of Si, Ti, Nb and Ta precursors for aqueous solution synthesis of advanced nanophotoceramics2009

    • Author(s)
      M.Kakihana, M.Kobayashi, Y.Suzuki, V.Petrykin, S.Tezuka, K.Tomita
    • Organizer
      The third international conference on the science and technology for advanced ceramics
    • Place of Presentation
      横浜市
    • Year and Date
      2009-06-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 多核金属錯体をテクトンとする溶液プロセスによるナノフォトセラミックス2009

    • Author(s)
      垣花眞人
    • Organizer
      日本化学会第89春季大会
    • Place of Presentation
      船橋市
    • Year and Date
      2009-03-28
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 「多核金属錯体をテクトンとする溶液プロセスによるナノフォトセラミックス」(特別講演)2009

    • Author(s)
      垣花眞人
    • Organizer
      日本化学会第89春季大会
    • Place of Presentation
      船橋市
    • Year and Date
      2009-03-28
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] 水溶性チタン錯体の構造を利用した酸化チタン多形の選択的合成2009

    • Author(s)
      小林亮、他
    • Organizer
      化学工学会第74年会
    • Place of Presentation
      横浜市
    • Year and Date
      2009-03-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Generation of Precursors for Highly Selective Synthesis of Nano-crystalline TiO_2 Polymorphs with Controlled Morphology2008

    • Author(s)
      M. Kakihana, M. Kobayashi, V. Petrykin, K. Tomita
    • Organizer
      (Invited Talk) IUMRS-ICA2008
    • Place of Presentation
      名古屋市
    • Year and Date
      2008-12-10
    • Related Report
      2009 Final Research Report
  • [Presentation] New Generation of Precursors for Highly Selective Synthesis of Nano-crystalline TiO_2 Polymorphs with Controlled Morphology2008

    • Author(s)
      M. Kakihana, M. Kobayashi, V. Petrykin, K. Tomita
    • Organizer
      (Invited Talk)IUMRS-ICA2008
    • Place of Presentation
      名古屋市
    • Year and Date
      2008-12-10
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] 「環境調和型水溶液プロセスによる高機能セラミックス」(特別講演)2008

    • Author(s)
      垣花眞人
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      八戸市
    • Year and Date
      2008-12-10
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] 環境調和型水溶液プロセスによる高機能セラミックス2008

    • Author(s)
      垣花眞人
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      名古屋市
    • Year and Date
      2008-12-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] 環境調和型水溶液プロセスによる高機能セラミックス2008

    • Author(s)
      垣花眞人
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      八戸市
    • Year and Date
      2008-10-12
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] New Generation of Precursors for Highly Selective Synthes is of Nano-crystalline TiO2 Polymorphs with Controlled Morphology2008

    • Author(s)
      Masato Kakihana, et.al.
    • Organizer
      The IUMRS International Conference in Asia 2008
    • Place of Presentation
      八戸市
    • Year and Date
      2008-10-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] 錯体をキーマテリアルとするソフト溶液プロセス-高機能セラミックス合成への展開-2008

    • Author(s)
      垣花翼人
    • Organizer
      素材プロセシング第69委員会第2分科会(新素材関連技術)[第62回]研究会
    • Place of Presentation
      東京目黒区
    • Year and Date
      2008-06-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水溶性チタン錯体を用いた水熱法による酸化チタン多形の選択的合成2007

    • Author(s)
      垣花眞人, 小林亮, ペトリキンヴァレリー, 冨田恒之
    • Organizer
      平成19年度粉体粉末冶金協会秋季大会
    • Place of Presentation
      京都市
    • Year and Date
      2007-11-19
    • Related Report
      2009 Final Research Report
  • [Presentation] 「水溶性チタン錯体を用いた水熱法による酸化チタン多形の選択的合成」(招待講演)2007

    • Author(s)
      垣花眞人, 小林 亮, ペトリキンヴァレリー, 冨田恒之
    • Organizer
      平成19年度粉体粉末冶金協会秋季大会
    • Place of Presentation
      京都市
    • Year and Date
      2007-11-19
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] 水溶性チタン錯体を用いた水熱法による酸化チタン多形の選択的合成2007

    • Author(s)
      垣花眞人、他
    • Organizer
      平成19年度粉体粉末冶金協会秋季大会
    • Place of Presentation
      京都
    • Year and Date
      2007-11-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Development of water-soluble titanium complexes with natural ligands for green water-based2007

    • Author(s)
      Masato Kakihana, et. al.
    • Organizer
      7th Pacific Rim Conference on Ceramic and Glass Technology(PacRim7)
    • Place of Presentation
      China, Shanghai,
    • Year and Date
      2007-11-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] Single-step synthesis of Tio_2(B)nano-particles by hydrothermal method using a water soluble2007

    • Author(s)
      Makoto Kobayashi, et. al.
    • Organizer
      7th Pacific Rim Conference on Ceramic and Glass Technology(PacRim7)
    • Place of Presentation
      China, Shanghai
    • Year and Date
      2007-11-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of oxide materials using new water soluble tantalum complex2007

    • Author(s)
      Valery Petrykin, et. al.
    • Organizer
      7th Pacific Rim Conference on Ceramic and Glass Technology(PacRim7)
    • Place of Presentation
      China, Shanghai
    • Year and Date
      2007-11-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] 四種の異なる構造を有する酸化チタンの選択的合成2007

    • Author(s)
      小林 亮、他
    • Organizer
      平成19年度日本セラミックス協会東北北海道支部研究発表会及び第27回基礎科学部会
    • Place of Presentation
      秋田
    • Year and Date
      2007-11-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水溶液チタン錯体を原料としたルチル型酸化チタンの水熱合成と添加物による形態制御2007

    • Author(s)
      小林 亮、他
    • Organizer
      第20回日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-13
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水溶液プロセスによるチタン系セラミックス材料の合成2007

    • Author(s)
      冨田恒之, 山本和広, 瀬戸智行, 藤田一美, 小林亮,ペトリキンヴァレリー, 垣花眞人
    • Organizer
      日本セラミックス協会第20回秋季シンポジウム
    • Place of Presentation
      名古屋市
    • Year and Date
      2007-09-12
    • Related Report
      2009 Final Research Report
  • [Presentation] 水溶液プロセスによるチタン系セラミックス材料の合成2007

    • Author(s)
      冨田恒之、他
    • Organizer
      第20回日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] 錯体重合法によるBa_3 Ta_6 Si_4 O_<26>関連化合物の合成と水分解光触媒特性の評価2007

    • Author(s)
      川畑詠孔、他
    • Organizer
      第20回日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] New water soluble and stable tantalum compound for synthesis multicomponent oxide materials via2007

    • Author(s)
      Masato Kakihana, et. al.
    • Organizer
      第20回日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水溶液チタン錯体を用いたマイクロ波水熱法によるプルカイト型酸化チタン高活性光触媒の合成2007

    • Author(s)
      森嶋勇介、他
    • Organizer
      第20回日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水溶液チタン錯体からのブルカイト型酸化チタン生成過程に関する考察2007

    • Author(s)
      小林 亮、他
    • Organizer
      日本ゾルーゲル学会第5回討論会
    • Place of Presentation
      京都
    • Year and Date
      2007-07-24
    • Related Report
      2007 Annual Research Report
  • [Presentation] 錯体重合法を用いたM_<6-x>Ta_6Si_4O_<26>(M=K, Ba, Sr)の合成と水分解光触媒特性2007

    • Author(s)
      川畑詠孔、他
    • Organizer
      CREST/研究領域「エネルギーの高度利用に向けたナノ構造材料・システムの創製」「可視光水分解を目指したナノ構造体光触媒の創製」工藤チーム成果報告会
    • Place of Presentation
      新潟
    • Year and Date
      2007-07-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] 種々の形態を有するブルカイト型酸化チタンの水熱合成およびその光触媒特性2007

    • Author(s)
      森嶋勇介、他
    • Organizer
      CREST/研究領域「エネルギーの高度利用に向けたナノ構造材料・システムの創製」「可視光水分解を目指したナノ構造体光触媒の創製」工藤チーム成果報告会
    • Place of Presentation
      新潟
    • Year and Date
      2007-07-11
    • Related Report
      2007 Annual Research Report
  • [Presentation] Application of new water soluble and stable tantalum compound for synthesis of photocatalytic materials2007

    • Author(s)
      Valery Petrykin, et. al.
    • Organizer
      Joint Conferences of The First International Conference on the Science and Technology for Advanced Ceramics(STAC)and The Second International Conference on Joining Technology for New Metallic Glasses and Inorganic Materials(JTMC)
    • Place of Presentation
      Kanagawa
    • Year and Date
      2007-05-24
    • Related Report
      2007 Annual Research Report
  • [Presentation] Analysis of crystal structures of novel sulfide photocatalysts by resonant X-ray diffraction2007

    • Author(s)
      Valery Petrykin, et. al.
    • Organizer
      Joint Conferences of The First International Conference on the Science and Technology for Advanced Ceramics(STAC)and The Second International Conference on Joining Technology for New Metallic Glasses and Inorganic Materials(JTMC)
    • Place of Presentation
      Kanagawa
    • Year and Date
      2007-05-23
    • Related Report
      2007 Annual Research Report
  • [Book] セラミックスデータブック2009(水溶液化学に立脚したナノセラミックス合成)2009

    • Author(s)
      鈴木義仁, 小林亮, 垣花眞人
    • Publisher
      (株)テクノプラザ
    • Related Report
      2009 Final Research Report
  • [Book] セラミックス製造プロセス、応用技術大全集(第1章第1節[3]液相合成法)2007

    • Author(s)
      垣花眞人
    • Publisher
      技術情報協会
    • Related Report
      2009 Final Research Report
  • [Book] ナノ蛍光体の開発と応用2007

    • Author(s)
      垣花眞人
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Final Research Report
  • [Book] "セラミックス製造プロセス、応用技術大全集"第1章第1節[3]液相合成法2007

    • Author(s)
      垣花眞人
    • Publisher
      技術情報協会
    • Related Report
      2008 Self-evaluation Report
  • [Book] "ナノ蛍光体の開発と応用"1.1「ゾルゲル法(錯体重合法)」2007

    • Author(s)
      垣花眞人
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Self-evaluation Report
  • [Remarks] 平成19年度日本セラミックス協会第62回学術賞 垣花眞人"溶液錯体化学に立脚した高機能セラミックスの合成"

    • Related Report
      2008 Self-evaluation Report
  • [Remarks] 平成19年度日本化学会第25回学術賞 垣花眞人"水溶性金属錯体を活用したナノフォトセラミックスの水溶液からの合成"

    • Related Report
      2008 Self-evaluation Report
  • [Remarks] 平成18年粉体粉末冶金協会研究功績賞 垣花眞人"錯体重合法による酸化物粉体の精密化学合成と高機能化"

    • Related Report
      2008 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 黄色蛍光体とその製造方法2009

    • Inventor(s)
      ペトリキンヴァレリー, 垣花眞人, 高塚裕二
    • Industrial Property Rights Holder
      住友金属鉱山 (株)、東北大学
    • Patent Publication Number
      2009-270056
    • Filing Date
      2009-11-19
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 水溶性Si化合物及び水溶性Siの製造方法2008

    • Inventor(s)
      鈴木義仁, 垣花眞人, 大豆生田勉
    • Industrial Property Rights Holder
      東北大学, マツモトファィンケミカル (株)
    • Industrial Property Number
      2008-171301
    • Filing Date
      2008-06-30
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 水溶性ケイ素化合物及び水溶性ケイ素化合物の製造方法2008

    • Inventor(s)
      鈴木義仁、垣花眞人
    • Industrial Property Rights Holder
      東北大学、マツモトファインケミカル株式会社
    • Industrial Property Number
      2008-171301
    • Filing Date
      2008-06-30
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 低アンモニウム型チタンペルオキソ化合物の合成方法2007

    • Inventor(s)
      小林亮, 冨田恒之, 垣花眞人, 樋口隆行, 吉野亮悦
    • Industrial Property Rights Holder
      東北大学・電気化学工業(株)
    • Filing Date
      2007-03-30
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 低アンモニウム型チタンペルオキソ化合物の合成方法2007

    • Inventor(s)
      小林亮, 冨田恒之, 垣花眞人, 樋口隆行, 吉野亮悦
    • Industrial Property Rights Holder
      東北大学・電気化学工業(株)
    • Patent Publication Number
      2008-247811
    • Filing Date
      2007-03-30
    • Related Report
      2008 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 低アンモニウム型チタンペルオキソ化合物の合成方法2007

    • Inventor(s)
      小林亮, 垣花眞人, 冨田恒之
    • Industrial Property Rights Holder
      東北大学電気化学工業(株)
    • Industrial Property Number
      2007-091347
    • Filing Date
      2007-03-30
    • Related Report
      2006 Annual Research Report
  • [Patent(Industrial Property Rights)] ブルッカイト型二酸化チタンの製造方法2006

    • Inventor(s)
      垣花眞人, 冨田恒之, 小林亮, 佐藤次雄, 殷シュウ
    • Industrial Property Rights Holder
      東北大学
    • Patent Publication Number
      2007-246301
    • Filing Date
      2006-03-13
    • Related Report
      2009 Final Research Report 2008 Self-evaluation Report

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Published: 2006-04-01   Modified: 2016-04-21  

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