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Construction of a supramolecular network with active functions and its self-organization

Research Project

Project/Area Number 18540385
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Mathematical physics/Fundamental condensed matter physics
Research InstitutionFukuoka University

Principal Investigator

MIYAKAWA Kenji  Fukuoka University, Faculty of Science, Professor (30037296)

Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,740,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥240,000)
Fiscal Year 2007: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2006: ¥2,700,000 (Direct Cost: ¥2,700,000)
Keywordsself-organization / network / stochastic resonance / Belousov-Zhabotinsky reaction / BZ反応
Research Abstract

We have prepared active elements involved an autonomous function by immobilizing the catalyst ruthenium (II) for Belousov-Zhabotinsky (BZ) reaction in microgels. First we investigated the characteristic of elements by varying control parameters, such as the composition and the temperature of the BZ solution. In order to investigate the effect of hierarchization on self-organization, we have constructed a two-dimensional network based on 10×10 of such elements. In this study, we tried to induce a novel self-organization in the excitable network subjected to an external noise. We have experimentally demonstrated that the coherence of noise-induced firings is improved and the optimal noise amplitude maximizing the coherence monotonically decreases with increasing the number of elements, i.e., the occurrence of array-enhanced coherence resonance (AECR). Furthermore, it is found that synchronization among oscillators which are barely coupled can be achieved via coherence resonance. Experimental observations are approximately reproduced in a numerical simulation with a forced Oregonator reaction-diffusion model.
We have controlled the coherence of the autonomous network system by adding a feedback with a time delay τ to it. Here the optical method has been used in a feedback, since the present system is light-sensitive. We have investigated the spatial and temporal coherence of the autonomous oscillation, R and σ^2, as a function of a time delay τ and the coupling strength between elements k. We have demonstrated that both R and σ^2 periodically vary with τ . Furthermore, we have found that the coherence strongly depends on k, and is improved in the particular range of k.

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (15 results)

All 2008 2007 2006

All Journal Article (13 results) (of which Peer Reviewed: 8 results) Presentation (2 results)

  • [Journal Article] Chain Structures of Microparticles Induced by Focusing a Laser Beam near the Liquid-air Interface of a Droplet2008

    • Author(s)
      Hiroto Adachi
    • Journal Title

      AIP Conference Proceedings CP982

      Pages: 721-724

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Chain Structures of Microparticles Induced by Focusing a Laser Beam near the Liquid-air Interface of a Droplet2008

    • Author(s)
      Hiroto Adachi
    • Journal Title

      AlP Conference Proceedings CP982

      Pages: 721-724

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Chain Structures of Microparticles Induced by Focusing a Laset Beam near the Liuid-air Interface of a Drolet2008

    • Author(s)
      Hiroto Adachi
    • Journal Title

      AIP Conference Proceedings CP982

      Pages: 721-724

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Orbital motion of spherical microparticles trapped in diffraction patterns of circularly polarized light2007

    • Author(s)
      Hiroto Adachi
    • Journal Title

      Physical Review A 75

      Pages: 634091-634095

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Array-enhanced coherence resonance and phase synchronization in a two-dimensional array of excitable chemical oscillators2007

    • Author(s)
      Taiji Okano
    • Journal Title

      Physical Review E 76

      Pages: 462011-462016

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Orbital motion of spherical microparticles trapped in diffraction patterns of circularly polarized light2007

    • Author(s)
      Hiroto Adachi
    • Journal Title

      Phys. Rev. A75

      Pages: 634091-634095

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Array-enhanced coherence resonance and phase synchronization in a two-dimensional array of excitable chemical oscillators2007

    • Author(s)
      Taiji Okano
    • Journal Title

      Phys. Rev. E76

      Pages: 462011-462016

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Array-enhanced coherence resonance and phase synchronization in a two-dimensional arra of excitable chemical oscillators2007

    • Author(s)
      Taiji Okano
    • Journal Title

      Phys.Rev.E 76

      Pages: 462011-462016

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Orbital motion of spherical microparticlest rapped in diffiraction patterns of circularlypolarized light2007

    • Author(s)
      Hiroto Adachi
    • Journal Title

      Phys.Rev.A 75

      Pages: 634091-634095

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spatiotemporal Dynamics in a Linear Array of Coupled Coherence Resonance Oscillators2006

    • Author(s)
      Kenji Miyakawa
    • Journal Title

      Progress of Theoretical Physics 161

      Pages: 260-264

    • NAID

      110004729441

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary 2006 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Successive splitting of autowaves in a nonlinear chemical reaction medium2006

    • Author(s)
      Taiji Okano
    • Journal Title

      Physical Review E 74

      Pages: 661031-661036

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary 2006 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spatiotemporal dynamics in a linear array of coupled coherence resonance oscillators2006

    • Author(s)
      Kenji Miyakawa
    • Journal Title

      Progress of Theoretical Physics supplement 161

      Pages: 260-264

    • NAID

      110004729441

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Successive splitting of autowaves in a nonlinear chemical reaction medium2006

    • Author(s)
      Taiji Okano
    • Journal Title

      Phys. Rev. E74

      Pages: 661031-661036

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 化学振動子ネットワークのダイナミクスのフィードバック制御2007

    • Author(s)
      岡野 太治
    • Organizer
      日本物理学会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-09-24
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Delayed feedback control of dynamics in a chemical oscillator network2007

    • Author(s)
      Taiji Okano
    • Organizer
      The physical Society of Japan annual meeting
    • Place of Presentation
      Hokkaido Univ
    • Year and Date
      2007-09-24
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2006-04-01   Modified: 2016-04-21  

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