| Project/Area Number |
18360121
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Intelligent mechanics/Mechanical systems
|
|---|
| Research Institution | Tokyo University of Agriculture and Technology |
|---|
Principal Investigator |
WATANABE Toshiyuki Tokyo University of Agriculture and Technology, Institute of Symbiotic Science and Technology, Professor (10210923)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
OGINO Kenji Tokyo University of Agriculture and Technology, Institute of Symbiotic Science and Technology, Professor (10251589)
TOTANI Kenro Tokyo University of Agriculture and Technology, Graduate School of Engineering, Research Associate (50397014)
|
|---|
| Project Period (FY) |
2006 – 2007
|
| Project Status |
Completed (Fiscal Year 2007)
|
| Budget Amount *help |
¥16,720,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2007: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2006: ¥9,700,000 (Direct Cost: ¥9,700,000)
|
|---|
| Keywords | Polymer Gel / Actuator / Photo-responsive / Ciliary Movement / Azobenzene / Polyamide acid / 二光子励起重合 |
|---|
| Research Abstract |
Photoresponsive poly(amide acid) (PAA) and polyimide (PI) gels consisting of 4, 4' diamino azobenzene (DAA) in backbone were synthesized in DMF, and mesh-size changes induced by photoirradiation were investigated by using scanning microscopic light scattering (SMILS). Three different kinds of amide acid oligomers derived from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA), 4,4'-oxydiphthalic anhydride (ODPA), pyromellitic dianhydride (PMDA), were end-crosslinked with trifunctional amine, 1,3,5-tris(4-aminophenyl)benzene (TAPB). In the case of PAA(OAA(6FDA/DAA)(4/3)-v-TAPB) gels, SMILS has revealed that mesh size change due to the photoisomerization of azobenzene from nanoscopically trans-form to cis-form amounts to be from 2.1 to 0.83 nm, and corresponds to the change in molecular length of azobenzene upon photo-irradiation. Photo-induced macroscopic bending of isotropic polymer gel rods was realized by introducing rigid aromatic rings into main chains of the polymer network.
The differences in formation and structural properties of polymer networks consisting of end-linked flexible or rigid chains were studied by molecular dynamics (MD) simulation. MD simulations showed that the flexible chains created an inhomogeneous network on a large scale via microgel cluster formation, in agreement with experimental observations, whereas the rigid chains rapidly created a homogeneous network in the entire system volume without first generating microgel clusters, with the additional difference that they gave rise to mutually interpenetrating networks at the local scale.
Needle array of photoresponsive gel were prepared by use of nano holes template fabricated by two-photon initiated polymerization. Ciliary movement of needle like array were observed by alternating laser excitation at two different wavelength, 405 nm and 532 nm.
|
