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Development ofinstrument for analysis of surface tension using radiation pressure of light

Research Project

Project/Area Number 18350012
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionHiroshima University

Principal Investigator

SAITOW Ken-ichi  Hiroshima University, Natural Scienc Center for Basic Research and Development, Associate Professor (80302579)

Co-Investigator(Kenkyū-buntansha) 楊井 美穂子  広島大学, 自然科学研究支援開発センター, 教務員 (80263672)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥10,690,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2007: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2006: ¥9,000,000 (Direct Cost: ¥9,000,000)
Keywordsradiation pressure / surface tension / critical point / supercritical fluid
Research Abstract

Matters obtain the momentum when the irradiate light is scatted by matters. This momentum is called radiation pressure of light. In the present study, we develop the instrument to evaluate surface tension using radiation pressure. In particular, vapor-liquid surface at around vapor-liquid critical point is very sensitive to perturbations. Such a sensitive interface or surface will be deformed by the radiation pressure of light, and the degree of deformation will be used to evaluate the surface tension.
We have developed the instrument to construct optical cell for high-pressure condition, optics, and detection system. Windows of the cell was made of sapphire. Temperature was controlled by a set of a ND controller, heaters, and a thermocouple, and its fluctuation was within 0.1 degree. Pressure was monitored by a strain gauge. Important points for the present study are in the following. i) interface and/or surface should be observed at 90 degree against incident laser at high pressure condition, ii) laser has good TEM_<00> mode, iii) laser output is variable and its power is greater than 5W. By using laser, optics, and cell, we can develop the system to observe vapor-liquid interface at around vapor-liquid critical point. However, a problem happens. That is, the laser incidence generates babbles in fluid, which disturb the observation of interface. Since the laser wavelength is 532 nm, the laser light is not absorbed by CO_2, because CO_2 dose not have absorption band of electronic transition in visible region. It seems that these babbles are generated by energy transfer from laser to fluid via inelastic scattering such as Raman scattering. As a result, the fluid heated by transferred energy most probably generates bubbles. We tried to diminish the bubble by changing the fluid temperature, but the situation was not changed. In near future, further changes of thermodynamic states and/or the use of Raman no active fluid will be needed to overcome this bubble problem.

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (29 results)

All 2008 2007 2006 Other

All Journal Article (8 results) (of which Peer Reviewed: 3 results) Presentation (21 results)

  • [Journal Article] Photodissociation of CH_2I_2 and Subsequent Electron Transfer in Solution2008

    • Author(s)
      K. Saitow, Y. Naitoh, T. Tominaga, K. Yoshihara
    • Journal Title

      Chemistry An Asian Journal 3

      Pages: 696-709

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Photodissociation of CH_2I_2 and Subsequent Electron Transfer in Solution2008

    • Author(s)
      K., Saitow, Y., Naitoh, T., Tominaga, K., Yoshihara
    • Journal Title

      Chemistry -An Asian Journal 3

      Pages: 696-709

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Development of polarized Raman spectrometer for supercritical fluids having high critical points2006

    • Author(s)
      K. Otake, M. Abe, K. Nishikawa, and K. Saitow
    • Journal Title

      Japanese Journal of Applied Physics 45

      Pages: 2801-2806

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 並進・回転・振動運動から眺めた超臨界流体の局所構造2006

    • Author(s)
      齋藤健一
    • Journal Title

      高圧力の科学と技術(日本高圧力学会誌) 16

      Pages: 120-130

    • NAID

      10017568752

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Development of polarized Raman spectrometer for supercritical fluids having high critical points2006

    • Author(s)
      K., Otake, M., Abe, K., Nishikawa, K., Saitow
    • Journal Title

      Japanese Journal of Applied Physics 45

      Pages: 2801-2806

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Local structure of supercritical fluids investigated by translational, rotational, and vibrational motions2006

    • Author(s)
      K. Saitow
    • Journal Title

      Koatsuryoku no Kagaku to Gijutsu 16

      Pages: 120-130

    • NAID

      10017568752

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 並進・回転・振動運転から眺めた超臨海流体の局所構造2006

    • Author(s)
      齋藤健一
    • Journal Title

      高圧力の科学と技術(日本高圧学会誌) 16

      Pages: 120-120

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Development of polarized Raman spectrometer for supercritical fluids having high critical points.2006

    • Author(s)
      K.Otake, M.Abe, K.Nishikawa, K.Saitow
    • Journal Title

      Japanese Journal of Applied Physics 45

      Pages: 2801-2801

    • Related Report
      2006 Annual Research Report
  • [Presentation] 金ナノネックレスに吸着した極微量蛍光分子の表面増強ラマンスペクトル2008

    • Author(s)
      齋藤健一, 荒川美紀, 加治屋大介
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界CHF_3中でのレーザーアブレーションによる金ナノ構造体の創製と密度による顕著な構造変化の観測2008

    • Author(s)
      岡本睦功, 加治屋大介, 齋藤健一
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界流体中での単結晶シリコンのパルスレーザー照射により創製した緑・赤色発光シリコンナノ結晶2008

    • Author(s)
      山村知玄, 加治屋大介, 齋藤健一
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 緑・赤で発光するシリコンナノ結晶の創製とその発光強度2007

    • Author(s)
      山村知玄, 加治屋大介, 齋藤健一
    • Organizer
      第4回ナノ・バイオ・インフォ化学シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2007-12-02
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 金ナノネックレスを用いた極微量蛍光分子のラマンスペクトル測定2007

    • Author(s)
      荒川美紀, 加治屋大介, 齋藤健一
    • Organizer
      第4回ナノ・バイオ・インフォ化学シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2007-12-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Solvent Dependence of Attractive and Repulsive Interactions in Supercritical Solution : Raman Spectroscopy and Perturbed Hard-sphere Theory for C_2H_2Cl_22007

    • Author(s)
      D., Kajiya, K., Saitow
    • Organizer
      Joint Conference of JMLG/EMLG Meeting 2007 and 30th Symposium on Solution Chemistry of Japan
    • Place of Presentation
      Fukuoka
    • Year and Date
      2007-11-23
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Laser ablation of gold in supercritical fluid generates nanonetwork and huge nanosphere2007

    • Author(s)
      Ken-ichi Saitow, Tomoharu Yamamura, Takamasa Minami
    • Organizer
      9th COLA (International Conference of Laser Ablation)
    • Place of Presentation
      テネリフェ
    • Year and Date
      2007-09-25
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Laser ablation of gold in supercritical fluid generates nanonetwork and huge nanosphere2007

    • Author(s)
      K., Saitow, T., Yamamura, T., Minami
    • Organizer
      9th COLA (International Conference of Laser Ablation)
    • Place of Presentation
      Tenerife
    • Year and Date
      2007-09-25
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 金ナノネックレスの創製とその表面増強効果の解明2007

    • Author(s)
      荒川美紀, 加治屋大介, 齋藤健一
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2007-09-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 可視領域で発光するシリコンナノ結晶・ネットワーク構造の創製とその光物性・構造観測2007

    • Author(s)
      山村知玄, 加治屋大介, 齋藤健一
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2007-09-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界溶液中での引力・斥力エネルギーの溶媒依存性〜1,2-ジクロロエチレンのラマン分光測定とその解析〜2007

    • Author(s)
      加治屋大介, 齋藤健一
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2007-09-18
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Development of time-resolved absorption spectrometer to observe nano-sized particles fabricated by intense laser irradiation in supercritical fluid2007

    • Author(s)
      魏紹禹, 加治屋大介, 齋藤健一
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2007-09-17
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 金ナノネックレスと巨大金ナノ球の創製とその生成メカニズム2007

    • Author(s)
      齋藤健一, 南孝将, 山村知玄, 加治屋大介
    • Organizer
      第1回分子科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2007-09-17
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界流体中でのパルスレーザー照射による金ナノ球・ナノネットワークの生成2007

    • Author(s)
      齋藤健一, 南孝将, 山村知玄
    • Organizer
      ナノ学会第5回大会
    • Place of Presentation
      筑波
    • Year and Date
      2007-05-21
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界流体中でのレーザーアブレーションにより生成する金ナノ粒子の生成メカニズム2007

    • Author(s)
      齋藤健一, 南孝将, 山村知玄
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2007-03-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界流体中でのレーザーアブレーションによる巨大金ナノ球の創製2007

    • Author(s)
      山村知玄, 齋藤健一
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2007-03-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Advanced Nanomaterials Fabricated by Laser Ablation in Supercritical Fluid2007

    • Author(s)
      Ken-ichi Saitow
    • Organizer
      JAPAN NANO 2007
    • Place of Presentation
      東京
    • Year and Date
      2007-02-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Advanced Nanomaterials Fabricated by Laser Ablation in Supercritical Fluid2007

    • Author(s)
      K., Saitow
    • Organizer
      JAPAN NANO 2007
    • Place of Presentation
      Tokyo
    • Year and Date
      2007-02-20
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界流体中でのレーザーアブレーションで創製した金ナノ粒子の形状・サイズ分布2006

    • Author(s)
      山村知玄, 南孝将, 齋藤健一
    • Organizer
      分子構造総合討論会2006
    • Place of Presentation
      静岡
    • Year and Date
      2006-09-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 超臨界流体中でのレーザーアブレーションによる金ナノ粒子の創製 -粒子間ネットワーク構造の密度・温度依存性-2006

    • Author(s)
      南孝将, 齋藤健一
    • Organizer
      分子構造総合討論会2006
    • Place of Presentation
      静岡
    • Year and Date
      2006-09-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Solvent Dependence of Attractive and Repulsive Interactions in Supercritical Solution: Raman Spectroscopy and Perturbed Hard-sphere Theory'for C_2H_2CI_2

    • Author(s)
      Daisuke Kajiya, Ken-ichi Saitow
    • Organizer
      Joint Conference of JMLG/EMLG Meeting 2007 and 30th Symposium on Solution Chemistry of Japan
    • Place of Presentation
      福岡
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2006-04-01   Modified: 2016-04-21  

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