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Preparation of nano-structured photocatalyst using self-organized catalyst

Research Project

Project/Area Number 18550182
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionTokyo University of Science

Principal Investigator

SAKAI Hideki  Tokyo University of Science, 理工学部, 准教授 (80277285)

Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥4,400,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥600,000)
Fiscal Year 2008: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2006: ¥1,800,000 (Direct Cost: ¥1,800,000)
Keywords界面活性剤 / 酸化チタン / 光触媒 / 自己組織化 / ゾル・ゲル反応 / ベシクル / ミセル / メソポーラス材料
Research Abstract

研究代表者らはこれまでに、酸化チタンの前駆体となるTiOSO4 のゾル-ゲル反応が、ある溶液条件(pH, 温度)ではカチオン界面活性剤が形成する自己組織化触媒の表面でのみ進行することを見いだしている。そこで、本研究では界面活性剤が形成するヘキサゴナル液晶、ベシクルなどを自己組織化触媒として用いて、ナノポーラス、中空などのナノ構造を有する酸化チタンを調製し、その光機能材料としての応用について検討した

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (29 results)

All 2008 2007 2006 Other

All Journal Article (19 results) (of which Peer Reviewed: 14 results) Presentation (9 results) Remarks (1 results)

  • [Journal Article] カチオン/アニオン界面活性剤混合系を利用したチタニア/界面活性剤複合粒子の調製とナノ構造制御2008

    • Author(s)
      酒井秀樹、河野浩輝、萩原英輝、小倉卓、柴田裕史、酒井健一、大久保貴広、阿部正彦
    • Journal Title

      色材協会誌 81

      Pages: 325-330

    • NAID

      10021998827

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] カチオン性シランカップリング剤で処理した基板上への酸化チタン薄膜の調製と光触媒特性2008

    • Author(s)
      河野浩輝、柴田裕史、大久保貴広、酒井俊郎、酒井秀樹、阿部正彦
    • Journal Title

      材料技術 26(3)

      Pages: 147-153

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Highly Ordered Mesoporous Silica with a Lamellar Structure Using Assembly of Cationic and Anionic Surfactant Mixtures as a Template2008

    • Author(s)
      Taku Ogura, Kenichi Sakai, Hideki Sakai, Masahiko Abe
    • Journal Title

      Journal of Physical Chemistry C 112(32)

      Pages: 12184-12187

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] カチオン性シランカップリング剤で処理した基板上への酸化チタン薄膜の調製と光触媒特性2008

    • Author(s)
      河野浩輝, 柴田裕史, 大久保貴広, 酒井俊郎, 酒井秀樹, 阿部正彦
    • Journal Title

      材料技術 26(3)

      Pages: 147-153

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] カチオン/アニオン界面活性剤混合系を利用したチタニア/界面活性剤複合粒子の調製とナノ構造制御2008

    • Author(s)
      酒井秀樹, 河野浩輝, 萩原英輝, 小倉 卓, 柴田裕史, 酒井健一, 大久保貴広, 阿部正彦
    • Journal Title

      色材協会誌 81(9)

      Pages: 325-330

    • NAID

      10021998827

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and photocatalytic activity under visible light irradiation of crystalline mesoporous titania particles.2008

    • Author(s)
      Hirobumi Shibata, Taku Ogura, Hideki Sakai, Mutsuyoshi Matsumoto, Masahiko Abe
    • Journal Title

      Journal of Japanese Societies of Colour Materials 81(7)

      Pages: 235-239

    • NAID

      10021124060

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room Temperature Synthesis of Crystalline Mesostructured Titania Particles using Gemini-type Surfactants as Templates2007

    • Author(s)
      Masahiko Abe, Hirobumi Shibata, Kazuyuki Tsubone, Hisashi Mihara, Toshio Sakai, Kanjiro Torigoe, Shuxi Dai, Takahiro Ohkubo, Shigenori Utsumi, Kazutami Sakamoto, Mutsuyoshi Matsumoto, Hideki Sakai
    • Journal Title

      Shikizai Kyokaishi, 80

      Pages: 450-452

    • NAID

      10019982984

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Highly-Ordered Mesoporous Silica Particles using Mixed Cationic and Anionic Surfactants as Templates2007

    • Author(s)
      Takahiro Ohkubo, Taku Ogura, Hideki Sakai, asahiko Abe
    • Journal Title

      Journal of Colloid and Interface Science 312(1)

      Pages: 42-46

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of a Microtube Photocatalyst with Photoactive Inner Surface and Inert Outer Surface2007

    • Author(s)
      Kohei Mitsuhashi. Naoki Tagami, Katsuyuki Tanabe, Sei Ssuzuki, Shinichi Iwanaga, Takahiro Ohkubo, Hideki Sakai, Masahiko Abe
    • Journal Title

      Journal of Phtochemistry and Photobiology A : Chemistry 185

      Pages: 133-139

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] メタロサーミックリダクション法によるホウ化物系硬質セラミックス粒子の創製とチタニアの高機能化に関する研究2007

    • Author(s)
      大久保貴広、酒井秀樹、阿部正彦、西山勝廣
    • Journal Title

      粉体および粉末冶金 54

      Pages: 251-259

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room Temperature Synthesis of Crystalline Mesostructured Titania Particles using Gemini-type Surfactants as Templates.2007

    • Author(s)
      Masahiko Abe, Hirobumi Shibata, Kazuyuki Tsubone, Hisashi Mihara, Toshio Sakai, Kanjiro Torigoe, Shuxi Dai, Takahiro Ohkubo, Shigenori Utsumi, Kezutami Sakamoto, Mutsuyoshi Matsumoto, Hideki Sakai
    • Journal Title

      Shikizai Kyokaishi 80

      Pages: 450-452

    • NAID

      10019982984

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] メソポーラスチタニアの細孔および結晶構造に及ぼす界面活性剤分子構造の影響2007

    • Author(s)
      酒井秀樹、柴田裕史、酒井俊郎、阿部正彦
    • Journal Title

      ゼオライト 24

      Pages: 51-59

    • NAID

      40015535920

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and properties of a microtube photocatalyst with photoactive inner surface and inert outer surface2007

    • Author(s)
      K.Mitsuhashi, N.Tagami, K.Tanabe, S.Suzuki, S.Iwanaga, T.Ohkubo, H.Sakai, M.Koishi, M.Abe
    • Journal Title

      Journal of Photochemistry and Photobiology, A : Chemistry, 185(2-3)

      Pages: 133-139

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Preparation and Photocatalytic Activity of Titania Particulate Film with Mesostructured Silica as Binder2006

    • Author(s)
      Hirobumi Shibata, Takahiro Ohkubo, Hiroki Kohno, Pramoch Rangsunvigit, Hideki Sakai, Masahiko Abe
    • Journal Title

      Journal of Photochemistry and Photobiology, A : Chemistry 181

      Pages: 357-362

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Highly Dispersed Core/Shell-Type Titania Nanocapsules Containing a Single Ag Nanoparticles2006

    • Author(s)
      Hideki Sakai, Takashi Kanda, Hirobumi Shibaya, Takahiro Ohkubo, Masahiko Abe
    • Journal Title

      Journal of the American Chemical Society 128

      Pages: 4944-4945

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Formation Mechanism of Mesoporous Titania Particles having Crystalline Wall2006

    • Author(s)
      H.Shibata, H.Mihara, T.Mukai, T.Ogura, H.Kohno, T.Ohkubo, H.Sakai, M.Abe
    • Journal Title

      Chemistry of Materials 18(9)

      Pages: 2256-2260

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Preparation and photcatalytic activity of titania particulate film with mesostructured silica as binder2006

    • Author(s)
      H.Shibata, T.Ohkubo, H.Khno, P.Rangsunvigit, H.Sakai, M.Abe
    • Journal Title

      Journal of Photochemistry and Photobiology, A : Chemistry, 181(2-3)

      Pages: 357-362

    • Related Report
      2006 Annual Research Report
  • [Journal Article] チタニア微粒子担持薄膜の高機能化とその光物性2006

    • Author(s)
      柴田裕史, 酒井秀樹, 松本睦良, 阿部正彦
    • Journal Title

      表面 44(4)

      Pages: 129-138

    • NAID

      40007397309

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 高機能性メソポーラスチタニアの調製2006

    • Author(s)
      柴田裕史, 酒井秀樹, 松本睦良, 阿部正彦
    • Journal Title

      表面 44(7)

      Pages: 259-268

    • NAID

      40015141584

    • Related Report
      2006 Annual Research Report
  • [Presentation] ω-チオール修飾カチオン界面活性剤を利用した金/チタニアーコア/シェル粒子の調製2008

    • Author(s)
      駒田和良, 神田 崇, 鳥越幹二郎, 酒井健一, 酒井秀樹, 阿部正彦
    • Organizer
      2008年度 色材協会研究発表会
    • Place of Presentation
      名古屋市工業研究所
    • Year and Date
      2008-09-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] ω-チオール修飾カチオン界面活性剤を利用した金/チタニア-コア/シェル型ナノ粒子の調製2008

    • Author(s)
      駒田和良、神田崇、鳥越幹二郎、酒井健一、酒井秀樹、阿部正彦
    • Organizer
      2008 年度 色材協会研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Final Research Report
  • [Presentation] チタニアの光触媒活性に及ぼす結晶子サイズ・比表面積の影響2008

    • Author(s)
      石坂淳一、酒井俊郎、土屋好司、遠藤健司、酒井健一、酒井秀樹、阿部正彦
    • Organizer
      第61 回コロイドおよび界面化学討論会
    • Place of Presentation
      福岡
    • Related Report
      2008 Final Research Report
  • [Presentation] Room Temperature Synthesis of Crystalline Mesoporous Titania Using Cationic Gemini-Type Surfactants as Structure Directing Agent2008

    • Author(s)
      Hideki Sakai, Hirobumi Shibata, Hisashi Mihara, Takeshi Endo, Koji Tsuchiya, Kazuyuki Tsubone, Kazutami Sakamoto, Toshio Sakai, Masahiko Abe
    • Organizer
      7th International Symposium on Surfactants in Solution
    • Place of Presentation
      Berlin
    • Related Report
      2008 Final Research Report
  • [Presentation] ジェミニ型界面活性剤を用いた結晶性壁膜を有するメソポーラスチタニアの室温合成2007

    • Author(s)
      三原尚、酒井俊郎、柴田裕史、坪根和幸、酒井健一、大久保貴広、酒井秀樹、阿部正彦
    • Organizer
      第60 回コロイドおよび界面化学討論会
    • Place of Presentation
      松本
    • Year and Date
      2007-09-20
    • Related Report
      2008 Final Research Report
  • [Presentation] 貴金属/チタニア コア/シェルナノ粒子の調製とフォトクロミック特性2007

    • Author(s)
      酒井秀樹、神田崇、鳥越幹二郎、酒井俊郎、阿部正彦
    • Organizer
      色材協会創立80 周年記念会議
    • Place of Presentation
      東京
    • Year and Date
      2007-09-14
    • Related Report
      2008 Final Research Report
  • [Presentation] Direct synthesis of Nanoporous Titania Bearing Crystalline Wall Type Surfactants2007

    • Author(s)
      Hideki Sakai, Hirobumi Shibata, Takahiro Ohkubo, Toshio Sakai, Masahiko Abe
    • Organizer
      The 15th International Conference on Composites /Nano Engineering
    • Place of Presentation
      海南、中華人民共和国
    • Year and Date
      2007-07-18
    • Related Report
      2008 Final Research Report
  • [Presentation] Direct Synthesis of Nanoporous Titania Bearing Crystalline Wall2007

    • Author(s)
      Hideki SAKAI, Hirobumi Shibata, Takahiro Ohkubo, Toshio Sakai, Masahiko Abe
    • Organizer
      ICCE-15(International Conference on Composite/Nano Engineering)
    • Place of Presentation
      中華人民共和国・海南市
    • Year and Date
      2007-07-18
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高分散な貴金属/チタニア-コア/シェル型ナノ粒子の調製2006

    • Author(s)
      神田崇、大久保貴広、酒井秀樹、阿部正彦
    • Organizer
      第59回コロイドおよび界面化学討論会
    • Place of Presentation
      札幌
    • Related Report
      2008 Final Research Report
  • [Remarks] 2008年度色材協会研究発表会ポスター賞駒田和良、神田 崇、鳥越幹二郎、酒井健一、酒井秀樹、阿部正彦ω-チオール修飾カチオン界面活性剤を利用した金/チタニア-コア/シェル型ナノ粒子の調製

    • Related Report
      2008 Final Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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