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A Novel Approach of Methane Activation and Conversion of Methane to Fine Chemicals

Research Project

Project/Area Number 18360384
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionTokyo Institute of Technology

Principal Investigator

BABA Toshihide  Tokyo Institute of Technology, 大学院・総合理工学研究科, 教授 (50165057)

Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥18,100,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥2,700,000)
Fiscal Year 2008: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2007: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2006: ¥6,400,000 (Direct Cost: ¥6,400,000)
Keywordsメタン / 活性化 / エチレン / プロピレン / 銀イオン / ゼオライト / 芳香族炭化水素 / メタンの活性化 / エチレン転化反応 / 銀イオン交換ゼオライト / 金属イオン交換ゼオライト / プロピレン合成 / SAPO-34
Research Abstract

新しいプロピレン合成法を見出した。そのひとつは, 銀イオン交換を用いたエチレン共存下でのメタン転化反応である。もうひとつはプロトン交換ゼオライトによるエチレン転化反応である。
銀イオン交換ゼオライトではメタンが不均等解離し, CH_3^+が生成する。これは400℃付近でエチレンと反応してCH_3CH^+CH_3を生成する。メタンが転化していることは, ^<13>CH_4とCH_2=CH_2とを反応させると^<13>CC_2H_6が生成することから支持された。一方, プロトン交換ゼオライトではC_3H_6が生成し, ^<13>CC_2H_6が生成しない。この結果はプロトン交換ゼオライトではエチレンからプロピレンが生成していることを示している。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (34 results)

All 2009 2008 2007 2006

All Journal Article (23 results) (of which Peer Reviewed: 20 results) Presentation (7 results) Book (4 results)

  • [Journal Article] Asymmetric 1, 3-Dipolar Cycloaddition Reactions of Nitrile Oxides Catalyzed by Chiral Binaphthyldiimine-Ni(II)Complexes2009

    • Author(s)
      Hiroyuki SUGA, Yuki ADACHI, Kouhei FUJIMOTO, Toshihide BABA
    • Journal Title

      J. Org. Chem. 74

      Pages: 1099-1113

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Acidic Property of Sulfo-group Functionalized Microporous and Mesoporous Silica by Adsorption Microcalorimetry2008

    • Author(s)
      Fei-Yee Yeoh, Akihiko Matsumoto, Yoshiyuki Iwase, Toshihide Baba
    • Journal Title

      Catal. Today 132

      Pages: 46-51

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Synthetic Methods for Propene Production Using Zeolite Catalysts2008

    • Author(s)
      Toshihide Baba , Koji Inazu, Toru Koyama, Akihiko Matsumoto
    • Journal Title

      Prep. Pap.-Am. Chem. Soc., Div. Pet. Chem. 53

      Pages: 1219-1222

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Propene Production from Ethene and Methane Using silver and Proton-exchanged Zeolite Catalysts2008

    • Author(s)
      Koji Inazu, Toru Koyama, Akimitsu Miyaji, Toshihide Baba
    • Journal Title

      J. JPN Petro. Inst. 51

      Pages: 205-216

    • NAID

      10022018196

    • Related Report
      2008 Annual Research Report 2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of Sulfo-functionalized Ordered Mesoporous Silica2008

    • Author(s)
      Fei-Yee YEOH, Akihiko MATSUMOTO, Yoshiyuki IWASE, Toshihide BABA
    • Journal Title

      Ads. Sci. Technol 26

      Pages: 479-490

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atmospheric Occurrence of 2-Nitrobenzanthrone Associated with Airborne Particles in Central Tokyo2008

    • Author(s)
      Koji Inazu, Vu Duc Nam , Takahiro Asato, Hiroshi Okochi,Yoshiharu Hisamatsu, Takaaki Kobayashi, Toshihide Baba
    • Journal Title

      Polycyclic Aromatic Compounds 28

      Pages: 562-577

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Acidic Property of Sulfo-group Functionalized Microporous and Mesoporous Silica by Adsorption Microcalorimetry2008

    • Author(s)
      Fei-Yee Yeoh, Akihiko Matsumoto, Yoshiyukl Iwase Toshihide Baba
    • Journal Title

      Catal. Today 132

      Pages: 46-51

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Synthetic Methods for Propene Production Using Zeolite Catalysts2008

    • Author(s)
      Toshihide Baba, Koji Inazu, Toru Koyama, Akihiko Matsumoto
    • Journal Title

      Prep. Pap. -Am. Chem. Soc, Div. Pet. Chem. 53

      Pages: 1219-1222

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction Kinetics of Methanol Carbonylation to Methyl Formate Catalyzed CH_3O^-exchange Resin2007

    • Author(s)
      Yasuyoshi Iwase, Takaaki Kobayashi, Koji Inazu, Akimitsu Miyaji, Toshihide Baba
    • Journal Title

      Catal. Lett 118

      Pages: 146-150

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis of Pure ZSM-22 under Mild Conditions2007

    • Author(s)
      Dilshad Masih, Takaai Kobayashi and Toshihide Baba
    • Journal Title

      Chem. Comm.

      Pages: 3303-3305

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electronic and Structural Promotion of Barium Hexaaluminate as a Ruthenium Catalyst Support for Ammonia Synthesis2007

    • Author(s)
      Zhixiong You, Koji Inazu, Toshihide Baba
    • Journal Title

      J. Catal. 251

      Pages: 321-331

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Properties of Silver-exchanged Zeolites for Propene Production by Conversion of Methane in the Presence of Ethene2007

    • Author(s)
      Toshihide Baba, Yasuyoshi Iwase, Koji Inazu, Dilshad Masih, Akihiko Matsumoto
    • Journal Title

      Micropor. Mesopor. Mater 101

      Pages: 142-147

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dipole-LUMO/Dipolarophile-HOMO Controlled Asymmetric Cycloadditions of Carbonyl Ylides Catalyzed by Chiral Lewis Acids2007

    • Author(s)
      Hiroyuki SUGA, Daisuke ISHIMOTO, Satoshi HIGUCHI, Motoo OHTSUKA, Tadashi ARIKAWA, Teruko TSUCHIDA, Toshihide BABA
    • Journal Title

      Org. Lett. 9

      Pages: 4359-4362

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of Methane over In-loaded ZSM-5 Zeolite in the Presence of Ethene2007

    • Author(s)
      Toshihide Baba, Koji Inazu, Yasuyoshi Iwase
    • Journal Title

      Stud. Surf. Sci. Catal. 172

      Pages: 425-428

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Properties of Silver-exchanged Zeolites for Propene Production by Conversion of Methane in the Presence of Ethene2007

    • Author(s)
      T. Baba, Y. Iwase, K. Inazu, and A. Matsumoto
    • Journal Title

      Micropor. Mesopor. Mater. 101

      Pages: 142-147

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of Methane over In-loaded ZSM-5 Zeolite in the Presence of Ethene2007

    • Author(s)
      T. Baba, K. Inazu and Y. Iwase
    • Journal Title

      Stud. Surf. Sci. Catal. 172

      Pages: 425-428

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterolytic Dissociation of C-H Bond of Methane over Ag^+-exchanged Zeolites and Conversion of Methane into Higher Hydrocarbons in the Presence of Ethene or Benzene2006

    • Author(s)
      Toshihide Baba, Koji Inazu
    • Journal Title

      Chem. Lett. High Light Review 35

      Pages: 142-147

    • NAID

      10017166618

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Acidic Character and Catalytic Activity of Sulpho-functionalized Porous Silica with an Ordered Structure2006

    • Author(s)
      Akihiko Matsumoto, Fei-Yee Yeoh, Shunsuke, Fujihara, Kazuo Tsutsumi, Toshihide Baba
    • Journal Title

      Ads. Sci. Technol. 24

      Pages: 450-459

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Selective Conversion of Ethene to Propene over SAPO-34 as a Solid Acid Catalyst, Appl2006

    • Author(s)
      Hiroshi Oikawa, Yasunori Shibata, Koji Inazu, Yasuyoshi Iwase, Kazuhito Murai, Toshihide Baba
    • Journal Title

      Catal. A General 312

      Pages: 181-185

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Steam Reforming of Acetic Acid as a Biomass Derived Oxygenate : Bifunctional Pathway for Hydrogen Formation over Pt/ZrO_2Catalysts2006

    • Author(s)
      Kazuhiro Takanabe, Ken-ichi Aika m Koji Inazu, Toshihidie Baba, K. Seschan, Leon Lefferts
    • Journal Title

      J. Catal. 243

      Pages: 263-269

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Heterolytic Dissociation of C-H Bond of Methane over Ag^+-exchanged Zeolites and Conversion of Methane into Higher Hydrocarbons in the Presence of Ethene or Benzene2006

    • Author(s)
      Toshihide Baba, Koji Inazu
    • Journal Title

      Chem. Lett. High light review 35

      Pages: 142-147

    • NAID

      10017166618

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Highly Selective Conversion of Ethene to Propene over SAPO-34 as a Solid Acid Catalyst2006

    • Author(s)
      Hiroshi Oikawa, Yasunori Shibata, Koj Inazu, Yasuyoshi Iwase, Kazuhito Murai, Shinya Hyodo, Genta Kobayashi, Toshihide Baba
    • Journal Title

      Appl. Catal. A General 312

      Pages: 181-185

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Acidic Character and Catalytic Activity of Sulpho-functionalized Porous Silica with an Ordered Structure2006

    • Author(s)
      Akihiko Matsumoto, Fei-Yee Yeoh, Shunsuke Fujihara, Kazuo Tsutsumi, Toshihide Baba
    • Journal Title

      Ads. Sci. Technol. 24

      Pages: 451-459

    • Related Report
      2006 Annual Research Report
  • [Presentation] Key Catalysis of Metal Cation-exchanged ZSM-5 Zeolites for Conversion of CH_4 in the Presence of C_2H_42009

    • Author(s)
      Toshihide Baba
    • Organizer
      American chemical Society
    • Place of Presentation
      237^<th> ACS Meeting Salt Lake City
    • Year and Date
      2009-03-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] Selective Conversion of Ethene to Propene over H^+-exchanged Zeolites2008

    • Author(s)
      Toshihide Baba, Koji Inazu, Yoshiyuki Iwase
    • Organizer
      14th International Congress on Catalysis
    • Place of Presentation
      Korea(PIII-51-20)
    • Year and Date
      2008-07-26
    • Related Report
      2008 Final Research Report
  • [Presentation] Effect of Cesium on Hydrogen Adsorption to magnesia-Supported Rethenium Catalysts for Ammonia Synthesis2008

    • Author(s)
      Koji Inazu, Shoko Sato Ken-ichi Aika, Toshihdie Baba
    • Organizer
      14th International Congress on Catalysis
    • Place of Presentation
      Korea(PII-25-19)
    • Year and Date
      2008-07-25
    • Related Report
      2008 Final Research Report
  • [Presentation] Catalytic Propene Production from Ethene Using Small Pore Molecular Sieves2008

    • Author(s)
      Toru Koyama, Koji Inazu, Akimitsu Miyaji, Toshihide Baba
    • Organizer
      ICC 14 Pre-Symposium 50^<th>Aniversary of the Catalysis Society of Japan
    • Place of Presentation
      Kyoto(2042)
    • Year and Date
      2008-07-20
    • Related Report
      2008 Final Research Report
  • [Presentation] Characteristics of Methoxycarbonylation of Aromatic Diamines with Dimethyl Carbonate to Dicarbamate Using Zinc Acetate Catalyst, The Netherlands-Japan Catalysis Seminar2006

    • Author(s)
      Toshihide Baba, Non phosgene reaction
    • Organizer
      Catalysis Technology for Green and Sustainable Chemistry
    • Place of Presentation
      Sophia University(2006)
    • Year and Date
      2006-11-07
    • Related Report
      2008 Final Research Report
  • [Presentation] Conversion of Methane over In-loaded ZSM-5 in the Presence of Ethene or Benzene2006

    • Author(s)
      Toshihide Baba, Koji Inadu
    • Organizer
      International Symposium on Zeolite and Microporous Crystals 2006
    • Place of Presentation
      Yonago, Japan(OC-25)
    • Year and Date
      2006-08-03
    • Related Report
      2008 Final Research Report
  • [Presentation] Conversion of Methane over In-loaded ZSM-5 Zeolite in the Presence of Ethene2006

    • Author(s)
      Toshihide Baba, Kazuhito Murai, Koji Inadu
    • Organizer
      Tokyo Conference on Advanced Catalytic Science and Technology 2006
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2006-07-16
    • Related Report
      2008 Final Research Report
  • [Book] 触媒技術の動向と展望2008

    • Author(s)
      馬場俊秀, 触媒学会, 触媒年鑑
    • Publisher
      プロピレンの合成法の現状とその触媒
    • Related Report
      2008 Final Research Report
  • [Book] メタン高度化学変換技術集成2008

    • Author(s)
      馬場俊秀
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] 触媒便覧2008

    • Author(s)
      馬場俊秀
    • Publisher
      講談社
    • Related Report
      2008 Final Research Report
  • [Book] 触媒の劣化原因解明と防止対策固体塩基触媒の特徴とその利用法2006

    • Author(s)
      馬場俊秀
    • Publisher
      技術情報協会
    • Related Report
      2008 Final Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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