Dynamical Spin Crossover Phenomenon in Organic-Inorganic Composite Complex and Its Development to Molecular System
| Project/Area Number |
18350069
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
KOJIMA Norimichi The University of Tokyo, Graduate School of Arts and Sciences, Professor (60149656)
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| Co-Investigator(Kenkyū-buntansha) |
ENOMOTO Masaya The University of Tokyo, Graduate School of Arts and Sciences, Assistant Professor (70345065)
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| Project Period (FY) |
2006 – 2007
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| Project Status |
Completed (Fiscal Year 2007)
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| Budget Amount *help |
¥15,610,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2007: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2006: ¥8,200,000 (Direct Cost: ¥8,200,000)
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| Keywords | organic-inorganic hybrid system / spin crossover / external perturbation responsiveness / light-induced magnetism / photoisomerization / functional complex film / charge transfer phase transition / ferromagnetism |
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| Research Abstract |
In the case of mixed-valence complexes whose spin states are situated in the spin-crossover region, it is expected that a cooperative phenomenon coupled with spin and charge takes place between neighboring metal ions in order to minimize the free energy in the whole system. From this viewpoint, we have investigated the charge transfer phase transition, which is a conjugated phenomenon coupled with spin and charge, (n-C_nH_<2n+1>)_4N[Fe^<II>Fe^<III> (dto)_3] (n=3-6,dto=C_2O_2S_2). The charge transfer phase transition takes place for n = 3 and 4, while it does not take place between 300 K and 4 K for n=5 and 6. In order to reveal the dynamics of the charge transfer phase transition, we have investigated muon spin relaxation (μSR) for n - 3 and 5. In the temperature range of the charge transfer phase transition for n = 3, an anomalous enhancement of the dynamic muon-spin depolarization rate with thermal hysteresis loop was observed at around 80 K in the temperature dependence of the depol
… More
arization rate. The origin of this anomaly has been successfully assigned to the dynamic process of electron-transfer between Fe^<II> and Fe^<III> and its frequency has been estimated from LF-μSR to be about the order of 0.1 MHz. This result is the first observation of dynamical electron transfer process by μSR technique for such mixed valence complexes.
Moreover, in order to control the magnetic properties and the electronic state in the dto-bridged iron mixed-valence system by means of photo-irradiation, we have synthesized a photo-sensitive organic-inorganic hybrid system, (SP)[Fe^<II>Fe^<III>(dto)_3] (SP = spiropyran), and investigated the photo-induced effect on the magnetic properties by the measurements of magnetic susceptibility, UV-vis and ^<57>Fe Mossbauer spectra. The UV irradiation changes the structure of spiropyran from the closed form to the open one in (SP)[Fe^<II>Fe^<III> (dto)_3], which induces the charge transfer phase transition in the two-dimensional honeycomb network structure of [Fe^<II>Fe^<III>(dto)_3]., and changes the ferromagnetic transition temperature. Less
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Report
(3 results)
Research Products
(91 results)
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[Journal Article] Structural Analysis of Iron Mixed-Valence Complex, (n-C_3H_7)_4N[Fe^IIFe^<III>(dto)_3](dto=C_2O_2S_2), under High Pressure.2007
Author(s)
M. Itoi, N. Kida. C. Lin, M. Koeda, N. Kojima, M. Hedo, Y. Uwatoko, Y. Kobayashi, K. Asai, Y. Ohishi and M. Takata
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Journal Title
J. Phys. Soc. Jpn. 76,Suppl. A
Pages: 190-191
Description
「研究成果報告書概要(和文)」より
Related Report
Peer Reviewed
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[Journal Article] "Structural Analysis of Iron Mixed-Valence Complex, (n-C_3H_7)_4N[Fe^<II>Fe^<III> (dto)_3](dto=C_2O_2S_2), under High Pressure."2007
Author(s)
M. Itoi, N. Kida, C. Lin, M. Koeda, N. Kojima, M. Hedo, Y. Uwatoko, Y. Kobayashi, K. Asai, Y. Ohishi, M. Takata
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Journal Title
J. Phys. Soc. Jpn. 76 Suppl.A
Pages: 190-191
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Charge-transfer phase transition and ferromagnetism of iron mixed-valence complexes (n-C_nH_<2n+1>)_4N[Fe^<II>Fe^<III>(dto)_3] (n=3-6; dto=C_2O_2S_2)2006
Author(s)
Itoi, Miho, Ono, Yuuki, Kojima, Norimichi, Kato, Kenichi, Osaka, Keiichi, Takata, Masaki.
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Journal Title
European Journal of Inorganic Chemistry
Pages: 1198-1207
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[Journal Article] A Binuclear Fe(III)Dy(III) Single Molecule Magnet Quantum Effects and Models2006
Author(s)
Ferbinteanu, Marilena, Kajiwara, Takashi, Choi, Kwang-Yong, Nojiri, Hiroyuki, Nakamoto, Akio, Kojima, Norimichi, Cimpoesu, Fanica, Fujimura, Yuichi, Takaishi, Shinya, Yamashita, Masahiro
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Journal Title
Journal of the American Chemical Society 128
Pages: 9008-9009
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[Presentation] Photo-Control of Charge Transfer Phase Transition and Ferromagnetism in Organic-Inorganic Hybrid System, (SP)[Fe^<II>Fe^<III>(dto)_3] (SP=Spiropyran, dto=C_2O_2S_2)2006
Author(s)
N. Kojima, M. Hikita, N. Kida, I. Kashima, M.Enomoto, M.Okubo, M. Itoi, K.Takahashi, H. Kobayashi
Organizer
10th International Conference on Molecule-based Magnets (ICMM2006)
Place of Presentation
Victoria, Canada
Description
「研究成果報告書概要(和文)」より
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[Presentation] "Photo-Control of Charge Transfer Phase Transition and Ferromagnetism in Organic-Inorganic Hybrid System, (SP)[Fe^<II>Fe^<III>(dto)_3] (SP=Spiropyran, dto=C_2O_2S_2)"2006
Author(s)
N. Kojima, M. Hikita, N. Kida, I. Kashima, M. Enomoto, M. Okubo, M. Itoi, K. Takahashi, H. Kobayashi
Organizer
10th International Conference on Molecule-based Magnets (ICMM2006)
Place of Presentation
Vctoria, Canada
Description
「研究成果報告書概要(欧文)」より
Related Report
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