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Preparation of superionic metastable crystals by crystallization of glass and their application to all-solid-state batteries

Research Project

Project/Area Number 18360319
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionOsaka Prefecture University

Principal Investigator

TATSUMISAGO Masahiro  Osaka Prefecture University, 大学院・工学研究科, 教授 (50137238)

Co-Investigator(Kenkyū-buntansha) TADANAGA Kiyoharu  大阪府立大学, 大学院・工学研究科, 准教授 (90244657)
HAYASHI Akitoshi  大阪府立大学, 大学院・工学研究科, 助教 (10364027)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥18,430,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥3,330,000)
Fiscal Year 2008: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2007: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Fiscal Year 2006: ¥4,000,000 (Direct Cost: ¥4,000,000)
Keywords固体電解質 / 全固体電池 / リチウムイオン / ガラス / イオン伝導体 / 硫化物 / ハイブリッド / メカノケミカル法
Research Abstract

Li_2S-P_2S_5系をベースとするガラス性液体からの超イオン伝導性Li_7P_3S_<11>結晶の析出条件を検討することによって、高いリチウムイオン伝導性と広い電位窓を兼ね備えた硫化物系固体電解質材料を開発した。得られた固体電解質を用いた全固体電池について、電極-電解質界面の構築と評価を行い、全固体リチウム電池が10mA cm^<-2>の大きな電流密度で二次電池として作動することを明らかにした。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (119 results)

All 2009 2008 2007 2006 Other

All Journal Article (52 results) (of which Peer Reviewed: 39 results) Presentation (57 results) Book (7 results) Remarks (3 results)

  • [Journal Article] Electrochemical Analysis of Li_4Ti_5O_<12> Electrode in All-Solid-State Lithium Secondary Batteries2009

    • Author(s)
      H. Kitaura, A. Hayashi, K. Tadanaga and M. Tatsumisago
    • Journal Title

      J. Electrochem. Soc 189

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure and Properties of Li_2S-P_2S_5-P_2S_3 Glass and Glass-Ceramic Electrolytes2009

    • Author(s)
      K. Minami, A. Hayashi, S. Ujiie and M. Tatsumisago
    • Journal Title

      J. Power Sources 189

      Pages: 651-654

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Modification of Interface between LiCoO_2 Electrode and Li_2S-P_2S_5 Solid Electrolyte Using Li_2O-SiO_2 Glassy Layers2009

    • Author(s)
      A. Sakuda, H. Kitaura, A. Hayashi, K. Tadanaga and M. Tatsumisago
    • Journal Title

      J. Electrochem. Soc 156

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Rate Performance of All-Solid-State Lithium Secondary Batteries Using Li_4Ti_5O_<12> Electrode2009

    • Author(s)
      H. Kitaura, A. Hayashi, K. Tadanaga and M. Tatsumisago,
    • Journal Title

      J. Power Sources 189

      Pages: 629-632

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Rate Performance of All-Solid-State Lithium Secondary Batteries Using Li_4Ti_5O_<12> Electrode2009

    • Author(s)
      H. Kitaura
    • Journal Title

      J. Power Sources 189

      Pages: 145-148

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] All-Solid-State Lithium Secondary Batteries with Oxide-Coated LiCoO_2 Electrode and Li_2S-P_2S_5 Electrolyte2009

    • Author(s)
      A. Sakuda
    • Journal Title

      J. Power Sources 189

      Pages: 527-530

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] All-Solid-state Lithium Secondary Batteries Using Nanocomposites of NiS Electrode/Li_2S-P_2S_5 Electrolyte Prepared Via Mechanochemical Reaction2009

    • Author(s)
      Y. Nishio
    • Journal Title

      J. Power Sources 189

      Pages: 629-632

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure and Properties of Li_2S-P_2S_5-P_2S_3 Glass and Glass-Ceramic Electrolytes2009

    • Author(s)
      K. Minami
    • Journal Title

      J. Power Sources 189

      Pages: 651-654

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Performance of NiP_2 Negative Electrodes in All-Solid-State Lithium Secondary Batteries2009

    • Author(s)
      A. Hayashi
    • Journal Title

      J. Power Sources 189

      Pages: 669-671

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of All-Solid-State Lithium Secondary Batteries Using Cu_xMo_6S_<8-y> Electrode and Li_2S-P_2S_5 Solid Electrolyte2009

    • Author(s)
      M. Nagao
    • Journal Title

      J. Power Sources 189

      Pages: 672-675

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modification of Interface between LiCoO_2 Electrode and Li_2S-P_2S_5 Solid Electrolyte Using Li_2O-SiO_2 Glassy Layers2009

    • Author(s)
      A. Sakuda
    • Journal Title

      J. Electrochem. Soc. 156

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Analysis of Li_4Ti_5O_<12> Electrode in All-Solid-State Lithium Secondary Batteries2009

    • Author(s)
      H. Kitaura
    • Journal Title

      J. Electrochem. Soc. 189

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] All-Solid-State Lithium Secondary Batteries Using Sulfide-Based Glass Ceramic Electrolytes,2008

    • Author(s)
      M. Tatsumisago and A. Hayashi
    • Journal Title

      Funct. Mater. Lett 1

      Pages: 31-36

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of New Glassy Materials for All-Solid-State Lithium Secondary Batteries : A Review2008

    • Author(s)
      A. Hayashi
    • Journal Title

      Glass Tech. : Eur. J. Glass Sci. Technol. A 49

      Pages: 213-220

    • Related Report
      2008 Annual Research Report 2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrical and Electrochemical Properties of the 70Li_2S・(30-x)P_2S_5・xP_2O_5 Glass-Ceramic Electrolytes2008

    • Author(s)
      K. Minami, A. Hayashi and M. Tatsumisago
    • Journal Title

      Solid State Ionics 179

      Pages: 1702-1705

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] リチウムイオン伝導性結晶化ガラス2008

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Journal Title

      セラミックス 43

      Pages: 1051-1054

    • NAID

      10024784568

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Novel Technique to form Electrode-Electrolyte Nanointerface in All-Solid-State Rechargeable Lithium Batteries2008

    • Author(s)
      A. Hayashi, Y. Nishio, H. Kitaura and M. Tatsumisago
    • Journal Title

      Electrochem. Commun 10

      Pages: 1086-1863

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanochemical Synthesis of α-Fe_2O_3 Nanoparticles and Their Application to All-Solid-State Lithium Batteries2008

    • Author(s)
      H. Kitaura
    • Journal Title

      J. Power Sources 183

      Pages: 418-421

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] All-Solid-State Rechargeable Lithium Batteries with Li_2 S as a Positive Electrode Material2008

    • Author(s)
      A. Hayashi
    • Journal Title

      J. Power Sources 183

      Pages: 422-426

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical and Electrochemical Properties of the 70Li_2S・(30-x) P_2S_5・xP_2O_5 Glass-Ceramic Electrolytes2008

    • Author(s)
      K. Minami
    • Journal Title

      Solid State Ionics 179

      Pages: 1282-1285

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Performance of All-Solid-State Lithium Batteries with Mechanochemically Activated Li_2S-Cu Composite Electrodes2008

    • Author(s)
      A. Hayashi
    • Journal Title

      Solid State Ionics 179

      Pages: 1702-1705

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] All-Solid-State Lithium Secondary Batteries Using Sulfide-Based Glass Ceramic Electrolytes2008

    • Author(s)
      M. Tatsumisago
    • Journal Title

      Funct. Mater. Lett. 1

      Pages: 31-36

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel Technique to form Electrode-Electrolyte Nanointerface in All-Solid-State Rechargeable Lithium Batteries2008

    • Author(s)
      A. Hayashi
    • Journal Title

      Electrochem. Commun 10

      Pages: 1860-1963

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] リチウムイオン伝導性結晶化ガラス2008

    • Author(s)
      辰巳砂昌弘
    • Journal Title

      セラミックス 43

      Pages: 1051-1054

    • NAID

      10024784568

    • Related Report
      2008 Annual Research Report
  • [Journal Article] Crystal structure of a superionic conductor, Li_7P_3S_<11>2007

    • Author(s)
      H. Yamane, A. Hayashi and M. Tatsumisago(他6名)
    • Journal Title

      Solid State Ionics 178

      Pages: 1163-1167

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lithium ion conductivity of the Li_2S-P_2S_5 glass-based electrolytes prepared by the melt quenching method2007

    • Author(s)
      K. Minami, F. Mizuno, A. Hayashi and M. Tatsumisago
    • Journal Title

      Solid State Ionics 178

      Pages: 837-841

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and characterization of glassy materials for all-solid-state lithium secondary batteries2007

    • Author(s)
      A. Hayashi
    • Journal Title

      J. Ceram. Soc. Jpn 115

      Pages: 110-117

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanochemical Synthesis and Li+ Ion Conductivity of Li_3N-based Amorphous Solid Electrolytes2007

    • Author(s)
      A. Hayashi, T. Ohtomo, F. Mizuno and M. Tatsumisago
    • Journal Title

      Chem. Sustainable Development 15

      Pages: 163-167

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structure of a superionic conductor,Li_7P_3S_112007

    • Author(s)
      H.Yamane
    • Journal Title

      Solid State Ionics 178

      Pages: 1163-1167

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical properties and local structure of tin borate glasses for lithium secon batteries2007

    • Author(s)
      M.Tatsumisago
    • Journal Title

      Glass Tech.Euro.J.Glass Sci.Tech.A 48

      Pages: 6-12

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium ion conductivity of Li_2S-P_2S_5 glass-based electrolytespreared by the melt quenching method2007

    • Author(s)
      K.Minami
    • Journal Title

      Solid State Ionics 178

      Pages: 837-841

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and chamcterization of glassy materials for all-solid-statelithium secondary batteries2007

    • Author(s)
      A.Hayashi
    • Journal Title

      J.Ceram.Soc.Jpn. 115

      Pages: 110-117

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanochemical Sythesis and Li^+ Ion Conductivity of Li_3N-basd Amohous Solid Electroles2007

    • Author(s)
      A.Hayashi
    • Journal Title

      Chem.Sustainable Development 15

      Pages: 163-167

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of α-Fe_2O_3 electrode materials via solution process and theirelectrochemical proerties in all-solid-state lithium batteries2007

    • Author(s)
      H.Kitaura
    • Journal Title

      J.Electrochem.Soc. 154

      Pages: 725-729

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanochemical Synthesis of Fast Lithium Ion Conducting Solid Electroles in the Li_2S-P_2S_5-SiS_2-Al_2S_3 System2007

    • Author(s)
      Y.Shibutani
    • Journal Title

      Chem.Sustailable Development 15

      Pages: 219-223

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 硫化物系ガラスセラミック電解質を用いた全固体リチウムニ次電池の開発2007

    • Author(s)
      辰巳砂 昌弘
    • Journal Title

      電池技術 19

      Pages: 104-114

    • Related Report
      2007 Annual Research Report
  • [Journal Article] All-Solid-State Lithium Secondary Batteries Using Sulfide-Based Glass-Ceramic Electrolytes2006

    • Author(s)
      M. Tatsumisago, F. Mizuno and A. Hayashi
    • Journal Title

      J. Power Sources 159

      Pages: 139-199

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] All-Solid-State Rechargeable Lithium Batteries Using SnX-P_2X_5(X=S and O) Amorphous Negative Electrodes,2006

    • Author(s)
      A. Hayashi, T. Konishi, K. Tadanaga, T. Minami and M. Tatsumisago
    • Journal Title

      Research on Chemical Intermediates 32

      Pages: 497-506

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanochemical Synthesis of Hybrid Electrolytes from the Li_2S-P_2S_5 Glasses and Polyethers2006

    • Author(s)
      A. Hayashi, T. Harayama, F. Mizuno and M. Tatsumisago
    • Journal Title

      J. Power Sources 163

      Pages: 289-293

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recent Progress of Glass and Glass-Ceramics as Solid Electrolytes for Lithium Secondary Batteries2006

    • Author(s)
      T. Minami, A. Hayashi and M. Tatsumisago
    • Journal Title

      Solid State Ionics 177

      Pages: 2715-2720

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] High Lithium Ion Conducting Glass-Ceramics in the System Li_2S-P_2S_52006

    • Author(s)
      F. Mizuno, A. Hayashi, K. Tadanaga and M. Tatsumisago
    • Journal Title

      Solid State Ionics 177

      Pages: 2721-2725

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] High Rate Performances of All-Solid-State In/LiCoO_2 Cells with the Li_2S-P_2S_5 Glass-Ceramics Electrolytes2006

    • Author(s)
      F. Mizuno, A. Hayashi, K. Tadanaga and M. Tatsumisago
    • Journal Title

      Solid State Ionics 177

      Pages: 2731-2735

    • Related Report
      2008 Final Research Report
  • [Journal Article] All-Solid-State Lithium Secondary Batteries Using Sulfide-Based Glass-Ceramic Electrolytes2006

    • Author(s)
      M.Tatsumisago
    • Journal Title

      J. Power Sources 159

      Pages: 193-199

    • Related Report
      2006 Annual Research Report
  • [Journal Article] All-Solid-State Researchable Lithium Batteries Using SnX-P_2X_5(X=S and O) Amorphous Negative Electrodes2006

    • Author(s)
      A.Hayashi
    • Journal Title

      Research on Chemical Intermediates 32[5-6]

      Pages: 497-506

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Mechanochemical Synthesis of Hybrid Electrolytes from the Li_2S-P_2S_5 Glasses and Polyethers2006

    • Author(s)
      A.Hayashi
    • Journal Title

      J. Power Sources 163

      Pages: 289-293

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Recent Progress of Glass and Glass-Ceramics as Solid Electrolytes for Lithium Secondary Batteries2006

    • Author(s)
      T.Minami
    • Journal Title

      Solid State Ionics 177

      Pages: 2715-2720

    • Related Report
      2006 Annual Research Report
  • [Journal Article] High Lithium Ion Conducting Glass-Ceramics in the System Li_2S-P_2S_52006

    • Author(s)
      F.Mizuno
    • Journal Title

      Solid State Ionics 177

      Pages: 2721-2725

    • Related Report
      2006 Annual Research Report
  • [Journal Article] High Rate Performances of All-Solid-State In/LiCoO_2 with the Li_2S-P_2S_5 Glass-Ceramics Electrolytes2006

    • Author(s)
      F.Mizuno
    • Journal Title

      Solid State Ionics 177

      Pages: 2731-2735

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Formation of Electrode-Electrolyte Interface by Lithium Insertion to SnS-P_2S_5 Negative Electrode Materials in All-Solid-State Cells2006

    • Author(s)
      A.Hayashi
    • Journal Title

      Solid State Ionics 177

      Pages: 2737-2740

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Lithium Ion Conducting Solid Electrolytes Prepared from Li_2S, Elemental P and S2006

    • Author(s)
      A.Hayashi
    • Journal Title

      Solid State Ionics 177

      Pages: 2753-2757

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 超イオン伝導ガラス2006

    • Author(s)
      辰巳砂昌弘, 林 晃敏
    • Journal Title

      光学 35[3]

      Pages: 139-144

    • NAID

      10017962535

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 硫化物系固体電解質材料を用いた全固体リチウム二次電池2006

    • Author(s)
      辰巳砂昌弘, 林 晃敏
    • Journal Title

      電池技術 18

      Pages: 36-44

    • Related Report
      2006 Annual Research Report
  • [Presentation] イオン液体を添加したLi_2S-P_2S_5系固体電解質の合成とキャラクタリゼーション2009

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都
    • Related Report
      2008 Final Research Report
  • [Presentation] 大気中におけるLi_2S-P_2S_5系固体電解質の構造変化2009

    • Author(s)
      林晃敏, 村松弘将, 南圭一, 濱重規, 辰巳砂昌弘
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] ガラス系固体電解質材料の開発と全固体リチウム二次電池への応用,2009

    • Author(s)
      辰巳砂昌弘
    • Organizer
      第47回ラミックス基礎科学討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Final Research Report
  • [Presentation] 金属硫化物によって表面修飾されたLiCoO_2を用いた全固体リチウム二次電池のキャラクタリゼーション2009

    • Author(s)
      中本尚之
    • Organizer
      第47回セラミックス基礎科学討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] ガラス系固体電解質材料の開発と全固体リチウム二次電池への応用2009

    • Author(s)
      辰巳砂昌弘
    • Organizer
      第47回セラミックス基礎科学討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] ホットソープ法を用いたSnP電極活物質の合成と全固体リチウム二次電池への応用2009

    • Author(s)
      林 晃敏
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Related Report
      2008 Annual Research Report
  • [Presentation] PLD法によるLiCoO_2電極活物質粒子表面へのLi_2S-P_2S_5系固体電解質薄膜のコーティング2009

    • Author(s)
      作田 敦
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都
    • Related Report
      2008 Annual Research Report
  • [Presentation] イオン液体を添加したLi_2S-P_2S_5固体電解質の合成とキャラクタリゼーション2009

    • Author(s)
      南 圭一
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都
    • Related Report
      2008 Annual Research Report
  • [Presentation] イオウ-銅系電極活物質の作製と全固体リチウム二次電池への応用2009

    • Author(s)
      長尾元寛
    • Organizer
      電気化学会第76回大会
    • Place of Presentation
      京都
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高リチウムイオン伝導性Li_2S-P_2S_5-P_2S_3系固体電解質の合成とキャラクタリゼーション2008

    • Author(s)
      南圭一, 林晃敏, 氏家諭, 辰巳砂昌弘
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] All-Solid-State Lithium Rechargeable Batteries with Sulfide Glass-Based Solid Electrolytes2008

    • Author(s)
      林晃敏
    • Organizer
      MRS Fall Meeting
    • Place of Presentation
      米国、ボストン
    • Related Report
      2008 Final Research Report
  • [Presentation] Li_2S-P_2S_5系電解質とNi系電極活物質からなるナノ複合体の作製と全固体リチウム二次電池への応用2008

    • Author(s)
      西尾勇祐, 北浦弘和, 林晃敏, 辰巳砂昌弘
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] Electrochemical Properties of All-Solid-State Li-In/Li_4Ti_5O_<12> Cells using Li_2S-P_2S_5 Solid Electrolytes, Pacific2008

    • Author(s)
      北浦弘和, 林晃敏, 忠永清治, 辰巳砂昌弘
    • Organizer
      Rim Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      米国, ホノルル
    • Related Report
      2008 Final Research Report
  • [Presentation] 高リチウムイオン伝導性Li_2S-P_2S_5系ガラスセラミック固体電解質の合成と評価2008

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州
    • Related Report
      2008 Final Research Report
  • [Presentation] Structure and Properties of Li_2S-P_2S_5-P_2S_3 Glass and Glass-Ceramic Electrolytes2008

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国, 天津
    • Related Report
      2008 Final Research Report
  • [Presentation] High Lithium Ion Conduction of Sulfide Glass-Based Solid Electrolytes and Their Application to All-Solid-State Lithium Secondary Batteries2008

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Organizer
      XVIth International Symposium on Non-Oxide and New Optical Glasses (ISNOG 2008)
    • Place of Presentation
      フランス, モンペリエ
    • Related Report
      2008 Final Research Report
  • [Presentation] ガラス性液体を経由する様々な手法で作製したLi_7P_3S_<11>電解質の評価2008

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨
    • Related Report
      2008 Final Research Report
  • [Presentation] ガラス系イオン伝導材料の開発とイオニクスデバイスへの応用2008

    • Author(s)
      辰巳砂昌弘
    • Organizer
      第55回応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] 硫化物系無機固体電解質材料を用いた全固体リチウム二次電池2008

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] High Lithium Ion Conduction of Sulfide Glass-Based Solid Electrolytes and Their Application to All-Solid-State Lithium Secondary Batteries2008

    • Author(s)
      辰巳砂昌弘
    • Organizer
      XVIth International Symposium on Non-Oxide and New optical Glasses
    • Place of Presentation
      フランス、モンペリエ
    • Related Report
      2008 Annual Research Report
  • [Presentation] Structure and Properties of Li_2S-P_2S_5-P_2S_3 Glass and Glass-Ceramic Electrolytes2008

    • Author(s)
      南 圭一
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国、天津
    • Related Report
      2008 Annual Research Report
  • [Presentation] Characterization of All-Solid-State Lithium Secondary Batteries Using Cu-Li_2S-P_2S_5 Electrode-Electrolyte Composites2008

    • Author(s)
      林 晃敏
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国、天津
    • Related Report
      2008 Annual Research Report
  • [Presentation] Characterization of All-Solid-State Lithium Secondary Batteries Using Cu_xMo_6S_<8-y> Electrode and Li_2S-P_2S_5 Solid Electrolyte2008

    • Author(s)
      長尾元寛
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国、天津
    • Related Report
      2008 Annual Research Report
  • [Presentation] High-Rate Performance of All-Solid-State Lithium Secondary Batteries Using Li_4Ti_5O_<12> Electrode2008

    • Author(s)
      北浦弘和
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国、天津
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Performance of NiP_2 Negative Electrodes in All-Solid-State Lithium Secondary Batteries2008

    • Author(s)
      林 晃敏
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国、天津
    • Related Report
      2008 Annual Research Report
  • [Presentation] All-Solid-State Lithium Secondary Batteries Using Nanocomposites of NiS Electrode/Li_2S-P_2S_5 Electrolyte Prepared Via Mechanochemical Reaction2008

    • Author(s)
      西尾勇祐
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国、天津
    • Related Report
      2008 Annual Research Report
  • [Presentation] All-Solid-State Lithium Secondary Batteries with Oxide-Coated LiCoO_2 Elctrode and Li_2S-P_2S_5 Electrolyte2008

    • Author(s)
      作田 敦
    • Organizer
      The 14th International Meeting on Lithium Batteries
    • Place of Presentation
      中国、天津
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高リチウムイオン伝導性Li_2S-P_2S_5系ガラスセラミック固体電解質の合成と評価2008

    • Author(s)
      南 圭一
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      福岡
    • Related Report
      2008 Annual Research Report
  • [Presentation] 表面修飾されたLiCoO_2正極を用いた全固体リチウム二次電池の作製と評価2008

    • Author(s)
      作田 敦
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      福岡
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrode Performance of NiS Nanoparticles Embedded in Sulfide Electrolyte for All-Solid-State Rechargeable Lithium Batteries2008

    • Author(s)
      林 晃敏
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science 2008
    • Place of Presentation
      米国、ホノルル
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Properties of All-Solid-State Li-In / Li_4Ti_5O_<12> Cells using Li_2S-P_2S_5 Solid Electrolytes2008

    • Author(s)
      北浦弘和
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science 2008
    • Place of Presentation
      米国、ホノルル
    • Related Report
      2008 Annual Research Report
  • [Presentation] High Temperature Performance of All-Solid-State Lithium Secondary Batteries with Oxide-Coated LiCoO_22008

    • Author(s)
      作田 敦
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science 2008
    • Place of Presentation
      米国、ホノルル
    • Related Report
      2008 Annual Research Report
  • [Presentation] 表面修飾LiCoO_2を用いた全固体リチウム二次電池の高電位における作動特性2008

    • Author(s)
      作田 敦
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] 銅Chevrel電極と硫化物電解質を用いた全固体リチウム二次電池の高温作動特性2008

    • Author(s)
      長尾元寛
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] Li_2S-P_2S_5系無機固体電解質を用いたIn / LiMn_2O_4全固体リチウム二次電池の作動特性2008

    • Author(s)
      北浦弘和
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] Electrochemical Performance of All-Solid-State Lithium Batteries Using Li_4Ti_5O_<12> Electrode and Li_2S-P_2S_5 Electrolyte2008

    • Author(s)
      北浦弘和
    • Organizer
      第49回電池討論会
    • Place of Presentation
      大阪
    • Related Report
      2008 Annual Research Report
  • [Presentation] All-Solid-State Lithium Rechargeable Batteries with Sulfide Glass-Based Solid Electrolytes2008

    • Author(s)
      林 晃敏
    • Organizer
      2008 MRS Fall Meeting
    • Place of Presentation
      米国、ボストン
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation and Characterization of Lithium Ion Conducting Li_2S-P_2S_5 Glass-Ceramic Electrolytes2008

    • Author(s)
      南 圭一
    • Organizer
      2008 MRS Fall Meeting
    • Place of Presentation
      米国、ボストン
    • Related Report
      2008 Annual Research Report
  • [Presentation] 表面修飾LiCoO_2を電極に用いた全固体リチウムニ次電池の特性評価2008

    • Author(s)
      林 晃敏
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] 硫化物系無機固体電解質を用いたLi-In/Li_4Ti_5O_<12>全固体セルの界面特性評価2008

    • Author(s)
      北浦 弘和
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨
    • Related Report
      2007 Annual Research Report
  • [Presentation] ガラス性液体を経由する様々な手法で作製したLi_7P_3S_11電解質の評価2008

    • Author(s)
      南 圭一
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨
    • Related Report
      2007 Annual Research Report
  • [Presentation] 融液からの超イオン伝導性Li_7P_3S_<11>結晶の作製2007

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Final Research Report
  • [Presentation] Li_2S-P_2S_5系ガラス固体電解質の軟化融着を用いた全固体電池界面の構築2007

    • Author(s)
      北浦弘和, 福島裕介, 林晃敏, 忠永清治, 辰巳砂昌
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Final Research Report
  • [Presentation] Li_2S-P_2S_5系無機固体電解質を用いたLi-In/Li_4Ti_5O_<12>全固体電池の電極特性と界面評価2007

    • Author(s)
      北浦弘和, 林晃敏, 忠永清治, 辰巳砂昌弘
    • Organizer
      第48回電池討論会
    • Place of Presentation
      福岡
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] Li_2SiO_3ガラスで表面修飾したLiCoO_2を用いた全固体リチウム二次電池2007

    • Author(s)
      林晃敏, 作田敦, 北浦弘和, 忠永清治, 辰巳砂昌弘
    • Organizer
      2007年電気化学会秋季大会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] Electrical and Electrochemical Properties of the 70Li_2S・(30-x)P_2S_5・xP2O_5 Grass-Ceramic Electrolytes2007

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      16^<th> International Conference on Solid State,Ionics
    • Place of Presentation
      中国, 上海
    • Related Report
      2008 Final Research Report
  • [Presentation] メカニカルミリング法を用いて作製したLi_2S-P_2S_5-LiX(X=TFSI, BF_4, PF_6)系ガラスの構造と特性2007

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      第9回化学電池材料研究会ミーティング
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] Solid-State Lithium Batteries Using Glass Electrolytes2007

    • Author(s)
      辰巳砂昌弘
    • Organizer
      Electrolytes, International Workshop on Scientific Challenges of New Functionalities in Glass
    • Place of Presentation
      米国, ワシントンDC
    • Related Report
      2008 Final Research Report
  • [Presentation] 様々なリチウム塩を添加したLi_2S-P_2S_5系ガラスのメカノケミカル合成と評価2007

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      電気化学会第74回大会
    • Place of Presentation
      千葉
    • Related Report
      2008 Final Research Report
  • [Presentation] 全固体リチウム二次電池用新規ガラス材料の開発に関する研究2007

    • Author(s)
      林晃敏
    • Organizer
      日本セラミックス協会2007年年会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] メカニカルミリング法を用いて作製したLi_2S-P_2S_5-LiX(X=TFSI,BF_4PF_6)系ガラスの構造と特性2007

    • Author(s)
      南 圭一
    • Organizer
      第9回化学電池材料研究会ミーティング
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] Li_2S-P_2S_5系ガラス電解質の軟化融着を利用した全固体電池の電極-電解質界面の作製2007

    • Author(s)
      福島 裕介
    • Organizer
      第9回化学電池材料研究会ミーティング
    • Place of Presentation
      東京
    • Related Report
      2007 Annual Research Report
  • [Presentation] Electrical and Electrochemical Properties of the 70Li_2S・(30-x)P_2S_5・xP_2O_5Glass-Ceramic Electrolytes2007

    • Author(s)
      南 圭一
    • Organizer
      16^<th> International Conference on Solid StateIonics
    • Place of Presentation
      中国・上海
    • Related Report
      2007 Annual Research Report
  • [Presentation] Modification of Interface between LiCoO_2 and Solid Electrolyte by Coating of Li^+ Ion Conducting Oxide Materials2007

    • Author(s)
      作田 敦
    • Organizer
      212^<th> Electrochemical Society (ECS)Meeting
    • Place of Presentation
      米国・ワシントンDC
    • Related Report
      2007 Annual Research Report
  • [Presentation] 融液からの超イオン伝導性Li_7P_3S_11結晶の作製2007

    • Author(s)
      南 圭一
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋
    • Related Report
      2007 Annual Research Report
  • [Presentation] レーザーアブレーション堆積法によるLi_2S-P_2S_5系固体電解質薄膜の作製2007

    • Author(s)
      作田 敦
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋
    • Related Report
      2007 Annual Research Report
  • [Presentation] Li_2S-P_2S_5系をベースとする多成分系固体電解質の作製とキャラクタリゼーション2006

    • Author(s)
      南圭一, 林晃敏, 辰巳砂昌弘
    • Organizer
      第32回固体イオニクス討論会
    • Place of Presentation
      福岡
    • Related Report
      2008 Final Research Report
  • [Book] 次世代自動車用リチウムイオン電池の材料開発2008

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] 次世代自動車用リチウムイオン電池の材料開発2008

    • Author(s)
      辰巳砂昌弘
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Annual Research Report
  • [Book] 全固体二次電池の開発-高性能化と製造技術-2008

    • Author(s)
      辰巳砂 昌弘
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2007 Annual Research Report
  • [Book] 全固体二次電池の開発-高性能化と製造技術-2007

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2008 Final Research Report
  • [Book] 全固体二次電池の開発-高性能化と製造技術-2007

    • Author(s)
      辰巳砂 昌弘
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2007 Annual Research Report
  • [Book] ユビキタスエネルギーの最新技術2006

    • Author(s)
      辰巳砂昌弘, 林晃敏
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] ユビキタスエネルギーの最新技術2006

    • Author(s)
      辰巳砂昌弘, 林 晃敏
    • Publisher
      シーエムシー出版
    • Related Report
      2006 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka2/index.html

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka2/index.html

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka2/index.html

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2006-04-01   Modified: 2016-04-21  

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