Catalytic reaction over oxide catalysts with an electric field at ambient temperature and atmospheric pressure

• Project/Area Number: 18360390
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Waseda University
• Principal Investigator: SEKINE Yasushi Waseda University, 理工学術院, 准教授 (20302771)
• Co-Investigator(Kenkyū-buntansha): KIKUCHI Eiichi 早稲田大学, 先進理工学部・応用化学科, 教授 (90063734) ; MATSUKATA Masahiko 早稲田大学, 先進理工学部・応用化学科, 教授 (00219411)
• Project Period (FY): 2006 – 2009
• Project Status: Completed (Fiscal Year 2009)
• Budget Amount: ¥18,350,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥3,150,000); Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2008: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000); Fiscal Year 2007: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000); Fiscal Year 2006: ¥4,700,000 (Direct Cost: ¥4,700,000)
• Keywords: 電場 / 非平衡 / 廃熱回収 / 非平衡放電 / メタンの酸化 / 触媒 / 低温化 / 水素製造

Research Abstract

We investigated synergetic effects of hybridization of electric field (or plasma) and catalyst. We found that catalytic reactions in plasma proceeded very effectively at ambient temperature, and catalytic reactions in an electric field promoted steam reforming of methane at very low temperature like as 423K.

Research Products

• [Journal Article] Low temperature hydrogen production by highly-efficient novel catalytic system assisted with electric field (2010)
  • Author(s): Y. Sekine*, M. Haraguchi, M. Tomioka, M. Matsukata, E. Kikuchi
  • Journal Title: J. Phys. Chem. A 114(11) Pages: 3824-3833
  • Peer Reviewed
• [Journal Article] Pt and/or Pd supported/incorporated catalyst on perovskite-type oxide for water gas shift reaction (2010)
  • Author(s): R. Watanabe, Y. Sekine, H. Takamatsu, Y. Sakamoto, S. Aramaki, M. Matsukata, E. Kikuchi
  • Journal Title: Top. in Catal. 53(7) Pages: 621-628
  • Peer Reviewed
• [Journal Article] Simultaneous dry reforming and desulfurization of biomethane with non equilibrium electrical discharge at ambient temperature (2010)
  • Author(s): Y. Sekine, J. Yamadera, M. Matsukata, E. Kikuchi
  • Journal Title: Chem. Eng. Sci. 65(1) Pages: 487-491
  • Peer Reviewed
• [Journal Article] Low temperature hydrogen production by highly-efficient novel catalytic system assisted with electricfield (2010)
  • Author(s): Y.Sekine, M.Haraguchi, M.Tomioka, M.Matsukata, E.Kikuchi
  • Journal Title: J.Phys.Chem.A. 114 Pages: 3824-3833
  • Peer Reviewed
• [Journal Article] Pt and/or Pd supported/incorporated catalyst on perovskite-type oxide for water gas shift reaction (2010)
  • Author(s): Y.Sekine, et al.
  • Journal Title: Topics in Catalysis (in press)
  • Peer Reviewed
• [Journal Article] Simultaneous Dry Reforming and Desulfurization of Biomethane with Non-equilibrium Electrical Discharge at Ambient Temperature (2010)
  • Author(s): Y.Sekine, J.Yamadera, M.Matsukata, E.Kikuchi
  • Journal Title: Chemical Engineering Science 65 Pages: 487-491
  • Peer Reviewed
• [Journal Article] Steam reforming of ethanol over cobalt catalyst modified with small amount of iron (2009)
  • Author(s): Y. Sekine, A. Kazama, Y. Izutsu, M. Matsukata, E. Kikuchi
  • Journal Title: Catal. Lett. 132 Pages: 329-334
  • Peer Reviewed
• [Journal Article] Novel perovskite-type oxide catalysts for dehydrogenation of ethylbenzene to styrene (2009)
  • Author(s): R. Watanabe, Y. Sekine, M. Matsukata, E. Kikuchi
  • Journal Title: Catal. Lett. 131 Pages: 1-2
  • Peer Reviewed
• [Journal Article] Catalytic degradation of ethanol in an electric field (2009)
  • Author(s): Y. Sekine, M. Tomioka, M. Matsukata, E. Kikuchi
  • Journal Title: Catal. Today 146,1-2 Pages: 183-187
  • Peer Reviewed
• [Journal Article] Oxidative coupling of methane on Fe doped La2O3 catalyst (2009)
  • Author(s): Y. Sekine, K. Tanaka, M. Matsukata, E. Kikuchi
  • Journal Title: Energy Fuels 23(2) Pages: 613-616
  • Peer Reviewed
• [Journal Article] Synergistic effect of Pt or Pd and perovskite oxide for water gas shift reaction (2009)
  • Author(s): Y. Sekine, H. Takamatsu, S. Aramaki, K. Ichishima, M. Takada, M. Matsukata, E. Kikuchi
  • Journal Title: Appl. Catal. A:Gen. 352 Pages: 214-222
  • Peer Reviewed
• [Journal Article] Steam reforming of ethanol over cobalt catalyst modified with small amount of iron (2009)
  • Author(s): Y.Sekine, A.Kazama, Y.Izutsu, M.Matsukata, E.Kikuchi
  • Journal Title: Catalysis Letters 132 Pages: 329-334
  • Peer Reviewed
• [Journal Article] Novel perovskits-type oxide catalysts for dehydrogenation of ethylbenzene to styrene (2009)
  • Author(s): R.Watanabe, Y.Sekine, M.Matsukata, E.Kikuchi
  • Journal Title: Catalysis Letters 131 Pages: 54-58
  • Peer Reviewed
• [Journal Article] Catalytic degradation of ethanol in anelectric field (2009)
  • Author(s): Y.Sekine, M.Tomioka, M.Matsukata, E.Kikuchi
  • Journal Title: Catalysis Today,in press doi : 10.1016/j.cattod(in press)
  • Peer Reviewed
• [Journal Article] Synergistic effect of Pt or Pd and perovskite oxide for water gas shift reaction (2009)
  • Author(s): Y.Sekine, H.Takamatsu, S.Aramaki, K.Ichishima, M.Takada, M.Matsukata, E.Kikuchi
  • Journal Title: Applied Catalysis A : General 352 Pages: 214-222
  • Peer Reviewed
• [Journal Article] Oxidative coupling of methane on Fe doped La203 catalyst (2009)
  • Author(s): Y. Sekine, K. Tanaka, E. Kikuchi, et al.
  • Journal Title: Energy and Fuels 23(2) Pages: 613-616
  • Peer Reviewed
• [Journal Article] Synergistic effect of Pt or Pd and perovskite oxide for water gas shift reaction (2009)
  • Author(s): Y. Sekine, H. Takamatsu, E. Kikuchi, et al.
  • Journal Title: Applied Catalysis A : General 352 Pages: 214-222
  • Peer Reviewed
• [Journal Article] Effective Utilization of Electrical Discharges for Hydrogen Production (2008)
  • Author(s): Y. Sekine, M. Matsukata, E. Kikuchi
  • Journal Title: Int. J. Plasma Environ. Sci. Technol. 2 Pages: 72-75
  • Peer Reviewed
• [Journal Article] High-Efficiency Dry Reforming of Biomethane Directly Using Pulsed Electric Discharge at Ambient Condition (2008)
  • Author(s): Y. Sekine, J. Yamadera, S. Kado, M. Matsukata, E. Kikuchi
  • Journal Title: Energy Fuels 22 Pages: 693-694
  • Peer Reviewed
• [Journal Article] Novel oxidation reaction at ambient temperature and atmospheric pressure with electric discharge and oxide surface (2008)
  • Author(s): Y. Sekine, S. Asai, S. Kado, M. Matsukata, E. Kikuchi
  • Journal Title: Chem. Eng. Sci. 63 Pages: 5056-5065
  • Peer Reviewed
• [Journal Article] Effective Utilization of Electrical Discharges for Hydrogen Production (2008)
  • Author(s): Y.Sekine, M.Matsukata, E.Kikuchi
  • Journal Title: Int. J. Plasma Environmental Science and Technology 2 Pages: 72-75
  • Peer Reviewed
• [Journal Article] High-Efficiency Dry Reforming of Biomethane Directly Using Pulsed Electric Discharge at Ambient Condition (2008)
  • Author(s): Y.Sekine, J.Yamadera, S.Kado, M.Matsukata, E.Kikuchi
  • Journal Title: Energy, Fuels 22 Pages: 693-694
  • Peer Reviewed
• [Journal Article] Novel oxidation reaction at ambient temperature and atmospheric pressure withelectric discharge and oxide surface (2008)
  • Author(s): Y.Sekine, S.Asai, S.Kado, M.Matsukata, E.Kikuchi
  • Journal Title: Chem.Eng.Sci 63 Pages: 5056-5065
  • Peer Reviewed
• [Journal Article] High performance of Fe-K oxide catalysts for dehydrogenation of ethylbenzene to styrene with an aid of ppm-order Pd (2008)
  • Author(s): Y. Sekine, R. Watanabe, M. Matsukata, E. Kikuchi
  • Journal Title: Catalysis Letters 125 Pages: 215-219
  • Peer Reviewed
• [Journal Article] Novel oxidation reaction at ambient temperature and atmospheric pressure with electric discharge and oxide surface (2008)
  • Author(s): Y. Sekine, S. Asai, E. Kikuchi, et. al.
  • Journal Title: Chemical Engineering Science 63 Pages: 5056-5065
  • Peer Reviewed
• [Journal Article] Effective Utilization of Electrical Discharges for Hydrogen Production (2008)
  • Author(s): Y. Sekine, E. Kikuchi, et. al.
  • Journal Title: Int. J. Plasma Environmental Science and Technology 2 Pages: 72-75
  • Peer Reviewed
• [Journal Article] High-Efficiency Dry Reforming of Biomethane Directly Using Pulsed Electric Discharge at Ambient Condition (2008)
  • Author(s): Y. Sekine, E. Kikuchi, et. al.
  • Journal Title: Energy&Fuels 22 Pages: 693-694
  • Peer Reviewed
• [Journal Article] High-Efficiency Dry Reforming of Biomethane Directly Using Pulsed Electric Discharge at Ambient Condition (2008)
  • Author(s): Y.Sekine, J.Yamadera, S.Kado, M.Matsukata, E.Kikuchi
  • Journal Title: Energy & Fuels 22 Pages: 693-694
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): Y.Sekine, S.Asai, S.Kado, M.Matsukata, E.Kikuchi
  • Journal Title: Chem.Eng.Sci. (in press)
  • Peer Reviewed
• [Journal Article] Steam Reforming of Ethanol over Co/LaSrBO3 Catalysts (2008)
  • Author(s): K.Urasaki, Y.Fukuda, Y.Sekine, M.Matsukata, E.Kikuchi
  • Journal Title: Journal of Japan Petro.Inst. (in press)
  • Peer Reviewed
• [Journal Article] Effective Utilization of Electrical Discharges for Hydrogen Production (2008)
  • Author(s): Y.Sekine, M.Matsukata, E.Kikuchi
  • Journal Title: Int.J.Plasma Sci. (in press)
  • Peer Reviewed
• [Journal Article] Hydrogen production from biomass-ethanol at ambient temperature with novel diaphragm reactor (2006)
  • Author(s): Y.Sekine, S.Asai, E.Kikuchi, M.Matsukata, F.Haga
  • Journal Title: Stud.Surf.Sci.Catal 159 Pages: 813-816
  • NAID: 10015543604
• [Journal Article] Promoting effect of small amount of Fe addition onto Co catalyst supported onα-Al2O3 for steam reforming of ethanol
  • Author(s): A. Kazama, Y. Sekine*, K. Oyama, M. Matsukata, E. Kikuchi
  • Journal Title: Appl. Catal. A: Gen., accepted.
  • Peer Reviewed
• [Presentation] 電場印加反応場中での触媒反応によるエタノールの分解 (2009)
  • Author(s): 関根 泰, 富岡真彦, ○原口将征, 松方正彦, 菊地英一
  • Organizer: 第8回GSGシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2009-03-10
• [Presentation] 電場印加反応場での触媒反応によるエタノール等の分解 (2008)
  • Author(s): 関根泰, ○富岡真彦, 松方正彦, 菊地英一
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2008-09-29
• [Presentation] 放電系と触媒反応系を組み合わせた水素製造システムに関する研究 (2008)
  • Author(s): 関根 泰
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2008-09-26
• [Presentation] Simultaneous dry reforming and desulfurization of bio-methane with non equilibrium electric dischargeat ambient temperature (2008)
  • Author(s): Y. Sekine, J. Yamadera, M. Hatsukata, E. Kikuchi
  • Organizer: 国際化学反応工学会議
  • Place of Presentation: 京都国際会議場
  • Year and Date: 2008-09-09
• [Presentation] Effective utilization of electrical field/discharges for hydrogen production (2008)
  • Author(s): Y. Sekine, M. Tomioka, M. Matsukata, E. Kikuchi
  • Organizer: 第5回国際環境触媒会議
  • Place of Presentation: イギリス ベルファスト
  • Year and Date: 2008-09-02
• [Presentation] Catalytic Reaction in Electric Field for Ethanol Decomposition (2008)
  • Author(s): Y. Sekine
  • Organizer: PostICC国際触媒会議
  • Place of Presentation: 韓国 慶州
  • Year and Date: 2008-07-21
• [Presentation] Hydrogen production by catalytic reaction in electric field (2008)
  • Author(s): Y. Sekine
  • Organizer: PreICC国際触媒会議
  • Place of Presentation: 京都大学
  • Year and Date: 2008-07-10
• [Presentation] Effective utilization of electrical discharges for hydrogen production (2008)
  • Author(s): Y. Sekine, M. Matsukata, E. Kikuohi
  • Organizer: アメリカ化学会年会
  • Place of Presentation: 米国 ニューオリンズ
  • Year and Date: 2008-04-07
• [Presentation] Effective utilization of electrical field/discharges for hydrogen production (2008)
  • Author(s): Y. Sekine
  • Organizer: Int. Cong. Environ. Catal.
  • Place of Presentation: Belfast, UK.
• [Presentation] Simultaneous dry reforming and desulfurization of bio-methane with non equilibrium electric discharge at ambient temperature (2008)
  • Author(s): Y. Sekine
  • Organizer: Int. Symp. Chem. Reaction Eng.
  • Place of Presentation: Kyoto, JPN.
• [Presentation] Catalytic Reaction in Electric Field for Ethanol Decomposition (2008)
  • Author(s): Y. Sekine
  • Organizer: Post Int. Cong. Catal.
  • Place of Presentation: Gyongyu, KOREA
• [Presentation] Hydrogen production by catalytic reaction in electric field (2008)
  • Author(s): Y. Sekine
  • Organizer: Pre Int. Cong. Catal.
  • Place of Presentation: Kyoto, JPN
• [Presentation] Effective utilization of electrical discharges for hydrogen production (2008)
  • Author(s): Y. Sekine
  • Organizer: 235th ACS meeting
  • Place of Presentation: New Orleans, USA
• [Presentation] Effective utilization of electrical field/discharges for hydrogen production (2008)
  • Author(s): Y. Sekine
  • Organizer: Int.Cong. Environ. Catal.,Cong. Environ. Catal.
  • Place of Presentation: Belfast, UK
• [Presentation] Catalytic Reaction in Electric Fieldfor Ethanol Decomposition (2008)
  • Author(s): Y. Sekine
  • Organizer: Cong. Catal., Gyongjyu, KOREA.
  • Place of Presentation: Post Int.
• [Presentation] Hydrogen production by catalyticreaction in electric field (2008)
  • Author(s): Y.Sekine
  • Organizer: Pre Int. Cong.Catal.
  • Place of Presentation: Kyoto, JPN.
• [Presentation] Effective utilization of electrical discharges for hydrogen production (2008)
  • Author(s): Y.Sekine
  • Organizer: 235^<th> ACS meeting
  • Place of Presentation: New Orleans, USA.
• [Book] メタン高度化学変換技術集成 (2008)
  • Author(s): 関根泰
  • Publisher: シーエムシー出版
• [Book] 然ガス資源とその応用技術 (2008)
  • Author(s): 関根泰
  • Publisher: シーエムシー出版
• [Book] メタン高度化学変換技術集成 (2008)
  • Author(s): 関根 泰
  • Publisher: シーエムシー出版
• [Book] 天然ガス資源とその応用技術 (2008)
  • Author(s): 関根 泰
  • Publisher: シーエムシー出版
• [Book] メタン高度化学変換技術集成 (2007)
  • Author(s): 関根 泰(分担執筆)
  • Total Pages: 207
  • Publisher: シーエムシー出版
• [Book] トコトンやさしい触媒の本(触媒学会編) (2007)
  • Author(s): 関根 泰(共著)
  • Total Pages: 158
  • Publisher: 日刊工業新聞社刊
• [Remarks] 「新規非平衡放電を用いる炭化水素からの水素製造に関する研究」を受賞、また、触媒学会奨励賞(2008)「放電系と触媒反応系を組み合わせた水素製造システムに関する研究」を受賞した
• [Remarks] 触媒学会にて2007年3月に「放電励起を用いた触媒反応による水素製造」早稲田大関根 泰ら、がプレス向け注目発表に取り上げられた。同様にして触媒学会にて2009年9月、アメリカ化学会にて2009年8月に注目発表として取り上げられた
• [Remarks] 本研究に関して石油学会奨励賞(2006)「新規非平衡放電を用いる炭化水素からの水素製造に関する研究」を受賞、また、触媒学会奨励賞(2008)「放電系と触媒反応系を組み合わせた水素製造システムに関する研究」を受賞した。
• [Remarks] 触媒学会にて2007年3月12日に「放電励起を用いた触媒反応による水素製造」早稲田大関根 泰ら、がプレス向け注目発表に取り上げられた。
• [Patent(Industrial Property Rights)] 鎖式炭化水素のスチームリフォーミング方法及びそのための装置 (2009)
  • Inventor(s): 関根泰・浦崎浩平・角茂・藤元薫
  • Industrial Property Rights Holder: 関根泰
  • Filing Date: 2009-02-06
• [Patent(Industrial Property Rights)] 鎖式炭化水素のスチームリフォーミング方法及びそのための装置 (2009)
  • Inventor(s): 関根 泰・浦崎浩平・角 茂・藤元 薫
  • Industrial Property Rights Holder: 関根 泰
  • Filing Date: 2009-02-06
• [Patent(Industrial Property Rights)] 燃料改質装置及び燃料改質ガスの製造方法 (2008)
  • Inventor(s): 関根泰・羽賀史浩・赤間弘、
  • Industrial Property Rights Holder: 関根泰・カルロスゴーン
  • Industrial Property Number: 2008-033053
  • Filing Date: 2008-02-14
• [Patent(Industrial Property Rights)] 炭化水素、含酸素化合物の液相リフォーミング方法及び装置 (2008)
  • Inventor(s): 関根泰・渡邊眞人
  • Industrial Property Rights Holder: 関根泰
  • Filing Date: 2008-01-18
• [Patent(Industrial Property Rights)] 燃料改質装置及び燃料改質ガスの製造方法 (2008)
  • Inventor(s): 関根 泰・羽賀史浩・赤間 弘
  • Industrial Property Rights Holder: 関根 泰・カルロスゴーン
  • Industrial Property Number: 2008-033053
  • Filing Date: 2008-02-14
• [Patent(Industrial Property Rights)] 炭化水素、含酸素化合物の液相リフォーミング方法及び装置 (2008)
  • Inventor(s): 関根 泰・渡邊眞人
  • Industrial Property Rights Holder: 関根 泰
  • Filing Date: 2008-01-18
• [Patent(Industrial Property Rights)] 燃料改質装置 (2007)
  • Inventor(s): 関根泰・羽賀史浩
  • Industrial Property Rights Holder: 関根泰・日産自動車株式会社
  • Patent Publication Number: 2007-137721
  • Filing Date: 2007-06-07
• [Patent(Industrial Property Rights)] Method for steam reforming of chain hydrocarbon (2007)
  • Inventor(s): Yasushi Sekine, Kouhei Urasaki, Shigeru Kado, Kaoru Fujimoto
  • Industrial Property Rights Holder: Yasushi Sekine
  • Filing Date: 2007-10-23
• [Patent(Industrial Property Rights)] 燃料改質装置 (2007)
  • Inventor(s): 関根 泰・羽賀史浩
  • Industrial Property Rights Holder: 関根 泰・日産自動車株式会社
  • Patent Publication Number: 2007-137721
  • Filing Date: 2007-06-07
• [Patent(Industrial Property Rights)] Method for steam reforming of chain hydrocarbon, Inventors (2007)
  • Inventor(s): Yasushi Sekine, Kouhei Urasaki, Shigeru Kado, Kaoru Fujimoto
  • Industrial Property Rights Holder: Yasushi Sekine
  • Filing Date: 2007-10-23