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Investigation of Mass Transfer Mechanism Associated with Water-Rock Reaction and Its Application to Resources and Environmental mental Problems

Research Project

Project/Area Number 18340175
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionKeio University

Principal Investigator

SHIKAZONO Naotatsu  Keio University, FACULTY OF SCIENCE AND TECHNILIGY, PROFESSOR (10011751)

Co-Investigator(Kenkyū-buntansha) FIJIMOTO Kouichiro  TOKYO GAKUGEI UNIVERSITY, FACULTY OF EDUCATION, ASSOCIATE PROFESSOR (80181395)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥16,520,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2007: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2006: ¥10,800,000 (Direct Cost: ¥10,800,000)
KeywordsWater-rock interaction / Reaction rate / Resources and environmental problems / Ore deposits / Mineral / Mass transfer / Kinetics / Dissolution reaction / 熱力学 / 二酸化炭素地中貯留 / 重金属元素 / 溶解速度
Research Abstract

Important results obtained by this study are summarized as follows.
(1) Analytical study on hydrothermally altered rocks associated with hydrothermal are deposits ( kuroko deposits) clarified geochemical behavior of rare earth elements during the hydrothermal alteration.
(2) Analytical study on base metals (i. e. Cr etc) and rare earth elements contaminated soils, river sediments and sands and experimental study on the extraction and water-rocks interaction clarified the concentrations and chemical states of base metal and rare earth elements.
(3) Groundwater chemistry was interpreted based on analytical and thermo chemical data and water-rock interaction experiments. Computer simulation was also used for its interpretation. Water-rock interaction experiments and simulations were also applied to CO_2 underground sequestration and CO_2 capacity in aquifer and CO_2 behavior in underground were estimated and clarified.
(4) Secondary minerals( clay minerals and carbonates) in sedimentary rocks were analyzed for base metals and rare earth elements and the factors controlling the concentrations of these elements ( ionic radii, charge, electronegativity etc) were considered. The retardation of radioactive elements released from nuclear waste was considered. The method preventing the release of base metal elements from contaminated soils was considered.
(5) The simulation based on kinetics-fluid flow coupling model was carried out to interpret groundwater geochemistry and estimate residence time of groundwater in Mt. Fuji area.

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (36 results)

All 2008 2007 2006 Other

All Journal Article (25 results) (of which Peer Reviewed: 16 results) Presentation (6 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Assessment of Pollution in Lower Torag River in Bangladesh.2008

    • Author(s)
      H. M. Zakir, Naotatsu SHIKAZONO.
    • Journal Title

      AMERICAN INSTITUTE of PHYSICS

      Pages: 86-90

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] METAL FRACTION IN SEDIMENTS : A COMPARATIVE ASSESSMENT OF FOUR SEQUENTIAL EXTRACTION SCHEMES.2008

    • Author(s)
      H. M. Zakir, Naotatsu SHIKAZONO.
    • Journal Title

      Journal of Environmental Science for Sustainable Society. Vol. 2

      Pages: 1-12

    • NAID

      130004949066

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Assessment of Pollution in Lower Torae River in Bangladesh.2008

    • Author(s)
      H. M. Zakir, Naotatsu SHIKAZONO
    • Journal Title

      American Institute of Physics.

      Pages: 86-90

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] METAL FRACTION IN SEDIMENTS : A COMPARATIVE ASSESSMENT OF FOUR SEQUENTIAL EXTRACTION SCHEMES.2008

    • Author(s)
      H. M. Zakir, Naotatsu SHIKAZONO
    • Journal Title

      Journal of Environmental Science for Sustainable Society. Vol. 2

      Pages: 1-12

    • NAID

      130004949066

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 土壌構成鉱物の化学風化, 溶解速度と元素移動度-神奈川県秦野市黒ぼく土の例-2007

    • Author(s)
      鹿園直建, 瀧野昌嗣, 大谷晴啓
    • Journal Title

      地質学雑誌 第113巻

      Pages: 593-610

    • NAID

      110006532324

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 神奈川県秦野地域の土壌水、河川水の湧水水質に与える影響について2007

    • Author(s)
      星野隆行, 鹿園直建
    • Journal Title

      地下水学会誌 第49巻

      Pages: 205-233

    • NAID

      10019540746

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 地球システムにおけるグローバル物質循環-炭素循環と気候変動-.2007

    • Author(s)
      鹿園直建, 柏木洋彦
    • Journal Title

      熱測定 Vol. 34

      Pages: 68-76

    • NAID

      10029866157

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 宮城県牡鹿半島と宮戸島の鳴き砂の元素挙動と地球化学的考察2007

    • Author(s)
      五十嵐智秋, 鹿園直建
    • Journal Title

      地学研究 第56巻

      Pages: 25-37

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Geochemical behavior of rare-earth elements and other major and minor elements in sound-producing and silent beach sands in Japan2007

    • Author(s)
      Chiaki IGARASHI, Naotatsu SHIKAZONO, Haruhiro Otani
    • Journal Title

      Chinese Journal of Geochemistry Vol. 26

      Pages: 35-45

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Immobilization of Cr6+ in Soil as Using a Mixed Soil by Inside Adsorption. In : WATER DYNAMICS 4th International Workshop on Water Dynamics Sendai, Japan 7-8 November 2006 (Editors Kazuyuki Tohji, Noriyoshi Tsuchiya, Balachandran Jeyadevan)2007

    • Author(s)
      Otomo, K., Shikazono, N.
    • Journal Title

      AMERICAN INSTITUTE of PHYSICS Volume 898

      Pages: 151-153

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Geochemical behavior of rare-earth elements and other major and minor elements in sound-producing and silent beach sands in Japan.2007

    • Author(s)
      Chiaki IGARASHI, Naotatsu SHIKAZONO, Haruhiro Otani
    • Journal Title

      Chinese Journal of Geochemistry Vol. 26

      Pages: 35-45

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 土壌構成鉱物の化学風化、溶解速度と元素移動度-神奈川県秦野市黒ぼく土の例-2007

    • Author(s)
      鹿園直建・瀧野昌嗣・大谷晴啓
    • Journal Title

      地質学雑誌 第113巻, 12号

      Pages: 593-610

    • NAID

      110006532324

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 神奈川県秦野地域の土壌水、河川水の湧水水質に与える影響について2007

    • Author(s)
      星野隆行・鹿園直建
    • Journal Title

      地下水学会誌 第49巻, 3号

      Pages: 205-233

    • NAID

      10019540746

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 地球システムにおけるグローバル物質循環-炭素循環と気候変動-2007

    • Author(s)
      鹿園直建・柏木洋彦
    • Journal Title

      熱測定 Vol. 34, No. 2

      Pages: 68-76

    • NAID

      10029866157

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高レベル放射性廃棄物からの核種移行に対する固溶体鉱物-水溶液間の元素分配の役割2006

    • Author(s)
      鹿園直建, 小川泰正
    • Journal Title

      原子力バックエンド研究 Vol. 12

      Pages: 3-9

    • NAID

      130003378421

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 鳥取県青谷浜の鳴き砂の地球化学的考察2006

    • Author(s)
      五十嵐智秋, 鹿園直建
    • Journal Title

      地学研究 第55巻

      Pages: 131-143

    • NAID

      40007476047

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 熱水変質に伴う希土類元素の地球化学的挙動 : 熱水系におけるAm, Cmの移行遅延に対する示唆2006

    • Author(s)
      鹿園直建, 小川泰正
    • Journal Title

      原子力バックエンド研究 Vol. 13

      Pages: 1-9

    • NAID

      130003378426

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 高レベル放射性廃棄物地層処分における地下水・熱水-岩石相互作用の重要性2006

    • Author(s)
      鹿園直建, 小川泰正, 大谷晴啓
    • Journal Title

      資源地質 56(2)

      Pages: 115-124

    • NAID

      10021999190

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary 2006 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heavy metal pollution assessment in water and sediments of Turag River at Tongi area in Bangladesh2006

    • Author(s)
      H. M. Zakir, Shaila Sharmin, Naotatsu Shikazono
    • Journal Title

      International Journal of Lakes and Rivers Vol. 1

      Pages: 85-96

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 稲城市で見られる根方タフの鉱物学的性質とその噴出源2006

    • Author(s)
      越智翔二, 藤本光一郎
    • Journal Title

      東京学芸大学紀要自然科学系 58

      Pages: 163-171

    • NAID

      110006414967

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary 2006 Annual Research Report
  • [Journal Article] Heavy metal pollution assessment in water and sediments of Turag River at Tongi area in Bangladesh.2006

    • Author(s)
      H. M. Zakir, Shaila Sharmin, Naotatsu Shikazono
    • Journal Title

      International Journal of Lakes and Rivers Vol. 1

      Pages: 85-96

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 高レベル放射性廃棄物からの核種移行に対する個溶体鉱物-水溶液間の元素分配の役割2006

    • Author(s)
      鹿園直建, 小川泰正
    • Journal Title

      原子力バックエント研究 Vol.12, No.1-2

      Pages: 3-9

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 鳥取県青谷浜の鳴き砂の地球科学的考察2006

    • Author(s)
      五十嵐智秋, 鹿園直建
    • Journal Title

      地学研究 第55巻,3号

      Pages: 131-143

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 熱水変質に伴う希土類元素の地球科学的挙動 : 熱水系におけるAm, Cmの移行遅延に対する示唆2006

    • Author(s)
      鹿園直建, 小川泰正
    • Journal Title

      原子力バックエント研究 Vol.13, No.1

      Pages: 1-9

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Heavy metal pollution assessment in water and sediments of Turag River at Tongi area in Bangladesh2006

    • Author(s)
      H.M.Zakir, Shaila Sharmin, Naotatsu Shikazono
    • Journal Title

      International Journal of Lakes and Rivers Vol.1, No.1

      Pages: 85-96

    • Related Report
      2006 Annual Research Report
  • [Presentation] Geochemical fractionation and anthropogenic metal pollution in sediments of Nakagawa River in Tokyo, Japan2007

    • Author(s)
      Zakir, H. M. *, Naotatsu Shikazono
    • Organizer
      17^<th> annual VM Goldschmidt Conference, Cologne
    • Place of Presentation
      Germany
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Zinc pollution level in sediments of Old Nakagawa River, Tokyo, Japan2007

    • Author(s)
      Zakir, H. M. *, Naotatsu Shikazono
    • Organizer
      5^<th> International Workshop on Water Dynamics
    • Place of Presentation
      Sendai, Japan
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Anthropogenic pollution of Pb, Cr and Cu in sediments of Old Nakagawa River, Tokyo, Japan2007

    • Author(s)
      Zakir, H. M. *, Naotatsu Shikazono
    • Organizer
      1^<st> International Symposium on Aqua Science, Water Resources and Innovation Development of countryside
    • Place of Presentation
      Sakawa, Kochi, Japan
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Geochemical fractionation and anthropogenic metal pollution in sediments of Nakagawa River in Tokyo, Japan.2007

    • Author(s)
      Zakir, H. M.^*, Naotatsu Shikazono
    • Organizer
      17^<th> annual VM Goldschmidt Conference, Cologne
    • Place of Presentation
      Germany
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Zinc pollution level in sediments of Old Nakagawa River, Tokyo, Japan.2007

    • Author(s)
      Zakir, H. M.^*, Naotatsu Shikazono
    • Organizer
      5^<th> International Workshop on W〓 Dynamics
    • Place of Presentation
      Sen〓, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Anthropogenic pollution of Pb, Cr and Cu in sediments of Old Nakagawa River, Tokyo, Japan2007

    • Author(s)
      Zakir, H. M.^*, Naotatsu Shikazono
    • Organizer
      1^<st> International Symposium on Aqua Science, Water Resources and Innovation Development of countryside
    • Place of Presentation
      Sakawa, Kochi, Japan.
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 地球化学講座7環境の地球化学地球システム化学から見た人間圏の地球環境への影響2007

    • Author(s)
      鹿園直建日本地球化学会監修蒲生俊敬編
    • Total Pages
      20
    • Publisher
      培風館
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 地球化学講座7 環境の地球化学地球システム化学から見た人間圏の地球環境への影響2007

    • Author(s)
      鹿園直建, (共書)
    • Total Pages
      20
    • Publisher
      日本地球化字会監修蒲生俊敬編培風館
    • Related Report
      2007 Annual Research Report
  • [Book] 地球学入門 (単書)2006

    • Author(s)
      鹿園直建
    • Publisher
      慶応義塾大学出版会株式会社
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 新・地学 (単書)2006

    • Author(s)
      鹿園直建
    • Publisher
      慶応義塾大学出版会株式会社
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Remarks] 「研究成果報告書概要(和文)」より

    • URL

      http://www.applc.keio.ac.jp/~sikazono/lab/

    • Related Report
      2007 Final Research Report Summary

URL: 

Published: 2006-04-01   Modified: 2016-04-21  

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