New Development in Chemistry of Hypervalent Radicals Approach from the Gas-phase
| Project/Area Number |
18350009
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
FUKE Kiyokazu Kobe University, GRADUATE SCHOOL OF SCIENCE, PROFESSOR (00111766)
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| Co-Investigator(Kenkyū-buntansha) |
ISHIKAWA Haruki KOBE UNIVERSITY, GRADUATE SCHOOL OF SCIENCE, ASSOCIATE PROFESSOR (80261551)
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| Project Period (FY) |
2006 – 2007
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| Project Status |
Completed (Fiscal Year 2007)
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| Budget Amount *help |
¥16,010,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2007: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2006: ¥11,200,000 (Direct Cost: ¥11,200,000)
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| Keywords | Hypervalent Radical / Ammonium Radicals / Oxisonium Radical / Ionization Energy / Femtosecond Spectroscopy / Dipeptide / Cluster / Infrared Spectroscopy / イオン化エネルギー / NH_4ラジカル / 光イオン化 / 赤外スペクトル / 反応中間体 |
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| Research Abstract |
In order to reveal the role of hypervalent radicals in chemical reactions including those in biological chemistry, we have studied on the following three subjects.
1. The electronic structures of Na-2^-(H_2O)_n (n〓6), which have a similar loosely-bounded electron to NH_4 have been investigated by a photoelectron spectroscopy (PES) to examine the solvation of sodium aggregates in small water clusters, From the analysis of the PES bands for the transitions from the anion to the neutral ground and first excited states derived from Na_2 (1^1Σ_g^+) and Na_2(1^3Σ_u^+) it is found that the Na_2-Na^+(H_2O)_n^-type electronic state grows with increasing cluster size, which can be regarded as a sign of the solvation of Na_2 with ionization of the hydrated Na.
2. Ionization potentials (IPs) of NR_4(CH_3OH)_m (NH_3)_n radicals produced by an ArF excimer laser photolysis of ammonia-methanol mixed clusters are determined by the photoionization threshold measurements. The observed IPs show the different evolutions with increasing the number of ammonia and methanol solvents. We have also examined the formation and relaxation dynamics of NH_4(CH_3OH)_m(NH_3)_n clusters produced by photolysis of ammonia-methanol mixed neutral clusters using a time-resolved pump-probe method with femtosecond pulse lasers. From the detailed analysis of the time evolutions of the protonated cluster ion, NH_4(CH_3OH)_m(NH_3)_n, the kinetic model is constructed.
3. A photodissociation spectrometer, containing a spray ionization source and a temperature-variable multipoleion trap, has been constructed to examine the structure and reactivity of gas phase biological molecular ionsat various temperatures. Ultraviolet (UV) and infrared (IR) photodissociation spectra of protonatedalanyltryptophan (Ala-TrpH+) and tryptophanylglycine (Trp-GlyH+) have been investigated to examine the effect of proton on the electronic structure and reactivity of the dipeptides.
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Report
(3 results)
Research Products
(44 results)
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[Presentation] 気体核磁気共鳴法の開発2007
Author(s)
冨宅喜代一
Organizer
日本質量分析学会イオン反応研究会
Place of Presentation
大阪
Year and Date
2007-08-04
Description
「研究成果報告書概要(和文)」より
Related Report
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