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Function Designing Map of B-H Complex Hydrides-From Fundamental Properties To Energy-Related Functions-

Research Project

Project/Area Number 18206073
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

ORIMO Shin-ichi  Tohoku University, 金属材料研究所, 教授 (40284129)

Co-Investigator(Kenkyū-buntansha) UWATOKO Yoshiya  東京大学, 物性研究所, 准教授 (40213524)
YUKAWA Hiroshi  名古屋大学, 工学研究科, 助教 (50293676)
NAKAMORI Yuko  東北大学, 金属材料研究所, 助教 (90359539)
大山 研司  東北大学, 金属材料研究所, 准教授 (60241569)
飛田 健次  独立行政法人日本原子力研究開発機構, 核融合炉システム研究グループ, グループリーダー (50354569)
Co-Investigator(Renkei-kenkyūsha) OHOYAMA Kenji  東北大学, 金属材料研究所, 准教授 (60241569)
TOBITA Kenji  日本原子力研究開発機構, 核融合炉システム研究グループ, グループリーダー (50354569)
MATSUO Motoaki  東北大学, 金属材料研究所, 博士研究員 (20509038)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥48,750,000 (Direct Cost: ¥37,500,000、Indirect Cost: ¥11,250,000)
Fiscal Year 2008: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2007: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Fiscal Year 2006: ¥20,410,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥4,710,000)
Keywords水素 / 水素化物 / エネルギー / 水素貯蔵 / リチウム / イオン伝導 / マイクロ波 / 中性子 / 錯体水素化物 / 電気陰性度 / 中性子遮蔽 / 超イオン伝導 / 複合材料 / ミリング
Research Abstract

B(ホウ素)-H(水素)系錯体水素化物でのエネルギー関連機能や基礎物性などに関わる研究を実施した。「高密度水素貯蔵機能」に加えて、構造相転移に伴う「マイクロ波吸収(自己発熱)機能」やその要因となる「リチウム超イオン伝導機能」などを見出した。これらの革新的機能は、「水素貯蔵技術とマイクロ波利用技術との融合研究」や「新たなリチウムイオン電池用固体電解質の開発研究」など、多様なエネルギー応用の観点から極めて重要である。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (66 results)

All 2009 2008 2007 2006 Other

All Journal Article (34 results) (of which Peer Reviewed: 17 results) Presentation (15 results) Book (9 results) Remarks (7 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Stabilization of lithium superionic conduction phase and enhancement of conductivity of LiBH_4 by LiCl addition2009

    • Author(s)
      M. Matsuo, H. Takamura, H. Maekawa, H.-W. Li, S. Orimo
    • Journal Title

      Applied Physics Letters 94(10.1063/1.3088857)

    • Related Report
      2008 Final Research Report
  • [Journal Article] Halide-stabilized LiBH4, a room-temperature lithium fast-ion conductor2009

    • Author(s)
      H. Maekawa, et.al.
    • Journal Title

      Journal of American Chemical Society 131

      Pages: 894-895

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and computational studies on solvent-free rare-earth metal borohydrides R(BH_4)_3(R=Y, Dy, and Gd)2008

    • Author(s)
      T. Sato, K. Miwa, Y. Nakamori, K. Ohoyama, H.-W. Li, T. Noritake, M. Aoki, S. Towata, S. Orimo
    • Journal Title

      Physical Review B 77(10.1103/PhysRevB.77.104114)

    • Related Report
      2008 Final Research Report
  • [Journal Article] Magnesium borohydride : A new hydrogen storage material2008

    • Author(s)
      T. Matsunaga, et.al.
    • Journal Title

      Renewable Energy 33

      Pages: 193-196

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of metal borohydrides for hydrogen storage2008

    • Author(s)
      Y. Nakamori, et.al.
    • Journal Title

      Journal of Physical Chemistry of Solids 69

      Pages: 2292-2296

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydiridng and rehydiridng processes of well-crystallized Mg(BH4)2 accompanying with formation of intermediate compounds2008

    • Author(s)
      H.-W. Li, et.al.
    • Journal Title

      Acta Materialia 56

      Pages: 1342-1347

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and dehydiridng properties of Ca(BH4)22008

    • Author(s)
      M. Aoki, et.al.
    • Journal Title

      Applied Physics A 92

      Pages: 601-605

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and computational studies on solvent-free rare-earth metal borohydrides R(BH4)3 (R=Y, Dy, and Gd)2008

    • Author(s)
      T. Sato, et.al.
    • Journal Title

      Physical Review B 77

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and hydrogen storage properties of a single-phase magnesium borohydride Mg(BH_4)_22008

    • Author(s)
      H.-W. Li, et.al.
    • Journal Title

      Materials Transactions 49

      Pages: 2224-2228

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure of Ca(BD_4)_2 β-phase from combined neulmn and synchrotron X-ray powder diffraction data and density functional calculations2008

    • Author(s)
      F. Buchter, et.al.
    • Journal Title

      Journal of Physical Chemistry B 112

      Pages: 8042-8048

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Differential scanning calorimetry measurements of magnesium borohydride Mg(BH_4)_22008

    • Author(s)
      Y. Yan, et.al.
    • Journal Title

      Materials Transactions 49

      Pages: 2751-2752

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen storage properties of Mg(BH_4)_22008

    • Author(s)
      T. Matsunaga, et.al.
    • Journal Title

      Journal of Alloys and Compounds 459

      Pages: 583-588

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] エネルギー利用を目指した水素化物の材料設計2008

    • Author(s)
      池田一貴, ら
    • Journal Title

      高圧力の科学と技術 18

      Pages: 180-185

    • Related Report
      2008 Annual Research Report
  • [Journal Article] 次世代水素貯蔵材料としての水素化物の材料設計2008

    • Author(s)
      池田一貴, ら
    • Journal Title

      化学工業 59

      Pages: 21-25

    • Related Report
      2008 Annual Research Report
  • [Journal Article] リチウムボロハイドライドLiBH4での多様なエネルギー関連機能-高密度水素貯蔵, マイクロ波吸収, そしてリチウム超イオン伝導-2008

    • Author(s)
      松尾元彰, 折茂慎一
    • Journal Title

      固体物理 43

      Pages: 921-927

    • NAID

      40016408652

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Dehydiridng and rehydiridng processes of well-crystallized Mg(BH_4)_2 accompanying with formation of intermediate compounds2008

    • Author(s)
      H.-W. Li, et. al.
    • Journal Title

      Acta Materialia 56

      Pages: 1342-1347

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium superionic conduction in lithium borohydride accompanied by structural transition2007

    • Author(s)
      M. Matsuo, Y. Nakamori, S. Orimo, H. Maekawa, H. Takamura
    • Journal Title

      Applied Physics Letters 91(10.1063/1.2817934)

    • NAID

      120002337960

    • Related Report
      2008 Final Research Report
  • [Journal Article] Complex hydrides for hydrogen storage2007

    • Author(s)
      S. Orimo, Y. Nakamori, J.R. Eliseo, A. Zuttel, C.M. Jensen
    • Journal Title

      Chemical Reviews 107(10.1021/cr0501846)

      Pages: 4111-4132

    • NAID

      10015596589

    • Related Report
      2008 Final Research Report
  • [Journal Article] Effects of microwave irradiation on the dehydriding reaction of the composites of lithium borohydride and microwave absorber2007

    • Author(s)
      M. Matsuo, Y. Nakamori, K. Yamada, S. Orimo
    • Journal Title

      Applied Physics Letters 90(10.1063/1.2746061)

    • NAID

      120002337949

    • Related Report
      2008 Final Research Report
  • [Journal Article] Complex hydrides for hydrogen storage2007

    • Author(s)
      S. Orimo, et. al.
    • Journal Title

      Chemical Reviews 107

      Pages: 4111-4132

    • NAID

      10015596589

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamical stabilities of metal-borohydrides2007

    • Author(s)
      Y. Nakamori, et. al.
    • Journal Title

      Journal of Alloys and Compounds 446-447

      Pages: 296-300

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Materials designing of metal borohydrides:Viewpoints from thermodynamical stabilities2007

    • Author(s)
      H.-W. Li, et. al.
    • Journal Title

      Journal of Alloys and Compounds 446-447

      Pages: 315-318

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of ball milling and additives on dehydriding behaviors of well-crystallized Mg(BH_4)_22007

    • Author(s)
      H.-W. Li, et. al.
    • Journal Title

      Scripta Materialia 57

      Pages: 679-682

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium superionic conduction in lithium borohydride accompanied by structural transition2007

    • Author(s)
      M. Matsuo, et. al.
    • Journal Title

      Applied Physics Letters 91

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and computational studies on solvent-free rare-earth metal borohydrides R(BH_4)_3(R=Y, Dy, and Gd)2007

    • Author(s)
      T. Sato, et. al.
    • Journal Title

      Physical Review B 77

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of microwave irradiation on metal hydrides and complex hydrides2007

    • Author(s)
      Y.Nakamori, et al.
    • Journal Title

      Journal of Alloys and Compounds (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Thermodynamical stabilities of metal-borohydrides2007

    • Author(s)
      Y.Nakamori, et al.
    • Journal Title

      Journal of Alloys and Compounds (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Effects of microwave irradiation on the dehydriding reaction of the composites of lithium-borohydride and microwave absorber2007

    • Author(s)
      M.Matsuo, et al.
    • Journal Title

      Applied Physics Letters (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Correlation between thermodynamical stabilities of metal-borohydrides and cation electronegativities : First-principle calculations and experiments2006

    • Author(s)
      Y.Nakamori, et al.
    • Journal Title

      Physical Review B 74

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Syntheses and hydrogen desorption properties of metal-borohydrides M(BH_4)_n (M = Mg, Sc, Zr, Ti, and Zn : n = 2 - 4) as advanced hydrogen storage materials2006

    • Author(s)
      Y.Nakamori, et al.
    • Journal Title

      Materials Transaction 47・8

      Pages: 1898-1901

    • NAID

      10019296708

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Tetrahydroborates as new hydrogen storage materials2006

    • Author(s)
      A.Zuttel, et al.
    • Journal Title

      Scripta Materialia 56

      Pages: 823-828

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Lithium colloids and color center creation in electron-irradiated Li_2NH observed by electron-spin resonance2006

    • Author(s)
      F.Beuneu, et al.
    • Journal Title

      Physical Review B 74

    • Related Report
      2006 Annual Research Report
  • [Journal Article] エネルギー利用を目指した錯体水素化物の研究2006

    • Author(s)
      折茂慎一, 中森裕子
    • Journal Title

      ケミカルエンジニアリング 51・7

      Pages: 73-77

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 水素貯蔵技術へのマイクロ波応用2006

    • Author(s)
      中森裕子, 折茂慎一
    • Journal Title

      金属 76・8

      Pages: 35-35

    • Related Report
      2006 Annual Research Report
  • [Presentation] Single- and double-cations borohydrides for hydrogen storage applications (invited)2008

    • Author(s)
      S. Orimo, et.al.
    • Organizer
      The 2008 Asian Conference on Nanoscience and Nanotechnology (AsiaNANO2008)
    • Place of Presentation
      シンガポール、シンガポール
    • Year and Date
      2008-11-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] エネルギー利用を目指した錯体水素化物の材料設計(招待講演)2008

    • Author(s)
      折茂慎一
    • Organizer
      化学工学会第40回秋季大会
    • Place of Presentation
      日本、宮城県仙台市
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Borohydrides for energy applications (invited)2008

    • Author(s)
      S. Orimo
    • Organizer
      The Third LANL-NEDO-AIST Workshop on Fuel Cell Performance Improvement & Hydrogen Storage Materials
    • Place of Presentation
      米国、サンディアゴ
    • Year and Date
      2008-09-10
    • Related Report
      2008 Annual Research Report
  • [Presentation] Structural investigation of metal borohydrides by X-ray/neutron diffraction and computational study (invited)2008

    • Author(s)
      T. Sato, et.al.
    • Organizer
      IUCr2008 Osaka, Japan XXI Congress and General Assembly of the International Union of Crystallography
    • Place of Presentation
      日本、大阪府大阪市
    • Year and Date
      2008-08-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Metal borohydrides for energy applications2008

    • Author(s)
      S. Orimo
    • Organizer
      MH2008 International Symposium on Metal-Hydrogen Systems
    • Place of Presentation
      Reykjavik, Iceland
    • Year and Date
      2008-07-19
    • Related Report
      2008 Final Research Report
  • [Presentation] Metal borohydrides for energy applications (invited)2008

    • Author(s)
      S. Orimo, et.al.
    • Organizer
      MH2008 International Symposium on Metal-Hydrogen Systems
    • Place of Presentation
      アイスランド、レイキャビック
    • Year and Date
      2008-06-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水素をもっと身近に -次世代水素貯蔵材料の研究開発- (依頼講演)2008

    • Author(s)
      折茂慎一
    • Organizer
      応用物理学会
    • Place of Presentation
      日本、千葉
    • Year and Date
      2008-03-28
    • Related Report
      2007 Annual Research Report
  • [Presentation] 水素エネルギー利用を目指した錯体水素化物の材料設計(依頼講演)2008

    • Author(s)
      折茂慎一
    • Organizer
      日本化学会
    • Place of Presentation
      日本、東京
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Materials for new energy needs2008

    • Author(s)
      S. Orimo
    • Organizer
      Japanese-French Frontiers of Science Symposium
    • Place of Presentation
      Roscoff, France
    • Year and Date
      2008-01-26
    • Related Report
      2008 Final Research Report
  • [Presentation] Metal borohydrides for energy applications(invited)2008

    • Author(s)
      S. Orimo
    • Organizer
      Second Japanese-French Frontiers of Science Symposium
    • Place of Presentation
      フフンス、ロスコフ
    • Year and Date
      2008-01-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] Metal borohydrides for energy applications(invited)2008

    • Author(s)
      S. Orimo
    • Organizer
      EMPA 2nd Symposium Hydrogen & Energy
    • Place of Presentation
      スイス、ブラウンバルド
    • Year and Date
      2008-01-23
    • Related Report
      2007 Annual Research Report
  • [Presentation] Single- and double-cations borohydrides for hydrogen storage applications(invited)2007

    • Author(s)
      S. Orimo
    • Organizer
      International Symposium on Materials Issues on a Hydrogen Economy
    • Place of Presentation
      米国、リッチモンド
    • Year and Date
      2007-11-14
    • Related Report
      2007 Annual Research Report
  • [Presentation] Metal borohydrides for hydrogen storage applications(invited)2007

    • Author(s)
      S. Orimo
    • Organizer
      Materials Science & Technology 2007
    • Place of Presentation
      米国、デトロイト
    • Year and Date
      2007-09-17
    • Related Report
      2007 Annual Research Report
  • [Presentation] Materials designing of complex hydrides(invited)2007

    • Author(s)
      S. Orimo
    • Organizer
      2nd China-Japan Seminar on Hydrogen Storage Materials
    • Place of Presentation
      中国、北京
    • Year and Date
      2007-05-15
    • Related Report
      2007 Annual Research Report
  • [Presentation] Materials designing of complex hydrides(invited)2007

    • Author(s)
      S. Orimo
    • Organizer
      The first Oxford-Kobe Energy Seminar
    • Place of Presentation
      日本、神戸
    • Year and Date
      2007-04-23
    • Related Report
      2007 Annual Research Report
  • [Book] Hydrogen as a future energy carrier,Ch. 6.5 Tetrahydroborates as a non-nontransitionmetal hydrides2008

    • Author(s)
      S. Orimo, A. Zuttel
    • Publisher
      WILEY-VCH
    • Related Report
      2008 Final Research Report
  • [Book] Solid-state hydrogen storage -materials and chemistry-, Ch. 15 Borohydrides as hydrogen storage materials2008

    • Author(s)
      Y. Nakamori, S. Orimo
    • Publisher
      Woodhead Publishing Limited
    • Related Report
      2008 Final Research Report
  • [Book] ホウ素・ホウ化物の基礎と応用2008

    • Author(s)
      李海文, ら
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Annual Research Report 2007 Annual Research Report
  • [Book] Hydrogen as a future carrier2008

    • Author(s)
      S. Orimo, A. Zuttel
    • Publisher
      WILEY-VCH
    • Related Report
      2008 Annual Research Report
  • [Book] Solid-state hydrogen storage -materials and chemistry-2008

    • Author(s)
      Y. Nakamori, S. Orimo
    • Publisher
      Woodhead Publishing Limited
    • Related Report
      2008 Annual Research Report
  • [Book] Hydrogen as a Future Carrier2008

    • Author(s)
      S. Orimo, A. Zuettel
    • Total Pages
      427
    • Publisher
      WILEY-VCH
    • Related Report
      2007 Annual Research Report
  • [Book] 有機貯蔵材料とナノ技術 -水素社会に向けて-2007

    • Author(s)
      折茂慎一, 中森裕子
    • Total Pages
      367
    • Publisher
      シーエムシー出版
    • Related Report
      2007 Annual Research Report
  • [Book] エコマテリアルハンドブック2006

    • Author(s)
      中森裕子, 折茂慎一
    • Total Pages
      823
    • Publisher
      朝倉書店
    • Related Report
      2006 Annual Research Report
  • [Book] 水素・燃料電池ハンドブック2006

    • Author(s)
      折茂慎一, 中森裕子
    • Total Pages
      1102
    • Publisher
      オーム社
    • Related Report
      2006 Annual Research Report
  • [Remarks]

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/

    • Related Report
      2008 Final Research Report
  • [Remarks] 科学新聞(2009年2月6日)

    • Related Report
      2008 Final Research Report
  • [Remarks] 日刊工業新聞(2009年1月27日)

    • Related Report
      2008 Final Research Report
  • [Remarks] 日経産業新聞(2007年12月7日)

    • Related Report
      2008 Final Research Report
  • [Remarks] 日刊工業新聞(2007年11月30日)など

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 水素貯蔵媒体の製造方法2007

    • Inventor(s)
      中森裕子、松尾元彰、山田啓太郎、折茂慎一
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2007-167182
    • Filing Date
      2007-06-26
    • Acquisition Date
      2009-01-15
    • Related Report
      2008 Final Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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