Catenation of transition metal chalcogenide complexes
Project/Area Number |
18550063
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | Okayama University of Science |
Principal Investigator |
AKASHI Haruo Okayama University of Science, 自然科学研究所, 教授 (30221708)
|
Project Period (FY) |
2006 – 2008
|
Project Status |
Completed (Fiscal Year 2008)
|
Budget Amount *help |
¥4,200,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥600,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2006: ¥1,600,000 (Direct Cost: ¥1,600,000)
|
Keywords | 金属錯体化学 / 配位高分子 / 金属有機系構造体 / ポリピラゾリル配位子 / 硫黄架橋 / モリブデン錯体 / 触媒 / チアカリックスアレーン |
Research Abstract |
複数の金属原子がカルコゲン原子で架橋されてできている金属錯体を基本単位として、これらを鎖状につなぎ合わせることにより、基本単位となる錯体の構造を維持しつつ、より複雑な構造をもった遷移金属カルコゲニドクラスター錯体を合成する方法を開発する研究を行った。
|
Report
(4 results)
Research Products
(38 results)
-
[Journal Article] Bis[hexaaquacobalt(II)]25,26,27,28-tetrahydroxy-2,8,14,19-tetrathiacalix[4] arene-5,11,17,23-tetrasulfonate monohydrate2008
Author(s)
H. Akashi, M. Ichikawa
-
Journal Title
Acta Crystallographica, Section E E64(6)
Related Report
Peer Reviewed
-
[Journal Article] Synthesis, Structures, and Magnetic Properties of Face-Sharing Heterodinuclear Ni(II)-Ln(III) (Ln= Eu, Gd, Tb, Dy) Complexes2008
Author(s)
T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
-
Journal Title
Inorganic Chemistry 47(13)
Pages: 5736-5745
Related Report
Peer Reviewed
-
[Journal Article] Synthesis, structures, and magnetic properties of doubly face-sharing heterotrinuclear NiII-LnIII-NiII (Ln = Eu, Gd, Tb, and Dy) complexes2008
Author(s)
T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
-
Journal Title
Bulletin of the Chemical Society of Japan 81(5)
Pages: 598-605
NAID
Related Report
Peer Reviewed
-
-
[Journal Article] Bis[hexaaquacobalt(II)]25, 26, 27, 28-tetrahydroxy-2, 8, 14, 19-tetra thiacalix[4]arene-5, 11, 17, 23-tetrasulfonate monohydrate.2008
Author(s)
H. Akashi, M. Ichikawa
-
Journal Title
Acta Crystallographica, Section E E64(6)
Related Report
Peer Reviewed
-
[Journal Article] Synthesis, Structures, and Magnetic Properties of Face-Sharing Heterodinuclear Ni (II)-Ln(III)(Ln=Eu, Gd, Tb, Dy) Complexes.2008
Author(s)
T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
-
Journal Title
Inorganic Chemistry 47(13)
Pages: 5736-5745
Related Report
Peer Reviewed
-
[Journal Article] Synthesis, structures, and magnetic properties of doubly face-sharing heterotrinuclear NiII-LnIII-NiII (Ln=Eu, Gd, Tb, and Dy) complexes.2008
Author(s)
T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi. N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
-
Journal Title
Bulletin of the Chemical Society of Japan 81(5)
Pages: 598-605
NAID
Related Report
Peer Reviewed
-
-
-
-
-
-
-
[Journal Article] Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type clusters, [Mo_3S_4Tp_3]^+ and [Mo_3OS_3Tp_3]^+, and a mixed-metal cubane-type cluster, [Mo_3FeS_4ClTp_3]. X-ray structures of [Mo_3S_4Tp_3]Cl, [Mo_3OS_3Tp_3]PF_6, and [Mo_3FeS_4ClTp_3]2006
Author(s)
Yamauchi, T., Akashi, H., Shibahara, T.
-
Journal Title
Inorg.Chem. 45(14)
Pages: 5429-5437
Related Report
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-