Development for producing fuel gases from dechlorinated PVC by means of mechanochemical treatment

• Project/Area Number: 18206093
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Recycling engineering
• Research Institution: Tohoku University
• Principal Investigator: SAITO Fumio Tohoku University, 多元物質科学研究所, 教授 (10007198)
• Co-Investigator(Kenkyū-buntansha): ZHANG Qiwu 東北大学, 多元物質科学研究所, 助教 (30292270) ; KANO Junya 東北大学, 多元物質科学研究所, 准教授 (40271978)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥43,160,000 (Direct Cost: ¥33,200,000、Indirect Cost: ¥9,960,000); Fiscal Year 2008: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000); Fiscal Year 2007: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000); Fiscal Year 2006: ¥25,870,000 (Direct Cost: ¥19,900,000、Indirect Cost: ¥5,970,000)
• Keywords: 混合粉砕 / 水素発生 / 廃プラスチック / バイオマス / 触媒 / メカノケミカル / 廃棄物 / 水素エネルギー

Research Abstract

本研究では、廃塩ビ(PVC)およびその他廃棄物に無機物を添加して粉砕し、更に加熱することによって高純度な水素を発生できる次世代エネルギー(水素)の回収法を開発し、ガス発生機構を明確にすることを目指した
平成18年度はPVCに、平成19年度はPVC以外のポリエチロンなどポリマーに、平成20年度はセルロース系の廃木片や廃紙などに、ガス発生のため、及ぼす添加物の種類と量の変化を把握し、両者の関連性をそれぞれ明確にした。

Research Products

• [Journal Article] Generation of High-purity Hydrogen from Cellulose by Its Mechanochemical Treatment (2009)
  • Author(s): Qiwu Zhang, In-Cheol Kang, William Tongamp and Fumio Saito
  • Journal Title: Bioresource Technol 100 Pages: 3731-3733
  • Peer Reviewed
• [Journal Article] Themelis,"Relation between mechanochemical dechlorination rate of polyvinyl chloride and mill power consumption" (2009)
  • Author(s): William TONGAMP, Junya KANO, Yuichiro SUZUTA, Fumio SAITO, and Nickolas J.
  • Journal Title: Journal of Material Cycles and Waste Management 11 Pages: 32-37
  • Peer Reviewed
• [Journal Article] Relation between mechanochemical dechlorination rate of polyvinyl chloride and mill power consumption (2009)
  • Author(s): W. Tongamp, J. Kano, Y. Suzut a, F. Saito, and N. J. Themelis
  • Journal Title: J. of Material Cycles and Waste Manazement 11 Pages: 32-37
  • NAID: 10024022837
  • Peer Reviewed
• [Journal Article] Generation of hydrogen from polyvinyl chloride by milling and heating with CaO and Ni(OH)_2 (2009)
  • Author(s): W. Tongamp, Q. Zhang, F. Saito
  • Journal Title: J. Hazardous Mater (印刷中)
  • Peer Reviewed
• [Journal Article] Generation of High-purity Hydrogen from Cellulose by Its Mechanochemical Treatment (2009)
  • Author(s): Q. Zhang, I. Kang, W. Tongamp, F. Saito
  • Journal Title: Bioresource Technol (印刷中)
  • Peer Reviewed
• [Journal Article] Generation of hydrogen gas from polyethylene mechanically milled with Ni-doned layered double hydroxide (2009)
  • Author(s): W. Tongamp, Q. Zhang, F. Saito
  • Journal Title: Fuel Processing Technol (印刷中)
  • Peer Reviewed
• [Journal Article] Hydrogen generation from polyethylene by milling and heating with Ca(OH)_2 and Ni(OH)_2 (2008)
  • Author(s): William Tongamp, Qiwu Zhang and Fumio Saito
  • Journal Title: Inter. J. Hydrogen Energy 33 Pages: 4097-4103
  • Peer Reviewed
• [Journal Article] Simultaneous treatment of PVC and oyster-shell wastes by mechanochemical means (2008)
  • Author(s): W. Tongamp, J. Kano, Q. Zhang, F. Saito
  • Journal Title: Waste Manag. 28 Pages: 484-488
  • Peer Reviewed
• [Journal Article] Mechanochemical Dechlorination of PVC with Calcium Sulfates (2008)
  • Author(s): Tongamp, William Junya Kano, Qiwu Zhang, Fumio Saito
  • Journal Title: J Mater. Cycles Waste Manag 10 Pages: 140-143
  • Peer Reviewed
• [Journal Article] Hydrogen generation from polyethylene by milling and heating with Ca(OH)_2 and Ni(OH)_2 (2008)
  • Author(s): W. Tongamp, Q. Zhang, F. Saito
  • Journal Title: Inter. J. Hydrogen Energy 33 Pages: 4097-4103
  • Peer Reviewed
• [Journal Article] Simultaneous treatment of PVC and oyster-shell wastes by mechanochemical means (2008)
  • Author(s): W. Tongamp, J. Kano, Q. Zhang, F. Saito
  • Journal Title: Waste Manag 28 Pages: 484-488
  • Peer Reviewed
• [Journal Article] Preparation of meixnerite(Mg-Al-OH)type layered double hydroxide by a mechanochemical route (2007)
  • Author(s): William Tongamp, Qiwu Zhang, Fumio Saito
  • Journal Title: J.Mater.Sci. 42 Pages: 9210-9215
  • Peer Reviewed
• [Journal Article] Generation of hydrogen from polyvinyl chloride by milling and heating with CaO and Ni(OH)_2
  • Author(s): William Tongamp, Qiwu Zhang and Fumio Saito
  • Journal Title: J. Hazardous Mater (In press)
  • Peer Reviewed
• [Journal Article] Generation of hydrogen gas from polyethylene mechanically milled with Ni-doped layered double hydroxide
  • Author(s): William Tongamp, Qiwu Zhang and Fumio Saito
  • Journal Title: Fuel Processing Technol (In press)
• [Presentation] 混合粉砕と低温加熱による塩化ビニルからの水素発生 (2008)
  • Author(s): 張其武
  • Organizer: 粉体工学会2008年度秋期研究発表会
  • Place of Presentation: 千葉
  • Year and Date: 2008-10-30
• [Presentation] 粉砕が拓く環境材料と次世代エネルギーの創造 (2008)
  • Author(s): 齋藤文良
  • Organizer: 第5回粉体工学大講演会
  • Place of Presentation: 東京
  • Year and Date: 2008-08-19
• [Presentation] H_2 gas generation from cellulose and PE resin by means of MC treatment with LDH as catalyst (2008)
  • Author(s): Chen Jie, Tongamp William, Zhang Qiwu, Saito Fumio
  • Organizer: 化学工学会第40回秋季大会
  • Place of Presentation: 仙台
• [Presentation] 粉砕加熱法によるセルロースからの水素発生に及ぼす水酸化リチウムの効果 (2008)
  • Author(s): 張其武, 姜寅〓, 本田至, 齋藤文良
  • Organizer: 化学工学会第40回秋季大会
  • Place of Presentation: 仙台
• [Presentation] Generation of high-purity hydrogen from cellulose by its mechanochemical treatment (2008)
  • Author(s): Qiwu Zhang, William Tongamp, Fumio Saito
  • Organizer: 2nd International Conference on Engineering for Waste Valorisation
  • Place of Presentation: Greece,Patras
• [Presentation] メカノケミカル法を利用したセルロースからの水素ガス製造 (2007)
  • Author(s): 本田 至
  • Organizer: 第7回多元物質科学研究所 研究発表会
  • Place of Presentation: 仙台市、東北大学
  • Year and Date: 2007-12-12
• [Presentation] Hydrogen production from cellulose by means of mechanochemic al method (2007)
  • Author(s): 本田 至
  • Organizer: Korea-Japan Joint Symposium on Powder Technology and ICRA Asian Workshop
  • Place of Presentation: 韓国ソウル市、ソウル大学
  • Year and Date: 2007-12-03
• [Presentation] Simultaneous Treatment of PVC and Oyster-shell Wastes by Mechanochemical Means (2007)
  • Author(s): ウィリアム トンガム
  • Organizer: THE 9th INTERNATIONAL SYMPOSIUM ON EAST ASIAN RESOURCES RECYCLING TECHNOLOGY
  • Place of Presentation: 仙台市、仙台国際ホテル
  • Year and Date: 2007-10-29
• [Presentation] 木片を粉砕して水素をつくる技術を開発しました (2007)
  • Author(s): 張 其武
  • Organizer: APPIE産学官連携フェア2007
  • Place of Presentation: 大阪市、インテックス大阪
  • Year and Date: 2007-10-18
• [Presentation] メカノケミカル処理と加熱法を組み合わせたセルロースからの水素発生 (2007)
  • Author(s): 張 其武
  • Organizer: 化学工学会 第39回秋季大会
  • Place of Presentation: 札幌市、北海道大学
  • Year and Date: 2007-09-13
• [Presentation] メカノケミカル処理と加熱法を組み合わせたセルロースからの水素発生 (2007)
  • Author(s): 張其武, 齋藤文良
  • Organizer: 化学工学会第39回秋季大会
  • Place of Presentation: 北海道
• [Patent(Industrial Property Rights)] 水素ガスの製造方法 (2009)
  • Inventor(s): 張其武、齋藤文良
  • Industrial Property Rights Holder: 東北大学
  • Patent Publication Number: 2009-018955
  • Acquisition Date: 2009-01-29
• [Patent(Industrial Property Rights)] エネルギーガス製造方法およびエネルギーガス貯蔵材料 (2008)
  • Inventor(s): 張其武など6名
  • Industrial Property Rights Holder: 東北大学、豊田中央研究所
  • Industrial Property Number: 2008-217435
  • Filing Date: 2008-08-26
• [Patent(Industrial Property Rights)] エネルギーガス製造方法およびエネルギーガス貯蔵材料 (2008)
  • Inventor(s): 張其武等2人, 松本満等4人
  • Industrial Property Rights Holder: 東北大学豊田中央研究所
  • Industrial Property Number: 2008-217435
  • Filing Date: 2008-08-26
• [Patent(Industrial Property Rights)] 水素ガスの製造方法 (2007)
  • Inventor(s): 張 其武, 齋藤文良
  • Industrial Property Rights Holder: 東北大学
  • Industrial Property Number: 2007-181827
  • Filing Date: 2007-07-11