Development and mechanism elucidation of novel photoreaction processes in microreactors

• Project/Area Number: 18510109
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Microdevices/Nanodevices
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: MATSUSHITA Yoshihisa Tokyo Institute of Technology, Graduate School of Science, Assistant Professor (80240753)
• Project Period (FY): 2006 – 2007
• Project Status: Completed (Fiscal Year 2007)
• Budget Amount: ¥3,100,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥300,000); Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2006: ¥1,800,000 (Direct Cost: ¥1,800,000)
• Keywords: Microreactor / Photocatalyst / Asymmetric Synthesis / Alkylation / Carbon Dioxide Recycling / Water-splitting / Multiphase Flow / 触媒・化学プロセス / システムオンチップ / 環境技術 / 表面・界面物性

Research Abstract

Photochemical reactions carried out in microreactors can be expected to exhibit some advantages, such as higher spatial illumination homogeneity and better light penetration through the entire reactor depth, and larger illuminated surface area per unit volume in comparison with those conducted in large-scale reactors. Therefore, we have developed microreactors optimized for photoreactions.
Photodimerization and asymmetric photocycloaddition reactions were examined as model reactions. We observed not only the drastic increase of the quantum efficiency of the reaction, but also the enhancement of stereoselectivity in the microreaction system. In the micro-flow system, the residence time of the substrate is very short and the reaction vessel does not retain the reaction products. These facts may prevent sequential side reactions and increase the yield and selectivity of the asymmetric reaction.
Photocatalytic oxidation and reduction of organic compounds, amine N-alkylation, and carbon dioxide fixation processes were investigated in the photocatalytic microreaction system. These model reactions proceeded quite rapidly with considerably large photonic efficiencies.
Photocatalytic reduction of CO 2 was examined by using several sort of metal co-catalyst loaded on the TiO 2 surface. Though it has been known that CO 2 in aqueous solution can be photocatalytically reduced, only very low reaction yields were reported by using large-scale batch reaction systems. The reaction proceeded very quickly to form methanol as the main product in our microreaction system. The yield of methanol is more than 1000 times larger than that obtained in conventional batch reaction systems and further increased under multiphase flow condition.

Research Products

• [Journal Article] Photocatalytic Oxidation and Alkylation Processes in Microreactors (2008)
  • Author(s): Yoshihisa Matsushita, Mayuko Iwasawa, Nobuko Ohba, Shinji Kumada, Tadashi Suzuki, Teijiro Ichimura
  • Journal Title: IEEE Review on Advances in Micro, Nano, and Molecular Systems 2(in press)
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Photocatalytic Reactions in Microreactors (2008)
  • Author(s): Y. Matsushita, N. Ohba, S. Kumada, T. Suzuki, T. Ichimura
  • Journal Title: Chem. Eng. J. 135S Pages: 303-308
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] N-Alkylation of Amines by Photocatalytic Reaction in a Microreaction System (2008)
  • Author(s): Y. Matsushita, N. Ohba, , T. Suzuki, T. Ichimura
  • Journal Title: Catalysis Today 132 Pages: 153-158
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] 4. Photocatalytic Oxidation and Alkylation Processes in Microreactors (2008)
  • Author(s): Y., Matsushita, N., Ohba, S., Kumada, K., Sakeda, T., Suzuki, T., Ichimura
  • Journal Title: IEEE Review on Advances in Micro, Nano, and Molecular Systems Volume 2(in press)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 9. Photocatalytic Reactions in Microreactors (2008)
  • Author(s): Y., Matsushita, N., Ohba, S., Kumada, K., Sakeda, T., Suzuki, T., Ichimura
  • Journal Title: Chem. Eng. J 135S Pages: 303-308
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 10. N-Alkylation of Amines by Photocatalytic Reaction in a Microreaction System (2008)
  • Author(s): Y., Matsushita, N., Ohba, T., Suzuki, T., Ichimura
  • Journal Title: Catal. Today 132 Pages: 153-158
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 11. Photoreactions (2008)
  • Author(s): Teijiro, Ichimura, Yoshihisa, Matsushita, Kosaku, Sakeda, Tadashi, Suzuki
  • Journal Title: In : Thomas R. Dietrich (ed.) Microchemical Engineering in Practice (in press)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] マイクロリアクターによる光触媒反応 (2007)
  • Author(s): 松下慶寿
  • Journal Title: Electrochemistry 75 Pages: 9-13
  • NAID: 10018286035
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Recent progress on photoreactions in microreactors (2007)
  • Author(s): Y. Matsushita, T. Ichimura, N. Ohba, S. Kumada, K, Sakeda, T. Suzuki, H. Tanibata, and T. Murata
  • Journal Title: Pure Appl. Chem. 79 Pages: 1959-1968
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Photosynthesis of High-Value Added Compounds in a Microreaction System (2007)
  • Author(s): Y. Matsushita, A. Murata, T. Murata, H. Tanibata, T. Suzuki, T. Ichimura
  • Journal Title: Micro Total Analysis System 2007 2 Pages: 1462-1464
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Photocatalytic N-alkylation of benzylamine in microreactors (2007)
  • Author(s): Y. Matsushita, N. Ohba, S. Kumada, T. Suzuki, T. Ichimura
  • Journal Title: Catalysis Communications 8 Pages: 2193-2196
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Asymmetric photosensitized addition of methanol to(R)-(+)-(Z)-limonene in a microreactor (2007)
  • Author(s): K. Sakeda, K. Wakabayashi, Y. Matsushita, T. Ichimura, T. Suzuki, T. Wada and Y. Inoue
  • Journal Title: J. Photochem. Photobiol. A: Chemistry 192 Pages: 166-171
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] 2. Photocatalytic Reaction in Microreactos (2007)
  • Author(s): Y., Matsushita
  • Journal Title: Electrochemistry 75 Pages: 9-13
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 5. Recent progress on photoreactions in microreactors (2007)
  • Author(s): Y., Matsushita, T., Ichimura, N., Ohba, S., Kumada, K., Sakeda, T., Suzuki, H., Tanibata, T., Murata
  • Journal Title: Pure Appl. Chem 79
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 6. Photosynthesis of High-Value Added Compounds in a Microreaction System (2007)
  • Author(s): Y., Matsushita, A., Murata, T., Murata, H., Tanibata, T., Suzuki, T., Ichimura
  • Journal Title: Micro Total Analysis Systems 2007,2 Pages: 1462-1464
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 7. Photocatalytic N-alkylation of benzylamine in microreactors (2007)
  • Author(s): Y., Matsushita, N., Ohba, S., Kumada, T., Suzuki, T., Ichimura.
  • Journal Title: Catalysis Communications 8 Pages: 2193-2196
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 8. Asymmetric photosensitized addition of methanol to (R)-(+)-(Z)-limonene in a microreactor (2007)
  • Author(s): K., Sakeda, K., Wakabayashi, Y., Matsushita, T., Ichimura, T., Suzuki, T., Wada, Y., Inoue, J., Photochem., Photobiol.
  • Journal Title: A : Chemistry 192 Pages: 166-171
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Recent progress on photoreactions in microreactors (2007)
  • Author(s): Y. Matsushita, T. Ichimura, N. Ohba, S. Kumada, K. Sakeda, T. Suzuki, H. Tanibata, and T. Murata
  • Journal Title: Pure Appl. Chem. 79 Pages: 1959-1968
  • Peer Reviewed
• [Journal Article] Asymmetric photosensitized addition of methanol to (R)-(+)-(Z)-limonene in a microreactor (2007)
  • Author(s): K. Sakeda, K. Wakabayashi, Y. Matsushita, T. Ichimura, T. Suzuki, T. Wada and Y. Inoue
  • Journal Title: J. Photochem. Photobiol. A: Chemistry 192 Pages: 166-171
  • Peer Reviewed
• [Journal Article] Photocatalytic Reactions in Microreactors (2007)
  • Author(s): Y.Matsushita, N.Ohba, S.Kumada, K.Sakeda, T.Suzuki, T.Ichimura
  • Journal Title: Chemical Engineering Journal (印刷中)
• [Journal Article] Recent Progress on Photoreactions in Microreactors (2007)
  • Author(s): Y.Matsushita, T.Ichimura, N.Ohba, S.Kumada, K.Sakeda, T.Suzuki, H.Tanibata, T.Murata
  • Journal Title: Pure and Applied Chemistry (印刷中)
• [Journal Article] Blackwell Publishing, Oxford (2007)
  • Author(s): T.Ichimura, Y.Matsushita, K.Sakeda, T.Suzuki
  • Journal Title: Photoreactions, in Microchemical Engineering in Practice (印刷中)
• [Journal Article] Photocatalytic Reduction in Microreactos (2006)
  • Author(s): Y. Matsushita, S. Kumada, K. Wakabayashi, K. Sakeda, T. Ichimura
  • Journal Title: Chemistry Letters 35 Pages: 410-411
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Photoreactions in Microreactors (2006)
  • Author(s): Teijiro Ichimura, Kosaku Sakeda, Yoshihisa Matsushita, Tadashi Suzuki, Hideki Tanibata, Toshinori Murata
  • Journal Title: Micro Total Analysis System 2006 1 Pages: 804-806
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] 1. Photocatalytic Reduction in Microreactos (2006)
  • Author(s): Y., Matsushita, S., Kumada, K., Wakabayashi, K., Sakeda
  • Journal Title: T. Ichimura Chem. Lett 35 Pages: 410-411
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] 3. Photoreactions in Microreactors2006, Society for Chemistry and Micro-Nano Systems (2006)
  • Author(s): T., Ichimura, K., Sakeda, Y., Matsushita, T., Suzuki, H., Tanibata, T., Murata
  • Journal Title: Micro Total Analysis System 2006 Pages: 804-806
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Photocatalytic Reduction in Microreactos (2006)
  • Author(s): Y.Matsushima, S.Kumada, K.Wakabayashi, K.Sakeda, T.Ichimura
  • Journal Title: Chemistry Letters 35 Pages: 410-411
• [Presentation] 光触媒担持マイクロリアクターによる二酸化炭素の還元と水の分解 (2008)
  • Author(s): 松下慶寿
  • Organizer: 第101回触媒討論会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-29
• [Presentation] マイクロリアクターを用いたスチルベンとキラルなフマル酸エステルとのジアステレオ選択的光環化付加反応 (2008)
  • Author(s): 松下慶寿
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-26
• [Presentation] 高付加価値化合物の合成と反応条件スクリーニングのためのマイクロ光反応場の開発 (2008)
  • Author(s): 松下慶寿
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-26
• [Presentation] マイクロリアクターによる光化学プロセス強化 (2008)
  • Author(s): 松下慶寿
  • Organizer: 第8回GSCシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-03-05
• [Presentation] 環境調和型マイクロ光触媒反応システムの開発 (2008)
  • Author(s): 佐藤有理子
  • Organizer: 第8回GSCシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2008-03-05
• [Presentation] 高付加価値化合物合成のためのマイクロ光反応場の開発 (2007)
  • Author(s): 松下慶寿
  • Organizer: 第16回化学とマイクロ・ナノシステム研究会
  • Place of Presentation: 筑波
  • Year and Date: 2007-10-30
• [Presentation] Photosynthesis Of High-Value Added Compounds In A Microreaction System (2007)
  • Author(s): Yoshihisa Matsushita, Akiko Murata, Toshiaki Murata, Hideki Tanibata, Tadashi Suzuki, and Teijiro Ichimura
  • Organizer: The 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences
  • Place of Presentation: Paris
  • Year and Date: 2007-10-12
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 12. Photosynthesis Of High-Value Added Compounds In A Microreaction System (2007)
  • Author(s): Yoshihisa, Matsushita, Akiko, Murata, Toshiaki, Murata, Hideki, Tanibata, Tadashi, Suzuki, Teijiro, Ichimura
  • Organizer: The 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences
  • Place of Presentation: Paris
  • Year and Date: 2007-10-12
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Photosynthesis Of High-Value Added Compounds In A Microreaction System (2007)
  • Author(s): 松下慶寿
  • Organizer: The 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences Photoreactions in Microreactors
  • Place of Presentation: パリ
  • Year and Date: 2007-10-12
• [Presentation] マイクロリアクターの特性を利用した光反応の効率、選択性の向上 (2007)
  • Author(s): 松下慶寿
  • Organizer: 光化学討論会2007
  • Place of Presentation: 松本
  • Year and Date: 2007-09-27
• [Presentation] マイクロリアクターを用いた光環化反応 (2007)
  • Author(s): 宇佐美直紀
  • Organizer: 光化学討論会2007
  • Place of Presentation: 松本
  • Year and Date: 2007-09-27
• [Presentation] 光触媒による多相流での二酸化炭素の資源化反応 (2007)
  • Author(s): 岩澤茉有子
  • Organizer: 光化学討論会2007
  • Place of Presentation: 松本
  • Year and Date: 2007-09-27
• [Presentation] 多相流を用いた光触媒反応 (2007)
  • Author(s): 松下慶寿
  • Organizer: 第100回触媒討論会
  • Place of Presentation: 札幌
  • Year and Date: 2007-09-17
• [Presentation] Photoreactions in Microspace (2007)
  • Author(s): Yoshihisa Matsushita, Mayuko Iwasawa, Nobuko Ohba, Shinji Kumada, Tadashi Suzuki, Teijiro Ichimura
  • Organizer: The XXIIIrd International Conference on Photochemistry
  • Place of Presentation: Cologne
  • Year and Date: 2007-08-01
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Multiphase Photocatalytic Reactions in Microreactors (2007)
  • Author(s): Mayuko Iwasawa, Yoshihisa Matsushita, Tadashi Suzuki, Teijiro Ichimura
  • Organizer: The XXIIIrd International Conference on Photochemistry
  • Place of Presentation: Cologne
  • Year and Date: 2007-08-01
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 10. Photoreactions in Microspace (2007)
  • Author(s): Yoshihisa, Matsushita, Mayuko, Iwasawa, Naoki, Usami, Tadashi, Suzuki, Teijiro, Ichimura
  • Organizer: The XXIIIrd International Conference on Photochemistry
  • Place of Presentation: Cologne
  • Year and Date: 2007-08-01
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] 11. Multiphase Photocatalytic Reactions in Microreactors (2007)
  • Author(s): Mayuko, Iwasawa, Yoshihisa, Matsushita, Tadashi, Suzuki, Teijiro, Ichimura
  • Organizer: The XXIIIrd International Conference on Photochemistry
  • Place of Presentation: Cologne
  • Year and Date: 2007-08-01
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Photoreactions in Microspace (2007)
  • Author(s): 松下慶寿
  • Organizer: The XXIIIrd International Conference on Photochemistry
  • Place of Presentation: ケルン
  • Year and Date: 2007-08-01
• [Presentation] Multiphase Photocatalytic Reactions in Microreactors (2007)
  • Author(s): 岩澤茉有子
  • Organizer: The XXIIIrd International Conference on Photochemistry
  • Place of Presentation: ケルン
  • Year and Date: 2007-08-01
• [Presentation] Organic syntheses by photocatalytic reaction in microreactors (2007)
  • Author(s): Yoshihisa Matsushita, Mayuko Iwasawa, Nobuko Ohba, Shinji Kumada, Tadashi Suzuki, Teijiro Ichimura
  • Organizer: The 11th Korea-Japan Symposium on Catalysis
  • Place of Presentation: Seoul
  • Year and Date: 2007-05-22
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Organic syntheses by photocatalytic reaction in microreactors (2007)
  • Author(s): 松下慶寿
  • Organizer: The 11th Korea-Japan Symposium on Catalysis
  • Place of Presentation: ソウル
  • Year and Date: 2007-05-22
• [Presentation] Microreaction System For Photosynthesis Of High-Value Added Compounds (2007)
  • Author(s): Y. Matsushita, M. Iwasawa, N. Ohoba, S. Kumada, T. Suzuki, T. Ichimura
  • Organizer: 1st International Symposium of Nanomedicine-from Basic to Applications-and 2nd Molecule-Based Information Transmission and Reception
  • Place of Presentation: 岡崎
  • Year and Date: 2007-04-20
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 8. Organic syntheses by photocatalytic reaction in microreactors (2007)
  • Author(s): Y., Matsushita, M., Iwasawa, N., Ohoba, S., Kumada, T., Suzuki, T., Ichimura
  • Organizer: 1st International Symposium of Nanomedicine -from Basic to Applications and 2nd Molecule-Based Information Transmission and Reception
  • Place of Presentation: Okazaki
  • Year and Date: 2007-04-20
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Microreaction System For Photosynthesis Of High-Value Added Compounds (2007)
  • Author(s): 松下慶寿
  • Organizer: 1st International Symposium of Nanomedicine-from Basic to Applications- and 2nd Molecule-Based Information Transmission and Reception
  • Place of Presentation: 岡崎
  • Year and Date: 2007-04-20
• [Presentation] 9. Organic syntheses by photocatalytic reaction in microreactors (2007)
  • Author(s): Yoshihisa, Matsushita, Mayuko, Iwasawa, Nobuko, Ohba, Shinji, Kumada, Tadashi, Suzuki, Teijiro, Ichimura
  • Organizer: The 11th Korea-Japan Symposium on Catalysis
  • Place of Presentation: Seoul
  • Year and Date: 2007-03-22
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Application of Photocatalytic Microreaction Systems to Organic Synthesis (2007)
  • Author(s): Yoshihisa Matsushita, Nobuko Ohoba, Shinji Kumada, Tadashi Suzuki, and Teijiro Ichimura
  • Organizer: 1st Asian-Oceanian Conference on Green and Sustainable Chemistry
  • Place of Presentation: 東京
  • Year and Date: 2007-03-06
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Multiphase Photocatalytic Reactions in Microreactors (2007)
  • Author(s): Mayuko Iwasawa, Yoshihisa Matsushita, Tadashi Suzuki, and Teijiro Ichimura
  • Organizer: 1st Asian-Oceanian Conference on Green and Sustainable Chemistry
  • Place of Presentation: 東京
  • Year and Date: 2007-03-06
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 6. Application of Photocatalytic Microreaction Systems to Organic Synthesis (2007)
  • Author(s): Yoshihisa, Matsushita, Nobuko, Ohoba, Shinji, Kumada, Tadashi, Suzuki, Teijiro, Ichimura
  • Organizer: 1st Asian-Oceanian Conference on Green and Sustainable Chemistry
  • Place of Presentation: Tokyo
  • Year and Date: 2007-03-06
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] 7. Multiphase Photocatalytic Reactions in Microreactors (2007)
  • Author(s): Mayuko, Iwasawa, Yoshihisa, Matsushita, Tadashi, Suzuki, Teijiro, Ichimura
  • Organizer: 1st Asian-Oceanian Conference on Green and Sustainable Chemistry
  • Place of Presentation: Tokyo
  • Year and Date: 2007-03-06
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Organic Reactions in a Photocatalytic Microreaction System (2007)
  • Author(s): Y. Matsushita, T. Ichimura, M. Iwasawa, N. Ohoba, S. Kumada, T. Suzuki
  • Organizer: The 5th Micro-chemical plant international workshop,
  • Place of Presentation: 京都
  • Year and Date: 2007-01-26
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 5. Organic Reactions in a Photocatalytic Microreaction System (2007)
  • Author(s): Y., Matsushita, T., Ichimura, M., Iwasawa, N., Ohoba, S., Kumada, T., Suzuki
  • Organizer: The 5th Micro-chemical plant international workshop
  • Place of Presentation: Kyoto
  • Year and Date: 2007-01-26
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Photocatalytic Oxidation and Alkylation Processes in Microreactors (2007)
  • Author(s): Yoshihisa Matsushita, Mayuko Iwasawa, Nobuko Ohba, Shinji Kumada, Tadashi Suzuki, Teijiro Ichimura
  • Organizer: The 2nd Annual IEEE International Conference on Nano/Micro Engineered and Molecular Systems
  • Place of Presentation: Bangkok
  • Year and Date: 2007-01-11
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 4. Photocatalytic Oxidation and Alkylation Processes in Microreactors (2007)
  • Author(s): Yoshihisa, Matsushita, Mayuko, Iwasawa, Nobuko, Ohba, Shinji, Kumada, Tadashi, Suzuki, Teijiro, Ichimura
  • Organizer: Conference on Nano/Micro Engineered and Molecular Systems
  • Place of Presentation: Bangkok
  • Year and Date: 2007-01-11
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Photocatalytic Organic Synthesis in Microreactors (2006)
  • Author(s): Yoshihisa Matsushita, Kosaku Sakeda, Tadashi Suzuki, Teijiro Ichimura, Hideki Tanibata, Toshinori Murata
  • Organizer: 10th International Conference on Miniaturized Systems for Chemistry and Life Sciences
  • Place of Presentation: Tokyo
  • Year and Date: 2006-11-07
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 1. Photocatalytic Organic Synthesis in Microreactors (2006)
  • Author(s): Yoshihisa, Matsushita, Kosaku, Sakeda, Tadashi, Suzuki, Teijiro, Ichimura, Hideki, Tanibata, Toshinori, Murata
  • Organizer: 10th International Conference on Miniaturized Systems for Chemistry and Life Sciences
  • Place of Presentation: Tokyo
  • Year and Date: 2006-11-07
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Photocatalytic Reaction in Microreactors (2006)
  • Author(s): Yoshihisa Matsushita, Yoshihisa Matsushita, Kosaku Sakeda, Tadashi Suzuki, Teijiro Ichimura, Hideki Tanibata, Toshinori Murata
  • Organizer: The 9th International Conference on Microreaction Technology
  • Place of Presentation: Berlin
  • Year and Date: 2006-09-07
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 3. Photocatalytic Reaction in Microreactors (2006)
  • Author(s): Yoshihisa, Matsushita, Yoshihisa, Matsushita, Kosaku, Sakeda, Tadashi, Suzuki, Teijiro, Ichimura, Hideki, Tanibata, Toshinori, Murata
  • Organizer: The 9th International Conference on Microreaction Technology
  • Place of Presentation: Berlin
  • Year and Date: 2006-09-07
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Multiphase Photocatalytic Reactions in Microreactors (2006)
  • Author(s): Yoshihisa Matsushita, Kosaku Sakeda, Tadashi Suzuki, Teijiro Ichimura, Hideki Tanibata, Toshinori Murata
  • Organizer: 1st European Chemistry Congress, Budapest
  • Place of Presentation: Budapest
  • Year and Date: 2006-08-31
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 2. Multiphase Photocatalytic Reactions in Microreactors (2006)
  • Author(s): Yoshihisa, Matsushita, Kosaku, Sakeda, Tadashi, Suzuki, Teijiro, Ichimura, Hideki, Tanibata, Toshinori, Murata
  • Organizer: 1st European Chemistry Congress
  • Place of Presentation: Budapest
  • Year and Date: 2006-08-31
  • Description: 「研究成果報告書概要(欧文)」より
• [Book] Photoreactions, in Microchemical Engineering in Practice (2008)
  • Author(s): T. Ichimura, Y. Matsushita, K. Sakeda, T. Suzuki
  • Publisher: Blackwell Publishing, Oxford(印刷中)
  • Description: 「研究成果報告書概要(和文)」より
• [Book] Photoreactions, in Microchemical Engineering in Practice (2007)
  • Author(s): T.Ichimura, Y.Matsushita, K.Sakeda, T.Suzuki
  • Publisher: Blackwell Publishing, Oxford(印刷中)
• [Patent(Industrial Property Rights)] 光触媒担持マイクロリアクター (2007)
  • Inventor(s): 松下慶寿他
  • Industrial Property Rights Holder: 東京工業大学他
  • Patent Publication Number: 2007-313426
  • Acquisition Date: 2007-12-06
• [Patent(Industrial Property Rights)] マイクロ反応装置、その製造方法、集積化マイクロ反応モジュール、および有機ヒ素汚染水の浄化方法 (2007)
  • Inventor(s): 松下慶寿, 市村禎二郎, 鈴木正 他
  • Industrial Property Rights Holder: 東京工業大学
  • Industrial Property Number: 2007-029780
  • Filing Date: 2007-02-08
• [Patent(Industrial Property Rights)] マイクロ反応装置および触媒反応方法 (2007)
  • Inventor(s): 松下慶寿, 市村禎二郎 他
  • Industrial Property Rights Holder: 東京工業大学
  • Industrial Property Number: 2007-030880
  • Filing Date: 2007-02-09
• [Patent(Industrial Property Rights)] パイプフローを用いた光触媒系マイクロ反応装置 (2006)
  • Inventor(s): 松下慶寿, 市村禎二郎, 鈴木正 他
  • Industrial Property Rights Holder: 東京工業大学
  • Industrial Property Number: 2006-244696
  • Filing Date: 2006-09-08