Development of silsesquioxane-based novel catalysts for environmentally benign organic transformations

• Project/Area Number: 18360388
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Kyoto University
• Principal Investigator: WADA Kenji Kyoto University, 大学院・工学研究科, 講師 (10243049)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥10,780,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥1,680,000); Fiscal Year 2008: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2007: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2006: ¥3,500,000 (Direct Cost: ¥3,500,000)
• Keywords: シルセスキオキサン / 環境対応型触媒 / ルテニウム / チタン / パラジウム / ナノクラスター / 固定化触媒 / ゲル触媒 / ナノ構造制御 / アルケンのエポキシ化 / ヒドロホルミル化 / アルコール酸化反応

Research Abstract

金属含有シルセスキオキサンの特長を生かして,制御された細孔・ビルドアップ構造を有する新しいタイプの環境対応型触媒開発を検討し,アルコールの空気酸化反応に有効なシルセスキオキサン保護パラジウムナノクラスター触媒,アルケンのヒドロホルミル化反応に有効なルテニウム種内包多孔質触媒,アルケンのエポキシ化反応に高活性を示すシリカ固定化チタン含有シルセスキオキサン触媒およびチタン含有シルセスキオキサンゲル触媒を新たに開発した.

Research Products

• [Journal Article] Preparation of porous ruthenium catalysts utilizing a silsesquioxane ligand ; catalytic activity towards hydroformylation of 1-octene (2009)
  • Author(s): Kenji WADA, Ryuta TOMOYOSE, Teruyuki KONDO, Take-aki MITSUDO
  • Journal Title: Applied Catalysis A General 365 Pages: 72-79
  • Peer Reviewed
• [Journal Article] Ti-Containing Silsesquioxane Gels with Tunable Porosity: Preparation and Catalytic Activity for the Epoxidation of Cyclooctene by Aqueous Hydrogen Peroxide (2009)
  • Author(s): Kenji WADA, Kazuhiko HIRABAYASHI, Naoki WATANABE, Shingo YAMAMOTO, Teruyuki KONDO, Take-aki MITSUDO, Masashi INOUE
  • Journal Title: Topics in Catalysis 52 Pages: 693-698
  • Peer Reviewed
• [Journal Article] Preparation of porous ruthenium catalysts utilizing a silsesquioxane ligand ; catalytic activity towards hydroformyation of l-octene (2009)
  • Author(s): Kenji Wada, Ryuta Tomoyose, Teruvuki Kondo, Take-aki Mitsudo
  • Journal Title: Applied Catalysis A General 356 Pages: 72-79
  • Peer Reviewed
• [Journal Article] Ti-Containing Silsesquioxane Gels with Tunable Porosity : Preparation and Catalytic Activity for the Epoxidation of Cyclooctene by Aqueous Hydrogen Peroxide (2009)
  • Author(s): Kenji Wada, Kazuhiko Hirabayashi, Naoki Watanabe, Shingo Yamamoto, Teruyuki Kondo, Take-aki Mitsudo, Masashi Inoue
  • Journal Title: Catalysis Today
  • Peer Reviewed
• [Journal Article] Preparation of silica-immobilized titanium-containing silsesquioxane catalysts and activity for the epoxidation of alkenes (2008)
  • Author(s): Kenji WADA, Naoki WATANABE, Teruyuki KONDO, Take-aki MITSUDO
  • Journal Title: Chemical Engineering Science 63 Pages: 4917-4923
  • Peer Reviewed
• [Journal Article] Preparation of silica-immobilized titanium-containing silsesquioxane catalysts and activity for the epoxidation of alkenes (2008)
  • Author(s): Kenji Wada, Naoki Watanabe, Teruyuki Kondo, Take-aki Mitsudo
  • Journal Title: Chemical Engineering Science (印刷中)(Web出版済)
  • Peer Reviewed
• [Journal Article] Preparation and the Catalytic Activity of Novel Pd Nanocluster Catalysts utilizing an Oligosilsesquioxane Ligand (2006)
  • Author(s): Kenji WADA, Kosuke, YANO, Teruyuki KONDO, Take-aki MITSUDO
  • Journal Title: Catalysis Letters 112 Pages: 63-67
  • Peer Reviewed
• [Journal Article] Preparation and the Catalytic Activity of Novel Pd Nanocluster Catalysts utilizing an Oligosilsesquioxane (2006)
  • Author(s): Kenji WADA, Kosuke, YANO, Teruyuki KONDO, Take-aki MITSUDO
  • Journal Title: Catalysis Letters 112 Pages: 63-67
• [Presentation] Ti含有シルセスキオキサンを活用した酸化物触媒の調製とアルケンのエポキ-シ化活性 (2008)
  • Author(s): 佐久川周子, 和田健司, 井上正志
  • Organizer: 石油学会関西支部第17回研究発表会日本エネルギー学会関西支部第53回研究発表会合同研究発表会
  • Place of Presentation: 京都市
  • Year and Date: 2008-12-05
• [Presentation] Ti含有シルセスキオキサンを活用した酸化物触媒の調製とアルケンのエポキシ化活性 (2008)
  • Author(s): 佐久川周子, 和田健司, 井上正志
  • Organizer: 石油学会関西支部第17回研究発表会日本エネルギー学会関西支部第53回研究発表会合同研究発表会
  • Place of Presentation: 京都市
  • Year and Date: 2008-12-05
• [Presentation] 金属含有籠状シルセスキオキサンを活かした触媒開発(依頼講演) (2008)
  • Author(s): 和田健司
  • Organizer: 第27回無機高分子研究討論会
  • Place of Presentation: 東京都
  • Year and Date: 2008-11-07
• [Presentation] チタン含有シルセスキオキサンを用いた新しい触媒の開発 (2008)
  • Author(s): 平林和彦, 和田健司, 光藤武明
  • Organizer: 第100回触媒討論会
  • Place of Presentation: 札幌市
  • Year and Date: 2008-09-19
• [Presentation] Ti-containing Silsesquioxane Gel Catalysts : Synthesis and Activity for Epoxidation of Alkenes by the Use of aq. H_2O_2 (2008)
  • Author(s): Kenji Wada, Kazuhiko Hirabayashi, Masashi Inoue
  • Organizer: International Symposium on Creation and Control of Advanced Selective Catalysis as the celebration of 50th anniversary of the Catalysis Society of Japan
  • Place of Presentation: 京都市
  • Year and Date: 2008-07-09
• [Presentation] Ti-containing Silsesquioxane Gel Catalysts : Synthesis and Activity for Epoxidation of Alkenes by the Use of aq. H202 (2008)
  • Author(s): Kenji Wada, Kazuhiko Hirabayashi, Masashi Inoue
  • Organizer: International Symposium on Creation and Control of Advanced Selective Catalysis as thecelebration of 50th anniversary of the Catalysis Society of Japan
  • Place of Presentation: 京都市
  • Year and Date: 2008-07-09
• [Presentation] シルセスキオキ-サンを活用した配位性官能基含有有機-無機複合ゲルの調製 (2008)
  • Author(s): 佐久川周子, 平林和彦, 和田健司, 井上正志
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京都
  • Year and Date: 2008-03-27
• [Presentation] ナノサイズのシルセスキオキサン分子を活用したチタン含有有機無機複合触媒の調製 (2008)
  • Author(s): 平林和彦, 和田健司, 井上正志
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京都
  • Year and Date: 2008-03-27
• [Presentation] ナノサイズのシルセスキオキサン分子を活用したチタン含有有機無機複合触媒の調製 (2008)
  • Author(s): 平林和彦、和田健司、井上正志
  • Organizer: 日本化学会第88春季年会(2PB173)
  • Place of Presentation: 立教大学池袋キャンパス(東京都)
  • Year and Date: 2008-03-27
• [Presentation] シルセスキオキサンを活用した配位性官能基含有有機-無機複合ゲルの調製 (2008)
  • Author(s): 佐久川周子、平林和彦、和田健司、井上正志
  • Organizer: 日本化学会第88春季年会(2PB174)
  • Place of Presentation: 立教大学池袋キャンパス(東京都)
  • Year and Date: 2008-03-27
• [Presentation] Preparation and Catalytic Activity of Silsesquioxane-based Transition Metal Catalysts C&FC2007 (2007)
  • Author(s): Kenji Wada, Kousuke Yano, Ryuta Tomoyose, Take-aki Mitsudo
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2007
  • Place of Presentation: シンガポール
  • Year and Date: 2007-12-20
• [Presentation] Preparation and Catalytic Activity of Silsesquioxane-based Transition Metal Catalysts (2007)
  • Author(s): K. Wada, K. Yano, R. Tomoyose, T. Mitsudo
  • Organizer: C&FC2007 International Symposium on Catalysis and Fine Chemicals 2007
  • Place of Presentation: 南洋工科大学(シンガポール)
  • Year and Date: 2007-12-20
• [Presentation] Ti-containing silsesquioxane gel catalysts : Synthesis and activity for epoxidation of alkenes by the use of aq. H_2O_2 (2007)
  • Author(s): Kazuhiko Hirabayashi, Kenji Wada, Masashi Inoue
  • Organizer: C&FC2007 International Symposium on Catalysis and Fine Chemicals 2007
  • Place of Presentation: シンガポール
  • Year and Date: 2007-12-18
• [Presentation] Ti-containing silsesquioxane gel catalysts: Synthesis and activity for epoxidation of alkenes by the use of aq. H202 (2007)
  • Author(s): K. Hirabayashi, K. Wada, M. Inoue
  • Organizer: C&FC2007 International Symposium on Catalysis and Fine Chemicals 2007
  • Place of Presentation: 南洋工科大学(シンガポール)
  • Year and Date: 2007-12-18
• [Presentation] チタン含有シルセスキオキサンを用いた新しい触媒の開発 (2007)
  • Author(s): 平林和彦、和田健司、光藤武明
  • Organizer: 第100回触媒討論会(3K12)
  • Place of Presentation: 北海道大学(札幌市)
  • Year and Date: 2007-09-19
• [Presentation] チタン含有シルセスキオキサンゲル触媒の細孔構造制御 (2007)
  • Author(s): 和田健司, 平林和彦, 山本伸吾, 光藤武明
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 吹田市
  • Year and Date: 2007-03-26
• [Presentation] シルセスキ-オキサン配位子を活用したRu種ナノ粒子内包多孔質酸化物の調製と触媒活性 (2006)
  • Author(s): 友寄隆太, 和田健司, 近藤輝幸, 光藤武明
  • Organizer: 石油学会関西支部第15回研究発表会日本エネルギー学会関西支部第51回研究発表会合同研究発表会
  • Place of Presentation: 京都市
  • Year and Date: 2006-12-08
• [Presentation] チタン含有シルセスキオキサンゲル触媒の構造制御とアルケンのエポキシ化活性 (2006)
  • Author(s): 和田健司, 平林和彦, 山本伸吾, 近藤輝幸, 光藤武明
  • Organizer: 石油学会鹿児島大会
  • Place of Presentation: 鹿児島市
  • Year and Date: 2006-12-01
• [Presentation] Preparation, Activity, and Dynamic Behavior of Ti-Containing Silsesquioxane Catalysts for the Epoxidation of Alkenes (2006)
  • Author(s): Kenji Wada, Shingo Yamamoto, Naoki Watanabe, Take-aki Mitsudo
  • Organizer: 5th International Conference on Unsteady-State Processes in Catalysis
  • Place of Presentation: 吹田市
  • Year and Date: 2006-11-24
• [Presentation] シルセスキオキサン配位子を活用したRu種ナノ粒子内包多孔質酸化物の調製と触媒活性 (2006)
  • Author(s): 和田健司, 友寄隆太, 近藤輝幸, 光藤武明
  • Organizer: 第98回触媒討論会
  • Place of Presentation: 富山市
  • Year and Date: 2006-09-29
• [Presentation] チタン含有シルセスキオキサンゲル触媒の調製とアルケンのエポキシ化活性 (2006)
  • Author(s): 和田健司, 山本伸吾, 渡辺直樹, 光藤武明
  • Organizer: 日本ゾルゲル学会第4回討論会
  • Place of Presentation: 岡山市
  • Year and Date: 2006-07-27
• [Presentation] Preparation of Novel Ti-Containing Silsesquioxane-Based Heterogeneous Catalysts for the Epoxidation of Alkenes (2006)
  • Author(s): Kenji Wada, Naoki Watanabe, Shingo Yamamoto, Teruyuki Kondo, Take-aki Mitsudo
  • Organizer: 5th Tokyo Conference on Advanced Catalytic Science and Technology
  • Place of Presentation: 東京都
  • Year and Date: 2006-07-26
• [Book] シルセスキオキ-サン材料の化学と応用展開(「金属含有シルセスキオキサンの触媒への応用」の章を分担執筆) (2007)
  • Author(s): 和田健司(分担執筆)
  • Publisher: シーエムシー出版
• [Book] 金属含有シルセスキオキサンの触媒への応用(シルセスキオキサン材料の化学と応用展開(分担執筆)) (2007)
  • Author(s): 和田健司
  • Total Pages: 15
  • Publisher: シーエムシー出版
• [Book] ケイ素化合物の選定と最適利用技術(「籠状シルセスキオキサンの触媒への応用」の章を分担執筆) (2006)
  • Author(s): 和田健司(分担執筆)
  • Publisher: (株)技術情報協会