Control of self-assembly using molecular designand the fabrication of novel nanostructured materials

• Project/Area Number: 18350077
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: Tokyo University of Science
• Principal Investigator: MATSUMOTO Mutsuyoshi Tokyo University of Science, 基礎工学部, 教授 (00358053)
• Project Period (FY): 2006 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥17,390,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥2,790,000); Fiscal Year 2009: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2008: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2007: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2006: ¥5,300,000 (Direct Cost: ¥5,300,000)
• Keywords: 自己組織化 / LB膜 / 相分離 / パターニング

Research Abstract

This project aimed at the fabrication of nanostructured materials using self-assembly, the clarification of the structures and functions of the nanostructured materials and the creation of novel nanostructured functionalized materials. The factors governing the phase-separated structures of mixed LB films were identified by changing the chemical structures of the components of the mixed LB films. This led to the development of a novel fabrication technique for nanoscale patterns. Templates were fabricated by using the mixed LB films and were used for the creation of novel nanostructured functionalized materials.

Research Products

• [Journal Article] Patterning of J-aggregated dyes using directed self-assembly on micro- and nanopatterned templates fabricated from phase-separated mixed Lanemuir-Blodeett films (2010)
  • Author(s): 渡邉智
  • Journal Title: J.Colloid Interface Sci. 343 Pages: 324-329
  • Peer Reviewed
• [Journal Article] Directed Self-Assembly of Gold Nanoparticles and Gold Thin Films on Micro-and Nanopatterned Templates Fabricated from Mixed Phase-Separated Langmuir-Blodgett Films (2009)
  • Author(s): S. Watanabe, H. Shibata, F. Sakamoto, R. Azumi, H. Sakai, M. Abe, M. Matsumoto
  • Journal Title: J. Mater. Chem. 19巻 Pages: 6796-6803
  • Peer Reviewed
• [Journal Article] Self-Assembled Arrays of Silica Particles on the Patterns Reflecting the Phase-Separated Structures of Mixed Langmuir-Blodgett Films (2009)
  • Author(s): 柴田裕史
  • Journal Title: Colloids and Surfaces A : Physicochem.Eng.Aspects 346 Pages: 58-60
  • Peer Reviewed
• [Journal Article] Directed Self-Assembly of Gold Nanoparticles and Gold Thin Films on Micro-and Nanopatterned Templates Fabricated from Mixed Phase-Separated Langmuir-Blodgett Films (2009)
  • Author(s): 渡邉智
  • Journal Title: J.Mater.Chem. 19 Pages: 6796-6803
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): 松本睦良
  • Journal Title: 自己組織化ハンドブック(株式会社エヌ・ティー・エス) Pages: 92-96
• [Journal Article] Matsumoto, Phase-Separated Structures of Mixed Langmuir-Blodgett Films of Fatty Acid and Hybrid Carboxylic Acid (2008)
  • Author(s): H. Kimura, S. Watanabe, H. Shibata, R. Azumi, H. Sakai, M. Abe, M
  • Journal Title: J. Phys. Chem. B 112巻 Pages: 15313-15319
  • Peer Reviewed
• [Journal Article] Micro-and Nano-Patterned Cupper Structures Using Directed Self-Assembly on Templates Fabricated from Phase-Separated Mixed Langmuir-Blodgett Films (2008)
  • Author(s): S. Watanabe, T. Kimura, T. Sato, H. Shibata, F. Sakamoto, R. Azumi, H. Sakai, M. Abe, M. Matsumoto
  • Journal Title: Langmuir 24巻 Pages: 8735-8741
  • Peer Reviewed
• [Journal Article] Nanowire Formation in Two-Component Mixed Langmuir-Blodgett Films of Fatty Acid and Silane-Coupling Agent (2008)
  • Author(s): T. Mazaki, H. Shibata, Y. Kondo, N. Yoshino, M. Matsumoto
  • Journal Title: Chem. Lett. 37巻 Pages: 480-481
  • NAID: 10021079997
  • Peer Reviewed
• [Journal Article] Phase-Separated Structures of Mixed Langmuir-Blodgett Films of Fatty Acid and Hybrid Carboxylic Acid (2008)
  • Author(s): H. Kimura, S. Watanabe, H. Shibata, R. Azumi, H. Sakai, M. Abe, M. Matsumoto
  • Journal Title: J. Phys. Chem. B 112巻 Pages: 15313-15319
  • Peer Reviewed
• [Journal Article] Micro- and Nano-Patterned Cupper Structures Using Directed Self-Assembly on Templates Fabricated from Phase-Separated Mixed Langmuir-Blodgett Films (2008)
  • Author(s): S. Watanabe, T. Kimura, T. Sato, H. Shibata, F. Sakamoto, R. Azumi, H. Sakai, M. Abe, M. Matsumoto
  • Journal Title: Langmuir 24巻 Pages: 8735-8741
  • Peer Reviewed
• [Journal Article] Nanowire Formation in Two-Component Mixed Langmuir-Blodgett Films of Fatty Acid and Silane-Coupling Agent (2008)
  • Author(s): 間崎卓明
  • Journal Title: Chem. Lett. 37 Pages: 480-481
  • Peer Reviewed
• [Journal Article] Micro- and Nano- Patterned Cupper Structures Using Directed Self-Assembly on Templates Fabricated from Phase-Separated Mixed Langmuir-Blodgett Films (2008)
  • Author(s): 渡邉 智
  • Journal Title: Langmuir 24 Pages: 8735-8741
  • Peer Reviewed
• [Journal Article] Phase-Separated Structures of Mixed Langmuir-Blodgett Films of Fatty Acid and Hybrid Carboxylic Acid (2008)
  • Author(s): 木村秀人
  • Journal Title: J. Phys. Chem. B 112 Pages: 15313-15319
  • Peer Reviewed
• [Journal Article] Phase-Separated Structures of Mixed LB Films of Silane Coupling Agents with Polymerization Initiating Groups and Amphiphilic Carboxylic Acids (2008)
  • Author(s): 石川貴智
  • Journal Title: Colloids and Surfaces A : Physicochem. Eng. Aspects 321 Pages: 76-81
  • Peer Reviewed
• [Journal Article] Control of Two-Dimensional Nanopatterns by Adjusting Intermolecular Interactions (2007)
  • Author(s): M. Matsumoto, S. Watanabe, K. Tanaka, H. Kimura, M. Kasahara, H. Shibata, R. Azumi, H. Sakai, M. Abe, Y. Kondo, N. Yoshino
  • Journal Title: Adv. Mater. 19巻 Pages: 3668-3671
  • Peer Reviewed
• [Journal Article] Photoreactions and Lateral Patterning in Langmuir and Langmuir-Blodgett Films (2007)
  • Author(s): M. Matsumoto
  • Journal Title: The Chemical Record 7巻 Pages: 69-77
  • Peer Reviewed
• [Journal Article] Photoreactions and Lateral Patterning in Langmuir and Langmuir-Blodgett Films (2007)
  • Author(s): 松本睦良
  • Journal Title: The Chemical Record 7 Pages: 69-77
  • Peer Reviewed
• [Journal Article] J会合体によるラングミュアーブロジェット膜のパターニング (2007)
  • Author(s): 中澤隆浩
  • Journal Title: 色材協会誌 80 Pages: 409-413
  • Peer Reviewed
• [Journal Article] Control of Two-Dimentional Nanopatterns by Adjusting Intermolecular Interactions (2007)
  • Author(s): 松本睦良
  • Journal Title: Advanced Materials 19 Pages: 3668-3671
  • Peer Reviewed
• [Journal Article] Langmuir-Bloodgett films of poly(phenylacetylene) derivative (2006)
  • Author(s): 高地清弘
  • Journal Title: Colloids and Surfaces A : Phjysicochem. Eng. Aspects 2006・284-285 Pages: 109-111
• [Journal Article] Hybrid Langmuir and Langmuir-Blodgett films composed of amphiphilic cyclodextrins and hydrophobic azobenzene derivative (2006)
  • Author(s): 松澤洋子
  • Journal Title: Thin Solid Films 510 Pages: 292-296
• [Presentation] 脂肪酸とシランカップリング剤からなる混合LB膜の相分離構造 (2009)
  • Author(s): 片山寛
  • Organizer: 第19回日本MRS学術シンポジウム
  • Place of Presentation: 横浜
  • Year and Date: 2009-12-09
• [Presentation] 脂肪酸, ハイプリットカルボン酸, シランカップリング剤を含む混合LB膜の相分離構造 (2009)
  • Author(s): 長島豊
  • Organizer: 第19回日本MRS学術シンポジウム
  • Place of Presentation: 横浜
  • Year and Date: 2009-12-09
• [Presentation] 相分離LB膜から作製した2次元パターン上における自己組織化を用いたシリカ粒子のパターニング (2009)
  • Author(s): 柴田裕史
  • Organizer: 第19回日本MRS学術シンポジウム
  • Place of Presentation: 横浜
  • Year and Date: 2009-12-09
• [Presentation] アラキジン酸、ハイブリッドカルボン酸を含む二成分LB膜の相分離構造 (2009)
  • Author(s): 太田佑
  • Organizer: 第19回日本MRS学術シンポジウム
  • Place of Presentation: 横浜
  • Year and Date: 2009-12-09
• [Presentation] 混合LB膜の相分離パターン上への自己組織化を用いたゾル・ゲル法を利用したチタニア薄膜のパターニング (2009)
  • Author(s): 野口俊介
  • Organizer: 第19回日本MRS学術シンポジウム
  • Place of Presentation: 横浜
  • Year and Date: 2009-12-09
• [Presentation] 製膜条件が混合LB膜の相分離構造に与える影響 (2009)
  • Author(s): 井上由葵
  • Organizer: 第19回日本MRS学術シンポジウム
  • Place of Presentation: 横浜
  • Year and Date: 2009-12-09
• [Presentation] Effect of Fabrication Condition on Phase-Separated Structures of Mixed Langmuir-Blodgett Films (2009)
  • Author(s): 柴田裕史
  • Organizer: 42nd IUPAC Congress
  • Place of Presentation: グラスゴー(英国)
  • Year and Date: 2009-08-05
• [Presentation] Preparation of Patterned Silica Particulate Films Using Directed Self-Assembly on the Templates Fabricated from Mixed LB Films (2008)
  • Author(s): 柴田裕史
  • Organizer: IUMRS-ICA 2008
  • Place of Presentation: 名古屋国際会議場(愛知)
  • Year and Date: 2008-12-12
• [Presentation] Phase-Separated Structures of Mixed Langmuir-Blodgett Films (2008)
  • Author(s): 松本睦良
  • Organizer: IUMRS-ICA 2008
  • Place of Presentation: 名古屋国際会議場(愛知)
  • Year and Date: 2008-12-12
• [Presentation] 5'位に置換基を有するスピロピランとアゾベンゼンの混合Langmuir-Blodgett膜の構造と光反応 (2008)
  • Author(s): 河崎 悠
  • Organizer: 2008年度材料技術研究討論会
  • Place of Presentation: 東京理科大学野田キャンパス(千葉)
  • Year and Date: 2008-12-06
• [Presentation] 成膜条件が混合LB膜の相分離構造に与える影響 (2008)
  • Author(s): 柴田裕史
  • Organizer: 2008年度材料技術研究討論会
  • Place of Presentation: 東京理科大学野田キャンパス(千葉)
  • Year and Date: 2008-12-06
• [Presentation] スピロピランとアゾベンゼンの混合Langmuir-Blodgett膜中での光照射によるJ会合体形成 (2008)
  • Author(s): 高松 崇
  • Organizer: 2008年度材料技術研究討論会
  • Place of Presentation: 東京理科大学野田キャンパス(千葉)
  • Year and Date: 2008-12-05
• [Presentation] Phase-Separated Structures of Mixed Langmuir-Blodgett Films Consisting of Fatty Acid, Hybrid Carboxylic Acid and Silane-Coupling Agent (2008)
  • Author(s): M. Matsumoto
  • Organizer: 17th International Symposium on Surfactants in Solution
  • Place of Presentation: ベルリン(ドイツ)
• [Presentation] Phase-Separated Structures of Two-Component Mixed Langmuir-Blodgett Films of Fatty Acid and Silane-Coupling Agent (2008)
  • Author(s): H. Katayama
  • Organizer: 17th International Symposium on Surfactants in Solution
  • Place of Presentation: ベルリン(ドイツ)
• [Presentation] 長鎖脂肪酸、ハイブリッドカルボン酸、シランカップリング剤からなる混合LB膜の相分離構造 (2008)
  • Author(s): 松本睦良
  • Organizer: 2008年度色材研究発表会
  • Place of Presentation: 名古屋市工業研究所
• [Presentation] Phase-Separated Structures of Mixed Langmuir-Blodgett Films Consisting of Fatty Acid, Hybrid Carboxylic Acid and Silane-Coupling Agent (2008)
  • Author(s): 松本睦良
  • Organizer: 17th International Symposium on Surfactants in Solution
  • Place of Presentation: Berlin Congress Centre (Berlin, Germany)
• [Presentation] Direct Patterning of Zirconia and Titania Thin Films Using the Templates Fabricated from Phase-Separated Langmuir-Blodgett Films (2008)
  • Author(s): 柴田裕史
  • Organizer: 17th International Symposium on Surfactants in Solution
  • Place of Presentation: Berlin Congress Centre (Berlin, Germany)
• [Presentation] Self-Assembled Arrays of Silica Particles on Templates Fabricated from Phase-Separated Langmuir-Blodgett Films (2008)
  • Author(s): 佐藤雅浩
  • Organizer: 17th International Symposium on Surfactants in Solution
  • Place of Presentation: Berlin Congress Centre (Berlin, Germany)
• [Presentation] Phase-Separated Structures of Two-Component Mixed Langmuir-Blodgett Films of Fatty Acid and Silane-Couplins Agent (2008)
  • Author(s): 片山 寛
  • Organizer: 17th International Symposium on Surfactants in Solution
  • Place of Presentation: Berlin Congress Centre (Berlin, Germany)
• [Presentation] 自己組織化による相分離混合LB膜へのコロイド粒子の配列制御 (2008)
  • Author(s): 松本睦良
  • Organizer: 第61回コロイドおよび界面化学討論会
  • Place of Presentation: 九州大学(福岡)
• [Presentation] 様々な加水分解基を有するシランカップリング剤と脂肪酸を用いた混合LB膜の相分離構造 (2008)
  • Author(s): 片山 寛
  • Organizer: 第61回コロイドおよび界面化学討論会
  • Place of Presentation: 九州大学(福岡)
• [Presentation] 長鎖脂肪酸、ハイブリッドカルボン酸、シランカップリング剤からなる混合LB膜の相分離構造 (2008)
  • Author(s): 松本睦良
  • Organizer: 2008年度色材研究発表会
  • Place of Presentation: 名古屋市工業研究所(愛知)
• [Presentation] 混合LB膜から調製した機能化テンプレートを用いた無機薄膜の直接パターニング (2008)
  • Author(s): 柴田裕史
  • Organizer: 2008年度色材研究発表会
  • Place of Presentation: 名古屋市工業研究所(愛知)
• [Presentation] Phase-Separated Structures of Mixed LB Films of Silane-Coupling Agents with Polymerization Initiating Groups and Amphiphilic Carboxylic Agent (2007)
  • Author(s): 松本睦良
  • Organizer: 12th International Conference on Organized Molecular Films
  • Place of Presentation: Krakow(Poland)
  • Year and Date: 2007-07-03
• [Presentation] Two-Dimensional Nanopatterns Using Templates Fabricated from Phase-Separated LB Films (2007)
  • Author(s): S. Watanabe
  • Organizer: 12th International Conference on Organized Molecular Films
  • Place of Presentation: Krakow (ポーランド)
• [Presentation] フッ化炭素素鎖を有するシランカップリング剤の合成と薄膜形成の詳細 (2007)
  • Author(s): 間崎卓明
  • Organizer: 第18回日本MRS学術シンポジウム
  • Place of Presentation: 日本大学(船橋)
• [Presentation] Two-Dimensional Nanopatterns Using Templates Fabricated from Phase-Separated LB Films (2007)
  • Author(s): S. Watanabe
  • Organizer: 12th International Conference on Organized Molecular Films
  • Place of Presentation: Krakow(ポーランド)
• [Presentation] フッ化炭素素鎖を有するシランカップリング剤の合成と薄膜形成の詳細 (2007)
  • Author(s): 間崎卓明
  • Organizer: 第18回日本MRS学術シンポジウム
  • Place of Presentation: 日大(船橋)
• [Book] 自己組織化ハンドブック (2009)
  • Author(s): 松本睦良
  • Publisher: 株式会社エヌ・ティー・エス
• [Book] Bottom-up Nanofabrication Volume 5 Organized Films (2009)
  • Author(s): M. Matsumoto
  • Publisher: American Scientific Publishers
• [Book] Bottom-up Nanofabrication Volume 5 Organized Films (2009)
  • Author(s): 松本睦良
  • Publisher: American Scientific Publishers
• [Book] 自己組織化ナノマテリアル-フロントランナー85人が語るナノテクノロジーの新潮流 (2007)
  • Author(s): 松本睦良
  • Publisher: フロンティア出版
• [Book] 自己組織化ナノマテリアル-フロントランナー85人が語るナノテクノロジーの新潮流- (2007)
  • Author(s): 松本睦良
  • Publisher: フロンティア出版