Photoinduced hydrogen evolution based on biological reaction
Project/Area Number |
18360386
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Catalyst/Resource chemical process
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Research Institution | Tokyo Institute of Technology |
Principal Investigator |
OKURA Ichiro Tokyo Institute of Technology, 大学院・生命理工学研究科, 教授 (90089821)
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Co-Investigator(Kenkyū-buntansha) |
朝倉 則行 東京工業大学, 大学院・生命理工学研究科, 講師 (40401559)
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Co-Investigator(Renkei-kenkyūsha) |
ASAKURA Noriyuki 東京工業大学, 大学院・生命理工学研究科, 講師 (40401559)
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Project Period (FY) |
2006 – 2009
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Project Status |
Completed (Fiscal Year 2009)
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Budget Amount *help |
¥17,310,000 (Direct Cost: ¥15,600,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2009: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2008: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2007: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2006: ¥9,900,000 (Direct Cost: ¥9,900,000)
|
Keywords | 水素生産 / ヒドロゲナーゼ / シトクロム / ヘム / ポルフィリン / 光暦電子移動 / 水素発生 / 光励起電子移動 |
Research Abstract |
Photoinduced hydrogen evolution with an enzyme and cytochrome c3 (an redox protein) was developed by addition photo-reactivity to cytochrome c3. Cytochrome c3 has four hemes in one molecule and one of hemes was exchange into Zn-porphryn, so that photoinduced electron transfer from Zn porphyrin to three hemes in cytochrome c3 occurred. The Zn porphrin cytochrome c3 applied to photoinduced hydrogen evolution and hydrogen production occurred.
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Report
(6 results)
Research Products
(36 results)
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[Journal Article]2007
Author(s)
Shin Iida, Yusuke Kawano, Noriyuki Asakura, Kenji Tabata, Ichiro Okura, Toshiaki Kamachi
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Journal Title
Chem. Let. 36
Pages: 184-185
Related Report
Peer Reviewed
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[Journal Article]2007
Author(s)
Shin Iida, Noriyuki Asakura, Kenji Tabata, Ichiro Okura, Toshiaki Kamachi
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Journal Title
Porphyrins and Phthalocyanines 11(1)
Pages: 66-66
Related Report
Peer Reviewed
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[Journal Article]2007
Author(s)
Ihara, M., Nakamoto, H., Kamachi, T., Okura, I., Maeda, M.
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Journal Title
Photoinduced Photochem Photobiol. 82
Pages: 1677-1686
Related Report
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[Journal Article]2007
Author(s)
Shin Iida, Noriyuki, Asakura, Kenji Tabata, Ichiro Okura, Toshiaki Kamachi
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Journal Title
Chem. Lett 36
Pages: 184-185
Related Report
Peer Reviewed
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[Journal Article]2007
Author(s)
飯田慎、朝倉則行、田畠健治、大倉一郎、蒲池利章
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Journal Title
J. Porphyrins and Phthalocyanines 11(1)
Pages: 66-66
Related Report
Peer Reviewed
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[Journal Article]2006
Author(s)
Shin Iida, Noriyuki Asakura, Kenji Tabata, Ichiro Okura, Toshiaki Kamachi
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Journal Title
ChemBioChem 7
Pages: 1853-1855
Related Report
Peer Reviewed
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[Journal Article]2006
Author(s)
飯田慎、朝倉則行、田畠健治、大倉一郎、蒲池利章
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Journal Title
Chembiochem 7
Pages: 1853-1853
Related Report
Peer Reviewed
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[Journal Article]2006
Author(s)
朝倉則行、蒲池利章、大倉一郎
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Journal Title
Measurement Science and Technology 17
Pages: 1237-124
Related Report
Peer Reviewed
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[Book] 化学同人2008
Author(s)
朝倉則行、蒲池利章、大倉一郎
Total Pages
190
Publisher
生物物理化学
Related Report
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