Synthesis of Novel Functionalized Polyoxometalates Utilizing Chemical Reaction Fields of the Lacunary Species

• Project/Area Number: 18550062
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Kanagawa University
• Principal Investigator: NOMIYA Kenji Kanagawa University, 理学部, 教授 (80119354)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥4,310,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥510,000); Fiscal Year 2008: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2007: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2006: ¥2,100,000 (Direct Cost: ¥2,100,000)
• Keywords: 酸化物クラスター / ポリ酸塩 / ポリオキソメタレート / 触媒設計 / チタン / ジルコニウム / ハフニウム / 無機-有機ハイブリッド化合物 / シランカップリング剤 / 無機-有機ハイブリッド型ポリ酸塩 / シロキサン結合 / ポリ酸塩オリゴマー / チタン(IV) / ジルコニウム(IV) / ハフニウム(IV) / 欠損型ポリ酸塩 / オルガノシリル基 / Dawson型 / 固定化 / 末端オレフィン / チタン置換体 / 固体プロトン酸 / 巨大分子 / 酸化触媒作用 / Keggin型

Research Abstract

分子性の金属酸化物クラスターであるポリ酸塩(polyoxometalate)の欠損種を用い、表面塩基性度が比較的高い欠損部位を新しい化学反応空間として利用して、これまでに知られていなかった構成美および触媒機能を有するポリ酸塩の合成を行った。とくにエネルギー環境問題対応の触媒に利用できる第4属元素(チタン、ジルコニウム、ハフニウム)含有ポリ酸塩やポリ酸塩触媒の固定化に利用できる無機-有機ハイブリッド型ポリ酸塩などを合成した。

Research Products

• [Journal Article] Sandwich-type hafnium(IV) and zirconium(IV) complexes composed of tri-lacunary Keggin polyoxometalates : Synthesis and structure of[M_3(μ-OH)_3(A-α-PW_9O_<34>)_2]^<9->(M = Hf and Zr) (2009)
  • Author(s): Y. Saku, Y. Sakai, A. Shinohara, K. Hayashi, S. Yoshida, C. N. Kato, K. Yoza and K. Nomiya
  • Journal Title: Dalton Trans. Pages: 805-813
  • Peer Reviewed
• [Journal Article] Sandwich-type hafnium(IV) and zirconium(IV) complexes composed of tri-lacunary Keggin polyoxometalates : Synthesis and structure of [M_3(μ-OH)_3(A-α-PW_9O_<34>)_2]^<9->(M=Hf and Zr) (2009)
  • Author(s): Y. Saku, Y. Sakai, A. Shinohara, K. Hayashi, S. Yoshida, C. N. Kato, K. Yoza, K. Nomiya
  • Journal Title: Dalton Trans. Pages: 805-813
  • Peer Reviewed
• [Journal Article] Syntheses, molecular structures and pH-dependent monomer-dimer equilibrium of Dawson α2-mono-titanium(IV)-substituted polyoxometalates (2008)
  • Author(s): S. Yoshida, H. Murakami, Y. Sakai and K. Nomiya
  • Journal Title: Dalton Trans. Pages: 4630-4638
  • Peer Reviewed
• [Journal Article] A Dawson-Type Dirhenium(V)-Oxido-Bridged Polyoxotungstate : X-ray Crystal Structure and Hydrogen Evolution from Water Vapor under Visible Light Irradiation (2008)
  • Author(s): C. N. Kato, K. Hara, A. Hatano, K. Goto, T. Kuribayashi, K. Hayashi, A. Shinohara, Y. Kataoka, W. Mori and K. Nomiya
  • Journal Title: Eur.J.Inorg. Chem. Pages: 3134-3141
  • Peer Reviewed
• [Journal Article] Formation of inorganic protonic-acid polymer via inorganic-organic hybridization. Synthesis and characterization of polymerizable olefinic organosilyl derivatives of mono-lacunary Dawson polyoxometalate (2008)
  • Author(s): T. Hasegawa, H. Murakami, K. Shimizu, Y. Kasahara, S. Yoshida, T. Kurashina, H. Seki and K. Nomiya
  • Journal Title: Inorg. Chim. Acta 361 Pages: 1385-1394
  • Peer Reviewed
• [Journal Article] Formation of inorganic protonic-acid polymer via inorganic-organic hybridization. Synthesis and characterization of polymerizable olefinic organosilyl derivatives of mono-lacunary Dawson polyoxometalate (2008)
  • Author(s): T. Hasegawa, H. Murakami, K. Shimizu, Y. Kasahara, S. Yoshida, T. Kurashina, H. Seki, K. Nomiya
  • Journal Title: Inorg. Chim, Acta 361 Pages: 1385-1394
  • Peer Reviewed
• [Journal Article] A Dawson-Type Dirhenium(V)-Oxido-Bridged Polyoxotungstate : X-ray Crystal Structure and Hydrogen Evolution from Water Vapor under Visible Light Irradiation (2008)
  • Author(s): C. N. Kato, K. Hara, A. Hatano, K. Goto, T. Kuribayashi, K. Hayashi, A. Shinohara, Y. Kataoka, W. Mori, K. Nomiya
  • Journal Title: Eur. J. Inorg. Chem. Pages: 3134-3141
  • Peer Reviewed
• [Journal Article] Syntheses, molecular structures and pH-dependent monomer-dimer equilibrium of Dawsonα_2-mono-titanium(IV)-substituted polyoxometalates (2008)
  • Author(s): S. Yoshida, H. Murakami, Y. Sakai, K. Nomiya
  • Journal Title: Dalton Trans. Pages: 4630-4638
  • Peer Reviewed
• [Journal Article] Organic-inorganic hybrid material as zwitterion. Synthesis and structure of terminal ammonium ions-containing organosilyl species supported on mono-lacunary Dawson polyoxometalate (2007)
  • Author(s): T. Hasegawa, Y. Kasahara, S. Yoshida, T. Kurashina, S. Aoki, K. Yoza and K. Nomiya
  • Journal Title: Inorg. Chem. Commun. 10 Pages: 1416-1419
  • Peer Reviewed
• [Journal Article] Novel Solid-State 8H^+- Heteropolyacid. Synthesis and Molecular Structure of a Free-Acid Form of a Dawson-Type Sandwich Complex, [Ti_2{P_2W_<15>O_<54>(OH_2)_2}_2]^<8-> (2007)
  • Author(s): H. Murakami, K. Hayashi, I. Tsukada, T. Hasegawa, S. Yoshida, R. Miyano, C. N. Kato and K. Nomiya
  • Journal Title: Bull. Chem. Soc. Jpn. 80 Pages: 2161-2169
  • NAID: 10019795164
  • Peer Reviewed
• [Journal Article] Tetrameric, Tri-Titanium(IV)-Substituted Polyoxometalates with an α-Dawson Substructure as Soluble Metal Oxide Analogues : Synthesis and Molecular Structure of Three Giant "Tetrapods" Encapsulating Different Anions (Br^-, I^- and NO_3^-) (2007)
  • Author(s): Y. Sakai, S. Yoshida, T. Hasegawa, H. Murakami, and K. Nomiya
  • Journal Title: Bull. Chem. Soc. Jpn. 80 Pages: 1965-1974
  • NAID: 10019825090
  • Peer Reviewed
• [Journal Article] Synthesis, isolation and spectroscopic characterization of Dawson polyoxotungstate-supported,organometallic complex [{(C_6H_6)Ru}P_2W_<15> V_3O_<62>]_7- : the two positional isomers (2007)
  • Author(s): K. Nomiya, Y. Kasahara, Y. Sado and A. Shinohara
  • Journal Title: Inorg. Chim. Acta. 360 Pages: 2313-2320
  • Peer Reviewed
• [Journal Article] Polymerizable inorganic-organic hybrid : Syntheses and structures of mono-lacunary Dawson polyoxometalate-based olefin-containing organosilyl derivatives (2007)
  • Author(s): T. Hasegawa, K. Shimizu, H. Seki, H. Murakami, S. Yoshida, K. Yoza and K. Nomiya
  • Journal Title: Inorg. Chem. Commun. 10 Pages: 1140-1144
  • Peer Reviewed
• [Journal Article] Organometallic Complexes Supported on a Metal-oxide Cluster. pH-Dependent Interconversion between the Monomeric and Dimeric Species of the Polyoxoanion-supported [(arene)Ru]^<2+> Complex (2007)
  • Author(s): K. Nomiya, K. Hayashi, Y. Kasahara, T. Iida, Y. Nagaoka, H. Yamamoto, T. Ueno and Y. Sakai
  • Journal Title: Bull. Chem. Soc. Jpn. 80 Pages: 724-731
  • NAID: 10019938000
  • Peer Reviewed
• [Journal Article] Scanning tunneling microscopy (STM) and tunneling spectroscopy (TS) studies of polyoxometalates (POMs) of the Wells-Dawson structural class (2007)
  • Author(s): K. Song, M. S. Kaba, K. Nomiya, R. G. Finke and M. A. Barteau
  • Journal Title: J.Mol. Catal. A.Chemical 262 Pages: 216-226
  • Peer Reviewed
• [Journal Article] Isolation, characterization, and reactivity of the reaction products of the dimeric, Ti-O-Ti bridged anhydride form of the 1, 2-di-titanium(IV)-substituted α-Keggin polyoxometalate with aqueous 30% H_2O_2 (2007)
  • Author(s): K. Hayashi, C. N. Kato, A. Shinohara, Y. Sakai and K. Nomiya
  • Journal Title: J.Mol. Catal. A.Chemical 262 Pages: 30-35
  • Peer Reviewed
• [Journal Article] A novel Ti-O-Ti bonding species constructed in a metal-oxide cluster [{Ti(OH_2)(ox)}_2(μ-O)(α-PW_<11>O_<39>)]^<5-> as a precatalyst : Epoxidation of alkenes with hydrogen peroxide (2007)
  • Author(s): C.N. Kato, K. Hayashi, S. Negishi and K. Nomiya
  • Journal Title: J.Mol. Catal. A.Chemical 262 Pages: 25-29
  • Peer Reviewed
• [Journal Article] Polymerizable inorganic-organic hybrid: Syntheses and structures of mono-lacunary Dawson polyoxometalate-based olefin-containing organosilyl derivatives (2007)
  • Author(s): T. Hasegawa, K. Shimizu, H. Seki, H. Murakami, S. Yoshida, K. Yoza and K. Nomiya
  • Journal Title: Inorg. Chem. Commun 10 Pages: 1140-1144
  • Peer Reviewed
• [Journal Article] Novel Solid-State 8H^+-Heteropolyacid. Synthesis and Molecular Structure of a Free-Acid Form of a Dawson-Type Sandwich Complex, [Ti_2{P_2W_<15>O_<54>(OH_2)_2}_2]^<8-> (2007)
  • Author(s): H. Murakami, K. Hayashi, I. Tsukada, T. Hasegawa, S. Yoshida, R. Miyano, C. N. Kato and K. Nomiya
  • Journal Title: Bull. Chem. Soc. Jpn. 80 Pages: 2161-2169
  • NAID: 10019795164
  • Peer Reviewed
• [Journal Article] Tetrameric, Tri-Titanium(IV)-Substituted Polyoxometalates with an □-Dawson Substructure as Soluble Metal Oxide Analogues: Synthesis and Molecular Structure of Three Giant "Tetrapods" Encapsulating Different Anions(Br^-,I^-and NO_3^-) (2007)
  • Author(s): Y. Sakai, S. Yoshida, T. Hasegawa, H. Murakami and K. Nomiya
  • Journal Title: Bull. Chem. Soc. Jpn. 80 Pages: 1965-1974
  • Peer Reviewed
• [Journal Article] Synthesis, isolation and spectroscopic characterization of Dawson polyoxotungstate-supported, organometallic complex[{(C_6H_6)Ru}P_2W_<15>V_3O_<62>]_<7->: the two positional isomers (2007)
  • Author(s): K. Nomiya, Y. Kasahara, Y. Sado and A. Shinohara
  • Journal Title: Inorg. Chim. Acta 360 Pages: 2313-2320
  • Peer Reviewed
• [Journal Article] Organometallic Complexes Supported on a Metal-oxide Cluster. pH-Dependent Interconversi on between the Monomeric and Dimeric Species of the Polyoxoanion-supported[(arene)Ru]^<2+> Complex (2007)
  • Author(s): K. Nomiya, K. Hayashi, Y. Kasahara, T. Iida, Y. Nagaoka, H. Yamamoto, T. Ueno and Y. Sakai
  • Journal Title: Bull. Chem. Soc. Jpn 80 Pages: 724-731
  • Peer Reviewed
• [Journal Article] A novel Ti-O-Ti bonding species constructed in a metal-oxide cluster as a precatalyst : Epoxidation of alkenes with hydrogen peroxide (2007)
  • Author(s): C.N.Kato, K.Hayashi, S.Negishi, K.Nomiya
  • Journal Title: J. Mol. Catal. A. Chemical 262 Pages: 25-29
• [Journal Article] Isolation, characterization, and reactivity of the reaction products of the dimeric. Ti-O-Ti bridged anhydride from of the 1, 2-di-titanium(IV)-substituted α-Keggin polyoxometalate with aqueous 30% H_2O_2 (2007)
  • Author(s): K.Hayashi, C.N.Kato, A.Shinohara, Y.Sakai, K.Nomiya
  • Journal Title: J. Mol. Catal. A. Chemical 262 Pages: 30-35
• [Journal Article] Syntheses, Characterization, and X-Ray Crystal Structures of Mono-lacunary Dawson Polyoxometalate- based, Organosilyl Complexes (2006)
  • Author(s): C.N. Kato, Y. Kasahara, K. Hayashi, A. Yamaguchi, T. Hasegawa, and K. Nomiya
  • Journal Title: Eur. J.Inorg. Chem. Pages: 4834-4842
  • Peer Reviewed
• [Journal Article] Syntheses and X-Ray Crystal Structures of Zirconium(IV) and Hafnium(IV) Complexes Containing Monovacant Wells-Dawson and Keggin Polyoxotungstates (2006)
  • Author(s): C. N. Kato, A. Shinohara, K. Hayashi and K. Nomiya
  • Journal Title: Inorg. Chem. 45 Pages: 8108-8119
  • Peer Reviewed
• [Journal Article] Novel Ti-O-Ti Bonding Species Constructed in a Metal-Oxide Cluster. Reaction Products of Bis(oxalato)oxotitanate(IV) with the Dimeric, 1,2-Di-Titanium(IV)-Substituted Keggin Polyoxotungstate (2006)
  • Author(s): K. Hayashi, H. Murakami and K. Nomiya
  • Journal Title: Inorg. Chem. 45 Pages: 8078-8085
  • Peer Reviewed
• [Journal Article] Water-soluble organometallic ruthenium(II) complexes supported on Dawson-type polyoxotungstates as precatalysts: Selective oxidation of alcohols with 1 atm molecular oxygen (2006)
  • Author(s): C. N. Kato, A. Shinohara, N. Moriya and K. Nomiya
  • Journal Title: Catal. Commun. 7 Pages: 413-416
  • Peer Reviewed
• [Journal Article] Water-soluble organometallic ruthenium(II) complexes supported on Dawson-type polyoxotungstates as precatalysts : Selective oxidation of alcohols with 1 atm molecular oxygen (2006)
  • Author(s): C.N.Kato, A.Shinohara, N.Moriya, K.Nomiya
  • Journal Title: Catal. Commun. 7 Pages: 413-416
• [Journal Article] Novel Ti-O-Ti Bonding Species Constructed in a Metal-Oxide Cluster. Reaction Products of Bis(oxalato)oxotitanate(IV) with theDimeric, 1,2-Di-Titanium(IV)-Substituted Keggin Polyoxotungstate (2006)
  • Author(s): K.Hayashi, H.Murakami, K.Nomiya
  • Journal Title: Inorg. Chem. 45 Pages: 8078-8085
• [Journal Article] Syntheses and X-Ray Crystal Structures of Zirconium(IV) and Hafnium(IV) Complexes Containing Monovacant Wells-Dawson and Keggin Polyoxotungstates (2006)
  • Author(s): C.N.Kato, A.Shinohara, K.Hayashi, K.Nomiya
  • Journal Title: Inorg. Chem. 45 Pages: 8108-8119
• [Journal Article] Syntheses, Characterization, and X-Ray Crystal Structures of Mono-lacunary Dawson Polyoxometalate-based, Organosilyl Complexes (2006)
  • Author(s): C.N.Kato, Y.Kasahara, K.Hayashi, A.Yamaguchi, T.Hasegawa, K.Nomiya
  • Journal Title: Eur. J. Inorg. Chem. Pages: 4834-4842
• [Presentation] アンモニウムイオンが中心空間にカプセル化されたテトラポッド型チタン(IV)三置換Dawson型ポリ酸塩の合成とカプセル化イオンの交換性 (2009)
  • Author(s): 野宮健司、太田秀司、坂井善隆、新豊幸広、吉田祥子
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部
  • Year and Date: 2009-03-28
• [Presentation] 末端にチオール基を含むシランカップリング剤によるKeggin型三欠損種上のシロキサン結合種の構築と分子構造 (2009)
  • Author(s): 野宮健司、青木正太郎、倉科隆之、關栄昭
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部
  • Year and Date: 2009-03-28
• [Presentation] ジルコニウム(IV)/ハフニウム(IV)4核クラスターカチオンをサンドイッチしたKeggin型ポリ酸塩-1, 4-二欠損種の合成と分子構造 (2009)
  • Author(s): 野宮健司, 坂井善隆, 関谷博美
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] Keggin型ポリ酸塩一欠損種でサンドイッチされた2核ジルコニウム(IV)及び2核ハフニウム(IV)錯体の合成、分子構造とエポキシ化触媒活性 (2009)
  • Author(s): 野宮健司, 石丸恵, 高橋 亘, 関谷博美, 山田新吾, 佐久 惟, 篠原 旭, 坂井善隆
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] Keggin型チタン(IV)三置換ポリ酸塩二量体から誘導される二種類の新規チタン(IV)含有ポリ酸塩の合成及び分子構造 (2009)
  • Author(s): 野宮健司, 毛利有貴, 坂井善隆
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] 金(I)四核クラスターカチオンとKeggin型ポリ酸塩から成るクラスター間化合物の形成と構造 (2009)
  • Author(s): 野宮健司, 吉田拓也, 坂井善隆, 南波麻里沙, 鶴田慎一朗
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] シロキサン結合を介した酸化物クラスターの環状オリゴマー。Dawson型ポリオキソメタレート-欠損種とテトラェトキシシラン及びテトラクロロシランとの反応生成物 (2009)
  • Author(s): 野宮健司, 倉科隆之, 青木正太郎, 与座健治
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] 無機-有機ハイブリッド型化合物。アリルシリル基を含有するDawson型ポリ酸塩一欠損種の合成と構造 (2009)
  • Author(s): 野宮健司, 關 栄昭, 長谷川 剛, 坂井善隆, 倉科隆之, 清水香織, 吉田祥子, 青木正太郎, 与座健治
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] 末端にチオール基を含むシランカップリング剤によるKeggin型三欠損種上のシロキサン結合種の構築と分子構造 (2009)
  • Author(s): 野宮健司, 青木正太郎, 倉科隆之, 關 栄昭
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] アンモニウムイオンが中心空間にカプセル化されたテトラポッド型チタン(IV)三置換Dawson型ポリ酸塩の合成とカプセル化イオンの交換性 (2009)
  • Author(s): 野宮健司, 太田秀司, 坂井善隆, 新豊幸広, 吉田祥子
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日大理工学部船橋キャンパス
  • Year and Date: 2009-03-28
• [Presentation] Ge-O-Ge結合を含むKeggin型ポリ酸塩ゲルマニウム四置換体の合成と分子構造 (2008)
  • Author(s): 倉科隆之, 野宮健司
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大角間キャンパス
  • Year and Date: 2008-09-21
• [Presentation] ジルコニウム(IV)含有Dawson型ポリ酸塩1:2型および2:2型錯体の反応性 (2008)
  • Author(s): 佐久 惟, 野宮健司
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大角間キャンパス
  • Year and Date: 2008-09-21
• [Presentation] 末端にチオール基を含むオルガノシリル基担持Keggin型ポリ酸塩の合成とキャラクタリゼーション (2008)
  • Author(s): 青木正太郎, 笠原友樹, 野宮健司
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大角間キャンパス
  • Year and Date: 2008-09-21
• [Presentation] ジルコニウム(IV)/ハフニウム(IV)4核クラスターカチオンをsandwichしたKeggin型ポリ酸塩二欠損種の合成と分子構造 (2008)
  • Author(s): 坂井善隆, 野宮健司
  • Organizer: 第58回錯体化学討論会
  • Place of Presentation: 金沢大角間キャンパス
  • Year and Date: 2008-09-20
• [Presentation] Formation of Inorganic Prptonic-acid Polymer via Inorganic-organic Hybridization (2008)
  • Author(s): T. Hasegawa, K. Nomiya
  • Organizer: Macro 2008
  • Place of Presentation: Taipei, Taiwan .
  • Year and Date: 2008-07-01
• [Presentation] α_1-及びα_2-ゲルマニウム(IV)一置換Dawson型タングストポリ酸塩の合成と分子構造 (2008)
  • Author(s): 野宮健司、倉科隆之、平澤竜太、与座健治
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] 2種類のアンモニウム基を末端に含むオルガノシリル基が担持された新Dawson型タングストポリ酸塩の合成と分子構造 (2008)
  • Author(s): 野宮健司、青木正太郎、長谷川 剛、笠原友樹、吉田祥子、倉科隆之、与座健治
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] Keggin型チタン(IV)三置換ポリ酸塩二量体からチタン(IV)四置換ポリ酸塩二量体の合成及び分子構造 (2008)
  • Author(s): 野宮健司、小林義孝、吉田祥子
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] チタン(IV)一置換Dawson型タングストポリ酸塩二量体の合成と分子構造 (2008)
  • Author(s): 野宮健司、吉田祥子、村上英幸
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] カチオン種をカプセル化したテトラポッド型チタン(IV)三置換Dawson型ポリ酸塩の合成と分子構造 (2008)
  • Author(s): 野宮健司、坂井善隆、新豊幸広、吉田祥子
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] ジルコニウム(IV)/ハフニウム(IV)含有 Dawson 型ポリオキソメタレート2:2型錯体の合成と分子構造 (2008)
  • Author(s): 佐久 惟、与座健治、野宮健司
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] ハフニウム(IV)含有 Keggin 型ポリオキソメタレートの1:2型および2:2型錯体の合成、分子構造と酸化触媒活性 (2008)
  • Author(s): 野宮健司、山田新吾、篠原 旭、坂井善隆、石丸 恵、佐久 惟
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] Keggin 飽和型ポリ酸塩を用いたチタン、ジルコニウム、ハフニウム一置換体ポリ酸塩の合成及び性質 (2008)
  • Author(s): 石丸 恵、山田新吾、野宮健司
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-28
• [Presentation] ハフニウム(IV)を含む種々のポリオキソメタレートの合成と分子構造 (2007)
  • Author(s): 野宮健司、佐久 惟、篠原 旭、吉田祥子、加藤知香、与座健治
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋工大
  • Year and Date: 2007-09-26
• [Presentation] 末端にオレフィンを含むオルガノシリル基を担持したDawson型ポリ酸塩の合成と分子構造 (2007)
  • Author(s): 野宮健司、關 栄昭、長谷川剛、村上英幸、清水香織、吉田祥子、与座健治
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋工大
  • Year and Date: 2007-09-26
• [Presentation] Electrocatalytic Properties of Pt/Heteropoly Acids for the Oxygen Reduction Reaction in PEM Fuel Cells (2007)
  • Author(s): H. Okura, M. Kumagai, Y. Okumura, M. Shibata, K. Eguchi, H. Murakamai, Y. Kasahara, S. Yoshida and K. Nomiya
  • Organizer: 211th ECS Meeting
  • Place of Presentation: Chicago, USA
• [Remarks]
  • URL: http://www.chem.kanagawa-u.ac.jp/detail/id34.html
• [Remarks]
  • URL: http://www.chem.kanagawa-u.ac.jp/detail/id34.html
• [Patent(Industrial Property Rights)] 可逆性記録媒体 (2006)
  • Inventor(s): 野宮健司、長谷川剛、栗嶋進
  • Industrial Property Rights Holder: 野宮健司、長谷川剛、栗嶋進
  • Industrial Property Number: 2006-180701
  • Filing Date: 2006-06-30