Synthesis and Photophysical Properties of Helical Molecules based on Metacyclophan-1-enes

• Project/Area Number: 18550039
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Saga University
• Principal Investigator: YAMATO Takehiko Saga University, 理工学部, 教授 (60136562)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥4,120,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥420,000); Fiscal Year 2008: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2007: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2006: ¥2,300,000 (Direct Cost: ¥2,300,000)
• Keywords: 架橋芳香族化合物 / シクロファン / ヘリセン / らせん型分子 / 光学分割 / 光化学的特性 / ホトクロミズム / 分子素子 / 構造特性 / 光化学 / 旋光度の光制御システム / 光駆動型分子認識素子 / 光応答性不斉触媒

Research Abstract

本研究では、架橋芳香族化合物に関する研究の一環として、その剛直なシクロファン骨格を利用して、系統的な研究が全くなされていないシクロファンを構成単位とするらせん状分子に着目し、これらの実用的な一般性の高い合成法を開発し、構造と物理的及び光化学的特性との相関関係を調べることを目的とするものである。本研究を遂行することにより、ラセミ化が全く起こらないらせん状分子の構築のみならず、従来のヘリセン研究における問題点を克服できたことは特筆すべき研究成果である。すなわち、現在まで報告例の少ない従来のヘリセン骨格を簡略化したo-ターフェニル骨格をもつシクロファン誘導体を構成単位とするらせん型分子の簡便な合成法を開発し、シクロファン骨格に基づく相互作用、光化学特性を解明することが本研究の特色である。さらに、一方の架橋鎖に二重結合を導入したベンゾ[2.2]メタシクロファン-1-エン型分子を合成し、原子価異性化による10b, 10c-ジヒドロピレン体への可逆的な相互変換に基づくホトクロミズム能のみならずヘリセン特有の旋光度の光制御システムを構築する。本研究成果を基に光駆動型分子認識素子、光応答性らせん状超分子ポリマー、光応答性不斉触媒の開発へと展開できる。

Research Products

• [Journal Article] Synthesis of polymethyl substituted[2.2]metaparacyclophanes and their Lewis-acid induced isomerisation to[2.2]metacyclophanes (2009)
  • Author(s): T. Shimizu, K. Hita, A. Paudel, J. Tanaka and T. Yamato
  • Journal Title: J. Chem. Research Pages: 246-249
• [Journal Article] The metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix[4]arenes with cone and 1, 3-alternate conformation (2009)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 1-4
  • Peer Reviewed
• [Journal Article] Medium-size cyclophanes, 81 Synthesis and conformational studies of 9-substituted [3.3]metacyclophane-2, 11-diones and conversion to the corr esponding [3.3]metacyclophanes (2009)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 60-64
  • Peer Reviewed
• [Journal Article] Synthesis, structure and inclusion properties of distal-bis[(5-(5'-methyl-2, 2'-bipyridyl)yl)methoxy]tetrathiacalix[4]arene with 1, 3-alternate conformation (2009)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 104-108
  • Peer Reviewed
• [Journal Article] Synthesis and spectral properties of 2, 7-di-tert-butyl-4, 9-bis(arylethynyl)- and 4, 10-bis(arylethynyl)pyrenes (2009)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 109-113
  • Peer Reviewed
• [Journal Article] Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1, 3-alternate conformation (2009)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Incl. Phenom. Macrocyclic Chem. 63 Pages: 301-308
  • Peer Reviewed
• [Journal Article] Medium-size cyclophanes, 81 Synthesis and conformational studies of 9-substituted [3.3]metacyclophane-2, 11-diones and conversion to the corresponding [3.3]metacyclophanes (2009)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 60-64
  • Peer Reviewed
• [Journal Article] Synthesis of polymethyl substituted [2.2]metaparacyclophanes and their Lewis-acid induced isomerisation to [2.2]metacyclophanes (2009)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 246-249
  • Peer Reviewed
• [Journal Article] Medium-size cyclophanes, 79 Synthesis and photoreaction of polymethyl substituted[2.2]metacyclophanes (2008)
  • Author(s): A. Paudel, T. Shimizu and T. Yamato
  • Journal Title: J. Chem. Research Pages: 649-652
• [Journal Article] Medium-size cyclophanes, 78 Synthesis and structures of [2.n]metacyclophan-1, 2-diones (2008)
  • Author(s): T. Saisyo, M. Shiino, T. Shimizu, A. Paudel and T. Yamato
  • Journal Title: J. Chem. Research Pages: 479-483
• [Journal Article] Allosteric bindings of thiacalix[4]arene-based receptors with 1, 3-alternate conformation having two different side arms (2008)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Incl. Phenom. Macrocyclic Chem. 60 Pages: 173-185
  • Peer Reviewed
• [Journal Article] Electrophilic aromatic substitution of 7-tert-butyl-1, 3-dimethylpyrene. A new route for the preparation of 5-mono- and 5, 9-disubstituted 7-tert-butyl-1, 3-dimethylpyrenes (2008)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 308-311
  • Peer Reviewed
• [Journal Article] Medium-size cyclophanes, 78 Synthesis and structures of [2. n]metacyclophan-1, 2-diones (2008)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 479-483
  • Peer Reviewed
• [Journal Article] Synthesis and structural properties of novel polycyclic aromatic compounds using photo-induced cyclization of 2, 7-di-tert-butyl-4-(phenylethenyl)pyrenes (2008)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 457-460
  • Peer Reviewed
• [Journal Article] Medium-size cyclophanes, 79 Synthesis and photoreaction of polymethyl substituted [2.2]metacyclophanes (2008)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 649-652
  • Peer Reviewed
• [Journal Article] Medium-sized cyclophanes. Part 80. Synthesis and conformational studies of 2, 11-dithia[3]metacyclo[3](1, 3)pyreno- phanes : the ring current in teractions derived from pyrene ring (2008)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research 無 Pages: 731-734
  • Peer Reviewed
• [Journal Article] Allosteric bindings of thiacalix[4]arene-based receptors with 1,3-alternate conformation having two different side arms (2008)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Incl.Phenom.Macrocyclic Chem. 60 Pages: 173-185
  • Peer Reviewed
• [Journal Article] Niobium-and Tantalum-Baed Ethylene Polymerisation Catalysts Bearing Methylene-or Dimethyleneoxa-Bridged Calixarene Ligands (2007)
  • Author(s): C. Redshaw, M. Rowan, D. M. Homeden, M. R. J. Elsegood, T. Yamato and C. Perez-Casas
  • Journal Title: Chem. Eur, J 13 Pages: 10129-10139
• [Journal Article] Medium-sized cyclophanes. Part 76.^1 Synthesis of syn-9-methoxy(1, 4)naphthaleno[3.3]metacyclophanes and their charge-transfer complexes with tetracyanoethylene in CH_2Cl_2 (2007)
  • Author(s): J. Hu, R. Ueno, M. Miyazaki and T. Yamato
  • Journal Title: J. Chem. Research Pages: 404-406
• [Journal Article] Medium-size cyclophanes, 75 Synthesis of anti-[2.3]metacyclophan-1-ene and conversion to syn-1, 2-epoxy[2.3]metacyclophane (2007)
  • Author(s): T. Saisyo, M. Shiino, T. Hironaka and T. Yamato
  • Journal Title: J. Chem. Research Pages: 141-143
• [Journal Article] Synthesis and structure of a 1,3-alternate-thiacalix[4]arene diamide derivative (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Incl.Phenom.Macrocyclic Chem. 58 Pages: 193-197
  • Peer Reviewed
• [Journal Article] Medium-size cyclophanes, 75 Synthesis of anti-[2.3]metacyclophan-1-ene and conversion to syn-1,2-epoxy[2.3]metacyclophane (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Chem.Research Pages: 141-143
  • Peer Reviewed
• [Journal Article] Synthesis and inclusion properties of a novel double thiacalix[4]arene having (N,N-diethylaminocarbonyl)methoxy group (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Incl.Phenom.Macrocyclic Chem. 58 Pages: 383-388
  • Peer Reviewed
• [Journal Article] Supramolecular assemblages from uranyl ion complexes of calixarences and potassium complexes of 18-crown-6 or dibenzo-18-crown-6 (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: Inorg.Chem.Commun. 10 Pages: 795-799
  • Peer Reviewed
• [Journal Article] Synthesis and complexation behaviour of tetrakis[(N,N-diethylamino-carbonyl)methoxy] tetrahomodioxacalix[4]arene (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Chem.Research Pages: 400-403
  • Peer Reviewed
• [Journal Article] Medium-sized cyclophanes.Part 76.^1 Synthesis of syn-9-methoxy(1,4)-naphthaleno[3,3]metacyclophanes and their charge-transfer complexes with tetracyanoethylene in CH_2Cl_2 (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Chem.Research Pages: 404-406
  • Peer Reviewed
• [Journal Article] Synthesis and inclusion properties of thiacalix[4]arene tetraamides in cone-and 1,3-alternate conformation (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Chem.Research Pages: 557-560
  • Peer Reviewed
• [Journal Article] Niobium- and Tantalum-Baed Ethylene Polymerisation Catalysts Bearing Methylene- or Dimethyleneoxa-Bridged Calixarene Ligands (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: Chen.Eur, J. 13 Pages: 10129-10139
  • Peer Reviewed
• [Journal Article] Medium-size cyclophones, 77 Synthesis and addition of bromine to syn-[2.n]metacyclophan-1-enes (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Chem.Research Pages: 621-625
  • Peer Reviewed
• [Journal Article] Perfluorinated sulfonic acid resin (Nafion-H) catalysed Ritter reaction of benzyl alcohols (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Chem.Research Pages: 641-643
  • Peer Reviewed
• [Journal Article] Synthesis and structural properties of novel calixarene analogues having Schiff base units (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J.Chem.Research Pages: 649-652
  • Peer Reviewed
• [Journal Article] Oxo-and Imidovanadium complexes incorporating Methylene- and Dimethylene- oxa-Bridged Calix[3]- and -[4]arenas : Synthesis, structures and Ethylene Polymerisation Catalysis (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: Chem. Eur. J. 13 Pages: 1090-1107
• [Journal Article] Synthesis and inclusion properties of 1,3-alternate-bis[(ethoxycarbonyl)methoxy]-thiacalix[4]arene-mono(crown-4) ether (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 73-75
• [Journal Article] Synthesis and structure of a 1,3-alternate-thiacalix[4]arene diamide derivative (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Incl. Phenom. (印刷中)
• [Journal Article] Synthesis and inclusion properties of a novel double thiacalix[4]arene having (N,N-diethylaminocarbonyl)methoxy group (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research (印刷中)
• [Journal Article] Medium-size cyclophanes, 751 Synthesis of anti-[2.3]metacyclophan-1-ene and conversion to syn-1,2-epoxy[2.3]metacyclophane (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Incl. Phenom. (印刷中)
• [Journal Article] Medium-size cyclophanes, 74 Synthesis of novel helically twisted anti-1,2-areno[2.n]metacyclophanes (2007)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research (印刷中)
• [Journal Article] Medium-size cyclophanes, 74 Synthesis of novel helically twisted anti-1, 2-areno[2.n]metacyclophanes (2006)
  • Author(s): Tatsunori Saisyo, Tohru Hironaka, Mikiko Shiino and Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 661-663
• [Journal Article] Medium-sized cyclophanes. 71. Synthesis, structures and photo-induced cyclization of 1, 2-diphenyl[2.n]metacyclophan-1-enes (2006)
  • Author(s): T. Yamato, T. Saisyo, T. Hironaka and S. Miyamoto
  • Journal Title: J. Chem. Research Pages: 558-560
• [Journal Article] Ditopic receptors of hexaamide derivatives derived from hexahomotrioxacalix-[3]arene triacetic acid (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: Can. J. Chem. 85 Pages: 58-64
• [Journal Article] Regioselective synthesis and inclusion properties of distal-disubstituted tetrathiacalix[4]arenes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Incl. Phenom. 54 Pages: 261-269
• [Journal Article] Synthesis and inclusion properties of a novel thiacalix[4]arene-based hard-soft receptor with 1,3-alternate conformation (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Incl. Phenom. 55 Pages: 231-236
• [Journal Article] Formation of Dimmeric Molecular Capsule For Supramolecular Applications (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: CHEMICAL ENGINEERING COMMUNICATIONS 193 Pages: 1185-1193
• [Journal Article] Medium-size cyclophanes, 68 Synthesis and bromination of 1,2-dimethyl[2.3]metacyclophan-1-enes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 110-114
• [Journal Article] Synthesis, structures and inclusion properties of distal-bis[(2-pyridylmethyl)-oxy]tetrathiacalix[4]arenes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 270-273
• [Journal Article] Preparation and Binding Properties of A Novel C3 Symmetrical Hexahomo-trithiacalix[3]arene (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 251-253
• [Journal Article] Medium-size cyclophanes, 69 Synthesis and ipso-nitration of 1,2-dimethyl-[2.10]metacyclophan-1-enes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 393-395
• [Journal Article] Synthesis and Inclusion Properties of O-Tris(benzyloxy)hexahomotrioxacalix-[3]arenes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 496-498
• [Journal Article] Medium-sized cyclophanes. Part 70. Direct introduction of bromo group to the bridged methylene of 5,13-di-tert-butyl-8,16-dimethyl[2.2]metacyclophane (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 493-495
• [Journal Article] Uranium(V) and uranium(IV/V) mixed valence complexes with p-tert-butylhomocalix[n]arenes (n=4,6) (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: Polyhedron 25 Pages: 2439-2446
• [Journal Article] Medium-sized cyclophanes. 71. Synthesis, structures and photo-induced cyclization of 1,2-diphenyl[2.n]metacyclophan-1-enes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 558-560
• [Journal Article] Medium-sized cyclophanes. Part 72. Synthesis and structures of 9-methoxy(1,4)- naphthaleno[3.3]metacyclophane-2,11-diones (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 593-595
• [Journal Article] Synthesis, structure and magnetic behaviour of dinuclear uranium(IV) complexes with a 'calixsalophen' type macrocycle (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: New. J. Chem. 30 Pages: 1220-1227
• [Journal Article] Medium-size cyclophanes, 74 Synthesis of novel helically twisted anti-1,2-areno[2.n]metacyclophanes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 661-663
• [Journal Article] Perfluorinated sulfonic acid resin (Nafion-H) catalysed trans-tert-butylation of 7-tert-butyl-1,3-disubstituted pyrenes, A new route for the prepartion of 1,3-disubstituted pyrenes (2006)
  • Author(s): Takehiko Yamato
  • Journal Title: J. Chem. Research Pages: 762-765
• [Presentation] Synthesis and structural properties of novel polycondensed aro matic compounds with double-helicene structure derived from 4, 9-bis(arylethenyl)pyrenes (2009)
  • Author(s): Takehiko Yamato
  • Organizer: The 3rd Joint Symposium of Saga University and Daegu University
  • Place of Presentation: 佐賀市
  • Year and Date: 2009-02-25
• [Presentation] イミダソリル基を有する金属イオン認識レセプターの合成と評価 (2009)
  • Author(s): 大和武彦
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 船橋市
• [Presentation] ポリメチル置換[2.2]シクロフアンの合成・構造及び反応性 (2009)
  • Author(s): 大和武彦
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 船橋市
• [Presentation] 4, 5, 9, 10-テトラキス(アリールエチニル)ピレン誘導体の選択的合成とスペクトル特性 (2009)
  • Author(s): 大和武彦
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 船橋市
• [Presentation] トリアソール基を有するホモオキサカリツクス[3]アレーンの合成・構造特性及び金属イオン認識評価 (2009)
  • Author(s): 大和武彦
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 船橋市
• [Presentation] ピリジルメチル基を有するチアカリツクス[4]アレーンの合成と金属イオン認識評価 (2009)
  • Author(s): 大和武彦
  • Organizer: 日本化学会第89回春季年会
  • Place of Presentation: 船橋市
• [Presentation] 高歪み三重結合を持つ[2.n]メタシクロファン-1-イン類の合成・構造及び反応性 (2008)
  • Author(s): 田中彰吾(M2)・内川裕生・大和武彦
  • Organizer: 第18回九州沖縄地区高専フォーラム
  • Place of Presentation: 久留米市
  • Year and Date: 2008-12-06
• [Presentation] 高歪み三重結合を持つ[2. n]メタシクロフアンー1-イン類の合成・構造及び反応性 (2008)
  • Author(s): 大和武彦
  • Organizer: 第18回九州沖縄地区高専フォーラム
  • Place of Presentation: 久留米市
  • Year and Date: 2008-12-06
• [Presentation] 高歪み三重結合を持つ[2.n]MCP-1-yne類の合成および縮合多環芳香族化合物への変換 (2008)
  • Author(s): 田中彰吾(M2)・加藤利佳・大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州
  • Year and Date: 2008-07-05
• [Presentation] ウレア部位を有するチアカリツクス[4]アレーン類の合成とアニオン認識能 (2008)
  • Author(s): 大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2008-07-05
• [Presentation] イミダソリル基を有するチアカリツクス[4]アレーン類の合成及び金属錯体形成 (2008)
  • Author(s): 大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2008-07-05
• [Presentation] tert-ブチル[3.3]メタシクロフアン類の合成とipso-求電子置換反応 (2008)
  • Author(s): 大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2008-07-05
• [Presentation] オキサカリツクス[3]アレーンを基体とするレセプター合成とアニオン認識 (2008)
  • Author(s): 大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2008-07-05
• [Presentation] ヘキサホモトリオキサカリツクス[3]アレーンを基体とするアンモニウムイオンレセプターの合成 (2008)
  • Author(s): 大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2008-07-05
• [Presentation] Photo-induced cyclisation of styrylpyrenes to afford naphthalene condensed aromatic compounds (2008)
  • Author(s): 大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2008-07-05
• [Presentation] カリックス[n]アレーンを基体とするダイトピックレセプターの合成 (2008)
  • Author(s): 大和 武彦
  • Organizer: 先導物質化学研究所箱崎地区セミナー2008
  • Place of Presentation: 九州大学
  • Year and Date: 2008-03-18
• [Presentation] Homooxaclix[3]arene derivatives as ionophores for molecular recognition of biogenic amines (2008)
  • Author(s): Takehiko Yamato
  • Organizer: The 1st Workshop on New Trends in Chemistry and Biology
  • Place of Presentation: 佐賀大学
  • Year and Date: 2008-01-23
• [Presentation] Synthesis, structures and inclusion properties of distal-bis[2-(1-methyl-1H-imidazolyl)methoxy]tetrathiacalix[4]arenes (2008)
  • Author(s): Takehiko Yamato
  • Organizer: The 1st Workshop on New Trends in Chemistry and Biology
  • Place of Presentation: 佐賀大学
  • Year and Date: 2008-01-23
• [Presentation] Synthesis of ditopic receptors based on hexahomotrioxacalix[3]arenes (2008)
  • Author(s): Takehiko Yamato
  • Organizer: The 1st Workshop on New Trends in Chemistry and Biology
  • Place of Presentation: 佐賀大学
  • Year and Date: 2008-01-23
• [Presentation] Photo-induced aromatic cyclization in pyrene framework (2008)
  • Author(s): Takehiko Yamato
  • Organizer: The 1st Workshop on New Trends in Chemistry and Biology
  • Place of Presentation: 佐賀大学
  • Year and Date: 2008-01-23
• [Presentation] [3.3]-および[3.3.3]メタシクロファンケトン類の合成・構造および反応性 (2008)
  • Author(s): 上野隆治(M2), 日田勝弘, 大和武彦
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 東京
• [Presentation] Synthesis and anion recognition properties of urea and thiourea based on thiacalix[4]arene derivatives (2008)
  • Author(s): 大和武彦
  • Organizer: The 2nd Joint Symposium of Daegu University and Saga University
  • Place of Presentation: 大邸大学(韓国)
• [Presentation] Synthesis and structural properties of novel polycondensed aro matic compounds with double-helicene structure derived from 4, 9-bis(arylethenyl)pyrenes (2008)
  • Author(s): Takehiko Yamato
  • Organizer: 第2回有機π電子系シンポジウム
  • Place of Presentation: 広島
• [Presentation] イミダソリル基を有する金属イオン認識レセプターの合成と評価 (2008)
  • Author(s): 大和武彦
  • Organizer: 第2回有機π電子系シンポジウム
  • Place of Presentation: 広島
• [Presentation] テトラホモカリックス[4]アレーン類の合成・構造特性及び金属錯体形成 (2008)
  • Author(s): 大和 武彦
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 東京
• [Presentation] ヘキサホモトリオキサカリックス[3]アレーンを基体とするアンモニウムイオンレセプターの合成 (2008)
  • Author(s): 大和 武彦
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 東京
• [Presentation] 0-イミダゾリル基を持つチアカリックス[4]アレーンの合成と包接挙動 (2008)
  • Author(s): 大和 武彦
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 東京
• [Presentation] チアカリックス[4]アレーンを基体とするアニオンレセプターの合成と包接挙動 (2008)
  • Author(s): 大和 武彦
  • Organizer: 日本化学会第88回春季年会
  • Place of Presentation: 東京
• [Presentation] tert-ブチル[3.3]メタシクロファン類の合成とipso-求電子置換反応 (2007)
  • Author(s): 日田勝弘(M1)・上野隆治・大和武彦
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 北九州
  • Year and Date: 2007-08-05
• [Presentation] [3n]メタシクロファン類の合成・構造及び反応性 (2007)
  • Author(s): 大和 武彦
  • Organizer: 第44回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2007-07-08
• [Presentation] テトラホモジオキサカリックス[4]アレーン類の合成・構造特性 (2007)
  • Author(s): 大和 武彦
  • Organizer: 第44回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2007-07-08
• [Presentation] ベンゾフラノシクロファン類の合成および構造特性 (2007)
  • Author(s): 大和 武彦
  • Organizer: 第44回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2007-07-08
• [Presentation] ヘキサホモトリオキサカリックス[3]アレーンを基体とするダイトピックレセプターの合成 (2007)
  • Author(s): 大和 武彦
  • Organizer: 第44回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2007-07-08
• [Presentation] ウレア部位を持つチアカリックス[4]アレーン誘導体の合成とアニオン認識 (2007)
  • Author(s): 大和 武彦
  • Organizer: 第44回化学関連支部合同九州大会
  • Place of Presentation: 北九州市
  • Year and Date: 2007-07-08
• [Presentation] Synthesis and anion recognitions of 1,3-alternate-tetrathiacalix[4]arene derivatives having urea moieties (2007)
  • Author(s): 大和 武彦
  • Organizer: 第17回 万有福岡シンポジウム
  • Place of Presentation: 福岡市
  • Year and Date: 2007-05-12
• [Presentation] 高歪み三重結合を持つ[2.n]メタシクロファン-1-イン類の合成および構造特性 (2007)
  • Author(s): 田中彰吾(M2), 加藤利佳, 大和武彦
  • Organizer: 第37回構造有機化学連合討論会
  • Place of Presentation: 北海道大学(札幌)
• [Presentation] 架橋型syn-[2.2]メタシクロファン-1, 9-ジエン類の合成・構造およびスペクトル特性 (2007)
  • Author(s): 加藤利佳(M2), 田中彰吾, 大和武彦
  • Organizer: 2007年日本化学会西日本大会
  • Place of Presentation: 岡山大学
• [Presentation] 高歪み三重結合を持つ[2.n]メタシクロファン-1-イン類の合成・構造および反応性 (2007)
  • Author(s): 田中彰吾(M1), 加藤利佳, 大和武彦
  • Organizer: 2007年日本化学会西日本大会
  • Place of Presentation: 岡山大学
• [Presentation] Synthesis and characterization of artificial allosteric receptors derived from calix[n]arenes (2007)
  • Author(s): Takehiko Yamato
  • Organizer: post ISNA-12 in Fukuoka
  • Place of Presentation: FUKUOKA
• [Presentation] 擬似キャップしたヘキサホモトリオキサカリックス[3]アレーンの包接挙動 (2007)
  • Author(s): 大和 武彦
  • Organizer: 2007年日本化学会西日本大会
  • Place of Presentation: 岡山大学
• [Presentation] ヘキサホモトリオキサカリックス[3]アレーンを基体とするダイトピックレセプターの合成 (2007)
  • Author(s): 大和 武彦
  • Organizer: 2007年日本化学会西日本大会
  • Place of Presentation: 岡山大学
• [Presentation] ウレア部位を持つ1,3-alternate-テトラチアカリックス[4]アレーン誘導体の合成とアニオン認識 (2007)
  • Author(s): 大和 武彦
  • Organizer: 2007年日本化学会西日本大会
  • Place of Presentation: 岡山大学
• [Presentation] 架橋型syn-[2.2]メタシクロファン-1,9-ジエン類の合成・構造およびスペクトル特性 (2007)
  • Author(s): 大和 武彦
  • Organizer: 2007年日本化学会西日本大会
  • Place of Presentation: 岡山大学
• [Presentation] Physical and chemical properties of small-sized cyclophanes and related compounds (2007)
  • Author(s): Takehiko Yamato
  • Organizer: The Third Taiwan-Japan Bilateral Symposium on Functional Molecules
  • Place of Presentation: 中正大学(嘉義市 台湾)
• [Presentation] カリックスサロフェン型大環状化合物の金属二核錯体の合成および構造特性 (2007)
  • Author(s): 大和 武彦
  • Organizer: 第1回有機π電子系シンポジウム
  • Place of Presentation: 東京
• [Presentation] ベンゾフラノシクロファン類の合成および構造特性 (2006)
  • Author(s): 田中彰吾(M1), 加藤利佳、弘中徹、大和武彦
  • Organizer: 第44回化学関連支部合同九州大会
  • Place of Presentation: 北九州
  • Year and Date: 2006-07-08
• [Presentation] シクロファンエン類を基体とするヘリセン型分子の合成・構造及びスペクトル特性 (2006)
  • Author(s): 弘中徹(D3)、加藤利佳、大和武彦
  • Organizer: 2006年日本化学会西日本大会
  • Place of Presentation: 那覇
• [Presentation] 三架橋シクロファン-1.9-ジエン類の合成・構造及びスペクトル特性 (2006)
  • Author(s): 加藤利佳(M1)、宮本慎平、大和武彦
  • Organizer: 第18回基礎有機化学連合討論会
  • Place of Presentation: 福岡
• [Presentation]
  • Author(s): Takehiko Yamato
  • Organizer: post ISNA-12 in Fukuoka
  • Place of Presentation: FUKUOKA
• [Presentation] Synthesis,structure and reactivity of novel calix[3]benzofurans
  • Author(s): Takehiko Yamato
  • Organizer: post ISNA-12 in Fukuoka
  • Place of Presentation: FUKUOKA
• [Presentation] Synthesis, structural properties and metal complexation of novel tetrahomodioxacalix[4]arenes
  • Author(s): Takehiko Yamato
  • Organizer: post ISNA-12 in Fukuoka
  • Place of Presentation: FUKUOKA
• [Patent(Industrial Property Rights)] 常温りん光発光有機化合物 (2007)
  • Inventor(s): 大和 武彦
  • Industrial Property Rights Holder: 佐賀大学
  • Filing Date: 2007-05-17