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Fabrication of the High conductive diamond like carbon films and development of the novel nano-structumd electrochemical devioas

Research Project

Project/Area Number 18550166
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionYamaguchi University

Principal Investigator

HONDA Kensuke  Yamaguchi University, Graduate school of Science and Engineering, Associate professor (60334314)

Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥4,210,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2007: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2006: ¥2,000,000 (Direct Cost: ¥2,000,000)
KeywordsConductive DLC / Ideal oolarizable electrode / Template synthesis / Nano-structured material / Porous alumina
Research Abstract

In this study, highly conductive and polarizable electrode material was tried to be fabricated by improving the conductivity of diamond like carbon films using the impurity (nitrogen atoms) doping methods and the novel electrochemical device that combines the specificity of the nano-structure and the superior electrochemical properties of conductive DLC films was tried to be developed.
(1) Establishment of the deposition methods of highly conductive DLC films and its electrochemical properties. The heavily nitrogen doped DLC films was successfully fabricated by adding nitrogen atoms in the DLC thin films that was synthesized using plasma CVD methods. The resistivity of DLC films could be controlled by changing the RF plasma power during the CVD synthesis. The resulting highly conductive DLC films show the wide working potential range (ca. 4.0 V) in 0.1 M H_2SO_4, that is in the same range with that fir the boron-doped diamond electrodes (ca. 3.5 V). Therefore, it turned out that highly … More conductive DLC films works as an ideal polarizable electrode material with good response fix electrochemical reaction of typical redox species like Fe(CN)_6^<〓>. Moreover, the highly conductive DLC films show high corrosion resistance for the electrochemical treatment (long term potential cycling from -0.65 to 1.3 V) in strong acid solution (0.1M NaF in 1M HNO_3, indicating that the DLC films was highly stable fir the electrochemical application in extreme environmental conditions.
(2) Fabrication of the conductive DLC thorough-hole membrane and the development of the switching ion permeation filters
Conductive DLC thorough-hole membrane was fabricated by depositing DLC films with thickness of by nano meters on the surface of porous alumina with highly ordered nano-pore allays. By using the conductive nano-porous membrane with 25 nm of pore diameter as a filter material, the permeability of cation was suppressed by applying positive potential on conductive DLC membrane and the permeability of anion was suppressed by applying negative potential. For the mixed media of cation and anion, the selective permeability for cation could be achieved by applying negative potential Therefore the switching filters that can arbitrarily control the ion permeability by the size of pore diameters and the membrane potential could be successfully realized. Less

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (20 results)

All 2008 2007 2006

All Journal Article (11 results) (of which Peer Reviewed: 4 results) Presentation (7 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Simultaneous detection of purine and pyrimidine at highly boron-doped diamond electrodes by using liquid chromatography2007

    • Author(s)
      Tribidasari A. Ivandini
    • Journal Title

      Talanta 71(2)

      Pages: 648-655

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Fabrication of Covalent SAM/Au Nanoparticle/Boron-Doped Diamond Configurations with a Sequential Self-Assembly Method2007

    • Author(s)
      Takeshi Kondo,
    • Journal Title

      J.Phys.Chem.C 111(34)

      Pages: 12650-12657

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] プラズマCVDによる導電性DLC薄膜の作製と電気化学電極材料への応用2007

    • Author(s)
      本多 謙介
    • Journal Title

      NEW DIAMOND vol.23

      Pages: 24-29

    • NAID

      40015692693

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Journal Article] Ivandini, "Simultaneous detection of purine and pyrimidine at highly boron-doped diamond electrodes by using liquid chromatography2007

    • Author(s)
      Tribidasari, A
    • Journal Title

      Talanta 71(2)

      Pages: 648-655

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Fabrication of Covalent SAM/Au Nanoparticle/Boron-Doped Diamond Configurations with a Sequential Self-Assembly Method2007

    • Author(s)
      Takeshi, Kondo
    • Journal Title

      J Phys. Chem. C 111(34)

      Pages: 12650-12657

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Fabrication of the conductive DLC thin fdms using plasma CVD methods and application as an electrochemical electrode materials2007

    • Author(s)
      Kensuke, Honda
    • Journal Title

      NEW DIAMOND 23(4)

      Pages: 24-29

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Fabrication of Covalent SAM/Au Nanoparticle/Boron-Doped Diamond Conflgurations with a Sequential Self-Assembly Method2007

    • Author(s)
      Takeshi Kondo
    • Journal Title

      J. Phys. Chem. C 111(34)

      Pages: 12650-12657

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simultaneous detection of purine and pyrimidine at highly boron-doped diamond electrodes by using liquid chromatography2007

    • Author(s)
      Tribidasari A.Ivandini
    • Journal Title

      Talanta 71(2)

      Pages: 648-655

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Hybrid Electrochemical Treatment for Persistent Metal Complex at Boron-doped Diamond Electrodes and Clarification of its Reaction Route2006

    • Author(s)
      Y. Yamaguchi
    • Journal Title

      J. Electrochem. Soc. 153

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Hybrid Electrochemical Treatment for Persistent Metal Complex at Boron-doped Diamond Electrodes and Clarification of its Reaction Route2006

    • Author(s)
      Y. Yamaguchi
    • Journal Title

      J Electrochem. Soc 153(12)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Hybrid Electrochemical Treatment for Persistent Metal Complex at Boron-doped Diamond Electrodes and Clarification of its Reaction Route2006

    • Author(s)
      Y.Yamaguchi
    • Journal Title

      J.Electrochem.Soc. 153

    • Related Report
      2006 Annual Research Report
  • [Presentation] 不純物ドープ法によるダイヤモンドライクカーボン薄膜の作製とその電気化学特性2008

    • Author(s)
      田中 与子
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] 不純物ドープ法いよるダイヤモンドライクカーボン薄膜の導電性コントロール手法の確立とその電気化学特性および安定性2007

    • Author(s)
      本多 謙介
    • Organizer
      2007年電気化学秋季大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-09-16
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Establishment of the conductivity controlling for DLC thin films using impurity doping methods and its stability for electrochemical applications2007

    • Author(s)
      Kensuke, Honda
    • Organizer
      2007 Fall Meeting of the Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Institute of Technology (Tokyo)
    • Year and Date
      2007-09-16
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 不純物ドープ法によるダイヤモンドライクカーボン薄膜の導電性コントロール手法の確立とその電気化学特性および安定性2007

    • Author(s)
      本多 謙介
    • Organizer
      2007年電気化学秋季大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-09-16
    • Related Report
      2007 Annual Research Report
  • [Presentation] Fabrication of the conductivity controlling for DLC thin films using impurity doping methods and its electrochemical properties2007

    • Author(s)
      Yoriko, Tanaka
    • Organizer
      88th Annual Meeting of the Chemical Society of Japan
    • Place of Presentation
      Rikyo University (Tokyo)
    • Year and Date
      2007-03-28
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] プラズマCVD法による導電性ダイヤモンドライクカーボン(DLC)の成膜とそのく基礎電気化学特性2006

    • Author(s)
      香月 友紀子
    • Organizer
      2006年電気化学秋季大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2006-09-14
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication of the Conductive DLC Thin Films using Plasma CVD method and its Electrochemical Application2006

    • Author(s)
      Yikiko, Kastuki
    • Organizer
      2006 Fall Meeting of the Electrochemical Society of Japan
    • Place of Presentation
      Doshisha University (Kyoto)
    • Year and Date
      2006-09-14
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 導電性ダイヤモンドライクカーボンの製造方法2007

    • Inventor(s)
      本多 謙介, 辻 理, 本山 慎一, 楠 田豊
    • Industrial Property Rights Holder
      本多謙介, サムコ株式会社
    • Industrial Property Number
      2007-026084
    • Filing Date
      2007-02-05
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 導電性ダイヤモンドライクカーボンの製造方法2007

    • Inventor(s)
      本多謙介, 辻理, 本山慎一, 楠田豊
    • Industrial Property Rights Holder
      本多謙介, サムコ株式会社
    • Industrial Property Number
      2007-026084
    • Filing Date
      2007-02-05
    • Related Report
      2006 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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