Development of Supramolecular Emission Switching Systems Responsible for Chemical and Physical Stimuli and Clarification of Their Mechanisms

• Project/Area Number: 18350073
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: Osaka University
• Principal Investigator: MIYATA Mikiji Osaka University, 大学院・工学研究科, 教授 (90029322)
• Co-Investigator(Kenkyū-buntansha): TOHNAI Norimitsu 大阪大学, 大学院・工学研究科, 准教授 (30346184) ; HISAKI Ichiro 大阪大学, 大学院・工学研究科, 助教 (90419466)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥18,090,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥2,790,000); Fiscal Year 2008: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000); Fiscal Year 2007: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000); Fiscal Year 2006: ¥6,000,000 (Direct Cost: ¥6,000,000)
• Keywords: 光物性 / 結晶工学 / 超分子化学 / アントラセン / アヌレン / 超分子集合 / 固体蛍光 / ホストゲスト化学 / 有機塩 / 固体発光 / 有機結晶 / 超分子 / スルホン酸 / 分子集合体

Research Abstract

酸性部位をもつ共役パイ電子系化合物を種々のアミンと組み合わせたハイスループットな結晶工学的手法により、明確に定義できるナノクラスターや、様々の分子配列をもつ発光性結晶の作製に成功した。さらに、後者の一連の結晶の発光強度や発光色の体系的な分析により、固体蛍光発光の強度に関する新しい発光作用機序を提案した。また、結晶内の分子構造の情報を、転写、伝達しエキシマー発光として出力するモデル系を構築した。

Research Products

• [Journal Article] Systematic Investigation of Molecular Arrangements and Solid-State Fluorescence Properties by Using Organic Salts of Anthracene-2, 6-disulfonic Acid with Aliphatic Primary Amines (2009)
  • Author(s): Y. Mizobe, T. Hinoue, A. Yamamoto, I. Hisaki, M. Miyata, Y. Hasegawa, N. Tohnai
  • Journal Title: Chem. Eur. J (in press)
  • Peer Reviewed
• [Journal Article] Effect of steric complementarity on solid-state optical properties of ternary CT complexes ; BPDS, aliphatic amines and TCNQ (2009)
  • Author(s): N. Tohnai, M. Kurata, H. Nakajima, A. Yamamoto, T. Hinoue, Y. Mizobe, I. Hisaki, M. Miyata
  • Journal Title: J. Phys. Chem. C (in press)
  • Peer Reviewed
• [Journal Article] Octadehydrodibenzo[12]annulene-Based Organogels : Two Methyl Ester Groups Prevent Crystallization and Promote Gelation (2009)
  • Author(s): I. Hisaki, H. Shigemitsu, Y. Sakamoto, Y. Hasegawa, Y. Okajima, K. Nakano, N. Tohnai, M. Miyata
  • Journal Title: Angew. Chem. Int (in press)
  • Peer Reviewed
• [Journal Article] Structures of Brucinium Cholate: Bile Acid and Strychnine Derivatives Meet in the Crystals (2009)
  • Author(s): I. Hisaki, N. Shizuki, K. Aburaya, M. Katsuta, N. Tohnai, M. Miyata
  • Journal Title: Cryst. Grwoth Des (in press) Pages: 1280-1283
  • Peer Reviewed
• [Journal Article] Reversible Transformation and Fluorescence Modulation in Polymorphic Crystals of n-Butyl ammonium 2-Naphthalenesulfonate (2009)
  • Author(s): A. Yamamoto, M. Matsumoto, T. Hinoue, Y. Mizobe, I. Hisaki, M. Miyata, N. Tohnai
  • Journal Title: Synthetic Metals (in press)
  • Peer Reviewed
• [Journal Article] Conformational Polymorphism of Octadehydrodibenzo[12] annulene with Methyl Phthalate Moieties (2009)
  • Author(s): I. Hisaki, Y. Sakamoto, H. Shigemitsu, N. Tohnai, M. Miyata
  • Journal Title: Cryst. Growth Pages: 414-420
  • Peer Reviewed
• [Journal Article] Molecular Solid Solutions with Steric Complementary Pairing from the Binary Mixtures l-Naphthylmethylammonium Alkanoates (2009)
  • Author(s): Katsunari Inoue
  • Journal Title: Cryst. Growth Des 9 Pages: 1072-1076
  • Peer Reviewed
• [Journal Article] Conformational Polymorphism of Octadehydrodibenzo-[12]annulene with Methyl Phthalate Moieties (2009)
  • Author(s): Ichiro Hisaki
  • Journal Title: Cryst. Growth Des 9 Pages: 414-420
  • Peer Reviewed
• [Journal Article] Highly Efficient Enantio- resolution of 2, 2-Dimethyl-3-hexanol with Cholamide Crystals on the Basis of Intercalation and Bilayer Inversion (2008)
  • Author(s): K. Aburaya, T. Murai, I. Hisaki, N. Tohnai, M. Miyata
  • Journal Title: Chem. Lett 37 Pages: 1224-1225
  • NAID: 10024397806
  • Peer Reviewed
• [Journal Article] Modulation of Solid-state Luminescence Quantum Efficiency Based on CH-O Intermolecular Interaction (2008)
  • Author(s): T. Hinoue, Y. Mizobe, I. Hisaki, M. Miyata、N. Tohnai
  • Journal Title: Chem. Lett 37 Pages: 642-643
  • NAID: 10021081437
  • Peer Reviewed
• [Journal Article] Superstructure-Dependent Optical and Electrical Properties of Unusual Face-to-Face pi-Stacked One-Dimensional Assembly of Dehydrobenzo[12]annulene in Crystalline State (2008)
  • Author(s): I. Hisaki, Y. Sakamoto, H. Shigemitsu, N. Tohnai, M. Miyata, S. Seki, A. Saeki, S. Tagawa
  • Journal Title: Chem. Eur. J 14 Pages: 4178-4187
  • Peer Reviewed
• [Journal Article] Topological Classification and Supramolecular Chirality of 2_1-Helical Ladder-type Hydrogen-Bond Networks Composed of Primary Ammonium Carboxylates : Bundle Controls in 21-Helical Assemblies (2008)
  • Author(s): T. Yuge, T. Sakai, N. Kai, I. Hisaki, M. Miyata, N. Tohnai
  • Journal Title: Chem. Eur. J 14 Pages: 2984-2993
  • Peer Reviewed
• [Journal Article] Importance of Weak Hydrogen bonds in the Formation of Cholamide Inclusion Crystals with Aromatic Guests, Cryst (2008)
  • Author(s): K. Aburaya, K. Nakano, K. Sada, N. Yoswathananont, M. Shigesato, I. Hisaki, N. Tohnai, M. Miyata
  • Journal Title: Growth Des 8 Pages: 1013-1022
  • Peer Reviewed
• [Journal Article] Guest-Induced Topological Polymorphism of Pseudo-Cubic Hydrogen Bond Networks-Robust and Adaptable Supramolecular Synthon (2008)
  • Author(s): T. Yuge, I. Hisaki, M. Miyata, N. Tohnai
  • Journal Title: CrystEngComm 10 Pages: 263-266
  • Peer Reviewed
• [Journal Article] Supramolecular Tilt Chirality in Crystals of Steroids and Alkaloids (2008)
  • Author(s): I. Hisaki, N. Tohnai, M. Miyata
  • Journal Title: Chirality 20 Pages: 330-336
  • Peer Reviewed
• [Journal Article] Topological Classification and Supramolecular Chirality of 21-Helical Ladder-type Hydrogen-Bond Networks Composed of Primary Ammonium Carboxylates : Bundle Controls in 21-Helical Assemblies (2008)
  • Author(s): Tetsuharu Yuge
  • Journal Title: Chew. Eur. J 14 Pages: 2984-2993
  • Peer Reviewed
• [Journal Article] Superstructure-Dependent Optical and Electrical Properties of Unusual Face-to-Face pi-Stacked One-Dimensional Assembly of Dehydrobenzo [12] annulene in Crystalline State (2008)
  • Author(s): Ichiro Hisaki
  • Journal Title: Chem. Eur. J 14 Pages: 4178-4187
  • Peer Reviewed
• [Journal Article] Importance of Weak Hydrogen bonds in the Formation of Cholamide Inclusion Crystals with Aromatic Guests (2008)
  • Author(s): Kazuaki Aburaya
  • Journal Title: Cryst. Growth Des 8 Pages: 1013-1022
  • Peer Reviewed
• [Journal Article] Guest-Induced Topological Polymorphism of Pseudo-Cubic Hydrogen Bond Networks-Robust and Adaptable Supramolecular Synthon (2008)
  • Author(s): Tetsuharu Yuge
  • Journal Title: CrystEngComm 10 Pages: 263-266
  • Peer Reviewed
• [Journal Article] Modulation of Solid-state Luminescence Quantum Efficiency Based on CF-O Intermolecular Interaction (2008)
  • Author(s): Tomoaki Hinoue
  • Journal Title: Cbem. Lett. 37 Pages: 642-643
  • Peer Reviewed
• [Journal Article] Topologically Different Two Pseudo-Decahedral Hydrogen Bond Networks Composed of Triphenylmethyl-ammonium Phosphonates (2007)
  • Author(s): T. Yuge, N. Kai, I. Hisaki, M. Miyata, N. Tohnai
  • Journal Title: Chem. Lett 36 Pages: 1390-1391
  • NAID: 10019792709
  • Peer Reviewed
• [Journal Article] Dependence of the Enantioselectivity on Reversion of Layer Directions in Cholamide Inclusion Compounds (2007)
  • Author(s): K. Aburaya, I. Hisaki, N. Tohnai, M. Miyata
  • Journal Title: Chem. Commun Pages: 4257-4259
  • Peer Reviewed
• [Journal Article] Crystalline Host-guest Assemblies of Steroidal and Related Molecules : Diversity, Hierarchy and Supramolecular Chirality (2007)
  • Author(s): M. Miyata, N. Tohnai, I. Hisaki
  • Journal Title: Acc. Chem. Res 40 Pages: 694-702
  • Peer Reviewed
• [Journal Article] Topological Study of Pseudo-Cubic Hydrogen Bond Networks in a Binary System Composed of Primary Ammonium Carboxylates : An Analogue of Ice Cube (2007)
  • Author(s): T. Yuge, N. Tohnai, T. Fukuda, I. Hisaki, M. Miyata
  • Journal Title: Chem. Eur J 13 Pages: 4163-4168
  • Peer Reviewed
• [Journal Article] Guest-dependent Distinct Changes in Arrangements of Anthracene and the Corresponding Fluorescence Characteristics in Ternary System : Transcription and Translation of Guest Molecular Information (2007)
  • Author(s): Y. Mizobe, T. Hinoue, M. Miyata, I. Hisaki, Y. Hasegawa, N. Tohnai
  • Journal Title: Bull. Chem. Soc. Jpn 80 Pages: 1162-1172
  • Peer Reviewed
• [Journal Article] Well-Designed Supramolecular Clusters Comprising Triphenylmethylamine and Various Sulfonic Acids, Angew (2007)
  • Author(s): N. Tohnai, Y. Mizobe, M. Doi, S. Sukata, T. Hinoue, T. Yuge, I. Hisaki, Y. Matsukawa, M. Miyata
  • Journal Title: Chem. Int. Ed 46 Pages: 2220-2223
  • Peer Reviewed
• [Journal Article] Guest-Induced Supramolecular Isomerism and Chirality of Brucine Inclusion Crystals with Aliphatic Alcohols : A Hierarchical Interpretation (2007)
  • Author(s): T. Watabe, K. Kobayashi, I. Hisaki, N. Tohnai, M. Miyata
  • Journal Title: Bull. Chem. Soc. Jpn 80 Pages: 464-475
  • NAID: 10018876740
  • Peer Reviewed
• [Journal Article] Isomerism Effect on Flexibility of Layered Frameworks in Organic Salts of 4, 4'-Biphenyldisulfonic Acid with Primary Amines (2007)
  • Author(s): Y. Mizobe, M. Miyata, I. Hisaki, N. Tohnai
  • Journal Title: Chem. Lett 36 Pages: 280-281
  • NAID: 10018522760
  • Peer Reviewed
• [Journal Article] Supramolecular Tilt-Chirality Derived from Symmetric Benzene Molecules : Handedness of the 2_1 Helical Assembly (2007)
  • Author(s): A. Tanaka, I. Hisaki, N. Tohnai, M. Miyata
  • Journal Title: Chem. Asian J 2 Pages: 230-238
  • Peer Reviewed
• [Journal Article] Crystalline Host-guest Assemblies of Steroidal and Related Molecules: Diversity, Hierarchy and Supramolecular Chirality (2007)
  • Author(s): Mikiji Miyata
  • Journal Title: Acc. Chem. Res. 40 Pages: 694-702
  • Peer Reviewed
• [Journal Article] Dependence of the Enantioselectivity on Reversion of Layer Directions in Cholamide Inclusion Compounds (2007)
  • Author(s): Kazuaki Aburaya,
  • Journal Title: Chem. Commun Pages: 4257-4259
  • Peer Reviewed
• [Journal Article] Guest-Induced Supramolecular Isomerism and Chirality of Brucine Inclusion Crystals with Aliphatic Alcohols: A Hierarchical Interpretation (2007)
  • Author(s): Tsuyoshi Watabe
  • Journal Title: Bull. Chem. Soc. Jpn 80 Pages: 464-475
  • Peer Reviewed
• [Journal Article] Topological Study of Pseudo-Cubic Hydrogen Bond Networks in a Binary System Composed of Primary Ammonium Carboxylates: An Analogue of Ice Cube (2007)
  • Author(s): Tetsuharu Yuge
  • Journal Title: Chem. Eur J, 13 Pages: 4163-4168
  • Peer Reviewed
• [Journal Article] Guest-dependent Distinct Changes in Arrangements of Anthracene and the Corresponding Fluorescence Characteristics in Ternary System: Transcription and Translation of Guest Molecular Information (2007)
  • Author(s): Yuji Mizobe
  • Journal Title: Bull. Chem. Soc. Jpn 80 Pages: 1162-1172
  • Peer Reviewed
• [Journal Article] Four Kinds of 2_1 Helical Assemblies with the Molecular Tilt as well as Three-Directional and Facial Chirality (2007)
  • Author(s): Tsuyoshi Watabe
  • Journal Title: Chemistry Letters 36巻2号 Pages: 234-235
• [Journal Article] Supramolecular Tilt-Chirality Derived from Symmetric Benzene Molecules : Handedness of the 2_1 Helical Assembly (2007)
  • Author(s): Akira Tanaka
  • Journal Title: Chemistry-An Asian Journal 2巻2号 Pages: 230-238
• [Journal Article] Isomerism Effect on Flexibility of Layered Frameworks in Organic Salts of 4,4'-Biphenyldisulfonic Acid with Primary Amines (2007)
  • Author(s): Yuji Mizobe
  • Journal Title: Chemistry Letters 36巻4巻 Pages: 280-281
• [Journal Article] Guest-Induced Supramolecular Isomerism and Chirality of Brucine Inclusion Crystals with Aliphatic Alcohols : A Hierarchical Interpretation (2007)
  • Author(s): Tsuyoshi Watabe
  • Journal Title: Bulletin of Chemical Society of Japan (In press)
• [Journal Article] Well-designed Supramolecular Cluster composed of Triphenylmethyl Amine and Various Sulfonic acids : A Useful Approach to Nanoparticles. (2007)
  • Author(s): Norimitsu Tohnai
  • Journal Title: Angewandte Chemie International Edition (accepted)
• [Journal Article] Guest-dependent Distinct Changes in Arrangements of Anthracene and the Corresponding Fluorescence Characteristics in Ternary System : Transcription and Translation of Guest Molecular Information (2007)
  • Author(s): Yuji Mizobe
  • Journal Title: Bulletin of the Chemical society of Japan (In press)
• [Journal Article] Topological Study of Pseudo-Cubic Hydrogen Bond Networks in a Binary System Composed of Primary Ammonium Carboxylates : An Analogue of Ice Cube (2007)
  • Author(s): Tetsuharu Yuge
  • Journal Title: Chemistry-A European Journal (accepted)
• [Journal Article] Anomalous anthracene arrangement and the corresponding rare excimer emission in the solid-state by transcription and translation of molecular information (2006)
  • Author(s): TY. Mizobe, H. Ito, I. Hisaki, M. Miyata, Y. Hasegawa, N. Tohnai
  • Journal Title: Org. Lett 8 Pages: 4295-4298
  • Peer Reviewed
• [Journal Article] Supramolecular Chirality in Layered Crystals of Achiral Ammonium Salts and Fatty Acids : A Hierarchical Interpretation (2006)
  • Author(s): A. Tanaka, K. Inoue, I. Hisaki, N. Tohnai, M. Miyata, A. Matsumoto
  • Journal Title: Angew. Chem. Int. Ed 45 Pages: 4142-4145
  • Peer Reviewed
• [Journal Article] Novel Design of Tunable Organic Clay Mimic Structures Based On the Connection of One-Dimensional Supramolecular Synthons (2006)
  • Author(s): T. Yuge, M. Miyata, N. Tohnai
  • Journal Title: Cryst. Growth Des 6 Pages: 1271-1273
  • Peer Reviewed
• [Journal Article] A Novel Strategy for Fluorescence Enhancement in the Solid-State : Affording Rigidity to Fluorophores Packing (2006)
  • Author(s): Y. Mizobe, N. Tohnai, H. Ito, I. Hisaki, M. Miyata, Y. Hasegawa
  • Journal Title: Chem. Commun Pages: 2126-2128
  • Peer Reviewed
• [Journal Article] A Novel Strategy for Fluorescence Enhancement in the Solid-State : Affording Rigidity to Fluorophores Packing (2006)
  • Author(s): Yuji Mizobe
  • Journal Title: Chemical Communications 20号 Pages: 2126-2128
• [Journal Article] Novel Design of Tunable Organic Clay Mimic Structures Based On the Connection of One-Dimensional Supramolecular Synthons (2006)
  • Author(s): Tetsuharu Yuge
  • Journal Title: Crystal Growth and Design 6巻6号 Pages: 1271-1273
• [Journal Article] Supramolecular Chirality in Layered Crystals of Achiral Ammonium Salts and Fatty Acids : A Hierarchical Interpretation (2006)
  • Author(s): Akira Tanaka
  • Journal Title: Angewandte Chemie International Edition 45巻25号 Pages: 4142-4145
• [Journal Article] Guest-induced Inversion of an Asymmetric Host Layer in Inclusion Crystals of Cholic Acid (2006)
  • Author(s): Kazunori Nakano
  • Journal Title: Crystal Engineering Communication 8巻6号 Pages: 462-468
• [Journal Article] Supramolecular Chirality and Isomerism in Cinchonidine Crystals : Hierarchical Analysis on the Basis of the Asymmetric 2_1 Helical Columnar Assembly (2006)
  • Author(s): Tsuyoshi Watabe
  • Journal Title: Chemistry Letters 35巻7号 Pages: 806-807
• [Journal Article] Anomalous anthracene arrangement and the corresponding rare excimer emission in the solid-state by transcription and translation of molecular information (2006)
  • Author(s): Yuji Mizobe
  • Journal Title: Organic Letters 8巻19号 Pages: 4295-4298
• [Journal Article] 2_1 Helical Assemblies of Cinchona Alkaloids in Crystals : Definition of their Handedness Based on the Molecular Tilt (2006)
  • Author(s): Ichiro Hisaki
  • Journal Title: Chemistry Letters 35巻11号 Pages: 1274-1275
  • NAID: 10018405061
• [Journal Article] Reversible Transformation and Fluorescence Modulation in Polym orphic Crystals of n-Butylammonium 2-Naphthalenesulfonate
  • Author(s): Atsushi Yamamoto
  • Journal Title: Synthetic Metals (in press)
  • Peer Reviewed
• [Journal Article] Importance of Weak Hydrogen bonds in the Formation of Cholamide Inclusion Crystals with Aromatic Guests
  • Author(s): Kazuaki Aburaya
  • Journal Title: Cryst. Growth Des (in press)
  • Peer Reviewed
• [Journal Article] Superstructure-Dependent Optical and Electrical Properties of Unusual Face-to-Face Stacked One-Dimensional Assembly of Dehydrobenzo [12] annulene in Crystalline StateSuperstructure-Dependent Optical and Electrical Properties of Unusual Face-to-Face・-Stacked One-Dimensional Assembly of Dehydrobenzo [12] annulene in Crystalline State
  • Author(s): Ichiro Hisaki,
  • Journal Title: Chem. Eur. J. (in press)
  • Peer Reviewed
• [Journal Article] Topological Classification and Supramolecular Chirality of 21-Helical Ladder-type Hydrogen-Bond Networks Composed of Primary Ammonium Carboxylates: Bundle Controls in 21-Helical Assemblies
  • Author(s): Tetsuharu Yuge
  • Journal Title: Chem. Eur. J. (in press)
  • Peer Reviewed
• [Presentation] メチルエステル基をもつオクタデヒドロベンゾ[12]アヌレン誘導体の超分子構造 (2008)
  • Author(s): 重光孟
  • Organizer: 有機結晶シンポジウム
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-11-13
• [Presentation] アントラセン-1, 8-ジスルホン酸アンモニウム塩の形成する新奇アントラセン配列と特異的発光挙動 (2008)
  • Author(s): 樋上友亮
  • Organizer: 有機結晶シンポジウム
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-11-13
• [Presentation] シンコナアルカロイドとコール酸誘導体における螺旋をモチーフにした超分子構造 (2008)
  • Author(s): 志築宣江
  • Organizer: 有機結晶シンポジウム
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-11-13
• [Presentation] 胆汁酸誘導体包接結晶における層構造変化を伴うインターカレーションと高効率光学分割 (2008)
  • Author(s): 村井威俊
  • Organizer: 有機結晶シンポジウム
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-11-13
• [Presentation] コール酸誘導体包接化合物におけるキラルアルコールの光学分割とそのキラル認識 (2008)
  • Author(s): 金裕太
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-26
• [Presentation] デヒドロベンゾ[12]アヌレン骨格を有する新規超分子ゲル化剤の合成およびゲルの構造と物性 (2008)
  • Author(s): 重光孟
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-26
• [Presentation] 水素結合によって構築された蛍光性超分子集合体の配列特異的発光挙動 (2008)
  • Author(s): 樋上友亮
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-26
• [Presentation] シンコナアルカロイドとコール酸誘導体の有機結晶における高次構造の構築 (2008)
  • Author(s): 志築宣江
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-26
• [Presentation] コール酸アミド包接結晶を用いたインターカレーションによる光学分割と層構造変化 (2008)
  • Author(s): 村井威俊
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-26
• [Presentation] 2-アントラセンスルホン酸アミン塩の超分子クラスター集積による蛍光性多孔質構造の構築と機能 (2008)
  • Author(s): 山本淳志
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-26
• [Presentation] デヒドロベンソ[12]アヌレンの一次元超分子集合の構築と物性 (2008)
  • Author(s): 久木一朗, 他
  • Organizer: 高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-25
• [Presentation] アントラセンジスルホン酸アンモニウム塩とTCNBからなる非共有結合性分子集合体の構造制御とそれに起因する光電気物性 (2008)
  • Author(s): 中島裕美
  • Organizer: 高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-24
• [Presentation] 9, 10-ビスアミノフェニルアントラセン誘導体の包接結晶におけるゲスト依存的な固体発光変調 (2008)
  • Author(s): 田麦顕大
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-24
• [Presentation] コール酸アミドと芳香族ゲストとの包接結晶における弱い水素結合 (2008)
  • Author(s): 劉文姿
  • Organizer: 57回高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-24
• [Presentation] 水素結合性クラスターの連結による高次超分子構造体の構築と機能化 (2008)
  • Author(s): 藤内謙光・久木一朗・宮田幹二
  • Organizer: 高分子討論会
  • Place of Presentation: 大阪市立大学
  • Year and Date: 2008-09-23
• [Presentation] アントラセンジスルホン酸アンモニウム塩とTCNBからなる電荷移動錯体の積層様式の異なる結晶構造に起因した固体発光挙動 (2008)
  • Author(s): 中島裕美・藤内謙光・久木一朗・宮田幹二
  • Organizer: 光化学討論会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2008-09-13
• [Presentation] 9, 10-ビスフェニルアントラセン誘導体包接結晶におけるゲスト依存的固体発光変調 (2008)
  • Author(s): 田麦顕大
  • Organizer: 光化学討論会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2008-09-13
• [Presentation] 2-アントラセンスルホン酸トリフェニルメチルアミン塩を用いたゲスト依存的な多孔質構造の構築とその蛍光特性 (2008)
  • Author(s): 山本淳志
  • Organizer: 光化学討論会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2008-09-13
• [Presentation] デヒドロベンソ[12]アヌレン誘導体の結晶における光物性 (2008)
  • Author(s): 久木一朗, 他
  • Organizer: 光化学討論会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2008-09-11
• [Presentation] Supramolecular Tilt Chirality in Crystals of Cholic Acid (2008)
  • Author(s): 久木一朗, 他
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-24
• [Presentation] Chiral recognition in cholamide inclusion crystals : Four-location model for hydrogen and stereogenic carbon (2008)
  • Author(s): Mikiji Miyata
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-23
• [Presentation] Chiral recognition for inclusion compounds of 3-epicholic and 3-epideoxycholic acids with alcohols (2008)
  • Author(s): Yute Kin
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-23
• [Presentation] Crystalline molecular assemblies of dehydrobenzo [12] annulenes having carboxylic groups with amines (2008)
  • Author(s): Hajime Shigemitsu
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-23
• [Presentation] Luminescent Modulations Depending on Guest Molecules in Inclusion Crystals of 9, 10-Bisphenylanthracene Derivatives (2008)
  • Author(s): Akihiro Tamugi
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-23
• [Presentation] Drastic modulation of solid-state luminescence derived from molecular arrangement of organic salts (2008)
  • Author(s): Tomoaki Hinoue
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-23
• [Presentation] Supramolecular structures in co-crystals composed of steroidal acids and cinchona alkaloids (2008)
  • Author(s): Norie Shizuki
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-23
• [Presentation] Functional Porous Crystals with Supramolecular Clusters of Triphenylmethylammonium Sulfonates (2008)
  • Author(s): Atushi Yamamoto
  • Organizer: IUCr 2008, XXI Congress of the International Union of Crystallography
  • Place of Presentation: 大阪グランキューブ
  • Year and Date: 2008-08-23
• [Presentation] デヒドロベンゾアヌレン誘導体を用いた超分子集合体の構築 (2008)
  • Author(s): 重光孟
  • Organizer: 高分子研究発表会
  • Place of Presentation: 神戸
  • Year and Date: 2008-07-18
• [Presentation] 9, 10-ジフェニルアントラセン誘導体の包接結晶におけるゲスト依存的固体発光変調 (2008)
  • Author(s): 田麦顕大
  • Organizer: 高分子研究発表会
  • Place of Presentation: 神戸
  • Year and Date: 2008-07-18
• [Presentation] Tunable solid-state luminescent colors based on molecular arrangements of ammonium anthracenedisulfonates (2008)
  • Author(s): Tomoaki Hinoue, Norimitsu Tohnai, Ichiro Hisaki, Mikiji Miyata
  • Organizer: Joint International Symposium on Macrocyclic & Supramolecular Chemistry
  • Place of Presentation: Las Vegas, Nevada, USA
  • Year and Date: 2008-07-16
• [Presentation] Supramolecular Tilt Chirality in Crystals of Steroids and Alkaloids (2008)
  • Author(s): Ichiro Hisaki
  • Organizer: Chiraity 2008
  • Place of Presentation: Geneva, Switzerland
  • Year and Date: 2008-07-09
• [Presentation] HIGH ENANTIOSELECTIVITY OF SECONDARY ALIPHATIC ALCOHOLS IN INCLUSION CRYSTALS OF 3-EPICHOLIC ACID DERIVATIVES (2008)
  • Author(s): Yute Kin
  • Organizer: Chirality 2008
  • Place of Presentation: Geneva, Switzerland
  • Year and Date: 2008-07-06
• [Presentation] 2-アントラセンスルホン酸トリフェニルメチルアミン塩による多孔質構造の構築とそのゲスト依存的な蛍光特性 (2008)
  • Author(s): 山本淳志
  • Organizer: ホストゲスト化学シンポジウム
  • Place of Presentation: 上智大学
  • Year and Date: 2008-05-31
• [Presentation] コール酸アミド包接結晶におけるゲスト交換と層構造の反転 (2008)
  • Author(s): 村井威俊
  • Organizer: 57回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2008-05-30
• [Presentation] 立体規則性固相重合を指向したジベンゾデヒドロ[12]アヌレン誘導体の分子配列制御 (2008)
  • Author(s): 重光孟
  • Organizer: 57回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2008-05-28
• [Presentation] ステロイドの結晶中におけるらせん構造とその超分子キラリティー (2008)
  • Author(s): 久木一朗, 他
  • Organizer: モレキュラーキラリティー2008
  • Place of Presentation: 岡山大学
  • Year and Date: 2008-05-22
• [Presentation] 3-エピコール酸誘導体のキラルな脂肪族第2級アルコール包接結晶におけるキラル認識 (2008)
  • Author(s): 金裕太
  • Organizer: モレキュラーキラリティー2008
  • Place of Presentation: 岡山大学
  • Year and Date: 2008-05-22
• [Presentation] キラルアミンとアントラセンジスルホン酸からなる超分子集合体の構築とその固体発光挙動 (2008)
  • Author(s): 樋上友亮
  • Organizer: モレキュラーキラリティー2008
  • Place of Presentation: 岡山大学
  • Year and Date: 2008-05-22
• [Presentation] シンコナアルカロイドとコール酸誘導体の共結晶における超分子集合様式 (2008)
  • Author(s): 志築宣江
  • Organizer: モレキュラーキラリティー2008
  • Place of Presentation: 岡山大学
  • Year and Date: 2008-05-22
• [Presentation] 胆汁酸誘導体包接結晶を用いた光学分割と層構造変化を伴うインターカレーション (2008)
  • Author(s): 村井威俊
  • Organizer: モレキュラーキラリティー2008
  • Place of Presentation: 岡山大学
  • Year and Date: 2008-05-22
• [Presentation] アントラセンジスルホン酸アンモニウム塩を用いた特異的配列に基づく多様な固体発光挙動 (2007)
  • Author(s): 樋上友亮、・藤内謙光・久木一朗・宮田幹二
  • Organizer: 光化学討論会
  • Place of Presentation: 信州大学
  • Year and Date: 2007-09-28
• [Presentation] Creation of the Supramolecular Chirality in[4+4]Cubic Ion-Pair Cluster (2007)
  • Author(s): Norimitsu Tohnai, Ichiro Hisaki, Mikiji Miyata
  • Organizer: International Conference Chirality at the Nanoscale
  • Place of Presentation: シッチェス・スペイン
  • Year and Date: 2007-09-18
• [Presentation] Creation of the Supramolecular Chirality in [4+4] Cubic Ion-Pair Cluster (2007)
  • Author(s): Norimitsu Tohnai
  • Organizer: International Conference Chirality at the Nanoscale
  • Place of Presentation: Sitges, Barcelona, Spain
  • Year and Date: 2007-09-18
• [Presentation] ビフェニルアントラセン誘導体のゲスト依存的蛍光変調と動的挙動 (2007)
  • Author(s): 藤内謙光
  • Organizer: 有機結晶シンポジウム
  • Place of Presentation: 千葉大学
  • Year and Date: 2007-09-07
• [Presentation] Concomitant Polymorphism in Dibenzodehydro [12] annulene with Methyl Ester Groups (2007)
  • Author(s): Ichiro Hisaki,
  • Organizer: 12th International Symposium on Novel Aromatic Combounds
  • Place of Presentation: Awaji, Hyogo, Japan
  • Year and Date: 2007-07-22
• [Presentation] Supramolecular Tilt Chirality Based on 21 Helical Assemblies (2007)
  • Author(s): Ichiro Hisaki,
  • Organizer: 19th International Symposium on Chirality
  • Place of Presentation: San Diego, USA
  • Year and Date: 2007-07-08
• [Book] 「次世代共役ポリマーの超階層制御と革新機能」超分子ポリマーの階層的構築および機能性ナノ空間に基づく革新的機能の創出と応用展開 (2009)
  • Author(s): 藤内謙光
  • Total Pages: 7
  • Publisher: シーエムシー出版
• [Book] 「Bottom-Up Nanofabrication」 Inclusion Compounds of Steroidal Molecules : Molecular Information and Their Expression Through Molecular Assemblie (2009)
  • Author(s): 藤内謙光
  • Total Pages: 24
  • Publisher: Amer. Sci. Pub
• [Book] 「次世代共役ポリマーの超階層制御と革新機能」超分子ポリマーの階層的構築および機能性ナノ空間に基づく革新的機能の創出と応用展開
  • Author(s): 藤内謙光、久木一朗、宮田幹二
  • Publisher: シーエムシー出版