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Selforganization of Co and Fe nanoparticles in annealing process and their magnetic properties

Research Project

Project/Area Number 18560643
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionYokohama National University

Principal Investigator

TAKEDA Mahoto  Yokohama National University, Dept. Eng., Prof. (30188198)

Co-Investigator(Kenkyū-buntansha) HIROI Zenji  Univ. Tokyo, Inst. Soild State Physics, Prof. (30192719)
SONG Sungyu  Kyushu Univ., HVEM lab., Research associate (50403994)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,650,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥150,000)
Fiscal Year 2007: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2006: ¥3,000,000 (Direct Cost: ¥3,000,000)
Keywordsnano-scale magnetic particles / spontaneous formation / Lorentz Microscopy / SQUID measurement / 磁性微粒子 / 自己組織化過程 / TEM / 磁気特性
Research Abstract

The present study investigated the spontaneous formation of nano-scale cobalt and iron particles in copper matrices, using Lorentz microscopy, high-resolution TEM, EELS analysis and SQUID measurements.
1) Spherical iron, cobalt and iron-cobalt particles are formed at the initial stages of the precipitation. Although the spherical cobalt particles are transformed into cubic particles, iron particles have a less tendency to evolve in the shape, during the annealing.
2) Iron nano-particles also make a pair-wise couplings, but the couplings were more ambiguous than Co pairs. On the contrary, spherical iron-cobalt complex particles are arranged along <100> orientations of copper matrices.
3) The specimens receiving a short annealing shows a cusp at 40K, but they have another cusp around at 120K.
4) Lorentz microscopy shows that the magnetic moment of the particles are oriented to 100 of copper matrices. The magnitudes of the moments are increased with the sizes, but there seem a critical size switching from fcc to bcc in structure.

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (24 results)

All 2008 2007 2006

All Journal Article (11 results) (of which Peer Reviewed: 5 results) Presentation (11 results) Book (2 results)

  • [Journal Article] Cu-Co-Fe合金におけるナノ磁性粒子析出と磁気特性の関係2008

    • Author(s)
      桑田幸作、他
    • Journal Title

      銅及び銅合金技術研究会 論文集 第47巻(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Cu-Co系合金中のCo微粒子の析出過程と磁気特性の関係2008

    • Author(s)
      鶴田陽平、他
    • Journal Title

      銅及び銅合金技術研究会 論文集 第47巻(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Precipitation behavior of magnetic-particles in a Cu-Co-Fe alloy and their Magnetic properties2008

    • Author(s)
      K. Kuwada, M. Takeda, Y. Tsuruta, T. Muramatsu, M. Takeguchi
    • Journal Title

      J. Jap. Inst. of Copper and Copper alloys 17(in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Precipitation behavior of magnetic-particles in a Cu-Co alloy and their Magnetic properties2008

    • Author(s)
      Y. Tsuruta, M. Takeda, N. Wada, K. Kuwada, M. Takeguchi
    • Journal Title

      J. Jap. Inst. of Copper and Copper alloys 17(in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Cu-Co-Fe合金におけるナノ磁性粒子析出と磁気特性の関係2008

    • Author(s)
      桑田幸作
    • Journal Title

      銅及び銅合金 47(掲載予定)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cu-Co系合金中のCo微粒子の析出過程と磁気特性の関係2008

    • Author(s)
      鶴田陽平
    • Journal Title

      銅及び銅合金 47(掲載予定)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cu-Fe合金におけるナノ磁性鉄粒子の析出過程と磁気的特性の関係2007

    • Author(s)
      高松久美子、他
    • Journal Title

      銅及び銅合金技術研究会 論文集 第46巻

      Pages: 36-40

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Relationship between the microstructure and magnetic properties of Nanoscale Fe magnetic particles precipitated in a Cu-Fe alloy2007

    • Author(s)
      K. Takamatsu, M. Takeda, N. Wada, K. Kuwada
    • Journal Title

      J. Jap. Inst. of Copper and Copper alloys 16

      Pages: 36-40

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] History and Logics of Alloy Design2007

    • Author(s)
      M. Takeda, T. Tanabe, K. Hanawa, S. Yamamoto
    • Journal Title

      Muse Corporation

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Cu-Fe合金におけるナノ磁性鉄粒子の析出過程と磁気的特性の関係2007

    • Author(s)
      高松久美子
    • Journal Title

      銅及び銅合金技術研究会 論文集 第46巻

      Pages: 36-40

    • Related Report
      2006 Annual Research Report
  • [Journal Article] "Lorentz Microscopy and Monte-Carlo calculation of Nano-scale particles"2007

    • Author(s)
      N. Wada
    • Journal Title

      Proc. 11th Loius Neel Conference

      Pages: 13-14

    • Related Report
      2006 Annual Research Report
  • [Presentation] Lorentz Microscopy and Monte-Carlo calculation of Nano-scale particles2007

    • Author(s)
      N. Wada, et. al.
    • Organizer
      11th Louis Neel Conference
    • Place of Presentation
      Lyon, FRANCE
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Cu中に形成されたFe微粒子の磁性とローレンツ顕微鏡観察による磁区観察2007

    • Author(s)
      村松鉄平、他
    • Organizer
      第141回日本金属学会秋季講演大会
    • Place of Presentation
      岐阜,岐阜大
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Cu-Co-Fe合金におけるナノ磁性粒子析出と磁気特性の関係2007

    • Author(s)
      桑田幸作、他
    • Organizer
      第47回銅及び銅合金技術研究会講演大会
    • Place of Presentation
      吹田,関西大
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Cu-Co系合金中のCo微粒子の析出過程と磁気特性の関係2007

    • Author(s)
      鶴田陽平、他
    • Organizer
      第47回銅及び銅合金技術研究会講演大会
    • Place of Presentation
      吹田,関西大
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Lorentz Microscopy and Monte-Carlo calculation of Nano-scale particles2007

    • Author(s)
      N, Wada, M.G, Blanchin., M.Takeda., Z, Hiroi
    • Organizer
      lleme Colloque Louis Neel a Lyon
    • Place of Presentation
      Lyon
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Precipitation behavior of magnetic-particles in a Cu-Co-Fe alloy and their Magnetic properties2007

    • Author(s)
      K, Kuwada, M, Takeda, Y, Tsuruta, T, Muramatsu, M, Takeguchi
    • Organizer
      Annual Meeting of Jap. Inst. of Copper and Copper alloys
    • Place of Presentation
      Suita
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Precipitation behavior of magnetic-particles in a Cu-Co alloy and their Magnetic properties2007

    • Author(s)
      Y, Tsuruta, M, Takeda, N, Wada, K, Kuwada, M, Takeguchi
    • Organizer
      Annual Meeting of Jap. Inst. of Copper and Copper alloys
    • Place of Presentation
      Suita
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Lorentz Microscopy of nano-scale magnetic domains formed in a Cu-Fe alloy2007

    • Author(s)
      T, Muramatsu, K, Kuwada, Y, Noeuchi, M, Takeda
    • Organizer
      Annual Meeting of Jap. Inst. of metals
    • Place of Presentation
      Gifu
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Cu中に形成されたFe微粒子の磁性とローレンツ顕微鏡観察による磁区観察2007

    • Author(s)
      村松鉄平
    • Organizer
      日本金属学会141回秋季大会
    • Place of Presentation
      岐阜市・岐阜大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] Cu-Fe合金におけるナノ磁性鉄微粒子の析出過程と磁気特性の関係2006

    • Author(s)
      高松久美子、他
    • Organizer
      第46回銅及び銅合金技術研究会講演大会
    • Place of Presentation
      東京,電通大
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Relationship between the microstructure and magnetic properties of Nanoscale Fe magnetic particles precipitated in a Cu-Fe alloy2006

    • Author(s)
      K, Takamatsu, M, Takeda, N, Wada, K, Kuwada
    • Organizer
      Annual Meeting of Jap. Inst. of Copper and Copper alloys
    • Place of Presentation
      Kunitachi
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 合金論の歴史と論理2007

    • Author(s)
      竹田真帆人、他
    • Total Pages
      253
    • Publisher
      ミューズ・コーポレーション
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 合金論の歴史と論理2007

    • Author(s)
      竹田真帆人
    • Total Pages
      253
    • Publisher
      ミューズ・コーポレーション
    • Related Report
      2006 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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