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Fabrication of Highly Functional Potassium Niobate Piezoelectric Thin Films and Its Application to Wide-Band Low-Loss Surface Acoustic Wave Filters

Research Project

Project/Area Number 18560302
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionUniversity of Yamanashi

Principal Investigator

KAKIO Shoji  University of Yamanashi, Department of Research Interdisciplinary Graduate School of Medicine and Engineering, Associate Professor (70242617)

Co-Investigator(Kenkyū-buntansha) NAKAGAWA Yasuhiko  University of Yamanashi, Department of Research Interdisciplinary Graduate School of Medicine and Engineering, Professor (50006277)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,620,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥420,000)
Fiscal Year 2007: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2006: ¥1,800,000 (Direct Cost: ¥1,800,000)
Keywordspotassium niobate / RF-sputtering / surface acoustic wave / SAW filter / epitaxial growth / piezoelectric thin film / oriented KN thin film / poling
Research Abstract

Potassium niobate KNbO_3 (KN) is a promising material for realizing wide-band surface acoustic wave (SAW) filters owing to its large piezoelectric constant. However, it is difficult to grow a large KN single crystal due to the occurrence of several phase transitions. The objects of this study are the epitaxial growth of KN films on LiNbO_3 (LN) substrates and its application to the wide-band and low-loss SAW filters. In this project, the RF-sputtering conditions necessary for obtaining a highly oriented KN thin film, the formation of the epitaxial plane on LN substrate, and the SAW properties on KN/LN structure were investigated.
1. The KN thin films were deposited on MgO substrate using several types of target In single-target sputtering with a mixture target of KN:K_2CO_3, as the substrate temperature was decreased, although the K/Nb ratio increased and the (220)-plane spacing approached that of orthorhombic bulk KN, the orientation deteriorated. Using a single K-rich target, K_5NbO_x, a highly (110)-oriented KN thin film with a K/Nb ratio of 0.40 and a (220)-plane spacing near that of orthorhombic bulk KN was obtained by increasing the RF power applied to the O_2-radical source. Moreover, a multigrain structure on the deposited thin films was observed by atomic force microscopy. The displacement current in the oriented KN thin film was observed when an electric field was applied to the interdigital transducer formed on the thin film. This indicates the existence of spontaneous polarization.
2. By utilizing L_i_2O out-diffusion technique, an epitaxial plane with a plane spacing close to the (200)-plane spacing of orthorhombic bulk KN was formed on Y-cut LN substrate.
3. The analytical results showed that the coupling factor of 35% for a Rayleigh SAW and zero-attenuation for a leaky SAW are obtained on certain cuts of the KN/LN structure.

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (20 results)

All 2008 2007 2006

All Journal Article (6 results) (of which Peer Reviewed: 3 results) Presentation (14 results)

  • [Journal Article] Fabrication and evaluation of highly(110)-oriented potassium niobate thin films prepared by rf-magnetron sputtering2008

    • Author(s)
      Shoji Kakio, Hajime Kurosawa, Tatsunori Suzuki and Yasuhiko Nakagawa
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 3802-3806

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Fabrication and evaluation of highly (110)-oriented potassium niobate thin films prepared by rf-magnetron sputtering2008

    • Author(s)
      Shoji, Kakio, Hajime, Kurosawa, Tatsunori, Suzuki, Yasuhiko, Nakagawa
    • Journal Title

      Jpn. J. Appl. Phys Vol.47, No.5

      Pages: 3802-380

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Evaluation of highly(110)-oriented potassium niobate thin films prepared by rf-magnetron sputtering2008

    • Author(s)
      Shoji Kakio, Hajime Kurosawa, Tatsunori Suzuki and Yasuhiko Nakagawa
    • Journal Title

      Jpn. J. Appl. Phys. 47(掲載決定)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly(110)-oriented potassium niobate thin films prepared by RF-magnetron sputtering2007

    • Author(s)
      Shoji Kakio, Hajime Kurosawa, Tatsunori Suzuki and Yasuhiko Nakagawa
    • Journal Title

      Proceedings of 2007 IEEE International UItrasonics Symposium

      Pages: 1405-1408

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] KNbO_3/LiNbO_3構造における弾性表面波伝搬特性の解析2006

    • Author(s)
      鈴木 辰徳, 黒沢 元, 梅田 直樹, 垣尾 省司, 中川 恭彦
    • Journal Title

      日本音響学会2006年秋期研究発表会講演論文集

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fabrication and evaluation of potassium niobate thin-film by RF sputtering2006

    • Author(s)
      Tatsunori Suzuki, Hajime Kurosawa, Shoji Kakio, Yasuhiko Nakagawa
    • Journal Title

      Proceeding of The 27th Symposium on ULTRASONIC ELECTRONICS

    • Related Report
      2006 Annual Research Report
  • [Presentation] Highly(110)-oriented potassium niobate thin films prepared by RF-magnetron sputtering2007

    • Author(s)
      Shoji Kakio, Hajime Kurosawa, Tatsunori Suzuki and Yasuhiko Nakagawa
    • Organizer
      2nd Japan-Taiwan Workshop on Future Frequency Control Devices
    • Place of Presentation
      淡水大学・台湾
    • Year and Date
      2007-12-05
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Highly (110)-oriented potassium niobate thin films prepared by rf-magnetron sputtering2007

    • Author(s)
      Shoji, Kakio, Hajime, Kurosawa, Tatsunori, Suzuki, Yasuhiko, Nakagawa
    • Organizer
      2nd Japan-Taiwan Workshop on Future Frequency Control Devices Tam Kang University
    • Place of Presentation
      Taiwan
    • Year and Date
      2007-12-05
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication and evaluation of highly oriented potassium niobate thin films prepared by RF-magnetron sputtering,2007

    • Author(s)
      Hajime Kurosawa, Tatsunori Suzuki, Shoji Kakio and Yasuhiko Nakagawa
    • Organizer
      Proceedings of The 28th Symposium on Ultrasonic Electronics, 2-01P-05, pp.203-204.
    • Place of Presentation
      つくば国際会議場・つくば市
    • Year and Date
      2007-11-15
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication and evaluation of highly oriented potassium niobate thin films prepared by RF-magnetron sputtering2007

    • Author(s)
      Hajime, Kurosawa, Tatsunori, Suzuki, Shoji, Kakio, Yasuhiko, Nakagawa
    • Organizer
      Proceedings of The 28th Symposium on Ultrasonic Electronics
    • Place of Presentation
      Tsukuba Congress Center, Tsukuba
    • Year and Date
      2007-11-15
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication and evaluation of highly oriented potassium niobate thin films prepared by RF-magnetron sputtering2007

    • Author(s)
      Hajime Kurosawa, Tatsunori Suzuki, Shoji Kakio and Yasuhiko Nakagawa
    • Organizer
      The 28th Symposium on ULTRASONIC ELECTRONICS
    • Place of Presentation
      つくば国際会議場・つくば市
    • Year and Date
      2007-11-15
    • Related Report
      2007 Annual Research Report
  • [Presentation] Highly(110)-oriented potassium niobate thin films prepared by RF-magnetron sputtering2007

    • Author(s)
      Shoji Kakio, Hajime Kurosawa, Tatsunori Suzuki and Yasuhiko Nakagawa,
    • Organizer
      Proceedings of 2007 IEEE International Ultrasonics Symposium, P1G-3, pp.1405-1408.
    • Place of Presentation
      米国・ニューヨーク市
    • Year and Date
      2007-10-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Highly (110)-oriented potassium niobate thin films prepared by rf-magnetron sputtering2007

    • Author(s)
      Shoji, Kakio, Hajime, Kurosawa, Tatsunori, Suzuki, Yasuhiko, Nakagawa
    • Organizer
      Proceedings of 2007 IEEE International Ultrasonics Symposium
    • Place of Presentation
      NY, USA
    • Year and Date
      2007-10-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 高周波スパッタによる高配向KNbO_3薄膜の作製と評価2007

    • Author(s)
      黒沢 元, 鈴木 辰徳, 垣尾 省司, 中川 恭彦,
    • Organizer
      日本音響学会2007年秋期研究発表会講演論文集, 1-10-24, pp.1183-1184.
    • Place of Presentation
      山梨大学・甲府市
    • Year and Date
      2007-09-19
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Growth of highly oriented potassium niobate thin-film by RF sputtering2007

    • Author(s)
      Hajime, Kurosawa, Tatsunori, Suzuki, Shoji, Kakio, Yasuhiko, Nakagawa
    • Organizer
      2007 Autumn Meeting Acoustical Society of Japan
    • Place of Presentation
      University of Yamanashi, Kofu
    • Year and Date
      2007-09-19
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 高周波スパッタによる高配向KNbO_3薄膜の作製と評価2007

    • Author(s)
      黒沢 元, 鈴木 辰徳, 垣尾 省司, 中川 恭彦
    • Organizer
      日本音響学会2007年秋期研究発表会
    • Place of Presentation
      山梨大学・甲府市
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Fabrication and evaluation of potassium niobate thin-film by RF sputtering2006

    • Author(s)
      Tatsunori Suzuki, Hajime Kurosawa, Shoji Kakio and Yasuhiko Nakagawa
    • Organizer
      Proceedings of The 27th Symposium on Ultrasonic Electronics, P2-40, pp.287-288.
    • Place of Presentation
      名古屋国際会議場・名古屋市
    • Year and Date
      2006-11-16
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication and evaluation of potassium niobate thin-film by RF sputtering2006

    • Author(s)
      Tatsunori, Suzuki, Hajime, Kurosawa, Shoji, Kakio, Yasuhiko, Nakagawa
    • Organizer
      Proceedings of The 27th Symposium on Ultrasonic Electronics
    • Place of Presentation
      Nagoya Congress Center, Nagoya
    • Year and Date
      2006-11-16
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] KNbO_3/LiNbO_3構造における弾性表面波伝搬特性の解析2006

    • Author(s)
      鈴木 辰徳, 黒沢 元, 梅田 直樹, 垣尾 省司, 中川 恭彦
    • Organizer
      日本音響学会2006年秋期研究発表会講演論文集, 1-9-13, pp.863-864.
    • Place of Presentation
      金沢大学・金沢市
    • Year and Date
      2006-09-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Analysis of SAW propagation characteristics on KNbO_3/ LiNbO_3 structure2006

    • Author(s)
      Tatsunori, Suzuki, Hajime, Kurosawa, Shoji, Kakio, Yasuhiko, Nakagawa
    • Organizer
      2006 Autumn Meeting Acoustical Society of Japan
    • Place of Presentation
      Kanazawa University, Kanazawa
    • Year and Date
      2006-09-13
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2006-04-01   Modified: 2016-04-21  

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