• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Optimization of Oxygen Permeable Membrane by Applying to Hydrogen Production System Based on Partial Oxidation of Methane

Research Project

Project/Area Number 18360326
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

TAKAMURA Hitoshi  Tohoku University, Graduate School of Engineering, Associate Professor (30250715)

Co-Investigator(Kenkyū-buntansha) OKADA Masuo  Tohoku University, Graduate School of Engineering, Professor (80133049)
KAMEGAWA Atsunori  Tohoku University, Graduate School of Engineering, Associate Professor (90292242)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥12,290,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2007: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2006: ¥8,000,000 (Direct Cost: ¥8,000,000)
KeywordsOxygen permeable membrane / Methane reforming / Hydrogen Production / Exergy / Cerium oxide / Mixed conductivity
Research Abstract

A ceria-based oxygen permeable membrane was mounted on a stainless-steel separator to be a module and to optimize its mixed conductivity in the context of achieving high system efficiency for hydrogen production. For FY2006, 1) fabrication of the oxygen permeable membrane module and their methane reforming properties, and 2) mixed oxide-ion and electronic conductivity of the membrane were investigated. Expected amount of hydrogen was obtained by operating the module at around 780 to 950℃. The mixed ionic and electronic conductivities were separated by means of the Hebb-Wagner polarization technique; at 900℃, major carrier was found to be switched from oxide-ion to electron at an oxygen partial pressure of 10^<-7> bar by reducing the pressure from air. For FY2007, 1) heat balance of the oxygen permeable membrane module, and 2) exergy analysis of co-production system of hydrogen and electricity based on solid-oxide electrolytes were examined. Based on the mixed conductivity mentioned above, under an operating condition at 780℃ and a rate of 150 sccm methane input, the membrane module was found to emit a heat of 8.4 W. As a solid-oxide fuel cell system, 20mol%Sm-doped CeO_2, Ba_<0.5>Sr_<0.5>Co_<0.8>Sr_<0.2>O_<3-δ>, (Ce_<0.8>Sm_<0.2>)O_2-50vol%NiO were used as an electrolyte, cathode and anode, respectively. By supplying Ar-10%CH_4 as a fuel, the highest power density of 131 mW/cm^2 was attained at a current density of 288 mA/cm^2 at 700℃. Based on these value, an exergy compass diagram was constructed; under the optimum condition, an exergy efficiency reached to 46.7%. On the other hand, under short-circuited mode, which corresponds to an oxygen permeable membrane, the efficiency was 22.8%.

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (40 results)

All 2009 2008 2007 2006 Other

All Journal Article (22 results) (of which Peer Reviewed: 12 results) Presentation (15 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Preparation of Integrated Oxygen Permeable Membranes with a Porous Layer by Partial Reduction Process2009

    • Author(s)
      H. Takahashi, H. Takamura
    • Journal Title

      Mater. Trans. 50

      Pages: 506-508

    • NAID

      10024812445

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Electrical conductivity of ceria nanoparticles under high pressure2009

    • Author(s)
      H. Takamura, J. Kobayashi, N. Takahashi, M. Okada
    • Journal Title

      J. Electroceramics 22

      Pages: 24-32

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Preparation of Integrated Oxygen Permeable Membranes with a Porous Layer by Partial Reduction Process2009

    • Author(s)
      H. Takahashi, H. Takamura
    • Journal Title

      Mater, Trans. 50

      Pages: 506-508

    • NAID

      10024812445

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Electrical conductivity of ceria nanoparticles under high pressure2009

    • Author(s)
      H. Takamura, J. Kobayashi, N. Takahashi, M. Okada
    • Journal Title

      J. Electroceram 22

      Pages: 24-32

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 酸素透過性セラミック膜による天然ガスからの水素製造2008

    • Author(s)
      高村仁
    • Journal Title

      クリーンエネルギー 17

      Pages: 21-27

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Preparation of Oxygen Permeable Thin Films on YSZ Porous Substrates2008

    • Author(s)
      H. Takahashi, H. Takamura, M. Okada
    • Journal Title

      Mater. Trans. 49

      Pages: 453-456

    • NAID

      10021144653

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Fabrication and characteristics of planar-type methane reformer using ceria-based oxygen permeable membrane2008

    • Author(s)
      H. Takamura, M. Ogawa, K. Suehiro, H. Takahashi, M. Okada
    • Journal Title

      Solid State Ionics 179

      Pages: 1354-1359

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Review "Hydrogen production from natural gas by using oxygen permeable membrane" (in Japanese, w/o peer review)2008

    • Author(s)
      H. Takamura
    • Journal Title

      Clean Energy 17

      Pages: 21-27

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Preparation of Oxygen Permeable Thin Films on YSZ Porous Substrates2008

    • Author(s)
      H. Takahashi, H. Takamura, M. Okada
    • Journal Title

      Mater. Trans 49

      Pages: 453-456

    • NAID

      10021144653

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and Characteristics of Planar-Type Methane Reformer Using Ceria-Based Oxygen Permeable Membrane2008

    • Author(s)
      H. Takamura, M. Ogawa, K. Suehiro, H. Takahashi, M. Okada
    • Journal Title

      Solid State Ionics 179

      Pages: 1354-1359

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 解説「特集セリウム材料の新展開セリア系酸素透過膜の開発」2007

    • Author(s)
      高村仁
    • Journal Title

      セラミックス 42

      Pages: 872-876

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Review "Development of ceria-based oxygen permeable membrane" (in Japanese)2007

    • Author(s)
      H. Takamura
    • Journal Title

      Bulletin of The Ceramics Society of Japan 42

      Pages: 872-876

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Oxygen permeation properties and surface modification of acceptor-doped CeO_2/MnFe_2O_4 composites2007

    • Author(s)
      H.Takamura, et al.
    • Journal Title

      Journal of Electroceramics 17(2-4)

      Pages: 741-748

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electrode and Oxygen Permeation Properties of (Ce, Sm)O_2-MFe_2O_4 Composite Thin Films (M=Co and Mn)2006

    • Author(s)
      H. Takamura, Y. Koshino, A. Kamegawa, M. Okada
    • Journal Title

      Solid State Ionics 177

      Pages: 2185-2189

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Oxygen Permeation Properties and Surface Modification of Acceptor-Doped CeO_2/MnFe_2O_4 Composites2006

    • Author(s)
      H. Takamura, H. Sugai, M. Watanabe, T. Kasahara, A. Kamegawa, M. Okada
    • Journal Title

      J. Electroceramics 17

      Pages: 741-748

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Hydrogen Production From Methane by Using Oxygen Permeable Ceramics2006

    • Author(s)
      H. Takamura, Y. Aizumi, A. Kamegawa, M. Okada
    • Journal Title

      J. Fuel Cell Sci. Tech. 3

      Pages: 175-179

    • NAID

      10015596644

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 解説「セリア系酸素透過性セラミックスを利用したメタンからの水素製造」2006

    • Author(s)
      高村仁
    • Journal Title

      セラミックス 41

      Pages: 959-963

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Electrode and Oxygen Permeation Properties of (Ce, Sm)O_2 - MFe_2O_4 Composite Thin Films (M = Co and Mn)2006

    • Author(s)
      H. Takamura, Y. Koshino, A. Kamegawa, M. Okada
    • Journal Title

      Solid State Ionics 177

      Pages: 2185-2189

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Oxygen Permeation Properties and Surface Modification of Acceptor-Doped CeO_2 / MnFe_2O_4 Composites2006

    • Author(s)
      H. Takamura, H. Sugai, M. Watanabe, T. Kasahara, A. Kamegawa, M. Okada
    • Journal Title

      J. Electroceramics 17

      Pages: 741-748

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Review "Hydrogen production from methane by using oxygen permeable membrane" (in Japanese)2006

    • Author(s)
      H. Takamura
    • Journal Title

      Bulletin of The Ceramics Society of Japan 41

      Pages: 959-963

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Hydrogen Production From Methane by Using Oxygen Permeable Ceramics2006

    • Author(s)
      H.Takamura, et al.
    • Journal Title

      Journal of Fuel Cell Science and Technology 3

      Pages: 175-179

    • NAID

      10015596644

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electrode and oxygen permeation properties of (Ce, Sm)O_2- MFe_2O_4 composite thin films (M=Co and Mn)2006

    • Author(s)
      H.Takamura, et al.
    • Journal Title

      Solid State Ionics 177

      Pages: 2185-2189

    • Related Report
      2006 Annual Research Report
  • [Presentation] 酸素透過性セラミックスの基礎と水素製造技術への応用2008

    • Author(s)
      高村仁
    • Organizer
      第116回電子セラミック・プロセス研究会
    • Place of Presentation
      湘南工科大学
    • Year and Date
      2008-09-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fundamentals and Application of Oxygen Permeable Ceramics2008

    • Author(s)
      H. Takamura
    • Organizer
      116^<th> Electronic Ceramics and Devices meeting
    • Place of Presentation
      Shonan Institute of Technology
    • Year and Date
      2008-09-27
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] スリップキャスティング法による混合導電性薄膜の作製とその酸素透過特性2008

    • Author(s)
      高橋寛郎, 高村仁
    • Organizer
      日本金属学会2008年秋期講演大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-25
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 酸素ポテンシャル勾配下でのCe-Pr-Zr基酸素透過セラミックスの相安定性2008

    • Author(s)
      菊地俊光, 高村仁
    • Organizer
      日本金属学会2008年秋期講演大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-25
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation of Mixed Ionic and Electronic Conductive Thin Films by Slip Casting and Their Oxygen Permeation Properties2008

    • Author(s)
      H. Takahashi, H. Takamura
    • Organizer
      2008 Fall Annual Meeting of The Japan Institute of Metals
    • Place of Presentation
      Kumamoto University
    • Year and Date
      2008-09-25
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Phase Stability of Ce-Pr-Zr-Based Oxygen Permeable Ceramics under Oxygen Potential Gradients2008

    • Author(s)
      T. Kikuchi, H. Takamura
    • Organizer
      2008 Fall Annual Meeting of The Japan Institute of Metals
    • Place of Presentation
      Kumamoto University
    • Year and Date
      2008-09-25
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Cation Migration in Oxygen Permeable during Methane Reforming2008

    • Author(s)
      H. Takamura, H. Takahashi, T. Kikuchi, Y. Aizumi
    • Organizer
      213^<th> Electrochemical Society Meeting (ECS)
    • Place of Presentation
      Arizona, USA
    • Year and Date
      2008-05-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Cation Migration in 213^<th> Oxygen Permeable during Methane Reforming2008

    • Author(s)
      H. Takamura, H. Takahashi, T. Kikuchi, Y. Aizumi
    • Organizer
      Electrochemical Society Meeting (ECS)
    • Place of Presentation
      Arizona, U.S.A.
    • Year and Date
      2008-05-20
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 酸素ポテンシャル勾配下におけるセリア基酸素透過膜の耐久性2008

    • Author(s)
      高村仁, 高橋寛郎, 菊地俊光
    • Organizer
      日本金属学会2008年春期大会
    • Place of Presentation
      武蔵工業大学
    • Year and Date
      2008-03-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Durability of Ceria-Based Oxygen Permeable Membranes under Oxygen Potential Gradients2008

    • Author(s)
      H. Takamura, H. Takahashi, T. Kikuchi
    • Organizer
      2008 Spring Annual Meeting of The Japan Institute of Metals
    • Place of Presentation
      Musashi Institute of Technology
    • Year and Date
      2008-03-27
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] YSZ多孔質体上へのセリア基混合導電性薄膜の作製とその酸素透過特性2007

    • Author(s)
      高橋寛郎, 高村仁, 岡田益男
    • Organizer
      日本金属学会2007年秋期大会
    • Place of Presentation
      岐阜大学
    • Year and Date
      2007-09-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation of Ceria-Based Mixed Conductive Thin Films on YSZ Porous Substrates and Their Oxygen Permeable Properties2007

    • Author(s)
      H. Takahashi, H. Takamura, M. Okada
    • Organizer
      2007 Fall Annual Meeting of The Japan Institute of Metals
    • Place of Presentation
      Gifu University
    • Year and Date
      2007-09-20
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication and characteristics of planar-type methane reformer using ceria-based oxygen permeable membrane (Invited)2007

    • Author(s)
      H. Takamura
    • Organizer
      The 16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication and Characteristics of Planar-Type Methane Reformer using Ceria-Based Oxygen Permeable Membrane (Invited)2007

    • Author(s)
      H. Takamura
    • Organizer
      The 16^<th> International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-06
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication and characteristics of planar-type methane reformer using ceria-based oxygen permeable membrane2007

    • Author(s)
      H. Takamura
    • Organizer
      The 16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-06
    • Related Report
      2007 Annual Research Report
  • [Remarks] 「研究成果報告書概要(和文)」より

    • URL

      http://ceram.material.tohoku.ac.jp/takamuraken/

    • Related Report
      2007 Final Research Report Summary
  • [Remarks]

    • URL

      http://ceram.material.tohoku.ac.jp/takamuraken/node/4

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 酸素透過膜を用いた炭化水素改質方法及び炭化水素改質装置2009

    • Inventor(s)
      高村仁, 岡田益男, 小川将之, 齊藤智行
    • Industrial Property Rights Holder
      科学技術振興機構, TDK株式会社
    • Acquisition Date
      2009-02-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary

URL: 

Published: 2006-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi