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Formation of the concerted reaction field of sulfur skeletal poly-pyridine metal complex and its catalytic activity

Research Project

Project/Area Number 18350033
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka City University

Principal Investigator

KINOSHITA Isamu  Osaka City University, 大学院・理学研究科, 教授 (80128735)

Co-Investigator(Kenkyū-buntansha) NISHIOKA Takanori  大阪市立大学, 大学院・理学研究科, 准教授 (10275240)
田中 里佳  大阪市立大学, 事務局, 技術職員 (80433316)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥16,330,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2008: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2007: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2006: ¥7,100,000 (Direct Cost: ¥7,100,000)
Keywordsカルバニオン / トリスチオレート / 有機銅 / ポリピリジン錯体 / 大環状ピリジン / トリスピリジルチオメタン / 銅 / 鉄 / ニッケル / カルベン / 金属錯体化学 / 有機金属化学 / 銅錯体 / ニッケル錯体 / トリポッド配位子 / 亜鉛錯体 / 人工光合成 / カリックスピリジン / ロジウム / ヤーンテラー効果
Research Abstract

硫黄骨格の大環状ピリジン配位子、チアカリックス[n]ピリジン(n=3, 4, 6 ; Py_3S_3, Py_4S_4, 及びPy_6S_6)ならびにトリポッド配位子、トリスピリジルチオメタン(tptmH)を開発し、第一遷移金属錯体群の特異的性質を明らかにした。Py_3S_3配位子は低酸化状態を安定化し、銅錯体は空気中で、有用なオレフィンのアジリジン化反応の触媒となる。一方トリスピリジルチオメタン(tptmH)配位子前駆体は[CuIIICl(tptm)]^+となり初めての三角両錘型Cu^(III)錯体を合成した。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (51 results)

All 2009 2008 2007 2006 Other

All Journal Article (21 results) (of which Peer Reviewed: 16 results) Presentation (29 results) Remarks (1 results)

  • [Journal Article] Compressed'Icelike Structures between Molecular Films Comparable with Ice Phase III.2009

    • Author(s)
      Yuki Yoshida, Riichi Miyamoto, Takanori Nishioka, Hideki Hashimoto, Isamu Kinoshita
    • Journal Title

      Chem. Lett. 38

      Pages: 366-367

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] “Compressed"Icelike Structures between Molecular Films Comparable with Ice Phase III2009

    • Author(s)
      Yuki Yoshida
    • Journal Title

      Chemistry Letters 38

      Pages: 366-367

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Feasible attachment of dinuclear ruthenium complex to gold electrode surface via new ligand substitution reaction.2009

    • Author(s)
      Hideaki Takagi
    • Journal Title

      Electrochimica Acta 54

      Pages: 1286-1291

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C-S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes2008

    • Author(s)
      Mayuko Shibue, Masakazu Hirotsu, Takanori Nishioka, Isamu Kinoshita
    • Journal Title

      Organometallics 27

      Pages: 4475-4483

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Thiacalix[3]pyridine Copper(I) Complex as a Highly Active Catalyst for the Olefin Aziridination Reaction2008

    • Author(s)
      Yuhei Tsukahara, Masakazu Hirotsu, Shin-ichi Hattori, Yoshinosuke Usuki, and Isamu Kinoshita
    • Journal Title

      Chem. Lett. (4), 37

      Pages: 452-453

    • NAID

      10021079750

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn-C bond and DFT calculation of its one-electron oxidized species2008

    • Author(s)
      Ken'ichi Kitano, Naoto Kuwamura, Rika Tanaka, Ryoko Santo, Takanori Nishioka, Akio Ichimura and Isamu Kinoshita
    • Journal Title

      Chem. Commun

      Pages: 1314-1316

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mimicking the Photosynthetic system with Strong Hydrogen Bonds to Promote Proton Electron Concerted Reactions'2008

    • Author(s)
      I.Kinoshita, H.Hashimoto, T.Nishioka, R.Miyamoto, N.Kuwamura, and Y.Yoshida
    • Journal Title

      Photosyn. Res. 95

      Pages: 363-378

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C-S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes.2008

    • Author(s)
      Shibue, Mayuko
    • Journal Title

      Organometallics 27

      Pages: 4475-4483

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses, structural characterization and photophysical properties of 4-(2-pyridyl)-l, 2, 3-triazole rhenium(I)complexes.2008

    • Author(s)
      Obata, Makoto
    • Journal Title

      Dalton Transactions 2008

      Pages: 3292-3300

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Thiacalix[3]pyridine Copper(I)Complex as a Highly Active Catalyst for the Olefin Aziridination Reaction2008

    • Author(s)
      塚原 侑平
    • Journal Title

      Chem.Lett. 37

      Pages: 452-453

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn-C bond and DFT calculation of its one-electron oxidized species2008

    • Author(s)
      北野 健一
    • Journal Title

      Chem.Commun.

      Pages: 1314-1316

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure and dynamic properties of substituted carbonylhydride clusters H2RuOs3(CO)13 and H4Ru4(CO)12 containing functionalized phoshines2008

    • Author(s)
      I.A.Andreev
    • Journal Title

      Russian Chemical Bulletin, Internationa Edition 56

      Pages: 1343-1350

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses,structural characterization and photophysical properties of 4-(2-pyridyl)-1,2,3-triazole rhenium(l)complexes2008

    • Author(s)
      小幡 誠
    • Journal Title

      Photosyn.Res. (In press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sugar-Incorpolated N-Heterocyclic Carbene Complexes2007

    • Author(s)
      Takanori Nishioka, Teppei Shibata, Isamu Kinoshita
    • Journal Title

      Organometallics 26

      Pages: 1126-1128

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sugar-Incorporated N-Heterocyclic Carbene Complexes2007

    • Author(s)
      西岡孝訓
    • Journal Title

      Organometallics 26

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Structure-Activity Relationship of Insulinomimetic Activity of Zinc(II) Complexes with Pyridine-2-sulfonic Acid Derivatives2007

    • Author(s)
      吉川 豊
    • Journal Title

      Bull. Chem. Soc. Jpn 80

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Conformational Conversion of Copper Complexes Title : Observation of Halide Induced Conformational Conversion of Dinuclear Copper Complexes Having a Tetradentate Polypyridine Ligand with a p-Xylene Backbone2007

    • Author(s)
      西岡 孝訓
    • Journal Title

      Bull. Chem. Soc. Jpn 80(In press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Diamagnetic-paramagnetic conversion of tris(2-pyridylthio)methylcopper(III) through a structural change from trigonal bipyramidal to octahedral2006

    • Author(s)
      Santo, Ryoko ; Miyamoto, Riichi ; Tanaka, Rika ; Nishioka, Takanori ; Sato, Kazunobu ; Toyota, Kazuo ; Obata, Makoto ; Yano, Shigenobu ; Kinoshita, Isamu ; Ichimura, Akio ; Takui, Takeji
    • Journal Title

      Angew. Chem. Int. ed. 45

      Pages: 7611-7614

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect2006

    • Author(s)
      Rika Tanaka Hamazawa, Takanori Nishioka, Isamu Kinoshita, Takeji Takui, Ryoko Santo and Akio Ichimura
    • Journal Title

      Dalton Trans

      Pages: 1374-1376

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diamagnetic-paramagnetic conversion of tris(2-pyridylthio)methylcopper(III) through a structural change from trigonal bipyramidal to octahedral.2006

    • Author(s)
      山東 良子
    • Journal Title

      AngeWandte Chemie Int. ed. Engl 45

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect2006

    • Author(s)
      田中 里佳
    • Journal Title

      Dalton Transaction 2006

    • Related Report
      2006 Annual Research Report
  • [Presentation] ジチオカルペンを有するNCNピンサー型鉄錯体の合成と電子構造2009

    • Author(s)
      加藤 諒
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      日大舟橋
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Cu-C(sp^3)結合を持つトリポット型銅(II)及び銅(III)錯体の配位子酸化挙動2008

    • Author(s)
      大井秀隆
    • Organizer
      第41回酸化討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2008-11-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Properties of Multinuclear Carbonato Complexes2008

    • Author(s)
      Naoto Kuwamura, Ken'ichi Kitano, Riichi Miyamoto, Yuki Yoshida, Masakazu Hirotsu, Takanori Nishioka, Akio Ichimura, and Isamu Kinoshita
    • Organizer
      15th International SPACC Symposium
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2008-11-20
    • Related Report
      2008 Final Research Report
  • [Presentation] Diastereoselective Syntheses of"Sugar-Coated" N-Heterocyclic CarbeneIr(III)Complexes2008

    • Author(s)
      Shibata, Teppei
    • Organizer
      International symposium on Pure and Applied Coordination Chemistry (16^<th> SPACC Symposium)
    • Place of Presentation
      大阪市ホテルメトロ
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Coordination Ability of a Thiacalix[3]pyridine Copper Unit toward Olefins2008

    • Author(s)
      Nishikawa, Yusuke
    • Organizer
      (16^<th> SPACC Symposium)
    • Place of Presentation
      大阪市ホテルメトロ
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis of Ruthenium Complexes of N, S-Bidentate Ligands2008

    • Author(s)
      Yogi, Akira
    • Organizer
      (16^<th> SPACC Symposium)
    • Place of Presentation
      大阪市ホテルメトロ
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ligand Oxidation Behavior on the Tripodal Cu(II/III)Complex Containinga Cu-C(sp3)Bond2008

    • Author(s)
      Ohi, Hidetaka
    • Organizer
      (16^<th> SPACC Symposium)
    • Place of Presentation
      大阪市ホテルメトロ
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Reactivity of Pyridyl-Substituted Dibenzothiophenes toward Transition Metal Carbonyls2008

    • Author(s)
      Tsuboi, Chiaki
    • Organizer
      (16^<th> SPACC Symposium)
    • Place of Presentation
      大阪市ホテルメトロ
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Syntheses of Copper Complexes with Sugar Incorporated Sulfur-Bridged Polypyridine Ligands2008

    • Author(s)
      Takeguchi, Katsuya
    • Organizer
      (16^<th> SPACC Symposium)
    • Place of Presentation
      大阪市ホテルメトロ
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Structures of Two- and Three-Dimensional Cu(I, II)Mixed-Valence Coordination Polymers2008

    • Author(s)
      Yoshida, Yuki
    • Organizer
      (16^<th> SPACC Symposium)
    • Place of Presentation
      大阪市ホテルメトロ
    • Year and Date
      2008-11-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Organic Reactions on Metal Complexes with Tripodal Carbanion Ligands2008

    • Author(s)
      Ohi, Hidekazu
    • Organizer
      有機金属討論会2008
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Chelate Type Picolyl"sugar Coated" N-Heterocyclic Carbene Complex2008

    • Author(s)
      Shibata, Teppei
    • Organizer
      有機金属討論会2008
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Cu-C(sp3)結合を持つ銅二核錯体の合成と性質2008

    • Author(s)
      吉田佑希
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] C-H活性化を伴うトリポット型銅錯体の合成2008

    • Author(s)
      大井秀隆
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 糖修飾N一複素環カルペンイリジウム錯体の合成と構造2008

    • Author(s)
      柴田鉄平
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] C-Cu-Fを軸とする三方両錘型銅(III)錯体の性質2008

    • Author(s)
      加藤 諒
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] The Interaction of Macrocyclic Ag and Cu Complexes with Carotenoid2008

    • Author(s)
      Kinoshita, Isamu
    • Organizer
      The I5th International Symposium on Carotenoids
    • Place of Presentation
      Okinawa Moon Beach Hotel
    • Year and Date
      2008-07-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] C-H活性化を伴うトリポッド型銅錯体の合成2008

    • Author(s)
      大井秀隆、桑村直人、品田哲郎、大船泰史、廣津昌和、西岡孝訓、木下勇
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 不斉源を持つ三脚型有機銅(II)錯体の合成2008

    • Author(s)
      大井 秀隆
    • Organizer
      日本化学会第88春期年会1E5-37
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2007 Annual Research Report
  • [Presentation] ジベンゾチオフェン誘導体を用いたロジウム錯体の合成2008

    • Author(s)
      廣津 昌和
    • Organizer
      日本化学会第88春季年会4E8-52
    • Place of Presentation
      立教大学池袋キャンパス
    • Related Report
      2007 Annual Research Report
  • [Presentation] The oligo(pyridylthio)system for probing the suspicious oxidat ion states for metal ions2007

    • Author(s)
      I.Kinoshita
    • Organizer
      14^<th> International SPACC-CSJ Symposium AL2
    • Place of Presentation
      National Taipei University,Taipei,Taiwan
    • Year and Date
      2007-12-23
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthetic strategy of rare oxidation state complexes for copper and rhodium〔28^<th>〕International Conference on Science and Technolog2007

    • Author(s)
      Isamu Kinoshita
    • Organizer
      [28^<th>]International Conference on Science and Technolog
    • Place of Presentation
      Praha Czech
    • Year and Date
      2007-07-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] カルバニオンが配位する二核ニッケル(II)錯体の電極反応解析2007

    • Author(s)
      桑村直人・北野健一・西岡孝訓・木下勇・市村彰男
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学(名古屋市)、1C-05
    • Related Report
      2008 Final Research Report
  • [Presentation] Cu(II)カルバニオン錯体によるプロトン電子協奏系の構築2007

    • Author(s)
      木下勇
    • Organizer
      日本化学会第87春期年会
    • Place of Presentation
      関西大学千里山キャンパス(吹田市)、1S3-05
    • Related Report
      2008 Final Research Report
  • [Presentation] ジベンゾチオフェン含有配位子のC-S結合開裂によるS,C,N-三座配位ロジウム錯体の合成2007

    • Author(s)
      渋江 麻友子
    • Organizer
      第57回錯体化学討論会2Ab-16
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Related Report
      2007 Annual Research Report
  • [Presentation] 糖修飾N-ヘテロ環カルベンニッケル錯体の合成2007

    • Author(s)
      西岡 孝訓
    • Organizer
      第57回錯体化学討論会2Ab-07
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Related Report
      2007 Annual Research Report
  • [Presentation] カルバニオンが配位する二核ニッケル(II)錯体の電極反応解析2007

    • Author(s)
      桑村 直人
    • Organizer
      第57回錯体化学討論会1C-05
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Related Report
      2007 Annual Research Report
  • [Presentation] カルバニオンが配位した三方両錘型銅(III)錯体の合成と反応2006

    • Author(s)
      山東良子・宮本利一・木下勇・市村彰男
    • Organizer
      第56回錯体化学討論会
    • Place of Presentation
      広島大学東千田キャンパス(広島市)、2Ab07
    • Related Report
      2008 Final Research Report
  • [Presentation] 稀な酸化状態を持つ金属錯体の合成戦略2006

    • Author(s)
      木下勇
    • Organizer
      第56回錯体化学討論会
    • Place of Presentation
      広島大学東千田キャンパス(広島市)、2S5
    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.materials.sci.osaka-cu.ac.jp/SEKKEI./index.htm

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2006-04-01   Modified: 2016-04-21  

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