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Design Methodology of Thin Electrytes for the Development of Intermediate Temperature SOFCs

Research Project

Project/Area Number 18360053
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Materials/Mechanics of materials
Research InstitutionTohoku University

Principal Investigator

HASHIDA Toshiyuki  Tohoku University, 大学院・工学研究科, 教授 (40180814)

Co-Investigator(Kenkyū-buntansha) MIZUSAKI Junichro  東北大学, 多元物質科学研究所, 教授 (90092345)
YUGAMI Hiroo  東北大学, 大学院・工学研究科, 教授 (60192803)
KAWADA Tatsuya  東北大学, 大学院・環境科学研究科, 教授 (10271983)
SATO Kazuhisa  東北大学, 多元物質科学研究所, 助教 (50422077)
高橋 亨  東北大学, 大学院工学研究科, 助手 (50323051)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥17,260,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥2,460,000)
Fiscal Year 2008: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2007: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2006: ¥6,600,000 (Direct Cost: ¥6,600,000)
Keywords材料設計 / プロセス / 物性 / 評価 / 固体酸化物燃料電池 / 低温作動温度化 / 薄膜化 / ナノボア制御 / 特性評価システム / 機械的耐久性 / 電気的性能 / 設計法 / ナノポア制御
Research Abstract

固体酸化物燃料電池(SOFC)の機械的信頼性を向上させることを目的として, スプレー法を用いた電解質の簡易な薄膜化法を開発するとともに, SOFC機器要素の小型パンチ試験法を用いた弾性率や破壊強度などの機械的特性評価法, ならびにAE法を併用したSOFC単セルの信頼性評価法の開発を行い, これらの知見を総合することにより, 比較的低温で高いイオン導電性を示すガドリニアを添加したセリア系セラミックスを電解質とするSOFCを対象として電解質薄膜の厚みを最適にする方法を提案した.

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (43 results)

All 2008 2007 2006 Other

All Journal Article (22 results) (of which Peer Reviewed: 18 results) Presentation (20 results) Remarks (1 results)

  • [Journal Article] 固体酸化物燃料電池の損傷に及ぼす化学膨張の影響2008

    • Author(s)
      佐藤一永, 八代圭司, 橋田俊之, 川田達也, 湯上浩雄, 水崎純一郎
    • Journal Title

      日本機械学会論文集(A編) Vol.74,No.737

      Pages: 68-74

    • NAID

      110006571946

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Chemically-induced Expansion on Damage of Solid Oxide Fuel Cell2008

    • Author(s)
      Kazuhisa Sato, Kenji Yashiro, Toshiyuki Hashida, Tatsuya Kawada, Hiroo Yugami and Junichiro Mizusaki
    • Journal Title

      Transactions of the Japan Society of Mechanical Engineers Vol.74,No.737

      Pages: 68-74

    • NAID

      110006571946

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nanometer NiO-Ce_<0.8>Sm_<0.2>O_<1.9> Composite Nanopowders for Solid Oxide Fuel Cells2008

    • Author(s)
      Changsheng DING, H. Lin, Kazuhisa SATO, Toshiyuki HASHIDA
    • Journal Title

      5^<th> International Workshop on Water Dynamics(Sendai, Japan, September 25-27, 2007), AIP Conference Proceedings Vol.987

      Pages: 30-34

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Nanometer La_<0.8>Sr_<0.2>Co_<0.8>Fe_<0.2>O_3 Nanoparticles for Intermediate-Low Temperature Solid Oxide Fuel Cells2008

    • Author(s)
      Changsheng DING, H. Lin, Kazuhisa SATO, Toshiyuki HASHIDA
    • Journal Title

      5^<th> International Workshop on Water Dynamics,(Sendai, Japan, September 25-27, 2007), AIP Conference Proceedings Vol.987

      Pages: 35-38

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ni-GDC Anode-Supported Ceria Electrolyte Film and Its Application in Solid Oxide Fule Cells2008

    • Author(s)
      H. Lin, C. Ding, K. Kumada, K. Sato, Y. Tsutai, C. Wada,and T. Hashida
    • Journal Title

      5^<th> International Workshop on Water Dynamics,(Sendai, Japan, September 25-27, 2007), AIP Conference Proceedings Vol.987

      Pages: 54-57

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Application of AE Technique in Performance Evaluation of Anode-supported Ceria Electrolyte Thin Film-based SOFCs2008

    • Author(s)
      H. Lin, C. Ding, K. Kumada, K. Sato, Y. Tsutai, C. Wada,and T. Hashida
    • Journal Title

      5^<th> International Workshop on Water Dynamics,(Sendai, Japan, September 25-27, 2007), AIP Conference Proceedings Vol.987

      Pages: 163-166

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Application of AE Technique in Performance Evaluation of Anode-supported Ceria Electrolyte Thin Film-based SOFCs2008

    • Author(s)
      H. Lin, et.al.
    • Journal Title

      AIP Conference Proceedings 987

      Pages: 163-166

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体酸化物燃料電池の損傷に及ぼす化学膨張の影響2008

    • Author(s)
      佐藤一永, 八代圭司, 橋田俊之, 川田達也, 湯上浩雄, 水崎純一朗
    • Journal Title

      日本機械学会論文集(A編) 74

      Pages: 68-74

    • NAID

      110006571946

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nanometer NiO-Ce_<0.8>Sm_<0.2>O_<1.9>Composite Nanopowders for Solid Oxide Fuel Cells2008

    • Author(s)
      C. Ding, H. Lin, K. Sato, T. Hashida
    • Journal Title

      AIP Conference Proceedings 987

      Pages: 30-34

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体酸化物燃料電池の損傷に及ぼす化学膨張の影響2008

    • Author(s)
      佐藤一永, 他
    • Journal Title

      日本機械学会論文集(A編) 74,737

      Pages: 68-74

    • NAID

      110006571946

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nanometer NiO-Ce_<0.8>Sm_<0.2>0_<1.9> Composite Nanopowders for Solid Oxide Fuel Cells2008

    • Author(s)
      C. DING, et. al.
    • Journal Title

      AIP Conference Proceedings 987

      Pages: 30-34

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Nanometer La_<0.8>Sr_<0.2>Co_<0.8>Fe_<0.2>O_3 Nanoparticles for Intermediate-Low Temperature Solid Oxide Fuel Cells2008

    • Author(s)
      C. DING, et. al.
    • Journal Title

      AIP Conference Proceedings 987

      Pages: 35-38

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Autocombustion synthesis of La_<0.6>Sr_<0.4>Co_<0.2>Fe_<0.8>O_<3-□>(LSCF)perovskite nanosized powder via modified sol-gel route2007

    • Author(s)
      Hongfei Lin, Changsheng Ding, Kazuhisa Sato, Yoshifumi Tsutai, Chiharu Wada and Toshiyuki Hashida
    • Journal Title

      Proc.of 1st Int.Sympo. on Aqua Science, Water Resource and Innovation Development of Countryside,(Sakawa, Kochi, Japan, November 26-30, 2007)

      Pages: 297-302

    • Related Report
      2008 Final Research Report
  • [Journal Article] Microstructural Changes of Ni/YSZ Cermet under Repeated Redox Reaction in Environmental Scanning Electron Microscope(ESEM)2007

    • Author(s)
      Y.Nakagawa, K.Yashiro, K.Sato, T.Kawada, J.Mizusaki
    • Journal Title

      Electrochemical Society transactions Vol.7,No.1

      Pages: 1373-1380

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reliability Evaluation of SOFC under Simulated Operating Condition2007

    • Author(s)
      K.Sato, N.Imanaka, K.Fukui, M.Numao, S.Kyotani, K.Yashiro, T.Kawada, T.Hashida, J.Mizusaki
    • Journal Title

      Electrochemical Society transactions Vol.7,No.1

      Pages: 455-458

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tracking the onset of Damage Mechanism in Ceria-based Solid Oxide Fuel Cells under Simulated Operating Conditions2006

    • Author(s)
      Kazuhisa Sato, Hajime Omura, Toshiyuki Hashida, Keiji Yashiro, Tatsuya Kawada, Junichiro Mizusaki, Hiroo Yugami
    • Journal Title

      Journal of Testing and Evaluation Vol.34,No.3

      Pages: 246-250

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characteristics of Damage and Fracture Process of Solid Oxide Fuel Cells Under Simulated Operating Conditions By Using AE Method2006

    • Author(s)
      Kazuhisa Sato, Toshiyuki Hashida, Hiroo Yugami, Kenji Yashiro, Tatsuya Kawada, Junichiro Mizusaki
    • Journal Title

      Journal of Acoustic Emission Vol.24

      Pages: 215-221

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Mechanical Load on the Electrical Property of Yttria-Stabilized Zirconia2006

    • Author(s)
      Kazuhisa.Sato, R.Narumi, K.Yashiro, T.Kawada, H.Yugami, T.Hashida, J.Mizusaki
    • Journal Title

      Electrochemistry and Thermodynamics on Materials Processfor Sustainable Production, Masko Symposium

      Pages: 823-827

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A New Method for Evaluating Degradation of Solid Oxide Fuel Cell under Operating Conditions by Combining the Electrochemical Measuement with Non-Destructive Test2006

    • Author(s)
      Kazuhisa Sato, Shintaro Kyotani, Toshiyuki Hashida, Hirokazu Moriya, Tatsuya Kawada, Keiji Yashiro, Takashi Nakamura, Hiroo Yugami, Junichiro Mizusaki
    • Journal Title

      Proceedings of Asian Symposium on Materials and Processing 2006

      Pages: 132-132

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tracking the onset of Damage Mechanism in Ceria-based Solid Oxide Fuel Cells under Simulated Operating Conditions2006

    • Author(s)
      Kazuhisa Sato, et al.
    • Journal Title

      Journal of Testing and Evaluation 34・3

      Pages: 246-250

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Characterization of Damage and Fracture Process of Solid oxide Fuel Cells Under Simulated Operating Conditions by Using AE Method2006

    • Author(s)
      Kazuhisa Sato, et al.
    • Journal Title

      Progress in Acoustic Emission XIII, The Japanese Society for NDI

      Pages: 269-276

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Development of Mechanical Design Methodology for Solid Oxide Fuel Cells2006

    • Author(s)
      Toshiyuki Hashida, et al.
    • Journal Title

      Proceedings of International Conference For Mechanical and Automotive Technologies 2006 (ICMATE 2006), New University for Mechanical and Automotive Technology Education, (Chonbuk National University, Jeonju, Jeonbuk, Korea, April 26-28, 2006)

      Pages: 39-55

    • Related Report
      2006 Annual Research Report
  • [Presentation] 固体酸化物燃料電池用セラミックスの機械的特性に及ぼす還元処理の影響に関する研究2008

    • Author(s)
      武山陽平
    • Organizer
      日本機械学会M&M2008材料力学カンファレンス
    • Place of Presentation
      立命館大学, びわこ・くさつキャンパス
    • Year and Date
      2008-09-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高温還元環境下における固体酸化物燃料電池用セリア系セラミックスの機械的特性評価に関する研究2008

    • Author(s)
      武山陽平, 佐藤一永, 橋田俊之, 水崎純一郎
    • Organizer
      日本機械学会東北支部第38回学生員卒業研究演会
    • Place of Presentation
      八戸工業大学(講演番号115)(29-30)
    • Year and Date
      2008-03-07
    • Related Report
      2008 Final Research Report
  • [Presentation] SOFCの信頼性評価のための機械的解析2008

    • Author(s)
      佐藤一永、八代圭司、井口史匡、古山通久、雨澤浩史、寺田賢二郎、湯上浩雄、橋田俊之、水崎純一郎、川田達也
    • Organizer
      第17回SOFC研究発表会
    • Place of Presentation
      東京都科学技術館サイエンスホール
    • Related Report
      2008 Final Research Report
  • [Presentation] SOFCの機械的信頼性向上のための基礎研究2008

    • Author(s)
      川田達也, 佐藤一永, 古山通久, 井口史匡, 八代圭司, 雨澤浩史, 寺田賢二郎, 湯上浩雄, 橋田俊之, 水崎純一郎
    • Organizer
      第17回SOFC研究発表会
    • Place of Presentation
      東京都科学技術館サイエンスホール
    • Related Report
      2008 Final Research Report
  • [Presentation] 固体酸化物燃料電池用セラミックスの機械的特性に及ぼす還元処理の影響に関する研究2008

    • Author(s)
      武山陽平, 佐藤一永, 川田達也, 橋田俊之, 水崎純一郎
    • Organizer
      日本機械学会M&M2008材料力学カンファレンス講演論文集
    • Place of Presentation
      立命館大学,びわこ・くさつキャンパス
    • Related Report
      2008 Final Research Report
  • [Presentation] Application of AE Technique in Performance Evaluation of Ceria Electrolyte Thin Film-Based SOFCs2007

    • Author(s)
      H. Lin, et. al.
    • Organizer
      5th International Workshop on Water Dynamics
    • Place of Presentation
      仙台,仙台国際センター
    • Year and Date
      2007-09-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] Spray-coating thin GDC films for solid oxide fuel cell applications2007

    • Author(s)
      Changsheng Ding, Hongfei Lin, Kazuhisa Sato and Toshiyuki Hashida, Yoshifumi Tsutai, Mabito Iguchi and Chiharu Wada
    • Organizer
      資源・素材学会東北支部平成19年度春季大会講演予稿集(2007)
    • Place of Presentation
      東北大学さくらホール
    • Year and Date
      2007-06-08
    • Related Report
      2008 Final Research Report
  • [Presentation] 急速起動可能な小型固体酸化物燃料電池の試作と評価2007

    • Author(s)
      熊田圭吾, 佐藤一永, 水崎純一郎, 橋田俊之
    • Organizer
      資源・素材学会東北支部平成19年度春季大会講演予稿集
    • Place of Presentation
      東北大学さくらホール
    • Year and Date
      2007-06-08
    • Related Report
      2008 Final Research Report
  • [Presentation] 急速起動可能な固体酸化物燃料電池の概念設計と試作2007

    • Author(s)
      熊田圭悟, 佐藤一永, 橋田俊之, 水崎純一郎
    • Organizer
      日本機械学会東北支部第37回学生員卒業研究発表講演会
    • Place of Presentation
      弘前大学(講演番号203)
    • Year and Date
      2007-03-05
    • Related Report
      2008 Final Research Report
  • [Presentation] SOFCの信頼性向上のための評価手法と材料設計2007

    • Author(s)
      川田達也, 渡邊秀貴, 宇根本篤, 佐瀬摩耶, 雨澤浩史, 中村崇司, 佐藤一永, 八代圭司, 水崎純一郎, 橋田俊之, 湯上浩雄
    • Organizer
      第16回SOFC研究発表会,SOFC研究会
    • Place of Presentation
      科学技術館サイエンスホール,東京
    • Related Report
      2008 Final Research Report
  • [Presentation] Autocombustion synthesis of La_<0.6>Sr_<0.4>Co_<0.2>Fe_<0.8.O_<3-δ>(LSCF) perovskite nanosized powder via modified sol-gel route2007

    • Author(s)
      Hongfei Lin, Changsheng Ding, Kazuhisa Sato, Yoshifumi Tsutai, Chiharu Wada and Toshiyuki Hashida
    • Organizer
      1st Int.Sympo. On Aqua Science, Water Resource and Innovation Development of Countryside
    • Place of Presentation
      Sakawa,Kochi,Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis of Nanometer NiO-Ce_<0.8>Sm_<0.2>O_<1.9>Composite Nanopowders for Solid Oxide Fuel Cells2007

    • Author(s)
      Changsheng DING, H. Lin, Kazuhisa SATO, Toshiyuki HASHIDA
    • Organizer
      5^<th> International Workshop on Water Dynamics
    • Place of Presentation
      Sendai,Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis and Characterization of Nanometer La_<0.8>Sr_<0.2>Co_<0.8>Fe_<0.2>O_3 Nanoparticles for Intermediate-Low Temperature Solid Oxide Fuel Cells2007

    • Author(s)
      Changsheng DING, H. Lin, Kazuhisa SATO, Toshiyuki HASHIDA
    • Organizer
      5^<th> International Workshop on Water Dynamics
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Ni-GDC Anode-Supported Ceria Electrolyte Film and Its Application in Solid Oxide Fule Cells2007

    • Author(s)
      H. Lin, C. Ding, K. Kumada, K. Sato, Y. Tsutai, C. Wada,and T. Hashida
    • Organizer
      5^<th> International Workshop on Water Dynamics
    • Place of Presentation
      Sendai,Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Application of AE Technique in Performance Evaluation of Anode-supported Ceria Electrolyte Thin Film-based SOFCs2007

    • Author(s)
      H. Lin, C. Ding, K. Kumada, K. Sato, Y. Tsutai, C. Wada and T. Hashida
    • Organizer
      5^<th> International Workshop on Water Dynamics
    • Place of Presentation
      Sendai,Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] 自己組織化マッピング手法を用いたSOFCの損傷可視化に関する研究2006

    • Author(s)
      佐藤一永, 今中規景, 福井健一, 八代圭司, 沼尾正行, 川田達也, 湯上浩雄, 橋田俊之, 水崎純一郎
    • Organizer
      第14回SOFC研究発表会,SOFC研究会
    • Place of Presentation
      科学技術館サイエンスホール,東京
    • Related Report
      2008 Final Research Report
  • [Presentation] A New Method for Evaluating Degradation of Solid Oxide Fuel Cell under Operating Conditions by Combining the Electrochemical Measuement with Non-Destructive Test2006

    • Author(s)
      Kazuhisa Sato, Shintaro Kyotani, Toshiyuki Hashida, Hirokazu Moriya, Tatsuya Kawada, Keiji Yashiro, Takashi Nakamura, Hiroo Yugami, Junichiro Mizusaki
    • Organizer
      Asian Symposium on Materials and Processing 2006(ASMP 2006)
    • Place of Presentation
      Sofitel Central Plaza Bangkok, Thailand
    • Related Report
      2008 Final Research Report
  • [Presentation] イットリア安定化ジルコニアの電気特性に及ぼす力学的負荷の影響に関する研究2006

    • Author(s)
      鳴海涼, 佐藤一永, 橋田俊之, 川田達也, 八代圭司, 湯上浩雄, 水崎純一郎
    • Organizer
      2006年電気化学秋季大会講演要旨集
    • Place of Presentation
      同志社大学工学部(2F28)
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis and Characterization of Nanometer NiO-SDC Composite Powders for Solid Oxide Fuel Cells2006

    • Author(s)
      Changsheng Ding, Hajime Oomura, Kazuhisa Sato, Toshiyuki Hashida
    • Organizer
      Joint Conference of 8th Int.Sympo.on Hydrothermal Reactions and 7th Int.Conf.on Solvo-Thermal Reactions(ISHR & ICSTR 2006)
    • Place of Presentation
      Sendai,Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Development of Mechanical Design Methodology for Solid Oxide Fuel Cells, Proceedings of International Conference For Mechanical and Automotive Technologies 2006(ICMATE 2006)2006

    • Author(s)
      Toshiyuki Hashida, Kazuhisa Sato, Tatsuya Kawada, Junichiro Mizusaki,and Hiroo Yugami
    • Organizer
      New University for Mechanical and Automotive Technology Education
    • Place of Presentation
      Chonbuk National University, Jeonju, Jeonbuk, Korea
    • Related Report
      2008 Final Research Report
  • [Remarks] FC EXPO 2009第5回国際水素・燃料電池展(2009年2月25日-27日,東京ビッグサイト)において本研究の一環で開発したSOFC評価試験装置を展示した.

    • Related Report
      2008 Final Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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