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Control of high ordered structure and hierarchy for polymer electrolytes

Research Project

Project/Area Number 18350121
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionSophia University

Principal Investigator

RIKUKAWA Masahiro  Sophia University, 理工学部, 教授 (10245798)

Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥17,230,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2008: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2007: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2006: ¥6,700,000 (Direct Cost: ¥6,700,000)
Keywords高分子電解質 / 燃料電池 / プロトン伝導 / 共重合 / 相分離 / 階層化 / プロトン / 伝導性 / AFM / アノード / 直接メタノール形燃料電池 / フラーレン
Research Abstract

化学的な手法により高分子電解質における高次構造制御を確立し、さらに物理的な手法により、高分子電解質の階層化を試みた。系統的なブロック型の炭化水素系高分子電解質の合成に成功し、さらに製膜法の改良により、高次構造制御と階層化が可能になった。その結果として、今までの一次構造による材料検討では成しえなかった性能のトレードオフの関係を打破し、幅広い温度、湿度域で高い発電能力を示す高分子電解質が得られた。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (28 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (13 results) (of which Peer Reviewed: 11 results) Presentation (7 results) Book (4 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Hydration Behavior of Perfluorinated and Hydrocarbon-Type Proton Exchange Membranes: Relationship between Morphology and Proton Conduction2008

    • Author(s)
      N. Takimoto, L. Wu, A. Ohira, Y. Takeoka, M. Rikukawa
    • Journal Title

      Polymer 50

      Pages: 534-540

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface Morphology and Proton Conduction Imaging of Nafion Membrane2008

    • Author(s)
      N. Takimoto, A. Ohira, Y. Takeoka, M. Rikukawa
    • Journal Title

      Chem. Lett. 37

      Pages: 164-165

    • NAID

      10021077397

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lipase-catalyzed polymerization of L-lactide in ionicliquids2008

    • Author(s)
      M. Yoshizawa-Fujita, 他4名
    • Journal Title

      Polym. Adv. Technol. 19

      Pages: 1396-1400

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular recognition of Langmuir-Blodgett polymer films containing uracil groups2008

    • Author(s)
      N. Sugiyama, 他5名
    • Journal Title

      Colloids and Surfaces, A 321

      Pages: 60-64

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydration behavior of perfluorinated and hydrocarbon-type proton exchange membranes2008

    • Author(s)
      N. Takimoto, 他5名
    • Journal Title

      Polymer 50

      Pages: 534-540

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface morphology and proton conduction imaging of Nafionmembrane2008

    • Author(s)
      N. Takimoto, 他3名
    • Journal Title

      Chemistry Letter 37

      Pages: 164-165

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] イオン液体中における酵素触媒重合2008

    • Author(s)
      藤田 正博, 他1名
    • Journal Title

      化学工業 59

      Pages: 222-226

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ring-opening Bulk Polymerization of L-Lactide in Porous Hydroxyapatite2007

    • Author(s)
      N. Sugiyama, R. Kunibu, M. Yoshizawa-Fujita, Y. Takeoka, M. Aizawa, M. Rikukawa
    • Journal Title

      Chem. Lett. 36

      Pages: 1476-1477

    • NAID

      10020012134

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ring-opening bulk polymerization of L-lactide in porous hydroxyapatite2007

    • Author(s)
      N. Sugiyama, 他5名
    • Journal Title

      Chemistry Letter 36

      Pages: 1476-1477

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Systematic Studies on Chain Lengths, Halide Species, and Well Thicknesses for Lead Halide Layered Perovskit Thin Films2006

    • Author(s)
      Y. Takeoka, K. Asai, M. Rikukawa, K. Sanui
    • Journal Title

      Bull. Chem. Soc. Jpn 79

      Pages: 1607-1613

    • NAID

      10020528427

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Systematic Studies on Chain Lenghts, Halide Species, and Well Thicknesses for Lead Halide Layered Perovskit Thin Films2006

    • Author(s)
      Y.Tkeoka 他3名
    • Journal Title

      Bulletin of the Chemical Society of Japan 79

      Pages: 1607-1613

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fabrication of Artificial bone Materials Using Bioceramics and Polymers Having Phosphoric Acid Groups2006

    • Author(s)
      N.Sugiyama 他4名
    • Journal Title

      Archives of BioCeramics Research 6

      Pages: 315-318

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Intercalated Formation of Two-Dimensional and Multi-layered Perovskites in Organic Thin Films2005

    • Author(s)
      Y. Takeoka, M. Fukasawa, T. Matsui, K. Kikuchi, M. Rikukawa, K. Sanui
    • Journal Title

      Chem. Commun.

      Pages: 378-379

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Presentation] Preparation and characterization of phosphonium-based ionicliquid/hydroxide composites2008

    • Author(s)
      A. Itani, 他4名
    • Organizer
      Materials Research Society Fall meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2008-12-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高分子電解質の高次構造制御とPEFC特性の関係2008

    • Author(s)
      陸川政弘
    • Organizer
      高分子学会燃料電池材料研究会講座
    • Place of Presentation
      化学会館
    • Year and Date
      2008-10-02
    • Related Report
      2008 Final Research Report
  • [Presentation] 炭化水素系高分子電解質膜の構造と機能の関係2008

    • Author(s)
      陸川政弘
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-27
    • Related Report
      2008 Final Research Report
  • [Presentation] Super-hierarchical Structures and Their Properties Fabricated by Fullerene Derivatives2007

    • Author(s)
      M. Rikukawa
    • Organizer
      The 2nd International Workshop on Super-Hierarchical Structures
    • Place of Presentation
      Osaka University
    • Year and Date
      2007-09-30
    • Related Report
      2008 Final Research Report
  • [Presentation] 燃料電池用高分子電解質膜:デザインと機能2007

    • Author(s)
      陸川政弘
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-31
    • Related Report
      2008 Final Research Report
  • [Presentation] 燃料電池用高分子電解質膜:デザインと機能2007

    • Author(s)
      陸川 政弘
    • Organizer
      第56回高分子学会年次大会(招待講演)
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-31
    • Related Report
      2007 Annual Research Report
  • [Presentation] 炭化水素系高分子電解質のデザイン2006

    • Author(s)
      陸川政弘
    • Organizer
      第15回ポリマー材料フォーラム
    • Place of Presentation
      千里ライフサイエンスセンター
    • Year and Date
      2006-11-16
    • Related Report
      2008 Final Research Report
  • [Book] 次世代共役ポリマーの超階層制御と革新機能2009

    • Author(s)
      竹岡裕子、陸川政弘
    • Publisher
      CMC出版
    • Related Report
      2008 Final Research Report
  • [Book] 次世代共役ポリマーの超階層制御と革新機能2009

    • Author(s)
      赤木和夫, 他
    • Publisher
      シーェムシー出版
    • Related Report
      2008 Annual Research Report
  • [Book] 機能物質の集積膜と応用展開2006

    • Author(s)
      陸川政弘
    • Publisher
      CMC出版
    • Related Report
      2008 Final Research Report
  • [Book] 機能物質の集積膜と応用展開"半導体-有機層状複合体と光学機能"2006

    • Author(s)
      陸川政弘 他1名
    • Total Pages
      12
    • Publisher
      CMC
    • Related Report
      2006 Annual Research Report
  • [Remarks]

    • URL

      http://www.ch.sophia.ac.jp/polymer/

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.ch.sophia.ac.jp/polymer/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.ch.sophia.ac.jp/polymer/

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] プロトン伝導性を有する固体高分子電解質膜とその製造方法2007

    • Inventor(s)
      川原光泰、高見昌宜、陸川政弘、竹岡裕子、藤田正博
    • Industrial Property Rights Holder
      トヨタ自動車株式会社
    • Filing Date
      2007-03-07
    • Related Report
      2008 Final Research Report

URL: 

Published: 2006-04-01   Modified: 2016-04-21  

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