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Development of electron excited X-ray holography for micro-area 3D atomic structure analysis

Research Project

Project/Area Number 18360300
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionTohoku University

Principal Investigator

HAYASHI Koichi (HAYASHI Kouichi)  Tohoku University, 金属材料研究所, 准教授 (20283632)

Co-Investigator(Kenkyū-buntansha) USAMI Noritaka  東北大学, 金属材料研究所, 准教授 (20262107)
松原 英一郎  京都大学, 工学研究科, 教授 (90173864)
松下 智裕  東北大学, 高輝度光科学研究センター, 副主幹研究員 (10373523)
Project Period (FY) 2006 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥17,430,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2008: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2007: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2006: ¥6,900,000 (Direct Cost: ¥6,900,000)
Keywordsホログラフィー / 電子顕微鏡 / 三次元原子像 / 局所構造 / 結晶構造 / 3次元原子像
Research Abstract

We proposed the "electron excited X-ray holography", which can record the atomic resolution hologram by measuring an electron beam direction dependence of characteristic X-ray intensities from a sample. In this work, Ti K hologram was measured with 6 keV electron beam and atomic images of neighboring Sr and Ti were successfully reconstructed from its Fourier transform. Moreover, as advanced applications of atomic resolution holography, local lattice distortions of the mixed crystal of the diluted magnetic semiconductor Zn_<0.4>Mn_<0.6>Te and the shape memory alloy of Ti_<50>Ni_<44>Fe_6 were successfully estimated.

Report

(6 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report   Self-evaluation Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (44 results)

All 2010 2009 2008 2007 2006 Other

All Journal Article (26 results) (of which Peer Reviewed: 16 results) Presentation (9 results) Remarks (5 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Reconciling the Pauling bond length picture and Vegard's law in a mixed crystal : An x-ray fluorescence holographic study2009

    • Author(s)
      S. Hosokawa, N. Happo, K.Hayashi
    • Journal Title

      Phys.rev.B 80

      Pages: 134123-134123

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase transition in Ti_<50>Ni_<44>Fe_6 studied by x-ray fluorescence holography2009

    • Author(s)
      W. Hu, K. Hayashi, T. Yamamoto, N. Happo, et al.
    • Journal Title

      Phys.rev.B 80

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural analysis of Ti_<50>Ni_<44>Fe_6 single crystal by X-ray fluorescence holography2009

    • Author(s)
      W. Hu, K. Hayashi, N. Happo, et al.
    • Journal Title

      J.Cryst.Growth 311

      Pages: 982-985

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase transition in Ti_<50>Ni_<44>Fe_6 studied by x-ray fluorescence holography2009

    • Author(s)
      W.Hu, K.Hayashi, T.Yamamoto, N.Happo, et al.
    • Journal Title

      Physical Review B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reconciling the Pauling bond length picture and Vegard's law in a mixed crystal : An x-ray fluorescence holographic study2009

    • Author(s)
      S.Hosokawa, N.Happo, K.Hayashi
    • Journal Title

      Physical Review B 80

      Pages: 134123-134123

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      桜井健次, 林好一, 他
    • Journal Title

      X線反射率入門(講談社サイエンティフィク)

      Pages: 248-261

    • Related Report
      2009 Annual Research Report
  • [Journal Article] X-ray fluorescence holography of Inl-xGaxSb mixed crystal2009

    • Author(s)
      S. Hosokawa, T. Ozaki, N. Takata, et.al.
    • Journal Title

      Journal of Crystal Growth 311

      Pages: 978-981

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic image around Mn atoms in diluted magnetic semiconduct or Cd_<0.6>Mn_<0.4>Te obtained from X-ray fluorescence holography2009

    • Author(s)
      N. Happo, K. Hayashi, S. Hosokawa
    • Journal Title

      Journal of Crystal Growth 311

      Pages: 990-993

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural analysis of Ti_<50>Ni_<44>Fe_6 single crystal by X-ray fluorescence holography2009

    • Author(s)
      W. Hu, K. Hayashi, N. Happo
    • Journal Title

      Journal of Crystal Growth 311

      Pages: 982-985

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reconstruction algorithm for atomic-resolution holography using translational symmetry2008

    • Author(s)
      T. Matsushita, F. Z. Guo, M. Suzuki, F. Matsui, H. Daimon, K. Hayashi
    • Journal Title

      Phys. Rev. B 78

      Pages: 144111-144111

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Wave-dispersive x-ray spectrometer for simultaneous acquisition of several characteristic lines based on strongly and accurately shaped Ge crystal2008

    • Author(s)
      K. Hayashi, K. Nakajima, K. Fujiwara, and S. Nishikata
    • Journal Title

      Rev. Sci. Instrum. 79

      Pages: 33110-33110

    • Related Report
      2008 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Application of x-ray excited optical luminescence to x-ray standing wave method and atomic resolution holography2007

    • Author(s)
      K. Hayashi, T. Hayashi, T. Shishido, E. Matsubara, et al.
    • Journal Title

      Phys.rev.B 76

      Pages: 14119-14119

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Existence of tetrahedral site symmetry about Ge atoms in a single-crystal film of Ge2Sb2Te5 found by x-ray fluorescence holography2007

    • Author(s)
      S. Hosokawa, T. Ozaki, K. Hayashi, N. Happo, et al.
    • Journal Title

      Appl.Phys.Lett. 90

      Pages: 1361913-1361913

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Application of x-ray excited optical luminescence to x-ray standing wave method and atomic resolution holography2007

    • Author(s)
      K. Hayashi, T. Hayashi, T. Shishido, E. Matsubara, H. Makino, T. Yao, and T. Matsushita
    • Journal Title

      Phys. Rev. B 76

      Pages: 14119-14119

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Existence of tetrahedral site symmetry about Ge atoms in a single-crystal film of Ge2Sb2Te5 found by x-ray fluorescence holography, Appli2007

    • Author(s)
      S. Hosokawa, T. Ozaki, K. Hayashi, N. Happo, M. Fujiwara, K. Horii, P. Fons, A. V. Kolobov, J. Tominaga
    • Journal Title

      Appli. Phys. Letters 90

      Pages: 1361913-1361913

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Three-dimensional structural image of ZnO.4MnO.6Te diluted magnetic semiconductor obtained by X-ray fluorescence holography2007

    • Author(s)
      S. Hosokawa, N. Happo, K. Hayashi
    • Journal Title

      Journal of Magnetism and Magnetic Materials 310

      Pages: 2707-2709

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Existence of tetrahedral site symmetry about Ge atoms in a single-crystal film of Ge2Sb2Te5 found by x-ray fluorescence holography2007

    • Author(s)
      S. Hosokawa, T. Ozaki, K. Hayashi, N. Happo, et. al.
    • Journal Title

      Applied Physics Letters 90

      Pages: 1361913-1361913

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of x-ray excited optical luminescence to x-ray standing wave method and atomic resolution holography2007

    • Author(s)
      K. Hayashi, T. Hayashi, T. Shishido, E. Matsubara, et. Al.
    • Journal Title

      Physical Review B 76

      Pages: 14119-14119

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure Refinement Based on Inverse Fourier Analysis in X-Ray Fluorescence Holography2007

    • Author(s)
      Kouichi Hayashi
    • Journal Title

      AIP Conference Proceedings "Synchrotron Radiation Instrumentation : Ninth International Conference" 879

      Pages: 1857-1860

    • Related Report
      2006 Annual Research Report
  • [Journal Article] X-Ray Fluorescence Holographic Study on a Single-Crystal Thin Film of a Rewritable Optical Media2007

    • Author(s)
      S.Hosokawa, K.Hayashi, N.Happo, et al.
    • Journal Title

      AIP Conference Proceedings "Synchrotron Radiation Instrumentation : Ninth International Conference" 879

      Pages: 1309-1312

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Three-dimensional structural image of Zn_<o.4>Mn_<0.6>Te diluted magnetic semiconductor obtained by X-ray fluorescence holography2007

    • Author(s)
      S.Hosokawa, N.Happo, K.Hayashi
    • Journal Title

      Journal of Magnetism and Magnetic Materials 310

      Pages: 2707-2709

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Holographic Analysis of Incident Electron Beam Angular Distribution of Characteristic X-Rays : Internal Detector Electron Holography2006

    • Author(s)
      K. Hayashi, T. Matsushita, E. Matsubara
    • Journal Title

      J.Phys.Soc.Jpn. 75

      Pages: 53601-53601

    • NAID

      110004702307

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Holographic Analysis of Incident Electron Beam Angular Distribution of Characteristic X-Rays : Internal Detector Electron Holography2006

    • Author(s)
      K. Hayashi, T. Matsushita, and E. Matsubara
    • Journal Title

      J. Phys. Soc. Jpn. 75

      Pages: 53601-53601

    • NAID

      110004702307

    • Related Report
      2008 Self-evaluation Report
  • [Journal Article] Holographic Analysis of Incident Electron Beam Angular Distribution of Characteristic X-Rays : Internal Detector Electron Holography2006

    • Author(s)
      K.Hayashi, T.Matsushita, E.Matsubara
    • Journal Title

      Journal of the Physical Society of Japan 75

      Pages: 53601-53601

    • NAID

      110004702307

    • Related Report
      2006 Annual Research Report
  • [Journal Article] X線ルミネッセンス強度の入射角依存性の測定及び新しい原子分解能ホログラフィーの可能性2006

    • Author(s)
      林 好一, 林 徹太郎, 宍戸 統悦, 松原英一郎, 牧野久雄, 八百隆文
    • Journal Title

      分析化学 55

      Pages: 441-446

    • Related Report
      2006 Annual Research Report
  • [Journal Article] X-Ray Fluorescence Holography2006

    • Author(s)
      Kouichi Hayashi
    • Journal Title

      Advances in Imaging and Electron Physics 140

      Pages: 119-185

    • NAID

      10011244890

    • Related Report
      2006 Annual Research Report
  • [Presentation] Introductory Talk2010

    • Author(s)
      林好一
    • Organizer
      日本物理学会 第65回年次大会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-21
    • Related Report
      2009 Final Research Report
  • [Presentation] Introductory Talk2010

    • Author(s)
      林好一
    • Organizer
      日本物理学会 第65回年次大会
    • Place of Presentation
      岡出大学
    • Year and Date
      2010-03-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Recent advances in X-ray fluorescence holography2009

    • Author(s)
      K. Hayashi, N. Happo, S. Hosokawa, T. Matsushita
    • Organizer
      第11th international conference on electronic spectroscopy & structure
    • Place of Presentation
      奈良
    • Year and Date
      2009-10-07
    • Related Report
      2009 Final Research Report
  • [Presentation] Recent advances in X-ray fluorescence holography2009

    • Author(s)
      林好一, N.Happo, S.Hosokawa, T.Matsushita
    • Organizer
      11th international conference on electronic spectroscopy & structure
    • Place of Presentation
      Nara prefecture new public hall
    • Year and Date
      2009-10-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] X-ray fluorescence holography study of Ti_<50>Ni_<44>Fe_6 single crystal2008

    • Author(s)
      Wen Hu, 林好一, 他
    • Organizer
      日本金属学会秋季大会
    • Place of Presentation
      熊本市、熊本大学
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] X-ray fluorescence holography study of Ti_(50)Ni_(44)Fe_6 single crystal2008

    • Author(s)
      W. Hu, 林 好一、山本篤史郎、八方直久、細川伸也、寺井智之、福田 隆、掛下知行、H. Xie, T. Xiao,
    • Organizer
      日本金属学会
    • Place of Presentation
      熊本大学, 熊本
    • Year and Date
      2008-09-23
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] X-ray fluorescence holography of Ti-Ni-Fe alloy single crystal2008

    • Author(s)
      W. Hu, K. Hayashi, N. Happo, S. Hosokawa, T. Terai, T. Fukuda, T. Kakeshita, H. Xie, T. Xiao
    • Organizer
      IUCr2008
    • Place of Presentation
      Osaka
    • Year and Date
      2008-03-27
    • Related Report
      2008 Self-evaluation Report
  • [Presentation] 射入射条件におけるX線定在波法を用いたモデルフリー構造解析2007

    • Author(s)
      林好一, 竹中久貴, 他
    • Organizer
      第18回MRS学術シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2007-12-09
    • Related Report
      2009 Final Research Report 2007 Annual Research Report
  • [Presentation] 逆光電子ホログラフィー2006

    • Author(s)
      林 好一, 松下智裕, 松原英一郎
    • Organizer
      日本物理学会
    • Place of Presentation
      愛媛大学, 松島
    • Year and Date
      2006-03-30
    • Related Report
      2008 Self-evaluation Report
  • [Remarks] 東北大金材料研究所

    • URL

      http://www.xraylab.imr.tohoku.ac.jp/member/hayashi/index.html

    • Related Report
      2009 Final Research Report
  • [Remarks] 原子分解能X線励起研究会

    • URL

      https://sites.google.com/site/atomicholography/

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.xraylab.imr.tohoku.ac.jp/member/hayashi/index.html

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.xraylab.imr.tohoku.ac.jp/member/hayashi/

    • Related Report
      2008 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.xraylab.imr.tohoku.ac.jp/member/hayashi/

    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 分光結晶、波長分散型X線分析装置および元素分布測定方法2009

    • Inventor(s)
      林好一、中嶋一雄、森下浩平
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2009-252190
    • Filing Date
      2009-11-02
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 非走査型波長分散型X線分析装置及びそれを用いた測定方法2007

    • Inventor(s)
      林好一, 中嶋一雄
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2007-015569
    • Filing Date
      2007-01-25
    • Related Report
      2009 Final Research Report
  • [Patent(Industrial Property Rights)] 非走査型波長分散型X線分析装置及びそれを用いた測定装置2007

    • Inventor(s)
      林 好一, 中嶋一雄
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2007-015569
    • Filing Date
      2007-01-25
    • Related Report
      2008 Self-evaluation Report
  • [Patent(Industrial Property Rights)] 非走査型波長分散型X線分析装置及びそれを用いた測定方法2007

    • Inventor(s)
      林 好一, 中嶋一雄
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Number
      2007-015569
    • Filing Date
      2007-01-25
    • Related Report
      2006 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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