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Organo-functionalization of Mesoporous Silica by Hydrosilylation Reaction

Research Project

Project/Area Number 18560743
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionTeikyo University of Science & Technology

Principal Investigator

KUGITA Tsuyoshi  Teikyo University of Science & Technology, Department of Environmental Science, Associate Professor (80225127)

Co-Investigator(Kenkyū-buntansha) NAMBA Seitaro  Waseda University, School of Science and Engineering, Visiting Lecturer (80114883)
Project Period (FY) 2006 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥4,010,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥510,000)
Fiscal Year 2007: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2006: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsFunctionalization / MCM-41 / Mesoporous molecular sieve / Hydrosilylation / phenylsulforic acid / 固体酸触媒 / エステル化 / 固体酸 / 触媒反応
Research Abstract

The organic functionalized mesoporous molecular sieves such as MCM-41 have received much attention in terms of the application of such materials in the fields of catalysis and adsorption. We previously reported that the Si-H bond was introduced onto the surface of MCM-41 with high density, HSi-MCM-41, and hydrosilylation reactions of HSi-MCM-41 with olefins such as styrene were also carried out to obtain MCM-41 with organic group connected via Si-C bond which have a good stability. The ordered hexagonal structure is maintained during these process. Since Si-H bond react with an equivalent molar of carbon-carbon double bond, the organic group introduced by hydrosilylation reaction expected to exist in high density. In this work, MCM-41 functionalized with sulfonic and carboxyl group were synthesized by the hydrosilylation reaction of HSi-MCM-41 with styrene and methyl acrylate followed by sulfonation and hydrolysis process, respectively. The acidic capacities for resulting solid acids were determined by the acid-base titration.
MCM-41 functionalized with sulfonic and carboxyl group were synthesized by the hydrosilylation reaction of H-Si bond introduced MCM-41 with styrene and methyl acrylate followed by sulfonation and hydrolysis, respectively. The organic groups introduced by this method were connected to the surface of MCM-41 via Si-C bond, hence, had higher hydrothermal stability comparison with those introduced by the silane coupling method. The acidic capacities for resulting solid acids were determined by the acid-base titration

Report

(3 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • Research Products

    (34 results)

All 2008 2007 2006 2000

All Journal Article (9 results) (of which Peer Reviewed: 3 results) Presentation (25 results)

  • [Journal Article] Re-examination of the Photochemical Reaction of Octaisopropylcyclotetragermane2007

    • Author(s)
      釘田 強志
    • Journal Title

      J. Organomet. Chem. 692

      Pages: 2855-2860

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Activity of Zeolites for Synthesis Reaction of Methylenediamine from Aniline and Formaldehyde2006

    • Author(s)
      T.Kugita
    • Journal Title

      Catalysis Today 111

      Pages: 275-279

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Introduction of Si-H bond onto the surface of mesoporous molecular sieves and functionalization by hydrosilylation reaction2006

    • Author(s)
      T.Kugita
    • Journal Title

      Chemistry Letter 2006

      Pages: 906-907

    • NAID

      10018187769

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Catalytic Activity of Zeolites for Synthesis Reaction of Methylenediamine from Aniline and Formaldehyde2006

    • Author(s)
      T. Kugita S. Hirose, S. Namba
    • Journal Title

      Catalysis Today 111

      Pages: 275-279

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Introduction of Si-H bond onto the surface of meso-porous molecular sieves and functionalization by hydrosilylation reaction2006

    • Author(s)
      T. Kugita, H. Higuchi
    • Journal Title

      Chemistry Letter 2006

      Pages: 906-907

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Selective Synthesis of di-tert-butylperoxide catalyzed by Highly Active Microporous H-beta Zeolite2006

    • Author(s)
      S.Jana, M.Nakamura, T.Kugita, S.Namba
    • Journal Title

      Appl. Catal. A : Gen 313

      Pages: 101-101

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Introduction of Si-H Bond onto the surface of Mesoporous Molecular Sieves and Functionalization by Hydrosilylation Reaction2006

    • Author(s)
      T.Kugita, H.Higuchi
    • Journal Title

      Chem. Lett. 35

      Pages: 906-906

    • NAID

      10018187769

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Catalytic Activity of Zeolites for Synthesis Reaction of Methylenedianiline from Aniline and Formaldehyde2006

    • Author(s)
      T.Kugita, S.Hirose, S.Namba
    • Journal Title

      Catalysis Today 111

      Pages: 275-275

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Ion Pairing of Electrochemically Generated Fluorenyl Anions with Tetraalkylammonium Counter Cations, 74, 49-52 (2006).2006

    • Author(s)
      M Okano, T.Hino, T.Kugita
    • Journal Title

      Electrochemistry 74

      Pages: 49-49

    • Related Report
      2006 Annual Research Report
  • [Presentation] ヒドロシリル化反応を用いたMCM-41へのアミノ基の導入2008

    • Author(s)
      飯島 樹一
    • Organizer
      第101回触媒討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 酸性ならびに塩基性有機ケイ素デンドリマーの合成2008

    • Author(s)
      大原 三佳
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 酸性ならびに塩基性有機ケイ素デンドリマーの合成2008

    • Author(s)
      大原三佳, 釘田強志
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] アルキル基導入によるMCM-41細孔内の疎水性制御2008

    • Author(s)
      釘田 強志
    • Organizer
      第8回GSCNシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2008-03-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Control of hydrophobicity of MCM-41 pores by introducing alkyl groups2008

    • Author(s)
      T. kugita, et. al.
    • Organizer
      The 8th GSCN Symp.
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2008-03-06
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] アルキル基導入によるMCM-41細孔内の疎水性制御2008

    • Author(s)
      丸山浩二, 大原三佳, 釘田強志
    • Organizer
      GSCNシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2008-03-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヒドロシリル化によるMCM-41細孔内の疎水化2007

    • Author(s)
      釘田 強志
    • Organizer
      第37回石油・石油化学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-10-25
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Hydrophobicitization of MCM-41 pores by hydrosilylation2007

    • Author(s)
      T. Kugita, et. al.
    • Organizer
      The 37th Petroleum petrochemical Symp.
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2007-10-25
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ヒドロシリル化によるMCM-41細孔内の疎水化2007

    • Author(s)
      釘田強志, 丸山浩二, 飯島樹一
    • Organizer
      石油学会
    • Place of Presentation
      札幌
    • Year and Date
      2007-10-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] ヒドロシリル化によるMCM-41への塩基性有機基の導入2007

    • Author(s)
      飯島 樹一
    • Organizer
      第100回触媒討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-09-19
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Introduction of basic organo-group onto MCM-41 by hydrosilylation2007

    • Author(s)
      J. Iijima, et. al.
    • Organizer
      The 100th CSJMeeting
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2007-09-19
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ヒドロシリル化によるMCM-41への塩基性有機基の導入2007

    • Author(s)
      飯島樹一, 釘田強志
    • Organizer
      触媒討論会
    • Place of Presentation
      札幌
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Functionalization of Mesoporous Molecular Sieves by Hydrosilylation Reaction2007

    • Author(s)
      釘田強志, 観音寺功三
    • Organizer
      EUROPACAT
    • Place of Presentation
      Truku, Finland
    • Year and Date
      2007-08-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Functionalization of Mesoporous Molecular Sieves by Hydrosilylation Reaction2007

    • Author(s)
      T.Kugita
    • Organizer
      EUROPACAT VIII
    • Place of Presentation
      Turku,Finland
    • Year and Date
      2007-08-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Functionalization of mesoporous molecular sieves by hydrosilylation reaction2007

    • Author(s)
      T. Kugita, et. al.
    • Organizer
      EUROPACAT VIII
    • Place of Presentation
      Turku, Finland
    • Year and Date
      2007-08-28
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Introduction of amino-group onto MCM-41 by hydrosilylation2007

    • Author(s)
      Iijima, et. al.
    • Organizer
      The 101th CSJMeeting
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2007-03-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ヒドロシリル化反応を用いたMCM-41の有機修飾2007

    • Author(s)
      飯島 樹一
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2007-03-25
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Organomodification of MCM-41 by hydrosilylation2007

    • Author(s)
      J. Iijima, et. al.
    • Organizer
      The 87th Spring meeting, CSJ
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2007-03-25
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ハイドロシリレーションにより有機修飾したMCM-41への酸点の導入2006

    • Author(s)
      観音寺 功三
    • Organizer
      日本化学会第86春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2006-09-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ヒドロシリル化反応で有機修飾したMCM-41の水熱安定性と触媒活性2006

    • Author(s)
      観音寺 功三
    • Organizer
      第98回触媒討論会
    • Place of Presentation
      富山
    • Year and Date
      2006-09-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Hydrothermal stability and catalytic activity of organomodified MCM-41 by hydrosilylation2006

    • Author(s)
      K. Kannonji, et. al.
    • Organizer
      The 98th CSJMeeting
    • Place of Presentation
      Toyama, Japan
    • Year and Date
      2006-09-28
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Functionaliztion of MCM-41 by Hydrosilylation Reaction2006

    • Author(s)
      K.Kannonji
    • Organizer
      The 5th International Mesostructured Material Symposium
    • Place of Presentation
      Shanghai,China
    • Year and Date
      2006-08-05
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Functionaliztion of MCM-41 by hydrosilylation reaction2006

    • Author(s)
      K. Kannonji, et. al.
    • Organizer
      The 5th International Mesostructured Material Symposium
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2006-08-05
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Introduction of acid sites onto MCM-41 organomodified by hydrosilylation2006

    • Author(s)
      K. Kannonji, et. al.
    • Organizer
      The 86th Spring meeting, CSJ
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2006-03-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Synthesis of carbo-silane dendrimer with acid and base group2000

    • Author(s)
      M. Ohara, et. al.
    • Organizer
      The 88th Spring meeting, CSJ
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2000-03-27
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2006-04-01   Modified: 2016-04-21  

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