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Designing guideline of polymeric molecule structure for improving thermoelectric properties

Research Project

Project/Area Number 18560684
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

SHINOHARA Yoshikazu  National Institute for Materials Science, 材料ラボ, グループリーダー (70343853)

Co-Investigator(Kenkyū-buntansha) IMAI Yoshio  独立行政法人物質・材料研究機構, 材料ラボ, 主幹研究員 (40354138)
ISODA Yukihiro  独立行政法人物質・材料研究機構, 材料ラボ, 主任研究員 (80354140)
Project Period (FY) 2006 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥3,550,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥450,000)
Fiscal Year 2008: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2007: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2006: ¥1,600,000 (Direct Cost: ¥1,600,000)
Keywords熱・エネルギー材料 / 熱電エネルギー変換 / 高分子 / 熱電特性 / ポリチオフェン / 有機合成 / ゼーベック係数 / 導電率
Research Abstract

ポリチオフェン系導電性高分子の電気伝導は主鎖分子間伝導が支配的でることを明らかにした。高い熱電特性を有するポリチオフェン系材料を開発するためには、1)主鎖間隔を制御して室温以上の温度域でも最近接間ホッピングを実現すること、2)主鎖分子配向によって単位体積当たりの主鎖密度を高めて高い導電率を実現すること、が必要となる。主鎖分子の配列・配向制御がポリマー系熱電材料実現の鍵になると言える。

Report

(4 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • Research Products

    (38 results)

All 2009 2008 2007 2006

All Journal Article (16 results) (of which Peer Reviewed: 13 results) Presentation (16 results) Book (6 results)

  • [Journal Article] 有機系熱電材料2009

    • Author(s)
      篠原嘉一
    • Journal Title

      機能材料 29

      Pages: 38-42

    • Related Report
      2008 Annual Research Report 2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 共役高分子の熱電効果2008

    • Author(s)
      篠原嘉一
    • Journal Title

      高分子 57

      Pages: 514-517

    • NAID

      10021119725

    • Related Report
      2008 Annual Research Report 2008 Final Research Report
    • Peer Reviewed
  • [Journal Article]2008

    • Author(s)
      篠原嘉一、磯田幸宏、今井義雄
    • Journal Title

      傾斜機能材料論文集 21

      Pages: 49-53

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of synthetic conditions on the thermoelectric properties of polythiophene by electrolytic polymerization2008

    • Author(s)
      Y.Shinohara, K. Hiraishi, Y.Isoda, Y.Imai, H.Oikawa
    • Journal Title

      Proc 9th Inter. Sympo. FGM

      Pages: 628-633

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 高分子系熱電材料の分子構造と熱電特性の関係2008

    • Author(s)
      篠原嘉一, 磯田幸宏, 今井義雄
    • Journal Title

      傾斜機能材料論文集 21

      Pages: 49-53

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Challenge of Polymer Thermoelectric Materials as Ecomaterials2007

    • Author(s)
      Y.Shinohara, Y.Isoda, Y.Imai, K.Hiraishi, H.Oikawa
    • Journal Title

      Materials Science Forum 539-543

      Pages: 2329-2332

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] ラティスに着目した鉄シリサイド系熱電材料の開発2007

    • Author(s)
      篠原嘉一
    • Journal Title

      J. JAPAN INSTITUTE OF METALS 71

      Pages: 869-875

    • NAID

      10019955397

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] FGMレーザー素子の概念2007

    • Author(s)
      篠原嘉一
    • Journal Title

      傾斜機能材料論文集 20

      Pages: 159-166

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A NEW CHALLENGE OF POLYMER THERMOELECTRIC MATERIALS AS ECOMATERIALS2007

    • Author(s)
      Y. SHINOHARA, Y. IMAI, Y. ISODA, K. HIRAISHI, H. NAKANISHI
    • Journal Title

      MATERIALS SCIENCE FORUM 539-543

      Pages: 2329-2332

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ラティスに着目した鉄シリサイド系熱電材料の開発2007

    • Author(s)
      篠原 嘉一
    • Journal Title

      JOURNAL OF THE JAPAN INSTITUTE OF METALS 71

      Pages: 869-875

    • NAID

      10019955397

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] FGMレーザー素子の概念2007

    • Author(s)
      篠原 嘉一
    • Journal Title

      傾斜機能材料論文集 20

      Pages: 159-166

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Challenge of Polymer Thermoelectric Materials as Ecomaterials2007

    • Author(s)
      Y.Shinohara, Y.Isoda, Y.Imai, K.Hiraiahsi, H.Oikawa
    • Journal Title

      Materials Science Forum 539-543

      Pages: 2329-2332

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Thermoelectric Properties of Structure Controlled Polythiophene2006

    • Author(s)
      Y.Shinohara, K. Hiraishi, Y.Isoda, Y.Imai, H.Oikawa
    • Journal Title

      Proc. 7th Inter. Confer. Ecobalance

      Pages: 685-686

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] エネルギーデバイス用エコマテリアルの開発2006

    • Author(s)
      篠原嘉一
    • Journal Title

      工業材料 54(11)

      Pages: 40-43

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of synthetic conditions on the thermoelectric properties of polythiophene by electrolytic polymerization2006

    • Author(s)
      Y.Shinohara, K.Hiraiahsi, Y.Isoda, Y.Imai, H.Oikawa
    • Journal Title

      Proc 9^<th> International Symposium FGM (in printing)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Thermoelectric Properties of Structure Controlled Polythiophene2006

    • Author(s)
      Y.Shinohara, K.Hiraiahsi, Y.Isoda, Y.Imai, H.Oikawa
    • Journal Title

      Proc 9^<th> International Conference Ecobalance

      Pages: 685-686

    • Related Report
      2006 Annual Research Report
  • [Presentation] 共役高分子の熱電効果と展望2008

    • Author(s)
      篠原嘉一
    • Organizer
      日本化学会高分子コロキュウム
    • Place of Presentation
      山形大学、米沢、日本
    • Year and Date
      2008-11-21
    • Related Report
      2008 Final Research Report
  • [Presentation] Prospect of YAG Laser Medium for Laser Space Solar Power System2008

    • Author(s)
      Y.Shinohara, H.Suzuki, K.Kisara
    • Organizer
      0th Inter. Sympo. Functionally Graded Materials
    • Place of Presentation
      Sendai International Center, Sendai, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] Mg2Si-Sn系熱電材料におけるLi添加の影響2008

    • Author(s)
      多田智紀, 磯田幸宏, 永井貴寛, 藤生博文, 今井義雄, 篠原嘉一
    • Organizer
      日本熱電学会学術講演会
    • Place of Presentation
      早稲田大学、東京、日本
    • Related Report
      2008 Final Research Report
  • [Presentation] What are key points for creating thermoelectrci functions?2008

    • Author(s)
      Y.Shinohara
    • Organizer
      NIMS Conference 2008
    • Place of Presentation
      Tsukuba International Congress Center, Tsukuba, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] 共役高分子の熱電効果と展望2008

    • Author(s)
      篠原嘉一
    • Organizer
      日本化学会高分子コロキュウム
    • Place of Presentation
      山形大学,米沢,日本
    • Related Report
      2008 Annual Research Report
  • [Presentation] What are key points for creating thermoelectrci functions?2008

    • Author(s)
      Y. SHINOHARA
    • Organizer
      NIMS Conference 2008
    • Place of Presentation
      つくば国際会議場,つくば,日本
    • Related Report
      2008 Annual Research Report
  • [Presentation] Mg2Si-Sn系熱電材料におけるLi添加の影響2008

    • Author(s)
      多田智紀, 磯田幸宏, 永井貴寛, 藤生博文, 今井義雄, 篠原嘉一
    • Organizer
      日本熱電学会学術講演会
    • Place of Presentation
      早稲田大学,東京,日本
    • Related Report
      2008 Annual Research Report
  • [Presentation] Prospect of YAG Laser Medium for Laser Space Solar Power System2008

    • Author(s)
      Y. SHINOHARA, H. SUZUKI, K. KISARA
    • Organizer
      第10回傾斜機能材料国際会議
    • Place of Presentation
      仙台国際センター,仙台,日本
    • Related Report
      2008 Annual Research Report
  • [Presentation] Molecular Structure and Thermoelectric Properties of Polythiophene Series2007

    • Author(s)
      Y.Sinohara, Y.Isoda, Y.Imai
    • Organizer
      第18回日本MRS学術シンポジウム
    • Place of Presentation
      日本大学、東京、日本
    • Related Report
      2008 Final Research Report
  • [Presentation] 高分子系熱電材料の分子構造と熱電特性の関係2007

    • Author(s)
      篠原嘉一、磯田幸宏、今井義雄
    • Organizer
      第19回傾斜機能材料シンポジウム
    • Place of Presentation
      (独)物質・材料研究機構、つくば、日本
    • Related Report
      2008 Final Research Report
  • [Presentation] Thermoelectric Properties of Polythiophene : Related to Conduction Mechanism2007

    • Author(s)
      Y.Shinohara, Y.Imai, Y.Isoda, K.Hiraishi, H.Oikawa, H.Nakanishi
    • Organizer
      The Doyama Symposium on Advanced Materials
    • Place of Presentation
      Univ.Tokyo, Tokyo, Japan
    • Related Report
      2008 Final Research Report
  • [Presentation] The effect of Carreir Conduction between Main Chains on Thermoelectric Properties of Polythiophene2007

    • Author(s)
      Y.Shinohara, Y.Imai, Y.Isoda, K.Hiraishi, H.Oikawa, H.Nakanishi
    • Organizer
      26th Inter. Confer. Thermoelectrics
    • Place of Presentation
      hineville Luxury Resort,Jeju island, Korea
    • Related Report
      2008 Final Research Report
  • [Presentation] Molecular Structure and Thermoelectric Properties of Polythiophene Series2007

    • Author(s)
      Y. SHINOHARA, Y. ISODA, Y. TMAT
    • Organizer
      第18回日本MRS学術シンポジウム
    • Place of Presentation
      日本大学,東京,日本
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高分子系熱電材料の分子構造と熱電特性の関係2007

    • Author(s)
      Y. SEINOHARA, Y. ISODA, Y. IMAI
    • Organizer
      第19回傾斜機能材料シンポジウム
    • Place of Presentation
      日本大学,東京,日本
    • Related Report
      2007 Annual Research Report
  • [Presentation] Thefmoelectric Properties of Polythiophene:Related to Conducもion Mechanism2007

    • Author(s)
      Y. SHINOHARA, Y. IMAI, Y. ISODA, K. HIRAISHI, H. OIKAWA, H. NAKANISHI
    • Organizer
      The Doyama Symposium on Advanced Materials
    • Place of Presentation
      東京大学,東京,日本
    • Related Report
      2007 Annual Research Report
  • [Presentation] The effect of Carreir Conduction between Main Chains on Thermoelectric Properties of Polythiophene2007

    • Author(s)
      Y. SHINOHARA, Y. IMAI, Y. ISODA, K. HIRAISHI, H. OIKAWA, H. NAKANISHI
    • Organizer
      第26回熱電変換国際会議
    • Place of Presentation
      Shineville Luxury Resort,Jeju island,Korea
    • Related Report
      2007 Annual Research Report
  • [Book] 有機熱電変換材料の合成、熱電変換技術ハンドブック2008

    • Author(s)
      篠原嘉一
    • Publisher
      NTS
    • Related Report
      2008 Final Research Report
  • [Book] 熱電変換技術ハンドブック2008

    • Author(s)
      篠原嘉一
    • Total Pages
      5
    • Publisher
      NTS
    • Related Report
      2008 Annual Research Report
  • [Book] 熱電変換システムの高効率化に向けた材料・設計の最適化とその応用技術2006

    • Author(s)
      篠原嘉一
    • Publisher
      技術情報協会
    • Related Report
      2008 Final Research Report 2006 Annual Research Report
  • [Book] 電気学会技術報告-10422006

    • Author(s)
      篠原嘉一
    • Total Pages
      5
    • Publisher
      電気学会
    • Related Report
      2008 Final Research Report
  • [Book] エネルギーデバイス用エコマテリアルの開発2006

    • Author(s)
      篠原嘉一
    • Total Pages
      4
    • Publisher
      日刊工業新聞社
    • Related Report
      2006 Annual Research Report
  • [Book] 電気学会技術報告,10422006

    • Author(s)
      篠原嘉一
    • Total Pages
      5
    • Publisher
      電気学会
    • Related Report
      2006 Annual Research Report

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Published: 2006-04-01   Modified: 2016-04-21  

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