Experimental study of the changes in electronic states caused by structural phase transition of ferromagnetic shape memories

• Project/Area Number: 18360330
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Structural/Functional materials
• Research Institution: Ritsumeikan University (2008); Osaka University (2006-2007)
• Principal Investigator: IMADA Shin Ritsumeikan University, 理工学部, 教授 (90240837)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥7,320,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,020,000); Fiscal Year 2008: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000); Fiscal Year 2007: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2006: ¥2,900,000 (Direct Cost: ¥2,900,000)
• Keywords: 強磁性形状記憶合金 / 電子状態 / 構造相転移 / 光電子分光 / 内殻磁気円二色性 / 磁性 / 金属物性 / 構造・機能材料 / 物性実験 / 放射光物性 / 内殻磁気円二色性分光 / アクチュエータ

Research Abstract

強磁性形状記憶合金の動作の元となる構造相転移の発現機構において中心的な役割を果たしていることが期待される電子状態の変化を、実験的に解明することを目的に、バルク敏感光電子分光および内殻磁気円二色性などの電子分光実験を行った結果、Ni-Mn-Fe-Ga系形状記憶合金物質において1次構造相転移前後で電子状態および磁気状態に有意な変化が有り、特にNiの電子状態が特徴的に変化していることが明らかになった。これはこの系の構造相転移のメカニズムについての重要な特徴をあらわしていると考えられ、バンド計算などによる電子状態の理論的解明とも組み合わせることで、強磁性形状記憶合金の設計に指針を与えるものである。

Research Products

• [Journal Article] Kondo lattice effects and the collapse oflattice coherence in Yb1-xLuxB12 studiedby hard x-ray photoelectron spectroscopy (2009)
  • Author(s): J. Yamaguchi, A. Sekiyama, S. Imada, H. Fujiwara, M. Yano, T. Miyamachi, G. Funabashi, M. Obara, A. Higashiya, K. Tamasaku, M. Yabashi, T. Ishikawa, F. Iga,T. Takabatake, S. Suga
  • Journal Title: Phys. Rev. B 79(12)
• [Journal Article] Electronic structures and p-d exchange interaction of Mn-doped diluted magnetic semiconductors (2008)
  • Author(s): S. Ueda, A. Sekiyama, T. Iwasaki, S. Imada, S. Suga, Y. Saitoh, W. Giriat, and S. Takeyama
  • Journal Title: Phys. Rev. B 78(20)
• [Journal Article] Bulk electronic structures and strong electron- phonon interactions in an electron-doped high-temperature superconductor (2008)
  • Author(s): M. Tsunekawa, A. Sekiyama, S. Kasai, S. Imada, H. Fujiwara, T. Muro, Y. Onose, Y. Tokura, S. Suga
  • Journal Title: New J. Phys. 10(7)
• [Journal Article] Significance of the inter-site Coulomb interaction between the O 2p and Cu 3d holes revealed by resonant inelastic x-ray scattering of Sr14Cu24O41 (2008)
  • Author(s): A. Higashiya, S. Imada, T. Murakawa, H. Fujiwara, S. Kasai, A. Sekiyama, S. Suga, K. Okada, M. Yabashi, K. Tamasaku, T. Ishikawa, H. Eisaki
  • Journal Title: New J. Phys 10(5)
• [Journal Article] Stability of electronic states across the metal-insulator transition in PrRu4P12 (2008)
  • Author(s): A. Yamasaki, S. Imada, A. Sekiyama, H. Fujiwara, M. Yano, J. Yamaguchi, G. Funahashi, H. Sugawara, D. Kikuchi, H. Sato, T. Muro, A. Higashiya, K. Tamasaku, M. Yabashi, H. Kobori, A. Sugimura, T. Ishikawa, H. Harima, S. Suga
  • Journal Title: Phys. Rev. B 77(16)
  • Peer Reviewed
• [Journal Article] Electronic and magnetic states of Mn2.97Co0.03GaC studied by soft X-ray photoemission and magnetic circular dichroism (2008)
  • Author(s): Wada, T. Muro, T. Nakamura, S. Imada
  • Journal Title: Jpn. J. Appl. Phys 47(3) Pages: 1567-1569
  • NAID: 40015945444
• [Journal Article] Electronic structure of CeRu2X2 (X=Si, Ge) in the paramagnetic phase studied by soft x-ray ARPES and hard x-ray photoelectron spectroscopy (2008)
  • Author(s): M. Yano, A. Sekiyama, H. Fujiwara, Y. Amano, S. Imada, T. Muro, M. Yabashi, K. Tamasaku, A. Higashiya, T. Ishikawa, Y. Onuki, and S. Suga
  • Journal Title: Phys. Rev. B 77(3)
• [Journal Article] Stability of electronic states across the metal-insulat or transition in PrRu_4P_<12> (2008)
  • Author(s): A. Yamasaki, S. Imada, A. Sekiyama, 他16名
  • Journal Title: Phys. Rev. B 77
  • Peer Reviewed
• [Journal Article] Electronic and magnetic states of Mn_2.97Co_0.03GaC studied by soft X-ray photoemission and magnetic circular dichroism (2008)
  • Author(s): A. Matsumoto, M. Tsunekawa, S. Suga, ほか
  • Journal Title: Jpn. J. Appl. Phys. 47
  • Peer Reviewed
• [Journal Article] Soft x-ray spectroscopy of the possibly heavy-fermion compound NdOs4Sb12 (2007)
  • Author(s): S. Imada, H. Higashimichi, A. Yamasaki, M. Yano, T. Muro, A. Sekiyama, S. Suga, H. Sugawara, D. Kikuchi, H. Sato
  • Journal Title: Phys. Rev. B 76(15)
• [Journal Article] Electron correlation and magnetic properties of c(2X2)CuMn/Cu(001) two-dimensional surface alloys (2007)
  • Author(s): A. Kimura, S. Asanao, T. Kambe, T. Xie, S. Watanabe, M. Taniguchi, S. Qiao, E. Hashimoto, H. Namatame, T. Muro, S. Imada, S. Suga
  • Journal Title: Phys. Rev. B 76(11)
• [Journal Article] Reduction of Kondo lattice effects in Yb1-xLuxAl3 observed by soft x-ray photoelectron spectroscopy (2007)
  • Author(s): J. Yamaguchi, A. Sekiyama, S. Imada, A. Yamasaki, M. Tsunekawa, T. Muro, T. Ebihara, Y. Onuki, S. Suga
  • Journal Title: New J. Phys 9(9)
• [Journal Article] Coexistence of strongly mixed valence and heavy-Fermion character in SmOs4Sb12 studied by soft and hard x-ray spectroscopy (2007)
  • Author(s): A. Yamasaki, S. Imada, H. Higashimichi, H. Fujiwara, T. Saita, T.Miyamachi, A. Sekiyama, H. Sugawara, D. Kikuchi, H. Sato, A. Higashiya, M. Yabashi, K. Tamasaku, D. Miwa, T. Ishikawa, S. Suga
  • Journal Title: Phys. Rev. Lett 98(15)
• [Journal Article] Electron correlation and themetal-insulator transition of the pyrochlore molybdates R2Mo2O7 (R=Nd, Sm, Gd, Tb, Y) (2007)
  • Author(s): A. Higashiya, S. Imada, A. Yamasaki, A. Irizawa, A. Sekiyama, S. Suga, Y. Taguchi, M. Iwama, K. Ohgushi, Y. Tokura
  • Journal Title: Phys. Rev. B 75(15)
• [Journal Article] Soft x-ray spectroscopy and microspectroscopy of correlated materials : photoemission and magnetic circular dichroism (2007)
  • Author(s): S. Imada, A. Sekiyama, S. Suga
  • Journal Title: J. Phys.: Condens. Matter 19(12)
• [Journal Article] Magnetism of L10 ordered FePt in thethinnest limit (2007)
  • Author(s): S. Imada, A. Yamasaki, S. Suga, T. Shima, K. Takanashi
  • Journal Title: Appl. Phys. Lett 90(13)
• [Journal Article] Bulk valence band of Ce(Pd1-xCux) 3studied by 3d [○!R] 4f resonant photoemission (2007)
  • Author(s): Sekiyama, F. Iga, A. Kasaya, S. Suga
  • Journal Title: J. Electron Spectrosc. Relat. Phenom 156-158 Pages: 441-444
• [Journal Article] Electronic and magnetic states of Ce 4felectrons in CeRh3B2 (2007)
  • Author(s): S. Imada, A. Yamasaki, M. Tsunekawa, A. Higashiya, A. Sekiyama, H. Sugawara, H. Sato, S. Suga
  • Journal Title: J. Electron Spectrosc. Relat. Phenom. 156-158 Pages: 436-440
• [Journal Article] Ultraviolet photoemission of Ni2MnZ (Z = Ga, In, and Sn) (2007)
  • Author(s): S. Imada, A. Yamasaki, A. Kusuda, A. Higashiya, A. Irizawa, A. Sekiyama, T. Kanomata, S. Suga
  • Journal Title: J. Electron Spectrosc. Relat. Phenom 156-158 Pages: 433-435
• [Journal Article] Three-Dimensional Bulk Fermiology of CeRu2Ge2 in the Paramagnetic Phase by Soft X-Ray hn-Dependent(700-860 ev) ARPES (2007)
  • Author(s): M. Yano, A. Sekiyama, H. Fujiwara, T. Saita, S. Imada, T. Muro, Y. Onuki, S. Suga
  • Journal Title: Phys. Rev. Lett 98(3)
• [Journal Article] Electron correlation and the metal-insulator transition of the pyrochlore molybdates R_2Mo_2O_7(R=Nd, Sm, Gd, Tb, Y) (2007)
  • Author(s): A. Higashiya, S. Imada, A. Yamasaki, A.Irizawa, ほか
  • Journal Title: Phys. Rev. B 75
  • Peer Reviewed
• [Journal Article] Coexistence of strongly mixed valence and heavy-Fermion character in SmOs_4Sb_12 studied by soft and hard x-ray spectroscopy (2007)
  • Author(s): A. Yamasaki, S. Imada, H. Higashimichi, H. Fujiwara, ほか
  • Journal Title: Phys. Rev. Lett. 98
  • Peer Reviewed
• [Journal Article] Reduction of Kondo lattice effects in Yb1_XLu_XAI_3 observed by soft x-ray photoelectron spectroscopy (2007)
  • Author(s): J. Yamaguchi, A. Sekiyama, S. Imada, A. Yamasaki, ほか
  • Journal Title: New J. Phys. 9
  • Peer Reviewed
• [Journal Article] Soft x-ray spectroscopy of the possibly heavy-fermion compound NdOs_4Sb_12 (2007)
  • Author(s): S. Imada, H. Higashimichi, A. Yamasaki, M. Yano, ほか
  • Journal Title: Phys. Rev. B 76
  • Peer Reviewed
• [Journal Article] High-resolution high-energy photoemission study of rare-earth heavy fermion systems (2007)
  • Author(s): A.Sekiyama, S.Imada, A.Yamasaki, S.Suga
  • Journal Title: Lect. Notes Phys. (Springer, Berlin Heidelberg) 715 Pages: 351-372
• [Journal Article] Composition dependence of Ni magnetic moment in Ni-Mn-based Heusler-type intermetallic compounds (2007)
  • Author(s): S.Imada, A.Yamasaki, T.Kanomata, 他
  • Journal Title: J. Magn. Magn. Mater. 310(印刷中)
• [Journal Article] Evidence of electron correlation playing essential roles in the metal to insulator transition of pyrochlore-type molybdates R2M0207 (R=Nd, Sm, Gd, Tb, Y) (2007)
  • Author(s): A.Higashiya, S.Imada, A.Yamasaki, 他
  • Journal Title: Phys. Rev. B 75 (11)(印刷中)
• [Journal Article] Perpendicular magnetization of L1_0-ordered FePt films in the thinnest limit (2007)
  • Author(s): S.Imada, A.Yamasaki, S.Suga, 他
  • Journal Title: Appl. Phys. Lett. 90 (12)(印刷中)
• [Journal Article] Three-Dimensional Bulk Fermiology of CeRu2Ge2 in the Paramagnetic Phase by Soft X-Ray hvDependent (700□ 860 eV) ARPES (2007)
  • Author(s): M.Yano, A.Sekiyama, H.Fujiwara, T.Saita, S.Imada, 他
  • Journal Title: Phys. Rev. Lett. 98 (3)
• [Journal Article] Composition dependence of Nimagnetic moment in Ni-Mn based Heusler-type intermetallic compounds (2006)
  • Author(s): S. Imada, A. Yamasaki, T. Kanomata, T. Muro, A. Sekiyama, S. Suga
  • Journal Title: J. Mang. Magn. Mater 310 Pages: 1857-1858
• [Journal Article] Photoemission spectroscopy and X-ray absorption spectroscopy studies of the superconducting pyrochlore oxide Cd2Re2O7 (2006)
  • Author(s): A. Irizawa, A. Higashiya, S. Kasai, T. Sasabayashi, A. Shigemoto, A. Sekiyama, S. Imada S, S. Suga, H. Sakai, H. Ohno, M. Kato, K. Yoshimura, H. Harima
  • Journal Title: J. Phys. Soc. Jpn 75(9)
• [Presentation] 充填スクッテルダイトNdOs4Sb12の価電子帯Nd3d-4f共鳴光電子分光 (2006)
  • Author(s): 今田真、東道啓聡、山崎篤志、関山明、菊地大輔、菅原仁、佐藤英行、菅滋正
  • Organizer: 日本物理学会, 2006年秋季大会
  • Place of Presentation: 千葉大学
• [Presentation] 充填スクッテルダイトNdOs4Sb12の価電子帯Nd3d-4f共鳴光電子分光 (2006)
  • Author(s): 今田真、東道啓聡、山崎篤志、関山明、菊地大輔、菅原仁、佐藤英行、菅滋正
  • Organizer: 日本物理学会2006年秋季大会
  • Place of Presentation: 千葉大学
• [Book] High-Resolution High-Energy Photoemission Study of Rare-Earth Heavy Fermion Systems
  • Author(s): A. Sekiyama, S. Imada, A. Yamasaki, S. Suga, Springer, Heidelberg
  • Publisher: Very High Resolution Photoelectron Spectroscopy(The Lecture Notes in Physics 715)(S. Hufner編)