Synthesis of novel functional molecules based on small metallacycloalkynes
| Project/Area Number |
18550065
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
SUZUKI Noriyuki The Institute of Physical and Chemical Research, 理工学部, 准教授 (90241231)
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| Project Period (FY) |
2006 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥4,380,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2006: ¥1,000,000 (Direct Cost: ¥1,000,000)
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| Keywords | 有機金属錯体 / ジルコニウム / 環状アルキン / クムレン / 五員環 / ハプトトロピック / イソニトリル / 有機金属化学 / 前周期遷移金属 / シクロアルキン / ヘキサペンタエン / 五員環アルキン / 五員環アレン / ブタトリエン / シクロペンチン / シクロペンタジエン / シクロアレン / 5員環アルキン / チタニウム / アルデヒド |
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| Research Abstract |
We recently reported versatile synthesis of stable five-membered cycloalkyne comounds that include one transition metal atom in the cyclic structures. These compound are prepared from law-valent group 4 transition metal species and 1,2,3-butatriene derivatives. The chemical and physical properties of these novel compounds, however, have not been known. In this study we prepared conjugated system of the five-membered metallacycloalkyne compounds using highly cumulated polyenes, so that the resulted compounds showed redox characters and new functional properties.
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Report
(6 results)
Research Products
(44 results)
