Construction of Anion Receptors Bearing Silanol Groups

• Project/Area Number: 18550115
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: Gunma University
• Principal Investigator: KONDO Shin-ichi Gunma University, 大学院・工学研究科, 助教 (20281503)
• Co-Investigator(Kenkyū-buntansha): UNNO Masafumi 群馬大学, 大学院・工学研究科, 教授 (20251126)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥690,000); Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2007: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2006: ¥1,300,000 (Direct Cost: ¥1,300,000)
• Keywords: 分子認識 / ケイ素化学 / 水素結合 / アニオン認識 / シラノール / 水酸基 / ジシロキサンテトラオール / シラントリオール / ジシロキサンジオール / 不完全縮合シルセスキオキサン / シランジオール

Research Abstract

シラノール水酸基がアニオン認識における水素結合ドナーとして有効に利用可能であるかを検討するために、種々のシラノール誘導体を合成し、そのアニオン会合能について主にNMRスペクトルを用いて検討した。その結果、シラノール水酸基はアミドNHなどと同等程度のアニオン認識能を有することを初めて見出した。さらに、一つのケイ素原子上に複数のシラノール水酸基を有するレセプターは、協同的にアニオンを認識することが可能であることことを明らかとした。

Research Products

• [Journal Article] Anion recognition by 1,3-disiloxane-1,1,3,3-tetraols in organic solvents (2009)
  • Author(s): Shin-ichi Kondo, Natsumi Okada, Ryoji Tanaka, Masaki Yamamura, and Masafumi Unno
  • Journal Title: Tetrahedron Letters 50, No.23 Pages: 2754-2757
  • Peer Reviewed
• [Journal Article] Anion recognition by 1,3-disiloxane-I,1,3,3-tetraols in organic solvents (2009)
  • Author(s): S. Kondo, N. Okada, R. Tanaka, M. Yamamura, and M. Unno
  • Journal Title: Tetrahedron Letters 50 Pages: 2754-2757
  • Peer Reviewed
• [Journal Article] A Spectroscopic Investigation of Incompletely Condensed Polyhedral Oligomeric Silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol) : Hydrogen-Bonded Interaction and Host-Guest Complex (2008)
  • Author(s): Hongzhi Liu, Shin-ichi Kondo, Ryoji Tanaka, Hiroyuki Oku, and Masafumi Unno
  • Journal Title: Journal of Organometallic Chemistry 693,No.7 Pages: 1301-1308
  • Peer Reviewed
• [Journal Article] A spectroscopic investigation of incompletely condensed polyh edral oligomeric silsesquioxanes (POSS-mo-ol, POSS-diol and POSS-triol): Hydrogen-bonded interaction and host-guest complex (2008)
  • Author(s): H. Liu, S. Kondo, R. Tanaka, H. Oku, and M. Unno
  • Journal Title: Journal of Organometallic Chemistry 693 Pages: 1301-1308
  • Peer Reviewed
• [Journal Article] Anion recognition by a disiloxane-1,3-diol in organic solvents (2008)
  • Author(s): S.Kondo, A.Fukuda, T.Yamamura, R.Tanaka, and M.Unno
  • Journal Title: Tretrahedron Letters 48 Pages: 7946-7949
  • Peer Reviewed
• [Journal Article] Anion recognition by a disiloxane-1,3-diol in organic solvents (2007)
  • Author(s): Shin-ichi Kondo, Ayumi Fukuda, Takehide Yamamura, Ryoji Tanaka, and Masafumi Unno
  • Journal Title: Tetrahedron Letters 48, No.45 Pages: 7946-7949
  • Peer Reviewed
• [Journal Article] Synthesis of cyclic bis- and trismelamine derivatives and their complexation properties with barbiturates (2007)
  • Author(s): Shin-ichi Kondo, Tomohiro Hayashi, Yuichi Sakuno, Yoko Takezawa, Takashi Yokoyama, Masafumi Unno, and Yumihiko Yano
  • Journal Title: Organic & Biomolecular Chemistry 5, No.6 Pages: 907-916
• [Journal Article] A Spectroscopic Investigation of Incompletely Condensed Polyhedral Ohgomeric Sisesquioxanes(POSS-mono-ol,POSS-diol and POSS-triol):Hydrogen-Bonded Interaction and Host-Guest Complex (2007)
  • Author(s): H.Liu, S.Kondo, R.Tanaka, H.Oku, and M.Unno
  • Journal Title: Journal of Organometallic Chemistry 693 Pages: 1301-1308
  • Peer Reviewed
• [Journal Article] Synthesis of cyclic bis-and trismelamine derivatives and their complexation properties with barbiturates (2007)
  • Author(s): S.Kondo, T.Hayashi, Y.Sakuno, Y.Takezawa, T.Yokoyama, M.Unno, Y.Yano
  • Journal Title: Organic and Biomolecular Chemistry 5・6 Pages: 907-916
• [Journal Article] Anion Recognition by a Silanediol-based Receptor (2006)
  • Author(s): Shin-ichi Kondo, Tomomi Harada, Ryoji Tanaka, and Masafumi Unno
  • Journal Title: Organic Letters 8, No.20 Pages: 4621-4624
  • Peer Reviewed
• [Journal Article] Anion recognition by a silanediol-based receptor (2006)
  • Author(s): S.Kondo, T.Harada, R.Tanaka, M.Unno
  • Journal Title: Organic Letters 8・20 Pages: 4621-4624
• [Journal Article] Synthesis of crownophanes possessing bipydine moieties : bipydinocrownophanes exhibiting perfect extractability toward Ag^+ ion (2006)
  • Author(s): S.Inokuma, M.Kuramami, S.Otsuki, T.Shirakawa, S.Kondo, Y.Nakamura, J.Nishimura
  • Journal Title: Tetrahedron 62・42 Pages: 1005-10010
• [Presentation] 二つのアザー15-クラウン-5-工ーテルを有する2,2′-ビアントラセンによるアルカリ土類金属の認識 (2009)
  • Author(s): 高橋卓也・近藤慎一・海野雅史
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
• [Presentation] 水酸基を有するアニオンレセプターによるアニオン認識 (2008)
  • Author(s): 川上 晃弘、近藤 慎一、海野 雅史
  • Organizer: 平成19年度日本化学会関東支部群馬地区地域懇談会
  • Place of Presentation: 群馬
  • Year and Date: 2008-11-20
• [Presentation] シラントリオールと1,1,3,3,-ジシロキサンテトラオールによるアニオン認識 (2008)
  • Author(s): 岡田 奈津美・近藤 慎一・田中 陵二・海野 雅史
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋キャンパス
  • Year and Date: 2008-03-29
• [Presentation] 水酸基を有するアニオンレセプターによるアニオン認識 (2008)
  • Author(s): 川上 晃弘、近藤 慎一、海野 雅史
  • Organizer: 日本化学会第2回関東支部大会
  • Place of Presentation: 群馬
• [Presentation] Anion recognition by silanol-based receptors (2008)
  • Author(s): Shin-ichi Kondo, Natsumi Okada, Masaki Yamamura, and Masafumi Unno
  • Organizer: International Symposium on Macrocyclic and Supramolecular Chemistry
  • Place of Presentation: USA
• [Presentation] Anion receptors bearing silanol groups (2008)
  • Author(s): Shin-ichi Kondo, Tomomi Harada, Natsumi Okada, Ayumi Fukuda, Ryoji Tanaka, Masaki Yamamura, and Masafumi Unno
  • Organizer: The 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: Jeju, Korea
• [Presentation] Anion recogntion by silanetriols and disiloxanetetraols (2008)
  • Author(s): Natsumi Okada, Shin-ichi Kondo, Ryoji Tanaka, Nobuhiro Takeda, and Masafumi Unno
  • Organizer: The 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: Jeju, Korea
• [Presentation] Hydrogen-bonde interaction and host-guest complex based on imcompletely condensed polyhedral oligomeric silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol) (2008)
  • Author(s): Hongzhi Liu, Shin-ich Kondo, Ryoji Tanaka, Hiroyuki Oku, and Masafumi Unno
  • Organizer: The 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: Jeju, Korea
• [Presentation] シラントリオールと1,1,3,3,-ジシロキサンテトラオールによるアニオン認識 (2008)
  • Author(s): 岡田 奈津美、近藤 慎一、田中 陵二、海野 雅史
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
• [Presentation] 水酸基を用いた新規アニオンレセプターによるアニオン認識 (2008)
  • Author(s): 川上 晃弘、近藤 慎一、海野 雅史
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
• [Presentation] 新規なPOSSの合成と機能化 (2008)
  • Author(s): Liu, Hongzhi、近藤 慎一、武田 亘弘、海野 雅史
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
• [Presentation] Anion receptors bearing silanol groups (2008)
  • Author(s): S. Kondo, T. Harada, N. Okada, A. Fukuda, R. Tanaka, M. Yamamura, and M. Unno
  • Organizer: The 15th International Symposium on Organosilienn Chemistry
  • Place of Presentation: 韓国
• [Presentation] Anion recogntion by silanetriols and disiloxanetetraols (2008)
  • Author(s): N. Okada, S. Kondo, R. Tanaka, N. Takeda, and M. Unno
  • Organizer: The 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: 韓国
• [Presentation] Hydrogen-bonde interaction and host-guest complex based on imcompletely condensed polyhedral oligomeric silsesquioxanes (POSS-mono-ol, POSS-dinl and POSS-trioll) (2008)
  • Author(s): H. Liu, S. Kondo, R. Tanaka, H. Oku, and M. Unno
  • Organizer: The 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: 韓国
• [Presentation] Synthesis of a new spherosilicat (2008)
  • Author(s): H. Liu, S. Kondo, N. Takeda. and M. Unno
  • Organizer: Post ISOS XV Symposium
  • Place of Presentation: 高崎
• [Presentation] Anion recognition by silanol-basect receptors (2008)
  • Author(s): S. Kondo, N. Okada, M. Yamamura, and M. Unno
  • Organizer: International Symposium on Macrocyclic and Supramolecular Chemistry 2008
  • Place of Presentation: Las Vegas
• [Presentation] 機能性官能基を導入したオリゴアミド骨格を有するアニオンレセプター (2008)
  • Author(s): 近藤慎一・中島慎一郎・川上晃弘・海野雅史
  • Organizer: 第3回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 上智大学四谷キャンパス
• [Presentation] イミノニ酢酸を金属配位部位に導入した2,2ービナフタレンによるアニナン認識 (2008)
  • Author(s): 中台康紀・近藤慎一・武田亘弘・海野雅史
  • Organizer: 日本化学会第2回関東支部大会
  • Place of Presentation: 群馬大学桐生キャンパス
• [Presentation] 二つのアザ-15-クラウン-5-工ーテルを有する2,2′ビアントラセンによるアルカリ土類金属の認識 (2008)
  • Author(s): 高橋卓也・近藤慎一・海野雅史
  • Organizer: 日本化学会第2回関東支部大会
  • Place of Presentation: 群馬大学桐生キャンパス
• [Presentation] 水酸基を有するアニオンレセプターによるアニオソ認識 (2008)
  • Author(s): 川上晃弘・近藤慎一・海野雅史
  • Organizer: 日本化学会第2回関東支部大会
  • Place of Presentation: 群馬大学桐生キャンパス
• [Presentation] Anion recognition by silanetriols and 1,1,3,3-disiloxanetetraols (2007)
  • Author(s): Natsumi Okada, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The 3rd International Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: 群馬
  • Year and Date: 2007-11-30
• [Presentation] Anion recognition by novel receptors bearing hydroxy groups (2007)
  • Author(s): Akihiro Kawakami, Shin-ichi Kondo, and Masafumi Unno
  • Organizer: The 3rd International Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: 群馬
  • Year and Date: 2007-11-30
• [Presentation] Anion recognition by silanol-based receptors (2007)
  • Author(s): Tomomi Harada, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The 3rd International Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: 群馬
  • Year and Date: 2007-11-30
• [Presentation] Anion recognition by silanetriols and 1,1,3,3-disiloxanetetraols (2007)
  • Author(s): Natsumi Okada, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The 3rd Intemational Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: 群馬大学工学部
  • Year and Date: 2007-11-30
• [Presentation] Anion recognition by silanol-based receptors (2007)
  • Author(s): Tomomi Harada, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The 3rd Intemational Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: 群馬大学工学部
  • Year and Date: 2007-11-30
• [Presentation] Preparation and functinalization of new Poss-Q_8M_8<Tol> (2007)
  • Author(s): Hongzhi Liu, Shin-ichi Kondo, Nobuhiro Takeda, and Masafumi Unno
  • Organizer: The 3rd Intemational Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: 群馬大学工学部
  • Year and Date: 2007-11-30
• [Presentation] Anion Recognition by Silanediol (2007)
  • Author(s): Tomomi Harada, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The Second Gunma International Symposium on Chemistry
  • Place of Presentation: 群馬
  • Year and Date: 2007-07-21
• [Presentation] Synthesis of Silyl-substituted Siloxanes and Silanols (2007)
  • Author(s): Yoko Hori, Ryoji Tanaka, Shin-ichi Kondo, and Masafumi Unno
  • Organizer: The Second Gunma International Symposium on Chemistry
  • Place of Presentation: 群馬
  • Year and Date: 2007-07-21
• [Presentation] Anion Recognition by Novel Receptors Bearing Hydroxy Groups (2007)
  • Author(s): Akihiro Kawakami, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The Second Gunma International Symposium on Chemistry
  • Place of Presentation: 群馬
  • Year and Date: 2007-07-21
• [Presentation] Anion Recognition by Receptors Bearing Plural Silanol Groups (2007)
  • Author(s): Natsumi Okada, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The Second Gunma International Symposium on Chemistry
  • Place of Presentation: 群馬
  • Year and Date: 2007-07-21
• [Presentation] Anion Recognition by Silanediol (2007)
  • Author(s): Tomomi Harada, Shin-ichi Kondo, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The Second Gunma International Symposium on Chemistry
  • Place of Presentation: 群馬大学工学部
  • Year and Date: 2007-07-21
• [Presentation] Anion Recognition by Receptors Bearing Plural Silanol Groups (2007)
  • Author(s): Natsumi Okada, Shin-ichi Kolldo, Ryoji Tanaka, and Masafunli Unno
  • Organizer: The Second Gunma International Symposium on Chemistry
  • Place of Presentation: 群馬大学工学部
  • Year and Date: 2007-07-21
• [Presentation] シラノール基を有するレセプターによるアニオン認識 (2007)
  • Author(s): 近藤 慎一・原田 友美・岡田 奈津美・福田 歩美・海野 雅史
  • Organizer: 第2回ホスト・ゲストシンポジウム
  • Place of Presentation: 大阪市立大学学術情報総合センター
  • Year and Date: 2007-05-25
• [Presentation] 複数のシラノール基を有するレセプターによるアニオン認識 (2007)
  • Author(s): 近藤 慎一・岡田 奈津美・海野 雅史
  • Organizer: 第2回ホスト・ゲストシンポジウム
  • Place of Presentation: 大阪市立大学学術情報総合センター
  • Year and Date: 2007-05-24
• [Presentation] Anion Receptors Bearing Silanol Groups (2007)
  • Author(s): Shin-ichi Kondo, Tomomi Harada, Natsumi Okada, Ayumi Fukuda, Ryoji Tanaka, and Masafumi Unno
  • Organizer: The 1st Asian Silicon Symposium
  • Place of Presentation: 宮城
• [Presentation] シラノール基を有するレセプターによるアニオン認識 (2007)
  • Author(s): 近藤慎一、原田友美、岡田奈津美、福田歩美、海野雅史
  • Organizer: 第2回ホスト・ゲストシンポジウ
  • Place of Presentation: 大阪
• [Presentation] 水酸基を有するイソフタロイルアミド誘導体によるアニオン認識 (2007)
  • Author(s): 近藤慎一、川上晃弘。海野雅史
  • Organizer: 第2回ホスト・ゲストシンポジウム
  • Place of Presentation: 大阪
• [Presentation] 複数のシラノール基を有するレセプターによるアニオン認識 (2007)
  • Author(s): 近藤慎一、岡田奈津美、海野雅史
  • Organizer: 第2回ホスト・ゲストシンポジウム
  • Place of Presentation: 大阪
• [Presentation] シランジオールを有するレセプターによるアニオン認識 (2007)
  • Author(s): 原田 友美、近藤 慎一、田中 陵二、海野 雅史
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
• [Presentation] 有機溶媒中での三つの水酸基を有するかご状シルセスキオキサン誘導体の二量化 (2007)
  • Author(s): 劉 鴻志、近藤 慎一、田中 陵二、海野 雅史
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
• [Remarks]
  • URL: http://www.chem-bio.gunma-u.ac.jp/~kondo/
• [Remarks]
  • URL: http://www.chem-bio.gunma-u.ac.jp/~kondo/index.Html