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Studies of the reaction processes of atmospheric minor constituents related to the global warming

Research Project

Project/Area Number 18510009
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionNagoya University

Principal Investigator

MATSUMI Yutaka  Nagoya University, Solarlhrrestrial Environment Laboratory, Professor (30209605)

Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥4,110,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥510,000)
Fiscal Year 2007: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2006: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsEnvironmental changes / Physical chemistry / Green-house gases / Reaction processes / Laboratory experiment / 代替フロン / レーザー分光
Research Abstract

Absolute and relative rate techniques were used to study the reactivity of Cl atoms with cyclohexanone in 6 Torr of argon or 800-950 Torr of N2 at 295 2 K The absolute rate experiments gave k(Cl+cyclohexanone) = (1.88 0.38)×10^<-10> while the relative rate experiments gave k(Cl+cyclohexanone) = (1.66±026)×10^<-10> cm^3 molecule^<-1> s^<-1> methods. Cyclohexanone has a broad UV absorption band with a maximum cross section of (4.0±03)×10^-20 cm^2 molecule^<-1> near 285 nm The results are discussed with respect to the literature data.
The kinetics and mechanism of the reaction Cl + CH_3 (CH_2)_3CHO was investigated using absolute (PLP-LIF) and relative rate techniques in 8 Ton of argon or 800-950 Ton of N_2 at 295± 2K. The absolute rate experiments gave k(C1 + CH_3(CH_2)_3CHO) = (2.31±0.35)×10^<-10> in 8 Ton of argon while relative rate experiments gave k(CI + CH_3(CH_2)_3CHO) = (2.24±0.20)×10^<-10> cm^3 molecule^<-1> s^<-1> in 800-950 Ton of N_2. Additional relative rate experiments gave … More k(Cl+CH_3(CH_2)_3C(O)CI) = (8.74± 1.38)×10^<-11> cm^3 molecule^<-1> s^<-1> in 700 Ton of N_2. Smog chamber Fourier transform infrared (F IR) techniques indicated that the acyl-forming channel accounts for 42 ± 3% of the reaction. The results are discussed with respect to the literature data and the importance of long range (= 2 carbon atoms along the aliphatic chain) effects in determining the reactivity of organic molecules towards chlorine atoms.
The gas-phase reactions of Cl atoms with acetone, butanone, 2-pentanone, 3-pentanone, 2-hexanone, 3-hexanone, and cyclopentanone at 295±2 K were studied using pulsed laser photolysis vacuum UV laser-induced fluorescence (PLP-LIF) techniques. Cl(^2P_3/_2) atoms were produced by photolysis of Cl_2 at 351 nm and monitored by LIF spectroscopy at 134.72 nm (3p^5 2P_3/^2-3p^44s ^2_3/2 transition). Rate coefficients for reactions of Cl atoms with acetone, butanone, 2-pentanone, 3-pentanone, 2-hexanone, 3-hexanone, and cyclopentanone are : (2.30±0.12)×10_-12, (4.08±0.21)×10^<-11>, (1.23±013)-〜10^<-10>, (8.87s-0.92)40^<-1>1, (2.08±0.32)×10^<-10>, (1.43±0.19)×10^<-10> and (1.16±0.12)×10^<-10> cm^3 molecule^<-1>s^<-1>, respectively. The results for acetone and butanone are consistent with previous studies. The results for 2-pentanone, 3-pentanone, 2-hexanone, and 3-hexanone are approximately a factor of 2-3 higher than those from previous absolute rate studies. Likely explanations for these discrepancies are discussed. Tropospheric lifetimes of ketones with respect to reaction with Cl atoms are estimated and discussed. Less

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (73 results)

All 2008 2007 2006

All Journal Article (53 results) (of which Peer Reviewed: 25 results) Presentation (20 results)

  • [Journal Article] Single Particle Analysis of Secondary Organic Aerosols Formed from 1,4-Cyclohexadiene Ozonolysis Using a Laser-Ionization Single-Particle Aerosol Mass Spectrometer2008

    • Author(s)
      M. Narukawa, Y. Matsumi, 他5名
    • Journal Title

      Bulletin of the Chemical Society of Japan 81(1)

      Pages: 120-126

    • NAID

      10020139625

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Atmospheric Chemistry of Cyclohexanone: UV Spectrum and Kinetics of Reaction with Chlorine Atoms2008

    • Author(s)
      E. Iwasaki, Y. Matsumi, 他5名
    • Journal Title

      International Journal of Chemical Kinetics 40

      Pages: 223-229

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Nighttime measurements of ambient N2O5, NO2, NO and O3 in a sub-urban area, Toyokawa, Japan2008

    • Author(s)
      T. Nakayama, Y. Matsumi, 他4名
    • Journal Title

      Atmospheric Environment 42

      Pages: 1995-2006

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Kinetics and Mechanism of the Reaction of Chlorine Atoms with n-Pentanal2008

    • Author(s)
      E. Iwasaki, Y. Matsumi, 他5名
    • Journal Title

      J. Phys. Chem. A. 112(8)

      Pages: 1741-1746

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Approach to thermal equilibrium in atomic collisions2008

    • Author(s)
      Zhang, R., Y. Matsumi, 他4名
    • Journal Title

      Physical Review Letters 100

      Pages: 103001-103001

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Single Particle Analysis of Secondary Organic Aerosols Formed from 1,4-Cyclohexadiene Ozonolysis Using a Laser-Ionization Sinele-Particle Aerosol Mass Spectrometer2008

    • Author(s)
      M. Narukawa, Y. Matsumi, J. Matsumoto, K. Takahashi, A. Yabushita, K. Sato, T. Imamura
    • Journal Title

      Bulletin of the Chemical Society of Japan Vol.81, No.1

      Pages: 120-126

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Atmospheric Chemistry of Cyclohexanone : UV Spectrum and Kinetics of Reaction with Chlorine Atoms2008

    • Author(s)
      E. Iwasaki, Y. Matsumi, K. Takahashi, T.J. Wallington, M.D. Hurley, J. J. Orlando, E.W. Kaiser
    • Journal Title

      International Journal of Chemical Kinetics 40

      Pages: 223-229

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Nighttime measurements of ambient N2O5, NO2, NO and 03 in a sub-urban area, Toyokawa, Janan2008

    • Author(s)
      T. Nakayama, T. Ide, F. Taketani, M. Kawai, K. Takahashi, Y. Matsumi
    • Journal Title

      Atmospheric Environment 42

      Pages: 1995-2006

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Kinetics and Mechanism of the Reaction of Chlorine Atoms with n-Pentanal2008

    • Author(s)
      Iwasaki, E. T. Nakayama, Y. Matsumi, K. Takahashi, T.J. Wallington, M. D. Hurley, E. Kaiser
    • Journal Title

      J. Phys. Chem 112(8)

      Pages: 1741-1746

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Approach to thermal equilibrium in atomic collisions2008

    • Author(s)
      Zhang, P., V. Kharchenko, A. Dalgarno, Y. Matsumi, T. Nakayama, K. Takahashi
    • Journal Title

      Physical Review Letters 100

      Pages: 3001-3001

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Nighttime measurements of ambient N205, NO2, NO and O3 in a sub-urban area, Toyokawa, Japan2008

    • Author(s)
      T. Nakayama, Y. Matsumi, 他4名
    • Journal Title

      Atmospheric Environment 42

      Pages: 1995-2006

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Approach to thermal equilibrium in atomic collisions2008

    • Author(s)
      Zhang, P., Y. Matsumi, 他4名
    • Journal Title

      Physical Review Letters 100

      Pages: 103001-103001

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trace detection of atmospheric NO_2 by laser-induced fluorescence using a GaN diode laser and a diode-pumped YAG laser2007

    • Author(s)
      F. Taketani, Y. Matsumi, 他2名
    • Journal Title

      Applied Optics 46

      Pages: 907-914

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Atmospheric Chemistry of CF_3CH=CH_2 and C_4F_9CH=CH_2: Products of the Gas-Phase Reactions with Cl Atoms and OH Radicals2007

    • Author(s)
      T. Nakayama, Y. Matsumi, 他8名
    • Journal Title

      J. Phys. Chem A111

      Pages: 909-915

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Pulsed laser photolysis vacuum UV laser-induced fluorescence kinetic study of the gas-phase reactions of Cl(2P_<3/2>)atoms with C_3-C_6 ketones2007

    • Author(s)
      K. Takahashi, Y. Matsumi, 他2名
    • Journal Title

      J. Phys. Chem .A111

      Pages: 1271-1276

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Vacuum ultraviolet laser-induced fluorescence kinetic study of the reactions of Cl atoms with fluoroalkenes(C_xF_<2x+1>CH=CH_2,x=1,2,4,6, and 8)at low pressures,2007

    • Author(s)
      K. Takahashi, Y. Matsumi, 他3名
    • Journal Title

      International Jounal of Chemical Kinetics 39

      Pages: 328-332

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Mechanism of the gas phase reaction of chlorine atoms with butanone2007

    • Author(s)
      E. Iwasaki, Y. Matsumi, 他4名
    • Journal Title

      Chemical Physics Letters 439

      Pages: 274-279

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Real-time analysis of secondary organic aerosol particles formed from cyclohexene ozonolysis using a laser-ionization single-particle aerosol mass spectrometer2007

    • Author(s)
      M. Narukawa, Y. Matsumi, 他5名
    • Journal Title

      Analytical Sciences 23

      Pages: 507-512

    • NAID

      40015443191

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Measurements of Ammonium-and Sodium-salt Aerosol Particles Using a Laser-ionization Single-particle Aerosol Mass Spectrometer2007

    • Author(s)
      M. Narukawa, Y. Matsumi, 他2名
    • Journal Title

      Chemistry Letters 36(7)

      Pages: 904-905

    • NAID

      10019745570

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Atmospheric deuterium fractionation: HCHO and HCDO yields in the CH_2DO+O_2 reaction2007

    • Author(s)
      E. Nilsson, Y. Matsumi, 他4名
    • Journal Title

      Atmos. Chem. Phys 7

      Pages: 5873-5881

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Diagnostics of surface wave excited Kr/O2 plasma for low-temperature oxidation processes2007

    • Author(s)
      K. Takeda, Y. Matsumi, 他5名
    • Journal Title

      Journal of Applied Physics 102

      Pages: 13302-13302

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Trace detection of atmospheric NO2 by laser-induced fluorescence using a GaN diode laser and a diode-pumped YAG laser2007

    • Author(s)
      Fumikazu, Taketani, Megumi, Kawai, Kenshi, Takahashi, Yutaka, Matsumi
    • Journal Title

      Applied Optics 46

      Pages: 907-914

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Atmospheric Chemistry of CF_3CH=CH_2 and C_4F-9CH=CH_2 : Products of the Gas-Phase Reactions with Cl Atoms and OH Radicals2007

    • Author(s)
      T. Nakayama, K. Takahashi, Y. Matsumi, A. Taft, It, P. Sulbaek, Andersen, O. J,. Nielsen, R. L. Waterland, R. C. Buck, M. D. Hurley, T. J. Wallington
    • Journal Title

      J. Phys. Chem 111

      Pages: 909-915

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Pulsed laser photolysis vacuum UV laser-induced fluorescence kinetic study of the gas-phase reactions of Cl(^2P_3/2 atoms with C_3-C_6 ketones2007

    • Author(s)
      Kenshi, Takahashi, Erika, Iwasaki, Yutaka, Matsumi, Timothy, J. Wallington
    • Journal Title

      J Phys. Chem 111

      Pages: 1271-1276

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Vacuum ultraviolet laser-induced fluorescence kinetic study of the reactions of Cl atoms with fluoroalkenes (C_xF_2x+ICH=CH_2, x=1,2,4,6, and 8) at low pressures2007

    • Author(s)
      K. Takahashi, E. Iwasaki, T. Nakayama, Y. Matsumi, T. J. Wallington
    • Journal Title

      International Jounal of Chemical Kinetics 39

      Pages: 328-332

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Mechanism of the gas phase reaction of chlorine atoms with butanone2007

    • Author(s)
      E. Iwasaki, F. Taketanit, K. Takahashi, Y. Matsumi, T.J. Wallington, M.D. Hurley
    • Journal Title

      Chemical Physics Letters 439

      Pages: 274-279

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Real-time analysis of secondary organic aerosol particles formed from cyclohexene ozonolysis using a laser-ionization single-particle aerosol mass spectrometer2007

    • Author(s)
      M. Narukawa, Y. Matsumi, J. Matsumoto, K. Takahashi, A. Yabushita, K. Sato, T. Imamura
    • Journal Title

      Analytical Sciences 23

      Pages: 507-512

    • NAID

      40015443191

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Measurements of Ammonium- and Sodium-salt Aerosol Particles Using a Laser-ionization Single-particle Aerosol Mass Spectrometer2007

    • Author(s)
      M. Narukawa, Y. Matsumi, K. Takahashi, A. Yabushita
    • Journal Title

      Chemistry Letters 36(7)

      Pages: 904-905

    • NAID

      10019745570

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Atmospheric deuterium fractionation : HCHO and HCDO yields in the CH2D0 + 02 reaction2007

    • Author(s)
      E. Nilsson, M. Johnson, F. Taketani, Y. Matsumi, M. Hurley, T. Wallington
    • Journal Title

      Atmos. Chem. Phys 7

      Pages: 5873-5881

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Diagnostics of surface wave excited Kr/02 plasma for low-temperature oxidation processes2007

    • Author(s)
      K. Takeda, Y. Kubota, S. Tsunashima, M. Hori, A. Serdyuchenko, M. Ito, Y. Matsumi
    • Journal Title

      Journal of Applied Physics 102

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Pulsed laser photolysis vacuum UV laser-induced fluorescence kinetic study of the gas-phase reactions of cl(2P_<3/2>) atoms with C_3-C_6 ketones2007

    • Author(s)
      K. Takahashi, Y. Matsumi, 他2名
    • Journal Title

      J. Phys. Chem A111

      Pages: 1271-1276

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vacuum ultraviolet laser-induced fluorescence kinetic study of the reactions of cl atoms with fluoroalkenes (C_xF_<2x+1>CH=CH_2,x=1,2,4,6, and 8) at low pressures,2007

    • Author(s)
      K. Takahashi, Y. Matsumi, 他3名
    • Journal Title

      International Jounal of Chemical Kinetics 39

      Pages: 328-332

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of the gas phase reaction of chlorine atoms with butanone2007

    • Author(s)
      E. Iwasaki, , Y. Matsumi, 他4名
    • Journal Title

      Chemical Physics Letters 439

      Pages: 274-279

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurements of Ammonium- and Sodium-salt Aerosol Particles Using a Laser-ionization Single-particle Aerosol Mass Spectrometer2007

    • Author(s)
      M. Narukawa, Y. Matsumi, 他2名
    • Journal Title

      Chemistry Letters 36(7)

      Pages: 904-905

    • NAID

      10019745570

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of the gas phase reactions of chlorine atoms with a series of ketones2007

    • Author(s)
      F.Taketani, Y.Matsumi, 他2名
    • Journal Title

      Chem. Phys. Letters 431

      Pages: 257-260

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Trace detection of atmospheric NO2 by laser-induced fluorescence using a GaN diode laser and a diode-pumped YAG laser2007

    • Author(s)
      F.Taketani, Y.Matsumi, 他2名
    • Journal Title

      Applied Optics 46

      Pages: 907-914

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Atmospheric Chemistry of CF3CH=CH2 and C4F9CH=CH2 : Products of the Gas-Phase Reactions with Cl Atoms and OH Radicals.2007

    • Author(s)
      T.Nakayama, Y.Matsumi, 他8名
    • Journal Title

      J. Phys. Chem. A111

      Pages: 909-915

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Pulsed laser photolysis vacuum UV laser-induced fluorescence kinetic study of the gas-phase reactions of Cl(2P3/2) atoms with C3-C6 ketones2007

    • Author(s)
      K.Takahashi, Y.Matsumi, 他2名.
    • Journal Title

      J. Phys. Chem. A111

      Pages: 1271-1276

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Vacuum ultraviolet laser-induced fluorescence kinetic study of the reactions of Cl atoms with fluoroalkenes (CxF2x+1CH=CH2, x=1,2,4,6,and 8) at low pressures2007

    • Author(s)
      K.Takahashi, Y.Matsumi, 他3名
    • Journal Title

      International Journal of Chemical Kinetics (in press)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Laboratory study of O(1S)formation process in the photolysis of O_3 and its atmospheric implications2006

    • Author(s)
      T. Nakayama, Y. Matsumi, 他2名
    • Journal Title

      J. Atmospheric Chemistry 53

      Pages: 107-122

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Kinetic study of the collisional quenching of spin-orbitally excited atomic chlorine, Cl(2P_<1/2>),by H_2O, D_2O, and H_2O_22006

    • Author(s)
      M. Kono, Y. Matsumi, 他1名
    • Journal Title

      Chem. Phys. Lett. 418

      Pages: 15-18

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Scavenging of pollutant acid substances by Asian mineral dust particles2006

    • Author(s)
      J. Matsumoto, Y. Matsumi, 他5名
    • Journal Title

      Geophys. Res. Lett. 33(7)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Seasonal variation of carbon monoxide in northern Japan: Frourier transform IR measurements and source-labeled model calculations2006

    • Author(s)
      M. Koike, Y. Matsumi, 他6名
    • Journal Title

      J. Geophys. Res 111

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Kinetics of the gas phase reactions of chlorine atoms with a series of ketones2006

    • Author(s)
      F. Taketani, Y. Matsumi, 他2名
    • Journal Title

      Chem. Phys. Letters 431

      Pages: 257-260

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Laboratory study of O(1S) formation process in the photolysis of Os and its atmospheric implications2006

    • Author(s)
      T. Nakayama, K. Takahashi, Y. Matsumi, H. Fujiwara
    • Journal Title

      J. Atmospheric Chemistry 53

      Pages: 107-122

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Kinetic study of the collisional quenching of spin-orbitally excited atomic chlorine, Cl(^2P_1/2), by H_2O, D_20, and H_20_22006

    • Author(s)
      M. Kono, K. Takahashi, Y. Matsumi
    • Journal Title

      Chem. Phys. Lett 418

      Pages: 15-18

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Scavenging of pollutant acid substances by Asian mineral dust narticles2006

    • Author(s)
      Matsumoto, Jun, Takahashi, Kenshi, Matsumi, Yutaka, Yabushita, Akihiro, Shimizu, Atsushi, Matsui, Ichiro, Sugimoto, Nobuo
    • Journal Title

      Geophys. Res. Left Vol.33, No.7

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Seasonal variation of carbon monoxide in northern Japan : Frourier transform IR measurements and source-labeled model calculations2006

    • Author(s)
      M. Koike, N. B. Jones, P. I. Palmer, H. Matsui, Y. Zhao, Y. Kondo, Y. Matsumi, H. Tanimoto
    • Journal Title

      J. Geophys. Res 111

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Kinetics of the gas phase reactions of chlorine atoms with a series of ketones2006

    • Author(s)
      F. Taketani, Y. Matsumi, T.J. Wallington, M.D. Hurley
    • Journal Title

      Chem. Phys. Letters 431

      Pages: 257-260

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Laboratory study of O(^1S) formation process in the photolysis of O_3 and its atmospheric implications2006

    • Author(s)
      T.Nakayama, Y.Matsumi, 他2名
    • Journal Title

      J. Atmospheric Chemistry 53

      Pages: 107-122

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Kinetic study of the collisional quenching of spin-orbitally excited atomic chlorine, Cl(^2P_<1/2>), by H_2O, D_2O, and H_2O_22006

    • Author(s)
      M.Kono, Y.Matsumi, 他1名
    • Journal Title

      Chem. Phys. Lett. 418

      Pages: 15-18

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Scavenging of pollutant acid substances by Asian mineral dust particles2006

    • Author(s)
      J.Matsumoto, Y.Matsumi, 他5名
    • Journal Title

      Geophys. Res. Lett. 33・7

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Seasonal variation of carbon monoxide in northern Japan : Frourier transform IR measurements and source-labeled model calculations2006

    • Author(s)
      M.Koike, Y.Matsumi, 他6名
    • Journal Title

      J. Geophys. Res. 111

    • Related Report
      2006 Annual Research Report
  • [Presentation] 真空紫外レーザー誘起蛍光法を用いたCl原子とエステルとの反応速度定数の測定2007

    • Author(s)
      ○井出 智幸、岩崎 絵利果、高橋 けんし、松見 豊
    • Organizer
      日本地球惑星科学連合2007年大会
    • Place of Presentation
      幕張メッセ 国際会議場
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロヘキサノンの大気中からの消失過程2007

    • Author(s)
      ○岩崎 絵利果、高橋 けんし、松見 豊
    • Organizer
      日本地球惑星科学連合2007年大会
    • Place of Presentation
      幕張メッセ 国際会議場
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] メチルエチルケトンと塩素原子の気相反応過程2007

    • Author(s)
      ○岩崎絵利果・高橋けんし・松見 豊・M. D. Hurley・ T. J. Wallington
    • Organizer
      第23回化学反応討論会
    • Place of Presentation
      神戸大学百年記念館(神大会館)六甲ホール
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] 真空紫外レーザー誘起蛍光法を用いたCl(2P3/2)原子とギ酸エステルとの反応速度定数の計測2007

    • Author(s)
      ○井出智幸・岩崎絵利果・高橋けんし・松見 豊
    • Organizer
      第23回化学反応討論会
    • Place of Presentation
      神戸大学百年記念館(神大会館)六甲ホール
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ペンタナール(C4H9CHO)の大気化学反応過程2007

    • Author(s)
      ○千葉仁・岩崎絵利果・中山智喜・松見 豊・高橋けんし・T. J. Wallington
    • Organizer
      第13回大気化学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Measurements of the rate constants for the reactions between Cl atom and esters using a vacuum ultraviolet laser-induced fluorescence technique2007

    • Author(s)
      T. Ide, E. Iwasaki, K. Takahashi, Y. Matsumi
    • Organizer
      Japan Geoscience Union Meeting 2007
    • Place of Presentation
      Makuhari Messe International Conference Hall (Chiba)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Loss processes of cyclohexanorie in the atmosphere2007

    • Author(s)
      E. Iwasaki K. Takahashi, Y. Matsumi
    • Organizer
      Japan Geoscience Union Meeting 2007
    • Place of Presentation
      Makuhari Messe International Conference Hall (Chiba)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Reaction processes of the reaction beyween Cl atom and methv-ethvl-ketone2007

    • Author(s)
      E. Iwasaki, K. Takahashi, Y. Matsumi, M. D. Hurley, T. J. Wallington
    • Organizer
      23rd Conference on Chemical Reaction
    • Place of Presentation
      Kobe University
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Measurements of the rate constants for the reactions between CI atom and formic esters using a vacuum ultraviolet laser-induced fluorescence technique2007

    • Author(s)
      T. Ide, E. Iwasaki, K. Takahashi, Y. Matsumi
    • Organizer
      23rd Conference on Chemical Reaction
    • Place of Presentation
      Kobe University
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Atmospheric reaction processes of pentanal2007

    • Author(s)
      H. Chiba, E. Iwasaki, T. Nakayama, Y. Matsumi, K. Takahashi, T. J. Wallington
    • Organizer
      13th Conference on Atmospheric Chemistry
    • Place of Presentation
      Nagoya University
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 真空紫外レーザー誘起蛍光法を用いたC1原子とエステルとの反応速度定数の測定2007

    • Author(s)
      ○井出 智幸、岩崎 絵利果、高橋けんし、松見 豊
    • Organizer
      日本地球惑星科学連合2007年大会
    • Place of Presentation
      幕張メッセ 国際会議場
    • Related Report
      2007 Annual Research Report
  • [Presentation] 真空紫外レーザー誘起蛍光法を用いたC1(2P3/2)原子とギ酸エステルとの反応速度定数の計測2007

    • Author(s)
      ○井出智幸・岩崎絵利果・高橋けんし・松見 豊
    • Organizer
      第23回化学反応討論会
    • Place of Presentation
      神戸大学百年記念館(神大会館)六甲ホール
    • Related Report
      2007 Annual Research Report
  • [Presentation] 真空紫外レーザー誘起蛍光法を用いたC1(2P3/2)原子とケトンとの反応速度定数の計測2006

    • Author(s)
      ○岩崎 絵利果、高橋 けんし、松見 豊、Timothy J. Wallington
    • Organizer
      第22回化学反応討論会
    • Place of Presentation
      分子科学研究所(愛知県岡崎市)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ケトンの対流圏寿命についての新しい知見2006

    • Author(s)
      ○岩崎 絵利果、高橋 けんし、松見 豊、Timothy J. Wallington
    • Organizer
      第12回大気化学討論会
    • Place of Presentation
      山形蔵王温泉 こまくさ荘
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 大気中でのn-ブチルアルデヒドと塩素原子の気相化学反応2006

    • Author(s)
      ○竹谷文一(JAMSTEC)、高橋 けんし、松見 豊、M. D. Hurley. T. J. Wallington
    • Organizer
      第12回大気化学討論会
    • Place of Presentation
      山形蔵王温泉 こまくさ荘
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 臭素原子の真空紫外-光子励起LIF検出2006

    • Author(s)
      ○岩崎 絵利果、高橋 けんし、松見 豊
    • Organizer
      分子構造総合討論会2006
    • Place of Presentation
      グランシップ静岡
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Measurements of the rate constants for the reactions between Cl atom and ketones using a vacuum ultraviolet laser-induced fluorescence technique2006

    • Author(s)
      E. Iwasaki, K. Takahashi, Y. Matsumi, T. J. Wallington
    • Organizer
      12th Conference on Chemical Reaction
    • Place of Presentation
      Institute for Molecular Science (Okazaki, Aich)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Newaspects on the lifetimes of ketones in the troposphere2006

    • Author(s)
      E. Iwasaki, K. Takahashi, Y. Matsumi, T. J. Wallington
    • Organizer
      12th Conference on Atmospheric Chemistry
    • Place of Presentation
      Zao Spa, Yamagata
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Chemical reactions between n-butylaldehyde and Cl atom in the atmosphere2006

    • Author(s)
      F. Taketani, K. Takahashi, Y. Matsumi, M. D. Hurley, T. J. Wallington
    • Organizer
      12th Conference on Atmospheric Chemistry
    • Place of Presentation
      Zao Spa, Yamagata
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Detection of Br atoms using a vacuum ultraviolet laser-induced fluorescence technique2006

    • Author(s)
      E. Iwasaki, K. Takahashi, Y. Matsumi
    • Organizer
      Conference on Molecular Structure
    • Place of Presentation
      Shizuoka
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2006-04-01   Modified: 2016-04-21  

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