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Studies on Synthesis of New Polymers Based on Poly(substituted methylene) Synthesis

Research Project

Project/Area Number 18350066
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionEhime University

Principal Investigator

IHARA Eiji  Ehime University, 大学院・理工学研究科, 教授 (90243592)

Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥17,120,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2008: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2007: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2006: ¥10,100,000 (Direct Cost: ¥10,100,000)
Keywordsポリ(置換メチレン)合成 / ジアゾカルボニル化合物 / ジアゾ酢酸エステル / ジアゾケトン / ジアゾアセトアミド / 遷移金属触媒重合 / パラジウム錯体 / 網目状ポリマー / N-ヘテロカルベン / ジブロモトルエン / 共重合 / 2官能性求電子剤 / 高分子合成 / 機能性高分子 / 有機金属触媒 / 合成化学
Research Abstract

申請者が独自に開発したジアゾカルボニル化合物の重合という高分子合成手法において, これまでには使用していなかった各種のモノマーを新たに用いることによる, 様々な新しい化学構造を有する高分子の合成に成功した。さらに, この重合において従来用いてきた開始剤により得られるポリマーに比べて, はるかに高分子量のポリマーを与えることのできるパラジウム錯体の開発に成功した。これらの研究成果によって, 高分子合成手法としてのこのジアゾカルボニル化合物の重合の有用性を, 一段と高めることができた。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (38 results)

All 2009 2008 2007 2006

All Journal Article (15 results) (of which Peer Reviewed: 12 results) Presentation (23 results)

  • [Journal Article] Pd-mediated Polymerization of Diazoacetamides2008

    • Author(s)
      Eiji Ihara, Toshimitsu Hiraren, Tomomichi Itoh, Kenzo Inoue
    • Journal Title

      Polym. J 40

      Pages: 1094-1098

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] ポリ(置換メチレン)合成 : 1炭素ユニットから主鎖を構築する高分子合成法2008

    • Author(s)
      井原栄治
    • Journal Title

      有機合成化学協会誌 66

      Pages: 358-367

    • NAID

      10021174622

    • Related Report
      2008 Annual Research Report 2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mg-mediated Copolycondensation of α,α-Dibromotoluene with Bifunctional Electrophiles2008

    • Author(s)
      Eiji Ihara, Koh Kobayashi, Takao Wake, Tomomichi Itoh, Kenzo Inoue
    • Journal Title

      Polym. Bull 60

      Pages: 211-218

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-mediated Polymerization of Cyclic Diazoketones2008

    • Author(s)
      Eiji Ihara, Toshimitsu Hiraren, Tomomichi Itoh, Kenzo Inoue
    • Journal Title

      J. Polym. Sci., Part A., Polym. Chem 46

      Pages: 1638-1648

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pd-mediated Polymerization of Diazoacetamides2008

    • Author(s)
      Eiji Ihara
    • Journal Title

      Polym. J. 40

      Pages: 1094-1098

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mg-mediated Copolycondensation ofα,α・Dibromotoluene with Bifunctional Electrophiles2008

    • Author(s)
      Eiji Ihara
    • Journal Title

      Polym.Bull 60

      Pages: 211-218

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organoaluminum-mediated Polymerization of Diazoketones2007

    • Author(s)
      Eiji Ihara, Masami Kida, Tomomichi Itoh, Kenzo Inoue
    • Journal Title

      J. Polym. Sci., Part A., Polym. Chem 45

      Pages: 5209-5214

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Mediated Copolymerization of Diazocarbonyl Compounds with Phenyldiazomethane2007

    • Author(s)
      Eiji Ihara, Masami Kida, Masayasu Fujioka, Nobuyuki Haida, Tomomichi Itoh, Kenzo Inoue
    • Journal Title

      J. Polym. Sci., Part A., Polym. Chem 45

      Pages: 1536-1545

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Organoaluminum-mediated Polymerization of Diazoketones2007

    • Author(s)
      Eiji Ihara
    • Journal Title

      J.Polym.Sci., Part A., Polym.Chem 45

      Pages: 5209-5214

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-mediated Polymerization of Cyclic Diazoketones2007

    • Author(s)
      Eiji Ihara
    • Journal Title

      J.Polym.Sci., Part A., Polym.Chem 45

      Pages: 1638-1648

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Mediated Copolymerization of Diazocarbonyl Compounds with Phenyldiazomethane2007

    • Author(s)
      Eiji Ihara
    • Journal Title

      J.Polym.Sci., Part A., Polym.Chem. 45巻

      Pages: 1536-1545

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Transition Metal-Mediated Copolymerization of Diazocarbonyl Compounds with Alkyne and Isocyanide2006

    • Author(s)
      Eiji Ihara, Akiko Nakada, Tomimichi Itoh, and Kenzo Inoue
    • Journal Title

      Macromolecules 39

      Pages: 6440-6444

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] α,α-Dibromotoluene as a Monomer for Poly(substituted methylene)Synthesis : Magnesium-Mediated Polycondensation of α,α-Dibromotoluene and Magnesium/Copper-Mediated Copolycondensation of α,α-Dibromotoluene with 1,6-Dibromohexane2006

    • Author(s)
      Eiji Ihara, Takao Wake, Naoki Mokume, Tomomichi Itoh, Kenzo Inoue
    • Journal Title

      J. Polym. Sci., Part A., Polym. Chem 44

      Pages: 5661-5671

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] α,α-Dibromotoluene as a Monomer for Poly(substituted methylene) Synthesis : Magnesium-Mediated Polycondensation of α,α-Dibromotoluene and Magnesium/Copper-Mediated Copolycondensation of α,α-Dibromotoluene with 1,6-Dibromohexane2006

    • Author(s)
      Eiji Ihara
    • Journal Title

      J.Polym.Sci., Part A., Polym.Chem. 44巻

      Pages: 5661-5671

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Transition Metal-Mediated Copolymerization of Diazocarbonyl Compounds with Alkyne and Isocyanide2006

    • Author(s)
      Eiji Ihara
    • Journal Title

      Macromolecules 39巻

      Pages: 6440-6444

    • Related Report
      2006 Annual Research Report
  • [Presentation] ポリ(置換メチレン)合成 : Pd錯体を開始剤とするジアゾカルボニル化合物の重合2009

    • Author(s)
      井原栄治
    • Organizer
      京都大学大学院工学研究科高分子化学専攻での学術講演
    • Place of Presentation
      京都大学桂キャンパス
    • Year and Date
      2009-03-13
    • Related Report
      2008 Final Research Report
  • [Presentation] ポリ(置換メチレン)合成 : 1炭素ユニットから主鎖骨格を構築する高分子合成法の開発2009

    • Author(s)
      井原栄治
    • Organizer
      高分子学会中国四国支部第8回高分子材料研究会での招待講演
    • Place of Presentation
      岡山大学環境理工学部
    • Year and Date
      2009-03-10
    • Related Report
      2008 Final Research Report
  • [Presentation] Poly(substituted methylene Synthesis) : Pd-mediated Polymerization of Diazocarbonyl Compounds2008

    • Author(s)
      Eiji Ihara
    • Organizer
      オランダ・アムステルダム大学での学術講演
    • Place of Presentation
      アムステルダム大学
    • Year and Date
      2008-12-12
    • Related Report
      2008 Final Research Report
  • [Presentation] Pd錯体を開始剤とするジアゾカルボニル化合物の重合2008

    • Author(s)
      井原栄治
    • Organizer
      第17回ポリマー材料フォーラム
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2008-11-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] ポリ(置換メチレン)合成 : 炭素-炭素結合を主鎖骨格とする高分子の新しい合成法2008

    • Author(s)
      井原栄治
    • Organizer
      触媒学会重合触媒設計研究会セミナーでの招待講演
    • Place of Presentation
      広島大学
    • Year and Date
      2008-10-10
    • Related Report
      2008 Final Research Report
  • [Presentation] 炭素-炭素結合を主鎖骨格とする高分子の新しい合成法の開発2008

    • Author(s)
      井原栄治
    • Organizer
      高分子講演会(東海)での招待講演
    • Place of Presentation
      豊橋技術科学大学
    • Year and Date
      2008-07-18
    • Related Report
      2008 Final Research Report
  • [Presentation] 炭素-炭素結合を主鎖骨格とする高分子の新しい合成法の開発(招待講演)2008

    • Author(s)
      井原栄治
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 様々なリガンドを有する遷移金属錯体を会誌剤とするエチルジアゾアセテートの重合2008

    • Author(s)
      石黒靖章
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      パシフイコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Pd錯体を会誌剤とする様々なジアゾアセトアミドの重合2008

    • Author(s)
      井原栄治
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      パシフイコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 芳香族ジアゾ酢酸エステルのPd錯体による重合2008

    • Author(s)
      浅野鉄也
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 様々な二官能性ジアゾカルボニル化合物を用いた架橋ポリマーの合成2008

    • Author(s)
      五嶋優子
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 炭素-炭素結合を主鎖骨格とする高分子の新しい合成法の開発2008

    • Author(s)
      井原栄治
    • Organizer
      第57回高分子年次大会での招待講演
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-19
    • Related Report
      2008 Final Research Report
  • [Presentation] ベンゾキノン存在下におけるジアゾケトンの熱による単独重合とスチレンとの共重合2008

    • Author(s)
      西田裕紀
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] Palladium-Mediated Polymerization of Diazocarbonyl Compounds2008

    • Author(s)
      Eiji Ihara, Tomomichi Itoh, Kenzo Inoue
    • Organizer
      OMCOS15
    • Place of Presentation
      奈良100年会館
    • Related Report
      2008 Final Research Report
  • [Presentation] Poly (substituted methylene Synthesis): Pd-mediated Polymerization of Diazocarbonyl Compounds2007

    • Author(s)
      Eiji Ihara
    • Organizer
      IUPAC International Symposium on Ionic Polymerization(IP07)
    • Place of Presentation
      クロスターバンツ(ドイツ)
    • Year and Date
      2007-09-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] Palladium-Mediated Polymerization of Diazocarbonyl Compounds2007

    • Author(s)
      Eiji Ihara
    • Organizer
      OMCOS14
    • Place of Presentation
      奈良百年会館
    • Year and Date
      2007-08-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] Pd錯体を開始剤とする様々なジアゾカルボニル化合物の重合2007

    • Author(s)
      平連 利光
    • Organizer
      第56回高分子年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 様々なPd錯体を開始剤とするジアゾカルボニル化合物の重合2007

    • Author(s)
      西田 裕紀
    • Organizer
      第56回高分子年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] a,a-ジブロモトルエンと種々の二官能性求電子剤との共重合2007

    • Author(s)
      小林 航
    • Organizer
      第56回高分子年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] ジアゾアセチルフェロセンをモノマーとするポリ(置換メチレン)合成2007

    • Author(s)
      五嶋 優子
    • Organizer
      第56回高分子年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Pd錯体を開始剤とするアリールジアゾアセテートの重合2007

    • Author(s)
      井原 栄治
    • Organizer
      第56回高分子年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Pd-mediated Polymerization of Diazocarbonyl Compounds2007

    • Author(s)
      Eiji Ihara
    • Organizer
      20^<th> Japan-Korea Joint Symposium on Advanced Soft Materialsでの招待講演
    • Place of Presentation
      東京工業大学百年記念館
    • Year and Date
      2007-01-15
    • Related Report
      2008 Final Research Report
  • [Presentation] Poly(substituted methylene Synthesis) : Pd-mediated Polymerization of Diazocarbonyl Compounds2007

    • Author(s)
      Eiji Ihara
    • Organizer
      IUPAC International Symposium on Ionic Polymerization (IP07)での招待講演
    • Place of Presentation
      ドイツ・クロスターバンツ
    • Related Report
      2008 Final Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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