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Synthesize and development of unconventional physical property on transition metal oxide nanotube

Research Project

Project/Area Number 18540362
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

樹神 克明  Japan Atomic Energy Agency, 量子ビーム応用研究部門, 研究副主幹 (10313115)

Co-Investigator(Kenkyū-buntansha) 社本 真一 (社本 慎一)  独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究主席 (90235698)
田中 秀吉  独立行政法人通信総合研究機構, 関西先端研究センター, 主任研究員 (40284608)
瀧川 仁  東京大学, 物性研究所, 教授 (10179575)
Research Collaborator 飯久保 智  九州工業大学
田口 富嗣  日本原子力研究開発機構
竹中 康司  名古屋大学
BELIK Alexi. A.  物質材料研究機構
室町 英治  物質材料研究機構
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,710,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥510,000)
Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2006: ¥1,500,000 (Direct Cost: ¥1,500,000)
Keywords強相関電子系 / 磁性 / ナノチューブ / フラーレン / 物性実験 / ナノチューブ、フラーレン
Research Abstract

本研究ナノ粒子系の構造を調べるための手法であるPDF解析法について、粒子の有限サイズを考慮した、解析的に新しい式を導出し、実験的にその式の正当性を確認した。またバルク物質内に存在するナノスケールの構造歪みをPDF解析によって発見し、それらがマルチフェロイックや巨大負熱膨張などの物性に寄与していることを明らかにした。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (41 results)

All 2008 2007 2006 Other

All Journal Article (24 results) (of which Peer Reviewed: 20 results) Presentation (16 results) Remarks (1 results)

  • [Journal Article] Local lattice distortion in giant negative thermal expansion material Mn3Cu1-xGexN2008

    • Author(s)
      S. Iikubo, K. Kodama, T. Takenaka, H. Takagi, M. Takigawa and S. Shamoto
    • Journal Title

      Phys. Rev. Lett. 101

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Powder Diffraction Study on the Crystal and Magnetic Structures of BiCrO32008

    • Author(s)
      A. A. Belik, S. Iikubo, K. Kodama, N. Igawa, S. Shamoto, and E. Takayama-Muromachi
    • Journal Title

      Chemistry of Materials 20

      Pages: 3765-3769

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magneto-volume effect of Mn3Cu1-xGexN related to magnetic structure2008

    • Author(s)
      S. Iikubo, K. Kodama, K. Takenaka, H. Takagi and S. Shamoto
    • Journal Title

      Phys. Rev. B 77

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 原子対相関関数(atomic Pair Distribution Function : PDF)を用いた結晶性物質の局所構造解析2008

    • Author(s)
      樹神克明
    • Journal Title

      セラミックス 43

      Pages: 909-917

    • NAID

      10024784185

    • Related Report
      2008 Annual Research Report 2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 結晶PDF 解析の最前線2008

    • Author(s)
      社本真一、樹神克明、飯久保智
    • Journal Title

      波紋 18

      Pages: 203-207

    • NAID

      130001998214

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] パルス中性子を用いた構造解析の最前線2008

    • Author(s)
      社本真一、鈴谷賢太郎、神山崇、樹神克明、大友季哉、福永俊晴
    • Journal Title

      核融合学会誌 84

      Pages: 323-332

    • NAID

      110006794363

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local lattice distortion in giant negative thermal expansion material Mn_3Cu_<1-x>Ge_xN2008

    • Author(s)
      S. Iikubo, et al.
    • Journal Title

      Physical Review Letters 101

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Powder Diffraction Study on the Crystal and Magnetic Structures of BiCrO_32008

    • Author(s)
      A. A. Belik, et al.
    • Journal Title

      Chemistry of Materials 20

      Pages: 3765-3769

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magneto volume effect of Mn_3Cu_1-xGe_xN related to magnetic structure2008

    • Author(s)
      Iikubo, et. al.
    • Journal Title

      Physical Review B 77

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local Crystal Structure of Multiferroic System BiMnO3 by Atomic Pair Distribution Function2007

    • Author(s)
      K. Kodama, S. Iikubo, S. Shamoto, A. A. Belik and E. Takayama-Muromachi
    • Journal Title

      Analysis J. Phys. Soc. Jpn. 76(PDF)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Origin of the Monoclinic-Monoclinic Phase Transition and Evidence for the Centrosymmetric Crystal Structure of BiMnO32007

    • Author(s)
      A. A. Belik, S. Iikubo, T. Yokozawa, K. Kodama, N. Igawa, S. Shamoto, M. Azuma, M. Takano, K. Kimoto, Y. Matsui and E. Takayama-Muromachi
    • Journal Title

      J. Am. Chem. Soc. 129(4)

      Pages: 971-977

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local Crystal Structure of Multiferroic System BiMnO_3 by Atomic Pair Distribution Function(PDF)Analysis2007

    • Author(s)
      K. Kodama, et. al.
    • Journal Title

      Journal of the Physical Society of Japan 76

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origin of the Monochnic-Monochnic Phase Transition and Evidence for the Centrosymmetric Crystal Structure of BiMnO_32007

    • Author(s)
      A.A. Belik, et. al.
    • Journal Title

      Journal of American Chemical Society 129

      Pages: 971-977

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High field properties of the frustrated 2D dimer spin system SrCu2(BO3)22006

    • Author(s)
      M. Takigawa, K. Kodama, M. Horvatic, C. Berthier, S, Matsubara, H. Kageyama, Y. Ueda, S. Miyahara and F. Mila
    • Journal Title

      J. Phys.: Conf. Ser. 51

      Pages: 23-30

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local Crystal Structures of Ge2Sb2Te5 Revealed by the Atomic Pair Distribution Function Analysis2006

    • Author(s)
      S. Shamoto, K. Kodama, S. Iikubo, T. Taguchi, N. Yamada and T. Proffen
    • Journal Title

      Jpn. J. Appl. Phys 45

      Pages: 8789-8794

    • NAID

      40015145540

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Finite Size Effects of Nanoparticles to the Atomic Pair Distribution Functions2006

    • Author(s)
      K. Kodama, S. Iikubo, T. Taguchi and S. Shamoto
    • Journal Title

      Acta Crystallogr. A 62

      Pages: 444-453

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Charge disproportionation in highly one-dimensional molecular conductor TPP[Co(Pc)(CN)2]22006

    • Author(s)
      N. Hanasaki, K. Masuda, K. Kodama, M. Matsuda, H. Tajima, J. Yamazaki, M. Takigawa, J. Yamaura, E. Ohmichi, T. Osada, T. Naito and T. Inabe
    • Journal Title

      J. Phys. Soc. Jpn. 75

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] BiScO3 : Centrosymmetric BiMnO3-type Oxide2006

    • Author(s)
      A. A. Belik, S. Iikubo, K. Kodama, N. Igawa, S. Shamoto, M. Maie, T. Nagai, Y. Matsui, S. Y. Stefanovich, B. I. Lazoryak and E. Takayama-Muromachi
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 706-707

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron Powder Diffraction Study on the Crystal and Magnetic Structures of BiCoO3(解説記事)2006

    • Author(s)
      A. A. Belik, S. Iikubo, K. Kodama, N. Igawa, S. Shamoto, S. Niitaka, M. Azuma, Y. Shimakawa, M. Takano, F. Izumi and E. Takayama-Muromachi
    • Journal Title

      Chemistry of Materials 18

      Pages: 798-803

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 中性子散乱と核磁気共鳴を用いた低次元磁性体の研究2006

    • Author(s)
      樹神克明
    • Journal Title

      波紋 16

      Pages: 160-167

    • NAID

      130001998431

    • Related Report
      2008 Final Research Report 2006 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Finite size effects of nanoparticles on the atomic pair distribution functions2006

    • Author(s)
      K.Kodama et al.
    • Journal Title

      Acta Cryst.A 62

      Pages: 444-453

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Neutron Powder Diffraction Study on the Crystal and Magnetic Structures of BiCoO_32006

    • Author(s)
      Alexei A.Belik et al.
    • Journal Title

      Chem.Mater. 18

      Pages: 798-803

    • Related Report
      2006 Annual Research Report
  • [Journal Article] BiSeO_3 : Centrosymmetric BiMnO_3-type Oxide2006

    • Author(s)
      Alexei A.Belik et al.
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 706-707

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Charge disproportination in highly one-dimensional molecular conductor TPP[Co(Pc)(CN)_2]_22006

    • Author(s)
      N.Hanasaki et al.
    • Journal Title

      J.Phys.Soc.Jpn. 75

    • Related Report
      2006 Annual Research Report
  • [Presentation] 原子対相関関数(PDF)を用いた結晶性物質の局所構造解析2008

    • Author(s)
      樹神克明
    • Organizer
      粉末回折討論会
    • Place of Presentation
      高エネルギー加速器研究機構
    • Year and Date
      2008-12-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] 原子対相関関数(PDF)を用いた結晶性物質の局所構造解析2008

    • Author(s)
      樹神克明、飯久保智、社本真一
    • Organizer
      第4回粉末回折法討論会 : 粉末法の新しい技術と応用 高エネルギー加速器研究機構
    • Place of Presentation
      (招待講演)
    • Related Report
      2008 Final Research Report
  • [Presentation] 負熱膨張物質、マンガン逆ペロブスカイトの結晶、磁気構造2008

    • Author(s)
      飯久保智、樹神克明、竹中康司、高木英典、社本真一
    • Organizer
      日本物理学会
    • Place of Presentation
      岩手大学
    • Related Report
      2008 Final Research Report
  • [Presentation] Information Obtained by PDF at Long Range Distance2008

    • Author(s)
      K. Kodama
    • Organizer
      International Workshop on Structural Analyses Bridging overbetween Amorphous and Crystalline Materials (SABAC2008)
    • Place of Presentation
      Tokai, Ibaraki, Japan(招待講演)
    • Related Report
      2008 Final Research Report
  • [Presentation] 巨大負熱膨張物質Mn_3Cu_1-xGe_xNの14N-NMR2007

    • Author(s)
      樹神 克明
    • Organizer
      日本物理学会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2007-09-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] マルチフェロイック物質BiMnO3の局所構造解析2007

    • Author(s)
      樹神克明、飯久保智、社本真一、A. A. Belik、室町英治
    • Organizer
      日本中性子科学会
    • Place of Presentation
      九州大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 巨大負熱膨張物質Mn3Cu1-xNixNの中性子散乱2007

    • Author(s)
      飯久保智、樹神克明、竹中康司、高木英典、社本真一
    • Organizer
      日本中性子科学会
    • Place of Presentation
      九州大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 巨大負熱膨張物質Mn3Cu1-xNixNの14N-NMR2007

    • Author(s)
      樹神克明、瀧川仁、飯久保智、竹中康司、高木英典、社本真一
    • Organizer
      日本物理学会
    • Place of Presentation
      北海道大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 巨大負熱膨張物質Mn3Cu1-xNixNの中性子散乱2007

    • Author(s)
      飯久保智、樹神克明、竹中康司、高木英典、社本真一
    • Organizer
      日本物理学会
    • Place of Presentation
      北海道大学
    • Related Report
      2008 Final Research Report
  • [Presentation] マルチフェロイック物質BiMnO3の局所構造解析2007

    • Author(s)
      樹神克明、飯久保智、社本真一、A. A. Belik、室町英治
    • Organizer
      日本物理学会
    • Place of Presentation
      北海道大学
    • Related Report
      2008 Final Research Report
  • [Presentation] Mn3Cu1-xNixNの磁気構造2007

    • Author(s)
      飯久保智、樹神克明、竹中康司、高木英典、社本真一
    • Organizer
      日本物理学会
    • Place of Presentation
      鹿児島大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 対相関関数を用いた構造解析に対するナノ粒子の有限サイズ効果2006

    • Author(s)
      樹神克明、飯久保智、田口富嗣、社本真一
    • Organizer
      日本中性子科学会
    • Place of Presentation
      茨城県立県民文化センター
    • Related Report
      2008 Final Research Report
  • [Presentation] 結晶PDF 解析法でみた光相変化記録材料Ge2Sb2Te5のナノ構造2006

    • Author(s)
      社本真一、樹神克明、飯久保智、田口富嗣、山田昇、T. Proffen
    • Organizer
      日本中性子科学会
    • Place of Presentation
      茨城県立県民文化センター
    • Related Report
      2008 Final Research Report
  • [Presentation] Mn3Cu1-xNixNの磁気体積効果2006

    • Author(s)
      飯久保智、竹中康司、高木英典、樹神克明、社本真一
    • Organizer
      日本物理学会
    • Place of Presentation
      千葉大学
    • Related Report
      2008 Final Research Report
  • [Presentation] 対相関関数を用いた構造解析に対するナノ粒子の有限サイズ効果2006

    • Author(s)
      樹神克明、飯久保智、田口富嗣、社本真一
    • Organizer
      ナノ学会
    • Place of Presentation
      京都大学
    • Related Report
      2008 Final Research Report
  • [Presentation] マンガン酸化物ナノ粒子の局所構造解析2006

    • Author(s)
      飯久保智、古屋仲秀樹、竹内謙、小原真司、C.-K. Loong、樹神克明、社本真一
    • Organizer
      ナノ学会
    • Place of Presentation
      京都大学
    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.jaea.go.jp/02/press2008/p08111802/index.html

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2006-04-01   Modified: 2020-05-15  

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