Temporal and spatial distribution of carbonaceous material from biomass burning based on their molecular and isotopic compositions

• Project/Area Number: 18310012
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Environmental dynamic analysis
• Research Institution: Tokyo University of Pharmacy and Life Science
• Principal Investigator: KUMATA Hidetoshi Tokyo University of Pharmacy and Life Science, 生命科学部, 助教 (60318194)
• Co-Investigator(Kenkyū-buntansha): UCHIDA Masao 国立環境研究所, 化学環境研究領域, 研究員 (50344289)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥17,760,000 (Direct Cost: ¥15,600,000、Indirect Cost: ¥2,160,000); Fiscal Year 2008: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2007: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2006: ¥8,400,000 (Direct Cost: ¥8,400,000)
• Keywords: バイオマス燃焼 / ブラックカーボン / 不活性炭素種 / 放射性炭素 / 炭素埋没量 / 燃焼生成炭素系物質

Research Abstract

エアロゾル中BCの分離精製方法(CTO375_(24hrs))を確立した.同法で分離されたBCの^(14)C年代は, BCと同一のメカニズムで生成される不活性炭素種であるPAHの分子レベル^(14)C年代と一致した.沖縄辺戸岬で風送ダストイベント時のエアロゾル中BCで, 高い^(14)Cシグナルが観測され, 大陸から輸送されるBCのかなりの部分(~35%)をバイオマス炭素が占めることが明らかとなった.堆積物中のBCは燃焼に由来するsoot-BCと地質過程に由来するGBCからなり, これらを・^(13)Cによって定量的に区別するための手法を提案した.

Research Products

• [Journal Article] Radiocarbon-based source apportion-ment of incomplete combustion prod-ucts (PAHs, BC) in PM_<10> aerosols from residential area of suburban Tokyo (2008)
  • Author(s): Uchida, M., Kumata, H., Koike, Y., Suzuki, M., Matsuda, A., Tsuzuki, M., Uchida, T., Fujiwara, K., Shibata, Y.
  • Journal Title: In"Persistent Organic Pollutants (POPs) Research in Asia", Masatoshi Morita ed Pages: 219-225
• [Journal Article] 最終氷期・最終退氷期のブラックカーボンとPAHの堆積履歴 (2008)
  • Author(s): 熊田英峰, 内田昌男
  • Journal Title: 月刊地球 30 Pages: 198-204
• [Journal Article] 気候変動と高緯度北極土壌圏-土壌有機炭素リザーバーへの温暖化影響- (2008)
  • Author(s): 内田昌男, 内田雅己, 熊田英峰, 高橋善幸, 大塚俊之, 内海真生, 近藤美由紀, 中坪孝之, 柴田康行
  • Journal Title: 月刊地球 30 Pages: 216-229
• [Journal Article] Particulate PAHs levels at Mt. Halla site in Jeju Island, Korea : Regional background levels in northeast Asia (2008)
  • Author(s): Lee, J. Y., Kim, Y. P., Kaneyasu, N., Kumata, H., Kang, C.-H.
  • Journal Title: Atmos-pheric Research 90(1) Pages: 91-98
• [Journal Article] Sorptive Behavior of Nitro-PAHs in Street Runoff and Their Potential as Indicators of Diesel Vehicle Exhaust Particles. Environ. Sci (2008)
  • Author(s): Murakami, M., Yamada, J., Kumata, H., Takada, H.
  • Journal Title: Technol 42(4) Pages: 1144-1150
• [Journal Article] Particulate PAHs levels at Mt. Halla site in Jeju Island, Korea : Regional background levels in northeast Asia (2008)
  • Author(s): Lee, J. Y., Kim, Y. P., Kaneyasu, N., Kumata, H., Kang, C. -H.
  • Journal Title: Atmospheric Research 90 Pages: 91-98
  • Peer Reviewed
• [Journal Article] Radiocarbon-based source apportionment of incomplete combustion products (PAHs, BC) in PM10 aerosols from residential area of suburban Tokyo (2008)
  • Author(s): Uchida, M., Kumata, H., et al.
  • Journal Title: Persistent Organic Pollutants (POPs) Research in Asia Pages: 219-225
• [Journal Article] 北西太平洋における最終氷期・最終退氷期のブラックカーボンとPAHの堆積履歴 (2008)
  • Author(s): 熊田英峰, 内田昌男
  • Journal Title: 月刊地球 30 Pages: 198-204
• [Journal Article] 気候変動と高緯度北極土壌圏-土壌有機炭素リザーバーヘの温暖化影響- (2008)
  • Author(s): 内田昌男, 内田雅己, 熊田英峰, 高橋善幸, 大塚俊之, 内海真生, 近藤美由紀, 中坪孝之, 柴田康行
  • Journal Title: 月刊地球 30 Pages: 216-229
• [Journal Article] Sorptive Behavior of Nitro-PAHs in Street Runoff and Their Potential as Indicators of Diesel Vehicle Exhaust Particles (2008)
  • Author(s): Murakami, Michio, et. al.
  • Journal Title: Environ. Sci. Technol. 42 Pages: 1144-1150
  • Peer Reviewed
• [Journal Article] 韓国済州島ハルラ山における燃焼起源分子マーカーの季節変動 (2007)
  • Author(s): 熊田英峰, 兼保直樹, C.-H. Kang, 後藤優, 内田達也, 都筑幹夫, 藤原祺多夫
  • Journal Title: 地球化学 41 Pages: 135-143
  • NAID: 110009442219
• [Journal Article] Chemical and optical properties of 2003 Siberian forest fire smoke observed at the summit of Mt. Fuji, Japan (2007)
  • Author(s): Kaneyasu, N., Igarashi, Y., Sawa, Y., Takahashi, H., Takada, H., Kumata, H., Holler, R.
  • Journal Title: J. Geophys. Res[Atmospheres] 112
• [Journal Article] Chemical and optical properties of 2003 Siberian forest fire smoke observed at the summit of Mt. Fuji, Japan (2007)
  • Author(s): Kaneyasu, Naoki, et. al.
  • Journal Title: J. Geophys. Res., [Atmospheres] 112
  • Peer Reviewed
• [Journal Article] 韓国済州島ハルラ山における燃焼起源分子マーカーの季節変動 (2007)
  • Author(s): 熊田英峰, ほか
  • Journal Title: 地球化学 41 Pages: 135-143
  • NAID: 110009442219
  • Peer Reviewed
• [Presentation] Chukuchi~Bering海堆積物中の"ブラックカーボン(BC)"の起源, 立教大学 (2009)
  • Author(s): 熊田英峰, 岩本弘, 青木元秀, 内田昌男, 藤原祺多夫
  • Organizer: 第12回みらいシンポジウム(Blue Earth '09)
• [Presentation] チヤクチ〜ベーリング海表層堆積物中のブラックカーボンの分布と安定同位体的特徴 (2009)
  • Author(s): 熊田英峰, 内田昌男, 小崎沙織, 藤原祺多夫
  • Organizer: Blue Earth‘09
  • Place of Presentation: 立教大学
• [Presentation] Radiocarbon Analysis of Elemental Carbon and Total Organic Carbon in Atmospheric Aerosols Collected at Cape Hedo (2008)
  • Author(s): Arakaki, T., Handa, D., Nakajima, H., Kumata, H., Suzuki, M., Shibata, Y., Uchida, M.
  • Organizer: Okinawa, Japan, AGU Fall Meeting
  • Place of Presentation: San Francisco, USA
• [Presentation] Radiocarbon analysis of elemental carbon in PM10 aerosols at Cape Hedo, Okinawa, Japan, during a long range transport event from East Asian countries (2008)
  • Author(s): Handa, D., Nakajima, H., Arakaki, T., Kumata, H., Shibata, Y., Uchida, M
  • Organizer: AMS11(11th International Symposium on Accelerated Mass Spectrometry)
  • Place of Presentation: Rome, Italy
• [Presentation] 陸棚域堆積物中のブラックカーボンの起源識別 (2008)
  • Author(s): 熊田英峰, 内田昌男, 小崎沙織, 青木元秀, 藤原祺多夫
  • Organizer: 地球化学会年会
  • Place of Presentation: 東京大学
• [Presentation] チャクチ~ベーリング海表層堆積物中のブラックカーボンの分布と安定同位体的特徴 (2008)
  • Author(s): 熊田英峰, 内田昌男, 小崎沙織, 藤原祺多夫
  • Organizer: 第11回みらいシンポジウム(Blue Earth '08)
  • Place of Presentation: 横浜市大
• [Presentation] Radiocarbon Analysis of Elemental Carbon and Total Organic Carbon in Atmospheric Aerosols Collected at Cape Hedo, Okinawa, Japan (2008)
  • Author(s): Arakaki, T., Handa, D., Nakajima, H., Kumata, H., Suzuki, M., Shibata, Y., Uchida, M.
  • Organizer: AGU Fall Meeting
  • Place of Presentation: San Francisco, USA
• [Presentation] Radiocarbon analysis of elemental carbon in PM10 aerosols at Cape Hedo, Okinawa, Japan, during a long range transport event from East Asian countries (2008)
  • Author(s): Handa, D., Nakajima, H., Arakaki, T., Kumata, H., Shibata, Y., Uchida, M.
  • Organizer: AMS11 (11th International Symposium on Accelerated Mass Spectrometry)
  • Place of Presentation: Rome, Italy
• [Presentation] 陸棚域堆積物中のブラックカーボンの起源識別 (2008)
  • Author(s): 熊田英峰, 内田昌男, 小崎沙織, 青木元秀, 藤原祺多夫
  • Organizer: 日本地球化学会年会
  • Place of Presentation: 東京大学
• [Presentation] MR06-04leg2で採取したチャクチ~ベーリング海表層堆積物中の燃焼生成炭素系物質の分布 (2007)
  • Author(s): 熊田英峰, 小崎沙織, 内田昌男, 藤原祺多夫
  • Organizer: 堆積物試料中BCの分離条件の最適化, 地球化学会年会
  • Place of Presentation: 岡山大
• [Presentation] 地球化学会年会 (2007)
  • Author(s): 小池庸代, 熊田英峰, 内田達也, 都筑幹夫, 藤原祺多夫
  • Place of Presentation: 岡山大
• [Presentation] タイヤ摩耗粉塵指標としての樹脂酸 : 都市環境中の粒子状物質およびPAHの起源推定の試み (2007)
  • Author(s): 森美佳, 熊田英峰, 内田達也, 都筑幹夫, 藤原祺多夫
  • Organizer: 地球化学会年会
  • Place of Presentation: 岡山大
• [Presentation] Source ap- portioning and molecular characteri- zation of incomplete combustion products in PM^<1.1> and PM^<10> aerosols from residential areas of suburban Tokyo using natural abundance radiocarbon (2007)
  • Author(s): Uchida, M., Koike, Y., Kumata, H., Nakata, H., Tsuzuki, M., Uchida, T., Fujiwara, K., Shibata, Y.
  • Organizer: 27^<th> International Symposium on Halogenated Persistent Organic Pollutants (DIOXIN 2007)
  • Place of Presentation: Tokyo, Japan
• [Presentation] Evaluation of the utility of resin acids as molecular markers for tire debris (2007)
  • Author(s): Kumata, H., Mori, M., Takamiya, S., Tsuzuki, M., Uchida, T., Fujiwara, K.
  • Organizer: 234^<th> American Chemical Society National Meeting
  • Place of Presentation: Boston, MA, USA
• [Presentation] K., Evidences for wide influences of incomplete combustion products from biomass burning in East Asia resion : A case study of PM2.5 aerosols at Mt. Halla, Jeju Island, Korea (2007)
  • Author(s): Kumata, H., Kaneyasu, N., Kang, C.-H., Goto, Y., Tsuzuki, M., Uchida, T., Fujiwara, K.
  • Organizer: 234^<th> American Chemical Society National Meeting
  • Place of Presentation: Boston, MA, USA
• [Presentation] <13>^C and< 14>^C isotopic signatures of plant derived organic molecule in forest fine aerosol : Implication for a proxy for photosynthetic carbon isotopic discrimination at ecosystem-scale (2007)
  • Author(s): Uchida, M., Kumata, H., Kondo, M., Shibata, Y
  • Organizer: 234^<th> American Chemical Society National Meeting
  • Place of Presentation: Boston, MA, USA
• [Presentation] Intense signals of biomass burning in fine particulate mountain aerosols at Jeju, Korea (2007)
  • Author(s): Kumata, H., Kaneyasu, N., Kang, C.-H., Goto, Y., Tsuzuki, M., Uchida, T., Fujiwara, K.
  • Organizer: 21^<th> International Symposium for Polycyclic Aromatic Compounds, Trondheim
  • Place of Presentation: Norway
• [Presentation] Molecular and isotopic characterization of incomplete combustion products in PM10 aerosols from residential areas of suburban Tokyo (2007)
  • Author(s): Koike, Y., Kumata, H., Uchida, M., Nakata, H., Tsuzuki, M., Uchida, T., Fujiwara, K.
  • Organizer: 21^<th> International Symposium for Polycyclic Aromatic Compounds
  • Place of Presentation: Trondheim, Norway
• [Presentation] Resin acids as molecular markers for tire debris and tire derived PAHs in the urban environment (2007)
  • Author(s): Mori, M., Kumata, H., Takamiya, S., Tsuzuki, M., Fujiwara, K., Uchida, T.
  • Organizer: 21^<th> In-ternational Symposium for Polycyclic Aromatic Compounds
  • Place of Presentation: Trondheim, Norway
• [Presentation] Seasonal variation of PAH and molecular markers for biomass burning in fine particulate mountain aerosol at Jeju, Korea (2007)
  • Author(s): Kumata, H., Kaneyasu, N., Kang, C.-H., Goto, Y., Uchida, T., Tsuzuki, M.
  • Organizer: 日本地球惑星科学連合2007年大会
  • Place of Presentation: 幕張
• [Presentation] 下北半島沖海底コアに記録された最終氷期以降の大規模森林火災の履歴-バイオマス燃焼由来有機化合物による検証- (2007)
  • Author(s): 熊田英峰, 内田昌男
  • Organizer: ブルーアースシンポジウム07
  • Place of Presentation: 横浜
• [Presentation] Intense signals of biomass burning in fine particulate mountain aerosols at Jeju, Korea (2007)
  • Author(s): Kumata, Hidetoshi
  • Organizer: 21st International Symposium for Polycyclic Aromatic Compounds
  • Place of Presentation: Trondheim, Norway
• [Presentation] Molecular and isotopic characterization of incomplete combustion products in PM10 aerosols from residential areas of suburban Tokyo (2007)
  • Author(s): Koike, Yasuyo
  • Organizer: 21st International Symposium for Polycyclic Aromatic Compounds
  • Place of Presentation: Trondheim, Norway
• [Presentation] Resin acids as molecular markers for tire debris and tire derived PAHs in the urban environment (2007)
  • Author(s): Mori, Mika
  • Organizer: 21st International Symposium for Polycyclic Aromatic Compounds
  • Place of Presentation: Trondheim, Norway
• [Presentation] Evidences for wide influences of incomplete combustion products from biomass burning in the east Asia region:A case study of PM_<2.5> aerosols at Mt. Halla, Jeju Island, Korea (2007)
  • Author(s): Kumata, Hidetoshi
  • Organizer: 234th American Chemical Society National Meeting
  • Place of Presentation: Boston, USA
• [Presentation] 13C and 14C isotopic signatures of plant derived organic molecule in forest fine aerosol:Implication for a proxy for photosynthetic carbon isotopic discrimination at ecosystem-scale (2007)
  • Author(s): Kumata, Hidetoshi
  • Organizer: 234th American Chemical Society National Meeting
  • Place of Presentation: Boston, USA
• [Presentation] Evaluation of the utility of resin acids as molecular markers for tire debris (2007)
  • Author(s): Kumata, Hidetoshi
  • Organizer: 234th American Chemical Society National Meeting
  • Place of Presentation: Boston, USA
• [Presentation] Source apportioning and molecular characterization of incomplete combustion products in PM1.1 and PM10 aerosols from residential areas of suburban Tokyo using natural abundance radiocarbon (2007)
  • Author(s): Uchida, Masao
  • Organizer: 27th International Symposium on Halogenated Persistent Organic Pollutants(DIOXIN 2007)
  • Place of Presentation: 東京
• [Presentation] MR06-041eg2で採取したチャクチ〜ベーリング海表層堆積物中の燃焼生成炭素系物質の分布:堆積物試料中BCの分離条件の最適化 (2007)
  • Author(s): 熊田英峰
  • Organizer: 第54回地球化学会年会
  • Place of Presentation: 岡山
• [Presentation] 東京都八王子市におけるエアロゾル中の飽和脂肪族および多環芳香族炭化水素の濃度,組成の季節変化 (2007)
  • Author(s): 小池庸代
  • Organizer: 第54回地球化学会年会
  • Place of Presentation: 岡山
• [Presentation] タイヤ摩耗粉塵指標としての樹脂酸:都市環境中の粒子状物質およびPAHの起源推定の試み (2007)
  • Author(s): 森美佳
  • Organizer: 第54回地球化学会年会
  • Place of Presentation: 岡山
• [Presentation] チャクチ〜ベーリング海表層堆積物中のブラックカーボンの分布と安定同位体的特徴 (2007)
  • Author(s): 熊田英峰
  • Organizer: 第11回みらいシンポジウム
  • Place of Presentation: 横須賀
• [Presentation] 韓国Cheju島におけるPM^<2.5>エアロゾル中多環芳香族炭化水素及びバイオマス燃焼由来指標成分の季節変化 (2006)
  • Author(s): 後藤優, 熊田英峰, 兼保直樹, Kang Chang-Hee, 都筑幹夫, 内田達也
  • Organizer: 日本地球化学会第53年会
  • Place of Presentation: 東京
• [Presentation] 樹脂酸のタイヤ摩耗粉塵指標としての有用性の評価 (2006)
  • Author(s): 森美佳, 熊田英峰, 高宮渉平, 都筑幹夫, 内田達也
  • Organizer: 日本地球化学会第53年会
  • Place of Presentation: 東京
• [Presentation] 都市環境中のタイヤ摩耗粉塵由来のレジン酸の分析 (2006)
  • Author(s): 森美佳, 熊田英峰, 都筑幹夫, 内田達也
  • Organizer: 日本分析化学会第55年会
  • Place of Presentation: 大阪
• [Presentation] 分子マーカー及び同位体組成の解析によるバイオマス燃焼の影響評価 (2006)
  • Author(s): 小池康代, 熊田英峰, 都筑幹夫, 内田達也
  • Organizer: 日本分析化学会第55年会
  • Place of Presentation: 大阪
• [Presentation] 大気および底質試料に含まれるバイオマス燃焼指標化合物の分析 (2006)
  • Author(s): 後藤優, 熊田英峰, 内田達也, 都筑幹夫
  • Organizer: 日本分析化学会第55年会
  • Place of Presentation: 大阪
• [Presentation] 都市大気エアロゾル中の飽和脂肪族炭化水素の発生源の推定 (2006)
  • Author(s): 小池庸代, 熊田英峰, 内田達也, 都筑幹夫
  • Organizer: 第29回分析化学若手交流会
  • Place of Presentation: 東京
• [Remarks] 原著論文
  • URL: http://www.ls.toyaku.ac.jp/~kumata/publication_list.html
• [Remarks] 学会発表
  • URL: http://www.ls.toyaku.ac.jp/~kumata/meeting.html