| Budget Amount *help |
¥4,380,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2006: ¥1,000,000 (Direct Cost: ¥1,000,000)
|
|---|
| Research Abstract |
We recently reported versatile synthesis of stable five-membered cycloalkyne comounds that include one transition metal atom in the cyclic structures. These compound are prepared from law-valent group 4 transition metal species and 1,2,3-butatriene derivatives. The chemical and physical properties of these novel compounds, however, have not been known. In this study we prepared conjugated system of the five-membered metallacycloalkyne compounds using highly cumulated polyenes, so that the resulted compounds showed redox characters and new functional properties.
|
