Development of thin metallic glassy membrane for hydrogen separation produced by hot-roller pressing in supercooled liquid state

• Project/Area Number: 18360328
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Structural/Functional materials
• Research Institution: Tohoku University
• Principal Investigator: YAMAURA Shin-ichi Tohoku University, 金属材料研究所, 准教授 (50323100)
• Co-Investigator(Kenkyū-buntansha): KIMURA Hisamichi 東北大学, 金属材料研究所, 准教授 (00161571) ; INOUE Akihisa 東北大学, 総長 (10108566)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥16,840,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥1,140,000); Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2007: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2006: ¥11,900,000 (Direct Cost: ¥11,900,000)
• Keywords: 水素分離 / 非晶質 / 水素 / 金属ガラス / 圧延

Research Abstract

本研究では主に、非晶質金属水素分離膜の研究として新規合金の作製と水素透過性の評価、および得られた非晶質金属水素分離膜を用いたメタノール水蒸気改質水素製造を試みた。急冷凝固法を用いて得られた非晶質金属水素分離膜を使用してメタノール水蒸気改質による水素製造を試み、改質ガスから純水素を抽出精製することに成功した。さらに作製した水素分離用新規非晶質合金薄帯を用い、非晶質構造を有する薄帯試料を加熱して過冷却液体状態で多孔質基材と圧着接合させた新しい水素分離複合材料を作製した。

Research Products

• [Journal Article] 急冷凝固Ni-Nb-Ta-Zr-Coアモルファス合金の水素透過性とメタノール水蒸気改質による水素製造への適用 (2008)
  • Author(s): 山浦真一、木村久道、井上明久、新保洋一郎、西田元紀、上宮成之
  • Journal Title: 材料 57 Pages: 1031-1035
  • NAID: 130002085789
  • Peer Reviewed
• [Journal Article] 急冷凝固Ni-Nb-Ta-Zr-Coアモルファス合金の水素透過性とメタノール水蒸気改質による水素製造への適用 (2008)
  • Author(s): 山浦真一, 木村久道, 井上明久, 新保洋一郎, 西田元紀, 上宮成之
  • Journal Title: 材料 57 Pages: 1031-1035
  • NAID: 130002085789
  • Peer Reviewed
• [Journal Article] Hydrogen Production by Methanol Steam Reforming using Amorphous Metal Membranes (2007)
  • Author(s): S. Yamaura, S. Uemiya, H.M. Kimura and A. Inoue
  • Journal Title: Materials Science Forum 561-565 Pages: 1319-1322
  • Peer Reviewed
• [Journal Article] Supercooled Liquid Bonding of Metallic Glasses by Hot-Pressing (2007)
  • Author(s): S. Yamaura, H.M. Kimura and A. Inoue
  • Journal Title: Materials Transactions 48 Pages: 273-276
  • NAID: 10018509019
  • Peer Reviewed
• [Journal Article] Hydroen Production by Methanol Steam Reforming using Amorphous Metal Membranes (2007)
  • Author(s): S. Yamaura, S. Uemiya, H. M. Kimura and A. Inoue
  • Journal Title: Materials Science Forum 561-565 Pages: 1319-1322
  • Peer Reviewed
• [Journal Article] Supercooled Liquid tionaing of metallic Glasses by Hot-pressing (2007)
  • Author(s): S.Yamaura, H.M.Kimura, A.Inoue
  • Journal Title: Materials Transactions 48 Pages: 273-276
• [Presentation] Hydrogen Permeation of Melt-Spun Metallic Glassy Alloy Membrane and its Application to Hydrogen Production by Methanol Steam Reforming (2008)
  • Author(s): S. Yamaura, W. Zhang, A. Inoue
  • Organizer: The IUMRS International Conference in Asia 2008 (IUMRS-ICA 2008)
  • Place of Presentation: Nagoya,Japan
  • Year and Date: 2008-12-12
• [Presentation] Hydrogen Permeation of Melt-Spun Metallic Glassy Alloy Membrane and its Application to Hydrogen Production by Methanol Steam Reforming (2008)
  • Author(s): S. Yamaura, W. Zhang, A. Inoue
  • Organizer: The IUMRS International Conference in Asia 2008 (IUMRS-ICA 2008)
  • Place of Presentation: Nagoya Congress Center, Nagoya
  • Year and Date: 2008-12-12
• [Presentation] Ni-Nb-Zr系アモルファス合金の水素透過性に対する表面コーティングの影響 (2008)
  • Author(s): 山浦真一、木村久道、井上明久
  • Organizer: 日本金属学会
  • Place of Presentation: 熊本大学
  • Year and Date: 2008-09-24
• [Presentation] Ni-Nb-Zr系アモルファス合金の水素透過性に対する表面コーティングの影響 (2008)
  • Author(s): 山浦真一, 木村久道, 井上明久
  • Organizer: 日本金属学会秋期大会
  • Place of Presentation: 熊本大学
  • Year and Date: 2008-09-24
• [Presentation] Hydrogen Production by Methanol Steam Reforming using Amorphous Metal Membranes (2007)
  • Author(s): S. Yamaura, S. Uemiya, H.M. Kimura and A. Inoue
  • Organizer: The 6th Pacific Rim International Conference on Advanced Materials and Processing(PRICM-6)
  • Place of Presentation: Jeju,Korea
  • Year and Date: 2007-11-07
• [Presentation] Hydrogen Production by Methanol Steam Reforming using Amorphous Metal Membranes (2007)
  • Author(s): S. Yamaura, S. Uemiya, H. M. Kimura and A. Inoue
  • Organizer: The 6th Pacific Rim International Conference on Advanced Materials and Processing(PRICM-6)
  • Place of Presentation: ICC Jeju, Jeju, Korea
  • Year and Date: 2007-11-07
• [Presentation] Ni-Nb-Zr系アモルファス合金水素分離膜のメタノール水蒸気改質への適用 (2007)
  • Author(s): 山浦真一、上宮成之、木村久道、井上明久
  • Organizer: 日本金属学会
  • Place of Presentation: 岐阜大学
  • Year and Date: 2007-09-20
• [Presentation] Ni-Nb-Zr系アモルファス合金水素分離膜のメタノール水蒸気改質への適用 (2007)
  • Author(s): 山浦真一、上宮成之、木村久道、井上明久
  • Organizer: 日本金属学会秋期大会
  • Place of Presentation: 岐阜大学
  • Year and Date: 2007-09-20
• [Book] 「新機能材料金属ガラスの基礎と産業への応用」第2編第5章第1節1「水素透過膜」 (2009)
  • Author(s): 山浦真一
  • Publisher: 株式会社テクノシステム