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Catenation of transition metal chalcogenide complexes

Research Project

Project/Area Number 18550063
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOkayama University of Science

Principal Investigator

AKASHI Haruo  Okayama University of Science, 自然科学研究所, 教授 (30221708)

Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥4,200,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥600,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2006: ¥1,600,000 (Direct Cost: ¥1,600,000)
Keywords金属錯体化学 / 配位高分子 / 金属有機系構造体 / ポリピラゾリル配位子 / 硫黄架橋 / モリブデン錯体 / 触媒 / チアカリックスアレーン
Research Abstract

複数の金属原子がカルコゲン原子で架橋されてできている金属錯体を基本単位として、これらを鎖状につなぎ合わせることにより、基本単位となる錯体の構造を維持しつつ、より複雑な構造をもった遷移金属カルコゲニドクラスター錯体を合成する方法を開発する研究を行った。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (38 results)

All 2008 2007 2006

All Journal Article (14 results) (of which Peer Reviewed: 13 results) Presentation (24 results)

  • [Journal Article] Bis[hexaaquacobalt(II)]25,26,27,28-tetrahydroxy-2,8,14,19-tetrathiacalix[4] arene-5,11,17,23-tetrasulfonate monohydrate2008

    • Author(s)
      H. Akashi, M. Ichikawa
    • Journal Title

      Acta Crystallographica, Section E E64(6)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Magnetic Properties of Face-Sharing Heterodinuclear Ni(II)-Ln(III) (Ln= Eu, Gd, Tb, Dy) Complexes2008

    • Author(s)
      T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
    • Journal Title

      Inorganic Chemistry 47(13)

      Pages: 5736-5745

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structures, and magnetic properties of doubly face-sharing heterotrinuclear NiII-LnIII-NiII (Ln = Eu, Gd, Tb, and Dy) complexes2008

    • Author(s)
      T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
    • Journal Title

      Bulletin of the Chemical Society of Japan 81(5)

      Pages: 598-605

    • NAID

      130004058907

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantiopure Anthrylene-Ethynylene Cyclic Tetramer and Racemization via Rotation of Anthracene Unit about Acetylenic Axes2008

    • Author(s)
      T. Ishikawa, T. Shimasaki, H. Akashi, S. Toyota
    • Journal Title

      Organic Letters 10(3)

      Pages: 417-420

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bis[hexaaquacobalt(II)]25, 26, 27, 28-tetrahydroxy-2, 8, 14, 19-tetra thiacalix[4]arene-5, 11, 17, 23-tetrasulfonate monohydrate.2008

    • Author(s)
      H. Akashi, M. Ichikawa
    • Journal Title

      Acta Crystallographica, Section E E64(6)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Magnetic Properties of Face-Sharing Heterodinuclear Ni (II)-Ln(III)(Ln=Eu, Gd, Tb, Dy) Complexes.2008

    • Author(s)
      T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
    • Journal Title

      Inorganic Chemistry 47(13)

      Pages: 5736-5745

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structures, and magnetic properties of doubly face-sharing heterotrinuclear NiII-LnIII-NiII (Ln=Eu, Gd, Tb, and Dy) complexes.2008

    • Author(s)
      T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi. N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
    • Journal Title

      Bulletin of the Chemical Society of Japan 81(5)

      Pages: 598-605

    • NAID

      130004058907

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantiopure Anthrylene-Ethynylene Cyclic Tetramer and Racemization via Rotation of Anthracene Unit about Acetylenic Axes.2008

    • Author(s)
      T. Ishikawa, T. Shimasaki, H. Akashi, S. Toyota
    • Journal Title

      Organic Letters 10(3)

      Pages: 417-420

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantiomeric Resolution of Chiral 1,8-Anthrylene Cyclic Tetramers with Acetylene and Diacetylene Linkers2007

    • Author(s)
      M. Goichi, S. Yamasaki, H. Miyahara, K. Wakamatsu, H. Akashi, and S. Toyota
    • Journal Title

      Chemistry Letters 36(3)

      Pages: 404-405

    • NAID

      10018829637

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantiomeric Resolution of Chiral 1,8-Anthrylene Cyclic Tetramers with Acetylene and Diacetylene Linkers2007

    • Author(s)
      M. Goichi, S. Yamasaki, H. Miyahara, K. Wakamatsu, H. Akashi, S. Toyota
    • Journal Title

      Chemistry Letters 36

      Pages: 404-405

    • NAID

      10018829637

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type clusters, [Mo_3S_4Tp_3]^+ and [Mo_3OS_3Tp_3]^+, and a mixed-metal cubane-type cluster, [Mo_3FeS_4ClTp3_]_- X-ray structures of [Mo_3S_4Tp_3]Cl, [Mo_3O_S3Tp_3]PF_6, and [Mo_3FeS_4ClTp_3]_-2006

    • Author(s)
      T. Yamauchi, H. Takagi, T. Shibahara, H. Akashi
    • Journal Title

      Inorg. Chem. 45(14)

      Pages: 5429-5437

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Absolute configuration and chiroptical properties of an enantiopure [5-chloro-2-(dimethylaminomethyl)phenyl] phenylborane complex2006

    • Author(s)
      S. Toyota, F. Ito, T. Yamamoto, H. Akashi, T. Iwanaga
    • Journal Title

      Bull. Chem. Soc. Jpn. 79(5)

      Pages: 796-798

    • NAID

      10017499139

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 4-Carboxypyridinium hydrogen chloranilate monohydrate2006

    • Author(s)
      K. Gotoh, Y. Tabuchi, H. Akashi, H. Ishida
    • Journal Title

      Acta Cryst. Sect. E E62(10)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type clusters, [Mo_3S_4Tp_3]^+ and [Mo_3OS_3Tp_3]^+, and a mixed-metal cubane-type cluster, [Mo_3FeS_4ClTp_3]. X-ray structures of [Mo_3S_4Tp_3]Cl, [Mo_3OS_3Tp_3]PF_6, and [Mo_3FeS_4ClTp_3]2006

    • Author(s)
      Yamauchi, T., Akashi, H., Shibahara, T.
    • Journal Title

      Inorg.Chem. 45(14)

      Pages: 5429-5437

    • Related Report
      2006 Annual Research Report
  • [Presentation] Syntheses and characterization of the compounds with sulfur-bridged cubane-type mo3pds4 core and scorpionate ligands2008

    • Author(s)
      H. Akashi, R. Yoshida, T. Shibahara
    • Organizer
      XV^<th> International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz (Poland)
    • Related Report
      2008 Final Research Report
  • [Presentation] Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type molybdenum and tungsten complexes with tris(pyrazolyl)ethanol ligands2008

    • Author(s)
      R. Yoshida, H. Akashi, T. Shibahara
    • Organizer
      XVI^<th> International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz (Poland)
    • Related Report
      2008 Final Research Report
  • [Presentation] Syntheses and characterization of cubane-type molybdenum-palladium complexes with scorpionate ligands2008

    • Author(s)
      H. Akashi, R. Yoshida, K. Moriwaki, T. Shibahara
    • Organizer
      15^<th> International SPACC-CSJ
    • Place of Presentation
      Osaka (Japan)
    • Related Report
      2008 Final Research Report
  • [Presentation] 硫黄/酸素架橋不完全キュバン型M_3OS_3(M=Mo,W)骨格をもつトリスピラゾリルエタノール錯体の合成と性質2008

    • Author(s)
      吉田 諒一 ・ 柴原 隆志 ・ 赤司 治夫
    • Organizer
      錯体化学討論会
    • Place of Presentation
      金沢
    • Related Report
      2008 Final Research Report
  • [Presentation] トリスピラゾリルエタノールを配位子とするモリブデン-パラジウムクラスター錯体の合成と性質2008

    • Author(s)
      吉田 諒一 ・ 柴原 隆志 ・ 赤司 治夫
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      長崎
    • Related Report
      2008 Final Research Report
  • [Presentation] 硫黄/酸素架橋不完全キュバン型M_3OS_3(M=Mo, W)骨格をもつトリスピラゾリルエタノール錯体の合成と性質2008

    • Author(s)
      吉田諒一, 柴原隆志, 赤司治夫
    • Organizer
      錯体化学討論会
    • Place of Presentation
      金沢大学金沢市
    • Related Report
      2008 Annual Research Report
  • [Presentation] トリスピラゾリルエタノールを配位子とするモリブデンーパラジウムクラスター錯体の合成と性質2008

    • Author(s)
      吉田諒一, 柴原隆志, 赤司治夫
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      長崎大学長崎市
    • Related Report
      2008 Annual Research Report
  • [Presentation] Syntheses and characterization of cubane-type molybdenum-palladium complexes with scorpionate ligands.2008

    • Author(s)
      Akashi, H., Yoshida, R., Moriwaki, K., Shibahara, T.
    • Organizer
      15^<th> International SPACC-CSJ
    • Place of Presentation
      大阪市
    • Related Report
      2008 Annual Research Report
  • [Presentation] Syntheses and characterization of the compounds with sulfur-bridged cubane-type mo_3pds_4 core and scorpionate ligands2008

    • Author(s)
      Akashi, H., Yoshida, R., Shibahara, T.
    • Organizer
      XVI^<th> International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz (Poland)
    • Related Report
      2008 Annual Research Report
  • [Presentation] Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type molybdenum and tungsten complexes with tris (pyrazolyl) ethanol ligands.2008

    • Author(s)
      Yoshida, R., Akashi, H., Shibahara, T.
    • Organizer
      XVI^<th> International Winter School on Coor dination Chemistry
    • Place of Presentation
      Karpacz (Poland)
    • Related Report
      2008 Annual Research Report
  • [Presentation] Syntheses and characterization of sulfur-bridged incomplete cubane-type molybdenum complexes with scorpionate ligands2007

    • Author(s)
      赤司 治夫
    • Organizer
      14th International SPACC-CSJ Symposium
    • Place of Presentation
      Taipei,Taiwan
    • Year and Date
      2007-12-22
    • Related Report
      2007 Annual Research Report
  • [Presentation] 硫黄架橋不完全キュバン型M_3S_4(M=Mo,W)骨格をもつトリスピラゾリルエタノール錯体の合成と性質2007

    • Author(s)
      吉田 諒一・柴原 隆志・赤司 治夫
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      岡山
    • Year and Date
      2007-11-10
    • Related Report
      2007 Annual Research Report
  • [Presentation] DV-Xα法を用いたヒドロトリスピラゾリルボレートを配位子とするモリブデン(V)クラスター錯体の電子状態の計算2007

    • Author(s)
      下瀬 さちえ・赤司 治夫
    • Organizer
      錯体化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-09-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] Isostructural compounds with sulfur-bridged incomplete cubane-type M_3S_4cores(M=Mo,W)and tris(pyrazolyl)ethanol ligands2007

    • Author(s)
      赤司 治夫
    • Organizer
      The first Asian Conference on Coordination Chemistry
    • Place of Presentation
      Okazaki,Japan
    • Year and Date
      2007-08-01
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis and characterization of sulfur-bridged cubane-type molybdenum-nickel complex with hydrotris(pyrazolyl)borate ligands2007

    • Author(s)
      赤司 治夫
    • Organizer
      XXI.International Conference on Coordination and Bioinorganic Chemistry
    • Place of Presentation
      Smolenice,Slovakia
    • Year and Date
      2007-06-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] Syntheses and characterization of sulfur-bridged incomplete cubane-type molybdenum complexes with scorpionate ligands2007

    • Author(s)
      H. Akashi and T. Shibahara
    • Organizer
      14^<th> International SPACC-CSJ Symposium, 1042
    • Place of Presentation
      Taipei (Taiwan)
    • Related Report
      2008 Final Research Report
  • [Presentation] Isostructural compounds with sulfur-bridged incomplete cubane-type M_3S_4 cores (M = Mo, W) and tris(pyrazolyl)ethanol ligands2007

    • Author(s)
      H. Akashi and T. Shibahara
    • Organizer
      The first Asian Conference on Coordination Chemistry
    • Place of Presentation
      Okazaki (Japan)
    • Related Report
      2008 Final Research Report
  • [Presentation] Synthesis and characterization of sulfur-bridged cubane-type molybdenum-nickel complex with hydrotris(pyrazolyl)borate ligands2007

    • Author(s)
      H. Akashi
    • Organizer
      XXI. International Conference on Coordination and Bioinorganic Chemistry, 19
    • Place of Presentation
      Smolenice (Slovakia)
    • Related Report
      2008 Final Research Report
  • [Presentation] Syntheses and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Molybdenum Complexes with Hydrotris(Pyrazolyl)Borate Ligands2007

    • Author(s)
      H. Akashi, T. Yamauchi and T. Shibahara
    • Organizer
      XV Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz (Poland)
    • Related Report
      2008 Final Research Report
  • [Presentation] DV-Xα法を用いたヒドロトリスピラゾリルボレートを配位子とするモリブデン(V)クラスター錯体の電子状態の計算2007

    • Author(s)
      下瀬さちえ・坂根弦太・柴原隆志・赤司治夫
    • Organizer
      第57回錯体化学討論会 1PB-034
    • Place of Presentation
      名古屋
    • Related Report
      2008 Final Research Report
  • [Presentation] X-ray Structures and Characterizations of Iron Complexes of Thiacalixarenetetrasulfonate2006

    • Author(s)
      S. Shimose and H. Akashi
    • Organizer
      The joint conference of the Asian Crystallographic Association (AsCA) and the Crystallographic Society of Japan (CrSJ) P23-133
    • Place of Presentation
      Tukuba (Japan)
    • Related Report
      2008 Final Research Report
  • [Presentation] ヒドロトリスピラゾリルボレートを配位子とするモリブデン(V)クラスター錯体の合成と性質2006

    • Author(s)
      下瀬さちえ・柴原隆志・赤司治夫
    • Organizer
      第56回錯体化学討論会 1Ab19
    • Place of Presentation
      広島
    • Related Report
      2008 Final Research Report
  • [Presentation] 三脚型配位子を含む第一遷移金属-希土類金属系多核錯体の合成、構造および磁気的性質2006

    • Author(s)
      山口友佳・砂月幸成・小島正明・赤司治夫・Nazzareno Re・松本尚英・J.-P. Costes、J.-P. Tuchagues
    • Organizer
      第56回錯体化学討論会 2Ac04
    • Place of Presentation
      広島
    • Related Report
      2008 Final Research Report
  • [Presentation] 三脚型六座配位子を用いた同種・異種金属三核錯体の構造と磁気的性質2006

    • Author(s)
      小林玉実・山口友佳・砂月幸成・小島正明・赤司治夫・Nazzareno Re・松本尚英
    • Organizer
      第56回錯体化学討論会 2Ac05
    • Place of Presentation
      広島
    • Related Report
      2008 Final Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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