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Study on the correlation between the molecular structure and the reactivity of metalloporphyrins and related compounds

Research Project

Project/Area Number 18550052
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionAichi University of Education

Principal Investigator

INAMO Masahiko  Aichi University of Education, 教育学部, 教授 (20176407)

Co-Investigator(Kenkyū-buntansha) 高木 秀夫  名古屋大学, 物質科学国際研究センター, 准教授 (70242807)
Co-Investigator(Renkei-kenkyūsha) TAKAGID Hideo  名古屋大学, 物質科学国際研究センター, 准教授 (70242807)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥480,000)
Fiscal Year 2008: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2007: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2006: ¥1,300,000 (Direct Cost: ¥1,300,000)
Keywords金属ポルフィリン錯体 / 金属ポルフィセン錯体 / 電子移動反応 / 配位子置換反応 / 自己交換反応 / 光化学反応 / 構造の歪み
Research Abstract

本研究ではポルフィリンの分子構造が平面構造から歪んだ場合、その反応性にどのような影響が現れるか、また、ポルフィリンの構造異性体であるポルフィセンではどのように反応性が異なるかを研究した。各種分光法を駆使して、電子移動反応、光化学反応、配位子置換反応などのダイナミックスを調べ、分子構造の摂動がそれぞれの反応性に及ぼす影響を明らかにし、その機構を分子構造や電子状態の観点から考察した。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (19 results)

All 2009 2008 2007 2006

All Journal Article (15 results) (of which Peer Reviewed: 13 results) Presentation (4 results)

  • [Journal Article] Electron transfer reaction of porphyrin and porphycene complexes of Cu(II)and Zn(II)in acetonitrile2009

    • Author(s)
      Kaori Aoki, Toshimitsu Goshima, Yohei Kozuka, Yukiko Kawamori, Noboru Ono, Yoshio Hisaeda, Hideo D. Takagi and Masahiko Inamo
    • Journal Title

      Dalton Trans

      Pages: 119-125

    • NAID

      120002126688

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electron transfer reaction of porphyrin and porphycene complexes of Cu(II) and Zn(II) in acetonitrile2009

    • Author(s)
      Kaori Aoki
    • Journal Title

      Dalton Transactions

      Pages: 119-125

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic Evidence for High Reactivity of 3-Nitrophenylboronic Acid Compared to Its Conjugate Boronate Ion in Reactions with Ethylene and Propylene Glycols2008

    • Author(s)
      Chiaki Miyamoto, Kazunori Suzuki, Satoshi Iwatsuki, Masahiko Inamo, Hideo D. Takagi, and Koji Ishihara
    • Journal Title

      Inorg. Chem 47

      Pages: 1417-1419

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optimization of conditions for the determination of boron by a ruthenium(II)complex having diol moiety : A mechanistic study2008

    • Author(s)
      Eiko Nakano, Satoshi Iwatsuki, Masahiko Inamo, Hideo D. Takagi, and Koji Ishihara
    • Journal Title

      Talanta 74

      Pages: 533-538

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Optimization of conditions for the determination of boron by a ruthenium(II) complex having diol moiety : A mechanistic study2008

    • Author(s)
      Eiko Nakano
    • Journal Title

      Talanta 74

      Pages: 533-538

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic Evidence for High Reactivity of 3-Nitrophenylboronic Acid Compared to Its Conjugate Boionate Ion in Reactions with Ethylene and Propylene Glycols2008

    • Author(s)
      Chiaki Miyamoto
    • Journal Title

      Inorganic Chemistry 47

      Pages: 1417-1419

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Femtosecond Time-Resolved Photoabsorption Studies on the Excitation Dynamics of Chromium(III)Porphyrin Complexes in Solution2007

    • Author(s)
      Masahiko Inamo, Chie Okabe, Takakazu Nakabayashi, Nobuyuki Nishi, Mikio Hoshino
    • Journal Title

      Chem. Phys. Lett 445

      Pages: 167-172

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic studies on the reversible ring opening-closure reaction of the triazine ligand and structural properties of palladium(II)complexes2007

    • Author(s)
      Meishan Zhang, Masahiko Inamo, Masaaki Kojima and Kiyohiko Nakajima
    • Journal Title

      Inorg. Chim. Acta 360

      Pages: 3040-3046

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Which Is Reactive in Alkaline Solution, Boronate Ion or Boronic Acid? Kinetic Evidence for Reactive Trigonal Boronic Acid in an Alkaline Solution2007

    • Author(s)
      Satoshi Iwatsuki, Shihoko Nakajima, Masahiko Inamo, Hideo D. Takagi, and Koji Ishihara
    • Journal Title

      Inorg. Chem 46

      Pages: 354-356

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Femtosecond Time-Resoleved Photo-absorption Stedies on the Excitation Dynamics of Chromium(III) Porphyrin Complexes in Solution2007

    • Author(s)
      Masahiko Inamo
    • Journal Title

      Chem.Phys.Lett 445

      Pages: 167-172

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic studies on the recersible ring opening-closure reaction of the triazine ligand and structural properties of palladium(II) complexes2007

    • Author(s)
      Meishan Zhang
    • Journal Title

      Inorg.Chim.Acta 360

      Pages: 3040-3046

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Which Is Reactive in Alkaline Solution, Boronate Ion or Boronic Acid? Kinetic Evidence for Reactive Trigonal Boronic Acid in an Alkaline Solution2007

    • Author(s)
      S.Iwatsuki
    • Journal Title

      Inorganic Chemistry 46

      Pages: 354-356

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Kinetic Study of Thermal Z to E Isomerization Reactions of Azobenzene and 4-Dimethylamino-4'-nitroazobenzene in Ionic Liquids, 1-R-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide(R=butyl, pentyl, and hexyl)2006

    • Author(s)
      K. Baba, H. Ono, E. Itoh, S. Itoh, K. Noda, T. Usui, K. Ishihara, M. Inamo, H. D. Takagi, and T. Asano
    • Journal Title

      Chem. Euro. J 12

      Pages: 5328-5333

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Redox Reactions of[VO(salen)]+/0 Couple in Acetonitrile : Volume Analyses in Relation to Large Chiral Recognitions Observed for Electron Self-Exchnage Reactions of[VO(Schiff-Base)]^<+/0>2006

    • Author(s)
      Yasuhide Sasajima, Motoharu Shimizu, Norie Kuroyanagi, Nobuyuki Kishikawa, Kyoko Noda, Sumitaka Itoh, Hideo D. Takagi, and Masahiko Inamo
    • Journal Title

      Chim. Acta 359

      Pages: 346-354

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic Study of Thermal Z to E Isomerization Reactions of Azobenzene and 4-Dimethylamino-4-nitroazobenzene in Ionic Liquids, 1-R-3-methyl-imidazolium Bis(trifluoromethylsulfonyl)imide (R=butyl, pentyl, and hexyl)2006

    • Author(s)
      K.Baba
    • Journal Title

      Chemistry-A European Journal 12

      Pages: 5328-5333

    • Related Report
      2006 Annual Research Report
  • [Presentation] ひずんだ構造を持つポルフィリン錯体の配位子置換反応2008

    • Author(s)
      稲毛正彦
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] クロムポルフィリン錯体の光化学反応2007

    • Author(s)
      稲毛正彦
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] ポルフィリンおよびポルフィセン錯体の電子移動反応と構造の相関2007

    • Author(s)
      稲毛正彦
    • Organizer
      第57回錯体化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2008 Final Research Report
  • [Presentation] ポルフィリンおよびポルフィセン錯体の電子移動反応2006

    • Author(s)
      稲毛正彦
    • Organizer
      第56回錯体化学討論会
    • Place of Presentation
      広島大学
    • Related Report
      2008 Final Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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