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Development of the removal system of toxic metal ions for the reduction of environmental load

Research Project

Project/Area Number 18550083
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionKanazawa Institute of Technology

Principal Investigator

KOMATSU Yu  Kanazawa Institute of Technology, College of Environmental Engineering and Architecture, Professor (70339985)

Co-Investigator(Kenkyū-buntansha) FUJINAGA Kaoru  Kanazawa Institute of Technology, College of Environmental Engineering and Architecture, Professor (50156890)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥4,310,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥510,000)
Fiscal Year 2007: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2006: ¥2,100,000 (Direct Cost: ¥2,100,000)
KeywordsIon Exchange / Dihydrogen Tetratitanate Hydrate Fibers / Transition Metal Ions / Separation
Research Abstract

The purpose of this project is the development of the removal system of toxic metal ions for the reduction of environmental load. The synthesis of the ion exchange material (potassium tetratitanate fiber) was tried by flux (potassium molybdate) method using titanium dioxide and potassium carbonate between 2006 and 2007. After the investigation of physical characters of the potassium tetratitanate, this materials was changed to dihydrogen tetratitanate hydrate fibers by washing hydrochloric acid. The hydrogen type titanate was used to the ion exchanger for the three metal groups, such as alkali metal group, alkaline earth metal group, and transition metal group. These metals had high ion exchange ability by batch wise method.
In 2007 and 2008, the separation of these group metal ions (alkali metal ion group: lithium ions, sodium ions, potassium ions, rubidium ions, cesium ions. Alkaline earth metal ion group: magnesium ions, calcium ions, strontium ions, barium ions. Transition metal ion group: copper ions, nickel ions, zinc ions) were examined by column method to check the ability for the separation of these metal ions. The separation factor between two metal ions which belong to the same groups is very high and this method will be used to the removal system of toxic metal ions for the reduction of environmental load.
From these results, this method will be applied for the separation of cesium and strontium ions in high level radioactive waste, and the toxic long life radioactive waste can be decrease compare than those before the treatment. Finally, the separation of toxic metal ions can be separate from other materials.

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (17 results)

All 2007 2006

All Journal Article (13 results) (of which Peer Reviewed: 7 results) Presentation (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] イオン交換反応2007

    • Author(s)
      小松 優
    • Journal Title

      ぶんせき(日本分析化学会) 3号

      Pages: 138-142

    • NAID

      10018824498

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Peculiar extraction behavior of Nickel(II) Originated in Steric Effect of Schiff Base Ligands in Ion-pair Extraction Systems2007

    • Author(s)
      Yu Komatsu, et. al.
    • Journal Title

      Journal of Ion Exchange Vol.18

      Pages: 364-369

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Two-stage Ion-exchange Separation-Method for the Separation of Strontium from Other Alkaline Earth Metal Ions2007

    • Author(s)
      Yu Komatsu, et. al.
    • Journal Title

      Journal of Ion Exchange Vol.18

      Pages: 434-439

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 層状チタン酸塩を用いた金属イオンのイオン交換反応の詳細解析とゼオライトへの応用2007

    • Author(s)
      小松 優
    • Journal Title

      Journal of the Society of Inorganic Materials, Japan Vol.14

      Pages: 306-310

    • NAID

      10019151376

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Ion Exchange Reaction2007

    • Author(s)
      Yu Komatsu
    • Journal Title

      Bunseki No.3

      Pages: 138-142

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Peculiar extraction behavior of Nickel(II) Originated in Steric Effect of Schiff Base Ligands in Ion-pair Extraction Systems.2007

    • Author(s)
      Yu Komatsu, et. al.
    • Journal Title

      Journal of Ion Exchange Vol.18

      Pages: 364-369

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Ion Exchange Reaction of Metal Ions on Layered Titanate Conpounds and the application for Zeolite.2007

    • Author(s)
      Y. Komatsu
    • Journal Title

      Journal of Society of Inorganic Materials, Japan Vol.14

      Pages: 306-310

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Peculiar Extraction Behavior of Nickel(II)Originated in Steric Effect of Schiff Base Ligands in Ion-pair Extraction Systems.2007

    • Author(s)
      Yu Komatsu, et. al.
    • Journal Title

      Journal of Ion Exchange Vol.18

      Pages: 364-369

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-Stage Ion-Exchange Separation-Method for the Separation of Strontium from Other Alkaline Earth Metal Ions2007

    • Author(s)
      Yu Komatsu, et. al.
    • Journal Title

      Journal of Ion Exchange Vol.18

      Pages: 434-439

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] イオン交換反応2007

    • Author(s)
      小松 優
    • Journal Title

      ぶんせき(日本分析科学会) 3

      Pages: 138-142

    • NAID

      10018824498

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Ion-Exchange Separation of Cesium from Other Alkali Metal Ions on Dihy drogen Tetratitanate Hysrate Fibers by Column Method and Immobilization2006

    • Author(s)
      Y.Komatsu, Y.Michiue, Y.Watanabe, J.Noro, S.Tsurubou and K.Fujinaga
    • Journal Title

      The Proceedings of International Symposium on Ion Exchange in Korea(2006) (Japan Association of Ion Exchange) 1

      Pages: 53-54

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Ion-Exchange Separation of Cesium from Other Alkali Metal Ions on Dihydrogen Tetratitanate Hydrate Fibers by Column Method and Immobilization2006

    • Author(s)
      Y. Komatsu, et. al.
    • Journal Title

      The Proceedings of International Symposium on Ion Exchange in Korea(2006) (Japan Association of Ion Exchange) Vol.1

      Pages: 53-54

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Ion-Exchange Separation of Cesium form Other Alkali Metal Ions on Dihydorogen Tetratitanate Hysrate Fibers by Columm Method and Immobilization2006

    • Author(s)
      Y.Komatsu, Y.Mishiue, Y.Watanabe, J.Noro, S.Tsurubou, K.Fujinaga
    • Journal Title

      The Proceedings of International Symposium on Ion Exchange in Korea(2006)(Jaoan Association of Ion Exchange) 1

      Pages: 53-54

    • Related Report
      2006 Annual Research Report
  • [Presentation] Two-stage Ion-exchange Separation-Method for the Separation of Strontium from Other Alkaline Earth Metal Ions2007

    • Author(s)
      Yu Komatsu, et. al.
    • Organizer
      The 4th International Conference on Ion Exchange
    • Place of Presentation
      Keyaki Kaikan(Chiba Univ.)
    • Year and Date
      2007-10-17
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Two-stage Ion-exchange Separation-Method for the Separation of Strontium from Other Alkaline Earth Metal Ions(Chiba Univ.)2007

    • Author(s)
      Yu Komatsu, et. al.
    • Organizer
      The 4th International Conference on Ion Exchange
    • Place of Presentation
      Keyaki Kaikan
    • Year and Date
      2007-10-17
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Two-Stage Ion-Exchange Separation-Method for the Separation of Strontium from Other Alkaline Earth Metal Ions2007

    • Author(s)
      Yu Komatsu, et. al.
    • Organizer
      The 4th International Conference on Ion Exchange
    • Place of Presentation
      Keyaki Kaikan(University of Chiba)
    • Year and Date
      2007-10-17
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属イオンの分離法2006

    • Inventor(s)
      小松 優、鶴房 繁和
    • Industrial Property Rights Holder
      小松 優、鶴房 繁和
    • Acquisition Date
      2006
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2006-04-01   Modified: 2016-04-21  

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