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Design of the wall structure in metal confined metal oxide nano-composites aiming to develop a new method for catalyst preparation

Research Project

Project/Area Number 18360391
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKanagawa University

Principal Investigator

NAITO Shuichi  Kanagawa University, 工学部, 教授 (20011710)

Co-Investigator(Kenkyū-buntansha) 宮尾 敏広  神奈川大学, 工学部, 助教 (90312090)
Co-Investigator(Renkei-kenkyūsha) MIYAO Toshihiro  山梨大学, 燃料電池ナノ材料研究センター, 准教授 (90312090)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥17,500,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2008: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2007: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2006: ¥9,700,000 (Direct Cost: ¥9,700,000)
Keywords触媒 / ナノ材料 / 表面 / 界面現象 / ナノチューブ / 調製法 / 表面・界面物性 / 中空ナノ粒子 / 水素吸蔵 / 金属クラスター / EXAFS
Research Abstract

本研究では、金属アンミン錯体ナノ結晶を鋳型としその表面で選択的に金属アルコキシドを加水分解することにより、内部に空孔をもちサブナノメーターの金属クラスターを内包したSiO_2やTiO_2のnanotube, nanocapsule, hollowspherenoの調製に成功した。酸化物壁中に高分散された金属クラスターは多量の水素を吸蔵する性質や、COの水素化反応で含酸素化合物の生成に優れた選択性を示すことが明らかとなった。種々の表面分光法を駆使することにより、水素吸蔵・放出に伴いクラスター構造が離合集散する極めて特異な機構を解明した。更に、酸化物壁に不斉構造を導入する可能性を検討した。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (73 results)

All 2009 2008 2007 2006

All Journal Article (29 results) (of which Peer Reviewed: 23 results) Presentation (40 results) Book (4 results)

  • [Journal Article] Promoting effect of MgO addition to Pt/Ni/CeO_2/Al_2O_3 in the steam gasfication of biomass2009

    • Author(s)
      K. Nakamura, T. Miyazawa, T. Sakurai, T. Miyao, S. Naito, N. Begum, K. Kunimori, K. Tomishige
    • Journal Title

      Applied Catalysis B : Environmental 86

      Pages: 36-44

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Marked capability for hydrogen occlusion of hollow silica nanospheres containing group 8-10 metal clusters2008

    • Author(s)
      T. Miyao, K. Minoshima, Y. Kurokawa, K. Shinohara, W. Shen, and S. Naito
    • Journal Title

      Catalysis Today 132(1-4)

      Pages: 132-137

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Promoting effect of Co addition on the catalytic partial oxidation of methane at short contact time over a Rh/MgO catalyst2008

    • Author(s)
      S. Naito, H. Tanaka, S. Kado, T. Miyao, S. Naito, K. Okumura, K. Kunimori, K. Tomishige
    • Journal Title

      J. Catalysis 259(1)

      Pages: 138-146

    • NAID

      120007138511

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preferential CO oxidation in hydrogen-rich stream over Pt catalysts modified with alkali metals2008

    • Author(s)
      H. Tanaka, M. Kuriyama, Y. Ishida, S, Ito, T. Kubota, T. Miyao, S. Naito, K. Tomishige, K. Kunimori.
    • Journal Title

      Applied Catalysis, A : General 343(1-2)

      Pages: 125-133

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Promoting effect of Co addition on the catalytic partial oxidation of methane at short contact time over a Rh/MgO catalyst2008

    • Author(s)
      H. Tanaka, S. Kado, T. Miyao, S. Naito, K. Okumura, K. Kunimori, K. Tomishige
    • Journal Title

      Journal of Catalysis 259(1)

      Pages: 138-146

    • NAID

      120007138511

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative steam reforming of methane over Ni/α-A1_2O_3 modified with trace Pd2008

    • Author(s)
      K. Yoshida, K. Okumura, T. Miyao, S. Naito, S. Ito, K. Kunimod, K. Tomishige
    • Journal Title

      Applied Catalysis, A : General 351

      Pages: 217-225

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Marked capability for the hydrogen occlusion of hollow silica nanospheres containing group 8-10 metal clusters"2008

    • Author(s)
      T. Miyao, K. Minoshima, Y. Kurokawa, K. Shinohara, W. Shen, and S. Naito
    • Journal Title

      Catalysis Today, 132, 132-137(2008). 132

      Pages: 132-137

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The role of additives in the catalytic reduction of NO by CO over Pd-In/SiO_2 and Pd-Pb/SiO_2 catalysts2007

    • Author(s)
      T. Hirano, Y. Ozawa, T. Sekido, H. Ogino, T. Miyao, S. Naito
    • Journal Title

      Applied Catalysis. A, general 320

      Pages: 91-97

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable effect of addition of In and Pb on the reduction of N_2O by CO over SiO_2 supported Pd catalysts2007

    • Author(s)
      T.Hirano, Y.Kazahaya, A.Nakamura, T.Miyao, S.Naito
    • Journal Title

      Catalysis Letters 117(1-2)

      Pages: 73-78

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Marked effect of In, Pb and Ce addition upon the reduction of NO by CO over SiO_2 supported Pd catalysts2007

    • Author(s)
      T. Hirano, Y. Ozawa, T. Sekido, T. Ogino, T. Miyao and S. Naito
    • Journal Title

      Catal. Comm., 8(8), 1249-1254(2007). 8(8)

      Pages: 1249-1254

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable effect of addition of In and Pb on the reduction of N_2O by CO over SiO_2 supported Pd catalysts2007

    • Author(s)
      T. Hirano, Y. Kazahaya, A. Nakamura, T. Miyao, S. Naito
    • Journal Title

      1) Catalysis Letters, 117(1-2), 73-78(2007). 117(1-2)

      Pages: 73-78

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The role of additives in the catalytic reduction of NO by CO over Pd-In/SiO_2 and Pd-Pb/SiO_2 catalysts2007

    • Author(s)
      T. Hirano, Y. Ozawa, T. Sekido, H. Ogino, T. Miyao and S. Naito
    • Journal Title

      Appl. Catal. A, general, 320

      Pages: 91-97

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Catalytic performance and characterization of Pd/Ni_<0.2>Mg_<0.8>Al_2O_4 in oxidative steam reforming of methane under atmospheric and pressurized conditions"2007

    • Author(s)
      N. Mohammad Y. Mukainakano, S. Kado, T. Miyao, S. Naito, K. Okumura, K. Kunimori, K. Tomishige,
    • Journal Title

      Applied Catalysis, A: General 325

      Pages: 154-162

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Performance and characterization of NiO-MgO solid solution modified with noble metals in oxidative steam reforming of methane under pressurized conditions"2007

    • Author(s)
      S. Kado, N. Mohammad, Y. Mukainakano, Y. Miyazawa, K. Nakao, K. Okumura, T. Miyao, S. Naito, K. Suzuki, K. Fujimoto, K. Kunimori, K. Tomishige,
    • Journal Title

      ACS Symposium Series, (Ultraclean Transportation Fuels) 959

      Pages: 59-72

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Surface modification of Ni catalysts with trace Pd and Rh for oxidative steam reforming of methane"2007

    • Author(s)
      B. Li, S. Kado, T. Miyazawa, K. Okumura, T. Miyao; S. Naito, K. Kunimori, K. Tomishige,
    • Journal Title

      Applied Catalysis, A, general, 318, 252-264(2007). 318

      Pages: 252-264

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Surface modification of Ni catalysts with trace Pt for oxidative steam reforming of methane"2007

    • Author(s)
      B. Li; S. Kado; Y. Mukainakano; T. Miyazawa, T. Miyao; S. Naito; K. Okumura; K. Kunimori; K. Tomishige
    • Journal Title

      Journal of. Catalysis, 245, 144-155(2007). 245

      Pages: 144-155

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Promoting mechanism of potassium in preferential CO oxidationon Pt/Al_2O_3"2007

    • Author(s)
      M. Kuriyama, H. Tanaka, S. Ito, T. Kubota, T. Miyao, S. Naito, K. Tomishige, and K. Kunimor
    • Journal Title

      Journal of Catalysis. 252, 39-48(2007). 252

      Pages: 39-48

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of hollow silica-Rh,-Ir, and Rh/Ir-bimetallic nanocomposites by reverse micelle technique and their unique adsorption and catalytic behavior2006

    • Author(s)
      S.Naito, K.Minoshima, Y.Kurokawa,T. Miyao
    • Journal Title

      Sci. Bas.. Prepa.. Hetero. Catal 162

      Pages: 63-70

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unique adsorption and catalytic behavior of H_2 and CO over hollow silica-Rh,-Ir, and-Ru nano-composites prepared by reversed micelle technique2006

    • Author(s)
      S.Naito, K.Minoshima, T.Miyao
    • Journal Title

      Topics in Catalysis 39

      Pages: 131-136

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable Support Effect for Liquid Phase Methanol Reforming with Water over upported Pt-Ru Catalysts2006

    • Author(s)
      T.Miyao, M.Yamauchi, H.Narita, and S.Naito
    • Journal Title

      Applied Catalysis A General 299

      Pages: 285-291

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] The CO-H_2 and CO-H_2O reactions over TiO_2 nanotubes filled with Pt metal nanoparticles2006

    • Author(s)
      Y.Sato, M.Koizumi, T.Miyao, S.Naito
    • Journal Title

      Catalysis Today 111(3-4)

      Pages: 164-170

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A study on the Water-gas-shift Reaction over Ir/TiO_2 and Ir-Re/TiO_2 Catalysts2006

    • Author(s)
      Y.Sato, Y.Soma, T.Miyao and S.Naito
    • Journal Title

      Appl. Catal. A : General 304

      Pages: 78-85

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared spectroscopic study on the reaction mechanism of CO hydrogenation over Pd/CeO_22006

    • Author(s)
      S.Naito, S.Aida, T.Kasahara, and T.Miyao
    • Journal Title

      Research on Chemical Reaction Intermediates 32(3-4)

      Pages: 279-290

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of hollow silica-Rh, -Ir, and Rh/Ir- bimetallic nanocomposites by reverse micelle technique and their unique adsorption and catalytic behavior2006

    • Author(s)
      S.Naito, K.Minoshima, Y.Kurokawa, T.Miyao
    • Journal Title

      Scientific. Bases. Preparation. Heterogeneous Catalysts 162

      Pages: 63-70

    • Related Report
      2006 Annual Research Report
  • [Journal Article] The CO-H_2 and CO-H_2O Reactions over TiO_2 Nanotubes Filled with Pt Metal Nanoparticles2006

    • Author(s)
      Y.Sato, M.Koizumi, T.Miyao, S.Naito
    • Journal Title

      Catal. Today, Vol.111,pp.164-171(2006-2). 111

      Pages: 164-170

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Catalytic performance and characterization of RhVO_4/SiO_2 for hydroformylation and CO hydrogenation2006

    • Author(s)
      T.Yamagishi, I.Furikado, S.Ito, T.Miyao, S.Naito, K.Tomishige, K.Kunimori
    • Journal Title

      Journal of Molecular Catalysis A : Chemical, Vol.244, pp.201-212(2006-2). 244

      Pages: 201-212

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Marked Addition Effect of Re upon the Water Ges Shift Reaction over TiO_2 Supported Pt, Pd and Ir Catalysts2006

    • Author(s)
      Y.Sato, K.Terada, Y.Soma, T.Miyao, S.Naito
    • Journal Title

      Catal. Comm. Vol.7,pp.91-95(2006-2). 7

      Pages: 91-95

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Remarkable Support Effect for Liquid Phase Methanol Reforming with Water over Supported Pt-Ru Catalysts2006

    • Author(s)
      T.Miyao, M.Yamauchi, H.Narita, S.Naito
    • Journal Title

      Applied Catalysis A General. Vol.299,pp.285-291(2006-1). 299

      Pages: 285-291

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A study on the Water-gas-shift Reaction over Ir/TiO_2 and Ir-Re/TiO_2 Catalysts2006

    • Author(s)
      Y.Sato, Y.Soma, T.Miyao, S.Naito
    • Journal Title

      Appl. Catal. A : General, Vol.304,pp.78-85(2006-5). 304

      Pages: 78-85

    • Related Report
      2006 Annual Research Report
  • [Presentation] Selectivity controlling factors for the methanol formation in CO-H_2 reaction over Pt and Rh encapsulated TiO_2 nanotubes and nanocapsules2008

    • Author(s)
      S. Naito, H. Yamada, Y. Numao, Y. Kazehaya and T. Miyao
    • Organizer
      Presymposium on 14^<th> International Conference on catalysis
    • Place of Presentation
      Kyoto
    • Related Report
      2008 Final Research Report
  • [Presentation] Unique wall structures of Pt, Rh, Ir and Ru filled TiO_2 nanotubes andnanocapsules which possess noble catalytic property for CO-H_2 reaction2008

    • Author(s)
      S. Naito, H. Yamada, Y. Numao, Y. Kazehaya and T. Miyao
    • Organizer
      14^<th> International Conference on catalysis
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] Preferential oxidation of CO and water gas shift reaction over ordered mesoporous Cu/CeO_22008

    • Author(s)
      W. Shen, T, Miyao, and S. Naito
    • Organizer
      14^<th> International Conference on catalysis
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] Mechanistic study of remarkable hydrogen occlusion over hollow silica nano-spheres encapsulating iridium metal clusters2008

    • Author(s)
      T. Miyao, H. Yamada, W. Shen and S. Naito
    • Organizer
      14^<th> International Conference on catalysis
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] Selectivity controlling factors for the methanol formation in C0-H_2 reaction over Pt and Rh encapsulated TiO_2 nanotubes and nanocapsules2008

    • Author(s)
      S. Naito, H. Yamada, Y. Numao, Y. Kazehaya, T. Miyao
    • Organizer
      Presymposium on 14^<th> International Conference on Catalysis
    • Place of Presentation
      京都
    • Related Report
      2008 Annual Research Report
  • [Presentation] Unique wall structures of Pt, Rh, Ir and Ru filled TiO_2 nanotubes and nanocapsules which possess noble catalytic property for CO-H_2 reaction2008

    • Author(s)
      S. Naito, H. Yamada, Y. Numao, Y. Kazehaya, T. Miyao
    • Organizer
      14^<th> International Conference on catalysis
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preferential oxidation of CO and water gas shift reaction over ordered mesoporous Cu/CeO_22008

    • Author(s)
      W. Shen, T, Miyao, S. Naito
    • Organizer
      14^<th> International Conference on Catalysis
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Annual Research Report
  • [Presentation] Mechanistic study of remarkable hydrogen occlusion over hollow silica nano-spheres encapsulating iridium metal clusters2008

    • Author(s)
      T. Miyao, H. Yamada, W. Shen, S. Naito
    • Organizer
      14^<th> International Conference on Catalysis
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation of ordered mesoporous CuO/CeO_2 and their catalytic behavior in CO preferential oxidation and water gas shift reaction2008

    • Author(s)
      S. Naito, W. Shen, T. Hasegawa, T. Miyao
    • Organizer
      The 5th International Conference on Environmental Catalysis ( Belfast, UK. 2008-8).
    • Place of Presentation
      Belfast, U. K.
    • Related Report
      2008 Annual Research Report
  • [Presentation] Mechanism of remarkable hydrogen occlusion and catalytic reaction over Ir metal clusters confined in the hollow SiO_2 nanospheres2008

    • Author(s)
      S. Naito, H. Yamada, T. Miyao
    • Organizer
      The 5th International Conference on Environmental Catalysis
    • Place of Presentation
      Belfast, U. K.
    • Related Report
      2008 Annual Research Report
  • [Presentation] Noble hydrogen storage capacity of hollow silica nanospheres containing ultrafine Ir, Rh and Pt clusters2008

    • Author(s)
      Shuichi Naito
    • Organizer
      Japan-UK joint symposium on green chemistry
    • Place of Presentation
      Belfast, U. K.
    • Related Report
      2008 Annual Research Report
  • [Presentation] 赤外分光法によるCu/CeO_2触媒上でのCO-PROX反応の検討2008

    • Author(s)
      長谷川稔, 島田直樹, WEIHUA Shen, 吉田暁弘, 内藤周弌
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] 種々のアルミナ担持8-10族金属触媒上でのエタノール液相改質反応2008

    • Author(s)
      坂本峻彦, 原科良輔, 宮尾敏広, 羽賀史浩, 星野真樹, 吉田暁弘, 内藤周弌
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] Li-メソポーラスグラファイト系水素貯蔵材料の調製と水素吸放出特性2008

    • Author(s)
      中山保先, 菅沢加奈子, 堀田千晶, 沈衛華, 吉田暁弘, 内藤周弌
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] RhおよびPt内包中空シリカナノ粒子の特異的な水素吸蔵機構の解明2008

    • Author(s)
      山田祐泰, 吉田暁弘, 内藤周弌
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] 不斉構造を持つ金属錯体を鋳型にしたシリカナノカプセルの調製とそれを用いた錯体の吸着2008

    • Author(s)
      榎本ひとみ, 栗原啓一, 宮尾敏広, 吉田暁弘, 内藤周弌
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] 担持白金触媒上でのエタノール液相改質反応における担体効果2008

    • Author(s)
      竹本祥雄, 近藤浩正, 坂本峻彦, 宮尾敏広, 羽賀史浩, 星野真樹, 吉田暁弘, 内藤周弌
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] Marked effect of cerium addition upon lanthanide oxysulfate/ oxysulfide oxygen storage systems2008

    • Author(s)
      WEIHUA Shen, 吉田暁弘, 内藤周弌
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Annual Research Report
  • [Presentation] Marked effect of In, Pb, and Ce addition upon the reduction of NO by CO over SiO2 supported Pd catalysts2007

    • Author(s)
      S. Naito, H. Hirano, Y. Ozawa, and T. Miyao
    • Organizer
      20^<th> North American Catalysis Meeting
    • Place of Presentation
      Texax, Houston, USA
    • Related Report
      2008 Final Research Report
  • [Presentation] Marked Capability of Hydrogen Occulusion of Hollow Silica Nanosphers Containing Group 8-10 Metal Clusters2007

    • Author(s)
      Miyao, K. Minoshima, Y. Kurokawa, and S. Naito
    • Organizer
      11^<th> Korea-Japan ymposium on Catalysis
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of alkali metal-NHx graphite intercalation compounds for hydrogen storage and their absorption-desorption cyclic properties2007

    • Author(s)
      S. Naito, K. Kuno and T. Miyao
    • Organizer
      EuropaCat VIII
    • Place of Presentation
      Turk, Finland
    • Related Report
      2008 Final Research Report
  • [Presentation] The role of hydrogen in the preferential oxidation of CO over alumina supported group 8-10 metal catalysts2007

    • Author(s)
      S. Naito, H. Takanezawa, M. Hasegawa, and T. Miyao
    • Organizer
      EuropaCat, VIII
    • Place of Presentation
      Turk, Finland
    • Related Report
      2008 Final Research Report
  • [Presentation] New reaction pathway in the selective oxidation of carbon monoxide over Ru/Al_2O_32007

    • Author(s)
      S. Naito, H. Takanezawa, M. Hasegawa and T. Miyao
    • Organizer
      20th North American Catalysis Meeting
    • Place of Presentation
      Houston, Texas USA
    • Related Report
      2007 Annual Research Report
  • [Presentation] "New reaction pathway in the selective oxidation of carbon monoxide over Ru/Al_2O_3"2007

    • Author(s)
      S. Naito, H. Takanezawa, M. Hasegawa and T. Miyao
    • Organizer
      20th North American Catalysis Meeting
    • Place of Presentation
      Houston, Texas USA
    • Related Report
      2007 Annual Research Report
  • [Presentation] "Marked Capability for Hydrogen Occlusion of Hollow Silica Nanospheres Containing Group 8-10 Metal Clusters"2007

    • Author(s)
      T. Miyao, K. Minoshima, Y. Kurokawa, and S. Naito
    • Organizer
      11th Korea-Japan Symposium on Catalysis,
    • Place of Presentation
      Seoul, Korea.
    • Related Report
      2007 Annual Research Report
  • [Presentation] "Preparation of alkali metal-NHx graphite -intercalatioin compounds for hydrogen storage and their absorption-desorption cyclic properties"2007

    • Author(s)
      S. Naito, Y. Kuno and T. Miyao,
    • Organizer
      Europa Cat VIII
    • Place of Presentation
      Turk, Finland,
    • Related Report
      2007 Annual Research Report
  • [Presentation] "The role of hydrogen in the preferential oxidation of CO over alumina supported group 8-10 metal catalysts"2007

    • Author(s)
      S. Naito, H. Takanezawa, M. Hasegawa and T. Miyao
    • Organizer
      Europa Cat VIII
    • Place of Presentation
      Turk, Finland,
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「アルミナ担持8-10族金属触媒上でのCO選択酸化における反応機構」2007

    • Author(s)
      宮尾敏広, 高根澤豪紀, 長谷川稔, 佐藤康司, 南浦良太, 内藤周弌,
    • Organizer
      第99回触媒討論会
    • Place of Presentation
      神戸
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「アルミナ担持Pt触媒によるメタノール液相改質反応に対する遷移金属元素の添加効果」2007

    • Author(s)
      坂本峻彦, 森島裕之, 宮尾敏広, 内藤周弌
    • Organizer
      第99回触媒討論会
    • Place of Presentation
      神戸
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「アルミナ担持Ru、Rh、PdおよびPt金属触媒上でのCO選択酸化反応」2007

    • Author(s)
      高根澤豪紀, 長谷川稔, 宮尾敏広, 内藤周弌
    • Organizer
      第99回触媒討論会
    • Place of Presentation
      神戸
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「Ptを内包したZrO_2およびV_2O_5ナノ複合体の調製とその触媒特性」2007

    • Author(s)
      山田祐泰, 宮尾敏広, 内藤周弌
    • Organizer
      第99回触媒討論会
    • Place of Presentation
      神戸
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「Rhを内包したTiO_2ナノカプセル触媒によるCOの永素化反応」2007

    • Author(s)
      風早由比子, 沼尾善行, 宮尾敏広, 内藤周弌
    • Organizer
      第99回触媒討論会
    • Place of Presentation
      神戸
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「種々の金属錯体を鋳型とした金属内包シリカナノ構造体の調製とその触媒作用」2007

    • Author(s)
      榎本ひとみ, WEIHUA Shen, 宮尾敏広, 内藤周弌
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      大阪
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「担持金属触媒上でのC_1化学」2007

    • Author(s)
      内藤周弌
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「種々の8-10族金属超微粒子を内包した酸化物ナノ構造体の特異な壁構造と触媒特性」2007

    • Author(s)
      宮尾敏広, 風早由比子, 沼尾善行, 山田祐泰, WEIHUA Shen, 内藤周弌
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「白金ナノ粒子を内包したシリカナノチューブの壁構造の修飾とその触媒作用」2007

    • Author(s)
      榎本ひとみ, WEIHUA Shen, 宮尾敏広, 内藤周弌
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「アルミナ担持8-10族金属触媒上でのCO選択酸化反応に対する水素や水の添加効果」2007

    • Author(s)
      長谷川稔, 高根澤豪紀, 宮尾敏広, 内藤周弌
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] 「Preparation and catalytic property of Pt nanowires and nanoparticles confined helical mesoporous silica」2007

    • Author(s)
      WEIHUA Shen, 山田祐泰, 篠原和也, 宮尾敏広, 内藤周弌
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Related Report
      2007 Annual Research Report
  • [Presentation] Marked Effect of Mo, W, and Re Addition upon the Liquid Phase Reforming of methanol over TiO_2 Supported Pt and Ir Catalysts2006

    • Author(s)
      S. Naito, S. Sakamoto, T. Miyao
    • Organizer
      19^<th> International Symposium on Chemical reaction Engineering
    • Place of Presentation
      Jermany, Potsudam
    • Related Report
      2008 Final Research Report
  • [Presentation] Preparation of hollow silica-Rh, -Ir, and Rh/Ir-bimetallic nanocomposites by reverse micelle technique and their unique absorption and catalytic behavior2006

    • Author(s)
      S. Naito, K. Minoshima, Y. Kurokawa, T. Miyao
    • Organizer
      9^<th> International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts
    • Place of Presentation
      Brussels, Bergium
    • Related Report
      2008 Final Research Report
  • [Book] メタン高度化学変換技術集成2008

    • Author(s)
      内藤周弌
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] 触媒の本2007

    • Author(s)
      内藤周弌
    • Publisher
      日刊工業新聞
    • Related Report
      2008 Final Research Report
  • [Book] 実験化学講座25「触媒化学・電気化学」2006

    • Author(s)
      内藤周弌
    • Publisher
      丸善
    • Related Report
      2008 Final Research Report
  • [Book] 化学用語辞典(日本化学会編)2006

    • Author(s)
      内藤周弌(分担執筆)
    • Publisher
      丸善出版
    • Related Report
      2006 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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