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Preparation of gelation-causing segments, development of polymer tpte of gelators containing the segments and their function evaluation

Research Project

Project/Area Number 18350115
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionShinshu University

Principal Investigator

HANABUSA Kenji  Shinshu University, 大学院・総合工学系研究科, 教授 (60126696)

Co-Investigator(Kenkyū-buntansha) SUZUKI MASAHIRO  信州大学, 大学院・総合工学系研究科, 准教授 (30334915)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥14,950,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2008: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2007: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2006: ¥7,800,000 (Direct Cost: ¥7,800,000)
Keywordsゲル / ゲル化剤 / 物理ゲル / ポリマー / 水素結合
Research Abstract

私たちがこれまで開発してきた特に強いゲル化能を示すゲル化剤の構造をもとに、官能基を有する新規なゲル化駆動セグメントを合成した。非晶性のポリマーあるいはオリゴマーとして安価な工業中間体であるポリウレタン原料の種々のポリジオールを利用した。開発したポリマー型ゲル化剤は汎用溶媒に対し良好なゲル化能を確認した。ポリマー型ゲル化剤であるので結晶化することはなく、半永久的に安定なゲルを形成した。化粧品用のゲル化剤として有用であることを実証した。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (60 results)

All 2009 2008 2007 2006

All Journal Article (31 results) (of which Peer Reviewed: 26 results) Presentation (28 results) Book (1 results)

  • [Journal Article] 低分子ゲル化駆動セグメントを導入したポリマー型ゲル化剤の開発2009

    • Author(s)
      星沢裕子、小河睦、鈴木正浩、白井汪芳、英謙二、永井直、中井一宙
    • Journal Title

      繊維学会誌 65巻

      Pages: 103-109

    • NAID

      10024770433

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Gels Formed by Amphiphilic Low-Molecular-Weight Gelators of N^α, N^ε-Diacyl-L-Lysine Derivatives2008

    • Author(s)
      M. Suzuki, M. Yumoto, H. Shirai, K. Hanabusa
    • Journal Title

      Chem.Eur.J 14

      Pages: 2133-2144

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Polymer Organogelators with L-Isoleucine and L-Valine as a Gelation-Causing Segment : Organogelation by a Combination of Supramolecular Polymer and Conventional Polymer2008

    • Author(s)
      M. Suzuki, R. Yanagida, C. Setoguchi, H. Shirai, K. Hanabusa
    • Journal Title

      J.Polym.Sci.Part A : Polym.Chem 46

      Pages: 353-361

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A family of low-molecular-weight organogelators based on N^α, N^ε-diacyl-L-lysine : Effect of alkyl chains on their organogelation behaviour2008

    • Author(s)
      M. Suzuki, M. Yumoto, H. Shirai K. Hanabusa
    • Journal Title

      Tetrahedron 64

      Pages: 10395-10400

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hybrid silica nanotubes with chiral walls2008

    • Author(s)
      Y. Chen, B. Li, X. Wu, Z. Zhu, M. Suzuki, K. Hanabusa
    • Journal Title

      Y. Yang, Chem. Commun 49

      Pages: 48-4950

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Polymer Organogelators with L-Isoleucine, L-Valine as a Gelation-Causing Segment : Organogelation by a Combination of Supramolecular Polymer and Conventional Polymer2008

    • Author(s)
      M. Suzuki, R. Yanagida, C. Setoguchi, H. Shirai, K. Hanabusa
    • Journal Title

      J. Polym. Sci. Part A : Polym. Chem. 46

      Pages: 353-361

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Gels Formed by Amphiphilic Low-Molecular-Weight Gelatorsof Nα, Nε-Diacyl-L-Lysine Derivatives2008

    • Author(s)
      M. Suzuki, M. Yumoto. H. Shirai, K. Hanabusa
    • Journal Title

      Chem. Eur. J. 14

      Pages: 2133-2144

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A family of low-molecuiar-weight organogelators based on N□, N□-diacyl-L-1ysine : Effect of alkyl chains on their organogelation behavior2008

    • Author(s)
      M. Suzuki, M. Yumoto. H. Shirai, K. Hanabusa
    • Journal Title

      Tetrahedron 64

      Pages: 10395-10400

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hybrid silica nanotubes with chiral walls2008

    • Author(s)
      Y. Chen, B. Li, X. Wu, Z. Zhu, M. Suzuki, K. Hanabusa, Y, Yana
    • Journal Title

      Chem. Commun 2008

      Pages: 4948-4950

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The formation of helical mesoporous silica nanotubes2008

    • Author(s)
      X. Wan, X. Pei, H. Zhao, Y. Chen, Y. Guo, B. Li, K. Hanabusa, Y. Yang
    • Journal Title

      Nanotechnology 19

      Pages: 315-319

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Mesoporous Silica Nanostructures and Pore- Architectures Using a Thickener and a Gelator2007

    • Author(s)
      Y. Yang, M. Suzuki, S. Owa, H. Shirai, K. Hanabusa
    • Journal Title

      J.Am.Chem.Soc 129

      Pages: 581-587

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Hydrogel Formed by Glucoheptonamide of L-Lysine : Simple Preparation and Excellent Hydrogelation Ability2007

    • Author(s)
      M. Suzuki, S. Owa, H. Shirai, K. Hanabusa
    • Journal Title

      Tetrahedron 63

      Pages: 7302-7308

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of helical hybrid silica bundles2007

    • Author(s)
      Y. Yang, M. Nakazawa, M. Suzuki, H. Shirai, K. Hanabusa
    • Journal Title

      J.Mater Chem 17

      Pages: 2936-2943

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Organogelation by Novel Polymer Organogelators with L-Lysine Derivative : The Formation of a Three-Dimensional Network Consisting of Supramolecular Polymer and Conventional Polymer2007

    • Author(s)
      M. Suzuki, C. Setoguchi, H. Shirai, K. Hanabusa
    • Journal Title

      Chem.Eur.J 13

      Pages: 8193-8200

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cationic surfactanttriggered formation of a supramolecular hydrogel by a negatively charged L-valine derivative2007

    • Author(s)
      M. Suzuki, T. Sato, H. Shirai, K. Hanabusa
    • Journal Title

      New J.Chem 31

      Pages: 69-74

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Organogel Formation Triggered by Acid-Base Interaction in Two-Component System Consisting of L-Lysine Derivative and Aliphatic Acids2007

    • Author(s)
      M. Suzuki, H. Saito, H. Shirai, K. Hanabusa
    • Journal Title

      New J.Chem 31

      Pages: 1654-1660

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cationic surfactant-triggered formation of a supramolecular hydrogelby a negatively charged L-valine derivative2007

    • Author(s)
      M. Suzuki, T. Sato, H. Shirai, K. Hanabusa
    • Journal Title

      New J. Chem. 31

      Pages: 69-74

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular hydrogel formed by glucoheptonamide of L-lysine: simplepreparation and cxellent hydrogelation ability2007

    • Author(s)
      M. Suzuki, S. Owa, H. Shirai, K. Hanabusa
    • Journal Title

      Tetrahedron 63

      Pages: 7302-7308

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular organogel formation triggered by acid-base interaction in two-component system consisting of L-lysine derivative and aliphatic acids2007

    • Author(s)
      M. Suzuki, T. Sato, H. Shirai, K. Hanabusa
    • Journal Title

      New J. Chem. 31

      Pages: 1654-1660

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organogelation by polymer organogelatotrs with a L-lysine derivative: Foramation of a three-dimensional network consisting of supramolecular and conventional polymers2007

    • Author(s)
      M. Suzuki, C. Setoguchi, H. Shirai, K. Hanabusa
    • Journal Title

      Chem. Eur. J 13

      Pages: 8193-8200

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of TiO_2 using L-lysine-based organogelators as organic templates : control of the nanostructures2006

    • Author(s)
      M. Suzuki, Y. Nakajima, T. Sato, H. Shirai, K. Hanabusa
    • Journal Title

      Chem. Commun

      Pages: 377-379

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Helical Mesoporous Silica and Hybrid Silica Nanofibers Using Hydrogelator2006

    • Author(s)
      Y. Yang, M. Suzuki, H. Fukui, H. Shirai, K. Hanabusa
    • Journal Title

      Chem.Mater 18

      Pages: 1324-1329

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Poly(dimethylsiloxane)-Based Polymer Organogelators with L-Lysine Derivatives as a Organogelation-Causing Segment2006

    • Author(s)
      M. Suzuki, S. Owa, H. Shirai, K. Hanabusa
    • Journal Title

      J.Polym.Sci.Part A : Polym.Chem 44

      Pages: 3817-3824

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control of helical silica nanostructures using a chiral surfactant2006

    • Author(s)
      Y. Yang, M. Suzuki, S. Owa, H. Shirai, K. Hanabusa
    • Journal Title

      J.Mater.Chem 16

      Pages: 1644-1650

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Powerful low-molecularweight gelators based on L-valine and L-isoleucine with various terminal groups2006

    • Author(s)
      M. Suzuki, T. Sato, H. Shirai, K. Hanabusa
    • Journal Title

      New J.Chem 30

      Pages: 1184-1191

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of metal oxide Nanotubes Using Gelators as Structure-Directing Agents2006

    • Author(s)
      K. Hanabusa, T. Numazawa, S. Kobayashi, M. Suzuki, H. Shirai
    • Journal Title

      Macromol. Symp 235

      Pages: 52-56

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Poly(dimethylsiloxane)-Based Polymer Organogelators with L-Lysine Derivatives as Organogelation-Causing Segment2006

    • Author(s)
      M.Suzuki, S.Owa, H.Shirai, K.Hanabusa
    • Journal Title

      J. Polym. Sci. Polym. Chem. 44

      Pages: 3817-3824

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fabrication of TiO2 using L-lysine-based organogelators as organic templates : control of the nanostructure2006

    • Author(s)
      M.Suzuki, Y.Nakajima, T.Sato, H.Shirai, K.Hanabusa
    • Journal Title

      Chem. Commun.

      Pages: 377-379

    • Related Report
      2006 Annual Research Report
  • [Journal Article] ゲル化剤に見る自己組織化現象2006

    • Author(s)
      英謙二, 白井汪芳
    • Journal Title

      繊維と工業 62

      Pages: 109-113

    • NAID

      10018110363

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Oreparation of Metal Oxide Nanotubes Using Gelators as Structure-Directing Agents2006

    • Author(s)
      K.Hanabusa, T.Numazawa, S.Kobayashi, M.Suzuki, H.Shirai
    • Journal Title

      Macromol. Symp. 2

      Pages: 52-56

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Preparation of Helical Mesoporous Silica and Hybrid Silica Nanofibers Using Hydrogelator2006

    • Author(s)
      Y.Yong, M.Suzuki, H.Fukui, H.Shirai, K.Hanabusa
    • Journal Title

      Chem. Mater. 18

      Pages: 1324-1329

    • Related Report
      2006 Annual Research Report
  • [Presentation] L-アミノ酸を基盤とした両性イオン型低分子ゲル化剤の開発2008

    • Author(s)
      谷村咲, 鈴木正浩, 白井汪芳, 英謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      大阪・大阪市立大学
    • Year and Date
      2008-09-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] 低分子増粘剤として作用する5-アミノフタル酸誘導体2008

    • Author(s)
      船津絵里子, 鈴木正浩, 白井汪芳, 英謙二, 藤内謙光, 宮田幹二
    • Organizer
      高分子討論会
    • Place of Presentation
      大阪・大阪市立大学
    • Year and Date
      2008-09-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] ポリエチレングリコール鎖を持つL-イソロイシン型高分子ゲル化剤の特性2008

    • Author(s)
      岸幸代、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-25
    • Related Report
      2008 Final Research Report
  • [Presentation] ポリエチレングリコール鎖を持つL-イソロイシン型高分子ゲル化剤の特性2008

    • Author(s)
      岸幸代, 鈴木正浩, 白井汪芳, 英謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      大阪・大阪市立大学
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] L-リシン誘導体を有するポリエステル系高分子有機ゲル化剤2008

    • Author(s)
      瀬戸口千穂、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-30
    • Related Report
      2008 Final Research Report
  • [Presentation] L-リシン誘導体とN-ドデシルーL-アミノ酸から成る2成分系低分子有機ゲル化剤の開発2008

    • Author(s)
      齊藤宏明, 鈴木正浩, 白井汪芳, 英謙二
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      横浜・パシフイコ横浜
    • Year and Date
      2008-05-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 化粧品等への応用を目的とした環状ジペプチド誘導体を基盤とするゲル化剤の開発2008

    • Author(s)
      星沢裕子, 鈴木正浩, 英謙二
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      横浜・パシフイコ横浜
    • Year and Date
      2008-05-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] L-アミノ酸エステルの有機塩型低分子ゲル化剤2008

    • Author(s)
      丸山祐佳里、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-29
    • Related Report
      2008 Final Research Report
  • [Presentation] 両性イオン型低分子ゲル化剤の開発とゲルの評価2008

    • Author(s)
      谷村咲、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-29
    • Related Report
      2008 Final Research Report
  • [Presentation] L-リシン誘導体を有するポリエステル系高分子有機ゲル化剤2008

    • Author(s)
      瀬戸口千穂, 鈴木正浩, 白井汪芳, 英謙二
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      横浜・パシフイコ横浜
    • Year and Date
      2008-05-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] L-アミノ酸エステルの有機塩型低分子ゲル化剤2008

    • Author(s)
      丸山祐佳里, 鈴木正浩, 白井汪芳, 英謙二
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      横浜・パシフイコ横浜
    • Year and Date
      2008-05-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] チキソトロピー性を示すシロキサン含有ゲル化剤の開発2008

    • Author(s)
      星沢裕子、鈴木正浩、白井汪芳、英謙二
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
    • Related Report
      2008 Final Research Report
  • [Presentation] L-イソロイシンおよびL-バリンを基盤とした高分子型ゲル化剤の開発2008

    • Author(s)
      岸幸代、鈴木正浩、白井汪芳、英謙二
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-28
    • Related Report
      2008 Final Research Report
  • [Presentation] ゲル化駆動セグメントを導入したポリオレフィン型ゲル化剤の開発2007

    • Author(s)
      英謙二、小河睦、鈴木正浩、白井汪芳
    • Organizer
      平成19年度繊維学会秋季研究発表会
    • Place of Presentation
      京都
    • Year and Date
      2007-10-26
    • Related Report
      2008 Final Research Report
  • [Presentation] ゲル化駆動セグメントを導入したポリオレフィン型ゲル化剤の開発2007

    • Author(s)
      英謙二、小河睦、鈴木正浩、白井汪芳
    • Organizer
      繊維学会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2007-10-26
    • Related Report
      2007 Annual Research Report
  • [Presentation] L-バリンおよびL-イソロイシンを持つ高分子有機ゲル化剤2007

    • Author(s)
      鈴木正浩、柳田亮介、瀬戸口千穂、白井汪芳、英謙二
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] ゲル化駆動セグメントにL-アミノ酸誘導体を用いたポリビニルピリジン型ゲル化剤の合成と特徴2007

    • Author(s)
      太田佑樹、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] 低分子ゲル化剤を用いた酸含有極性溶媒のゲル化とその性質2007

    • Author(s)
      木村大輔、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] 低分子ゲル化剤を用いたナノ構造を持つ酸化チタンの調製とその光触媒活性2007

    • Author(s)
      菊池正寛、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] オレフィンオリゴマーを用いた新規ゲル化剤の開発2007

    • Author(s)
      小河睦、鈴木正浩、白井汪芳、英謙二、永井直、中井一宙
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] L-アミノ酸誘導体による液晶のゲル化2007

    • Author(s)
      中島正志・鈴木正浩・白井汪芳・英謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 低分子ゲル化剤をテンプレートにした中空繊維状金属酸化物の調整2007

    • Author(s)
      小河睦・鈴木正浩・白井汪芳・英謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] L-イソロイシン型ゲル化剤をテンプレートとして金属ナノ繊維の調製2007

    • Author(s)
      沖山敦・鈴木正浩・白井汪芳・英 謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 5-アミノイソフタル酸誘導体の増粘作用とゲル化2007

    • Author(s)
      船津絵里子・鈴木正浩・白井汪芳・英謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] チキソトロピー性を示すシロキサン含有ゲル化剤の開発2007

    • Author(s)
      星沢裕子・鈴木正浩・白井汪芳・英謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] L-リシン誘導体を持つポリエチレングリコール系高分子ゲル化剤2007

    • Author(s)
      瀬戸口千穂・鈴木正浩・白井汪芳・英謙二
    • Organizer
      高分子討論会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2007-09-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 糖を有するL-リシン誘導体を基盤とした双頭型ハイドロゲル化剤2007

    • Author(s)
      窪田はる香、鈴木正浩、白井汪芳、英謙二
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2007-03-26
    • Related Report
      2008 Final Research Report
  • [Presentation] ゲル化駆動部位にL-リシン誘導体を用いた高分子ゲル化剤2006

    • Author(s)
      瀬戸口千穂、鈴木正浩、白井汪芳、英謙二
    • Organizer
      第55回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2006-05-25
    • Related Report
      2008 Final Research Report
  • [Book] ゲル化剤をテンプレートとしたシリカ合成(246-261ページを分担執筆)2007

    • Author(s)
      英謙二
    • Total Pages
      16
    • Publisher
      シーエムシー出版
    • Related Report
      2007 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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