Innovative Porphyrin Synthesis Based on Transition Metal Catalysis

• Project/Area Number: 18685013
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Synthetic chemistry
• Research Institution: Nagoya University (2008); Kyoto University (2006-2007)
• Principal Investigator: SHINOKUBO Hiroshi Nagoya University, 大学院・工学研究科, 教授 (50281100)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥30,030,000 (Direct Cost: ¥23,100,000、Indirect Cost: ¥6,930,000); Fiscal Year 2008: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000); Fiscal Year 2007: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000); Fiscal Year 2006: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
• Keywords: 遷移金属触媒 / ポルフィリン / 炭素-水素結合活性化 / 炭素-炭素結合生成 / 機能性色素 / ビラジカル / 非線形光学材料 / 遷移金属 / π共役系 / 触媒 / パラジウム / クロスカップリング / 大環状化合物 / 一重項酸素 / 光酸化 / アルキン

Research Abstract

ポルフィリンは光合成中心やヘムなどの要素として天然に広く存在する色素である。また、光学材料や電子材料などへの応用も期待される。本研究では、遷移金属触媒反応を活用することによって、新規ポルフィリンを高効率に合成する手法を開発した。これにより、従来法では合成できなかったような斬新な構造をもつポルフィリン系分子を創成することに成功した。さらに、単に新しい分子を合成しただけでなく、その興味深い性質や機能性を明らかにした。

Research Products

• [Journal Article] Functionalization of BODIPY Dyes through Iridium and Rhodium Catalyses: A Complementary Approach to α- and β-Substituted BODIPYs (2009)
  • Author(s): J. Chen, M. Mizumura, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Eur. J. 15 Pages: 5924-5949
  • Peer Reviewed
• [Journal Article] Regioselective Nucleophilic Pyridination of a Doubly Linked Biscorrole (2009)
  • Author(s): S. Hiroto, N. Aratani, N. Shibata, Y. Higuchi, T. Sasamori, N. Tokitoh, H. Shinokubo, A. Osuka, Zwitterionic Corrole
  • Journal Title: Angew. Chem., Int. Ed. 48 Pages: 2388-2390
  • Peer Reviewed
• [Journal Article] Marriage of Porphyrin Chemistry with Metal-Catalysed Reactions (2009)
  • Author(s): H. Shinokubo A. Osuka
  • Journal Title: Chem. Commun. Pages: 1011-1021
  • Peer Reviewed
• [Journal Article] Synthesis of Norbornane-Bridged Diporphyrins via Pd-Catalyzed [3 + 2] Annulation Strategy (2009)
  • Author(s): M. Mizumura, H. Shinokubo, A. Osuka
  • Journal Title: Synthesis Pages: 59-61
  • Peer Reviewed
• [Journal Article] Functionalization of BODIPY Dyes through Iridium and Rhodium Catalyses : A Complementary Approach to α- and β-Substituted BODIPYs (2009)
  • Author(s): Jinping Chen
  • Journal Title: Chem. Eur. J 15(印刷中)
  • Peer Reviewed
• [Journal Article] Zwitterionic Corrole : Regioselective Nucleophilic Pyridination of a Doubly Linked Biscorrole (2009)
  • Author(s): Satoru Hiroto
  • Journal Title: Angew. Chem., Int. Ed 48 Pages: 2388-2390
  • Peer Reviewed
• [Journal Article] Synthesis of Directly and Doubly Linked Dioxoisobacteriochlorin Dimers (2008)
  • Author(s): S. Hiroto, I. Hisaki, H. Shinokubo, A. Osuka
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 16172-16173
  • Peer Reviewed
• [Journal Article] Photoelectrochemical Properties of Doubly β-Functionalized Porphyrin Sensitizers for Dye-Sensitized Nanocrystalline-TiO2 Solar Cells (2008)
  • Author(s): J. K. Park, H. R. Lee, J. Chen, H. Shinokubo, A. Osuka, D. Kim
  • Journal Title: J. Phys. Chem. C 112 Pages: 16691-16699
  • Peer Reviewed
• [Journal Article] 2,5-Thienylene- Bridged Triangular and Linear Porphyrin Trimers (2008)
  • Author(s): J. Song, S. Y. Jang, S. Yamaguchi, J. Sankar, S. Hiroto, N. Aratani, J.-Y. Shin, S. Easwaramoorthi, K. S. Kim, D. Kim, H. Shinokubo, A. Osuka
  • Journal Title: Angew. Chem., Int. Ed. 47 Pages: 6004-6007
  • Peer Reviewed
• [Journal Article] Synthesis of Novel Chiral Porphyrins through Pd-Catalyzed [3 + 2] Annulation and Heterochiral Self-Assembling to Form Heterodimers (2008)
  • Author(s): M. Mizumura, H. Shinokubo, A. Osuka
  • Journal Title: Angew. Chem., Int. Ed. 47 Pages: 5387-5381
  • Peer Reviewed
• [Journal Article] Efficient Rhodium-Catalyzed Installation of Unsaturated Ester Functions onto Porphyrins: Site-Specific Heck-Type Addition versus Conjugate Addition (2008)
  • Author(s): H. Baba, J. Chen, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Eur. J. 14 Pages: 4256-4262
  • Peer Reviewed
• [Journal Article] Highly selective Ir-catalyzed direct borylation of peripheral aromatic substituents on hexakisaryl- substituted [28]hexaphyrins(1.1.1.1.1.1) (2008)
  • Author(s): G. Mori, H. Shinokubo, A. Osuka
  • Journal Title: Tetrahedron Lett. 49 Pages: 2170-2172
  • Peer Reviewed
• [Journal Article] Dimeric Assemblies from 1,2,3-Triazole-Appended Zn(II) Porphyrins with Control of NH-Tautomerism in 1,2,3-Triazole (2008)
  • Author(s): C. Maeda, S. Yamaguchi, C. Ikeda, H. Shinokubo, A. Osuka
  • Journal Title: Org. Lett. 10 Pages: 549-552
  • Peer Reviewed
• [Journal Article] Synthesis of Directly and Doubly Linked Dioxoisobacteriochlorin Dimers (2008)
  • Author(s): Satoru Hiroto
  • Journal Title: J. Am. Chem. Soc 130 Pages: 16172-16173
  • Peer Reviewed
• [Journal Article] Synthesis of Novel Chiral Porphyrins through Pd-Catalyzed [3+2] Annulation and Heterochiral Self-Assembling to Form Heterodimers (2008)
  • Author(s): Masatoshi Mizumura
  • Journal Title: Angew. Chem., Int. Ed 47 Pages: 5387-5381
  • Peer Reviewed
• [Journal Article] Efficient Rhodium-Catalyzed Installation of Unsaturated Ester Functions onto Porphyrins : Site-Specific Heck-Type Addition versus Conjugate Addition (2008)
  • Author(s): Hiromi Baba
  • Journal Title: Chem. Eur. J 14 Pages: 4256-4262
  • Peer Reviewed
• [Journal Article] Dimeric Assemblies from 1,2,3-Triazole-Appended Zn(II) Porphyrins with Control of NH-Tautomerism in 1,2,3-Triazole (2008)
  • Author(s): C. Maeda
  • Journal Title: Org. Lett. 10 Pages: 549-552
  • Peer Reviewed
• [Journal Article] Highly selective Ir-catalyzed direct borylation of peripheral aromatic substituents on hexakisaryl-substituted [28] hexaphyrins(1.1.1.1.1.1) (2008)
  • Author(s): G. Mori
  • Journal Title: Tetrahedron Lett. 49 Pages: 2170-2172
  • Peer Reviewed
• [Journal Article] Synthesis of meso-5-Azaindolyl Appended Zn(II) Porphyrins via Pd-Catalyzed Annulation (2007)
  • Author(s): C. Maeda, H. Shinokubo, A. Osuka
  • Journal Title: Org. Lett. 9 Pages: 2493-2496
  • Peer Reviewed
• [Journal Article] Synthesis of Doubly β-to-β 1,3-Butadiyne-Bridged Diporphyrins: Enforced Planar Structures and Large Two-photon Absorption Cross Sections (2007)
  • Author(s): I. Hisaki, S. Hiroto, K. S. Kim, S. B. Noh, D. Kim, H. Shinokubo, A. Osuka
  • Journal Title: Angew. Chem., Int. Ed. 46 Pages: 5125-5128
  • Peer Reviewed
• [Journal Article] Regioselective Borylation of Porphyrins via C-H Bond Activation under Iridium Catalysis That Affords Useful Building Blocks for Porphyrin Assemblies (2007)
  • Author(s): H. Hata, S. Yamaguchi, G. Mori, S. Nakazono, T. Katoh, K. Takatsu, S. Hiroto, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Asian J. 2 Pages: 849-859
  • Peer Reviewed
• [Journal Article] Porphyrin Pincer Complexes: Peripherally Cyclometallated Porphyrins and Their Catalytic Activities Controlled by Central Metals (2007)
  • Author(s): S. Yamaguchi, T. Katoh, H. Shinokubo, A. Osuka
  • Journal Title: J. Am. Chem. Soc. 129 Pages: 6392-6393
  • Peer Reviewed
• [Journal Article] Synthesis of Doubly β-to-β 1,3-Butadiyne-Bridged Diporphyrins: Enforced Planar Structures and Large Two-photon Absorption Cross Sections (2007)
  • Author(s): H. Hisaki
  • Journal Title: Angew. Chem., Int. Ed. 46 Pages: 5125-5128
  • Peer Reviewed
• [Journal Article] Regioselective Borylation of Porphyrins via C-H Bond Activation under Iridium Catalysis That Affords Useful Building Blocks for Porphyrin Assemblies (2007)
  • Author(s): H. Hata
  • Journal Title: Chem. Asian J. 2 Pages: 849-859
  • Peer Reviewed
• [Journal Article] Synthesis of meso-5-Azaindolyl Appended Zn(II) Porphyrins via Pd-Catalyzed Annulation (2007)
  • Author(s): C. Maeda
  • Journal Title: Org. Lett. 9 Pages: 2493-2496
  • Peer Reviewed
• [Journal Article] Facile Peripheral Functionalization of Porphyrins via Pd-Catalyzed [3 + 2] Annulation with Alkynes (2006)
  • Author(s): A. K. Sahoo, S. Mori, H. Shinokubo, A. Osuka
  • Journal Title: Angew. Chem., Int. Ed. 45 Pages: 7972-7975
  • Peer Reviewed
• [Journal Article] Synthesis and Biradicaloid Character of Doubly Linked Corrole Dimers (2006)
  • Author(s): S. Hiroto, K. Furukawa, H. Shinokubo, A. Osuka
  • Journal Title: J. Am. Chem. Soc. 128 Pages: 12380-12381
  • Peer Reviewed
• [Journal Article] Synthesis of Brominated Directly Fused Diporphyrins through Gold(III)-Mediated Oxidation (2006)
  • Author(s): A. K. Sahoo, Y. Nakamura, N. Aratani, K. S. Kim, S. B. Noh, H. Shinokubo, D. Kim, A. Osuka
  • Journal Title: Org. Lett. 8 Pages: 4141-4144
  • Peer Reviewed
• [Journal Article] Facile Peripheral Functionalization of Porphyrins via Pd-Catalyzed[3+2]Annulation with Alkynes (2006)
  • Author(s): Akhila K. Sahoo
  • Journal Title: Angew. Chem., Int. Ed. 45・47 Pages: 7972-7975
• [Journal Article] Synthesis and Biradicaloid Character of Doubly Linked Corrole Dimers (2006)
  • Author(s): Satoru Hiroto
  • Journal Title: J. Am. Chem. Soc. 128・38 Pages: 12380-12381
• [Journal Article] Synthesis of Brominated Directly Fused Diporphyrins through Gold(III)-Mediated Oxidation (2006)
  • Author(s): Akhila K. Sahoo
  • Journal Title: Org. Lett. 8・18 Pages: 4141-4144
• [Journal Article] A Directly Fused Tetrameric Porphyrin Sheet and Its Anomalous Electronic Properties That Arise from the Planar Cyclooctatetraene Core (2006)
  • Author(s): Yasuyuki Nakamura
  • Journal Title: J. Am. Chem. Soc. 128・12 Pages: 4119-4427
• [Presentation] ピリジンが縮環したポルフィリンの合成と性質 (2009)
  • Author(s): 徳地澄人・高橋裕司・新森英之・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-30
• [Presentation] β、β-ジヒドロキシポルフィリンの合成および二量化反応 (2009)
  • Author(s): 廣戸聡
  • Organizer: 第89日本化学会春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-30
• [Presentation] ピリジンが縮環したポルフィリンの合成と性質 (2009)
  • Author(s): 徳地澄人
  • Organizer: 第89日本化学会春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-30
• [Presentation] ペリレンビスイミドの高選択的アリール化と機能評価 (2009)
  • Author(s): 中園智美・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-29
• [Presentation] β,β-ジヒドロキシポルフィリンの合成および二量化反応 (2009)
  • Author(s): 廣戸聡、久木一朗、忍久保洋、大須賀篤弘
  • Organizer: 第89日本化学会春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-29
• [Presentation] ペリレンビスイミドの高選択的アリール化と機能評価 (2009)
  • Author(s): 中園智美
  • Organizer: 第89日本化学会春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2009-03-29
• [Presentation] コロール二量体のビラジカル性 (2009)
  • Author(s): 忍久保洋
  • Organizer: 分子研研究会「ビラジカル化学とその展望」
  • Place of Presentation: 分子科学研究所
  • Year and Date: 2009-03-06
• [Presentation] 有機金属触媒反応を用いた新規コロール誘導体の合成と物性 (2009)
  • Author(s): 広戸聡・忍久保洋・大須賀篤弘
  • Organizer: 第53回有機金属討論会
  • Place of Presentation: 大阪市立大学
• [Presentation] Synthesis of Pyridine-fused Porphyrinoid (2008)
  • Author(s): Sumito Tokuji
  • Organizer: 10 th KAIST-KYOTO Chemstry Symposium
  • Place of Presentation: KAIST
  • Year and Date: 2008-12-11
• [Presentation] 2,18-ジヒドロキシポルフィリンの合成と物性 (2008)
  • Author(s): 廣戸聡、久木一朗、忍久保洋、大須賀篤弘
  • Organizer: 第19回基礎有機化学連合討論会
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-10-03
• [Presentation] ピリジンが縮環したポルフィリンの合成と性質 (2008)
  • Author(s): 徳地澄人・忍久保洋・大須賀篤弘
  • Organizer: 第19回基礎有機化学連合討論会
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-10-03
• [Presentation] 2, 18-ジヒドロキシポルフィリンの合成と物性 (2008)
  • Author(s): 廣戸聡
  • Organizer: 第19回基礎有機化学連合討論会
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-10-03
• [Presentation] ピリジンが縮環したポルフィリンの合成と性質 (2008)
  • Author(s): 徳地澄人
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 大阪大学
  • Year and Date: 2008-10-03
• [Presentation] C-H活性化を利用するペリレンビスイミドの高選択的アリール化 (2008)
  • Author(s): 中園智美・忍久保洋・大須賀篤弘
  • Organizer: 第55回有機金属化学討論会
  • Year and Date: 2008-09-30
• [Presentation] C-H活性化を利用するペリレンビスイミドの高選択的アリール化 (2008)
  • Author(s): 中園智美
  • Organizer: 第55回有機金属化学討論会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2008-09-30
• [Presentation] ペリレンビスイミドの高選択的官能基化とその機能 (2008)
  • Author(s): 中園智美・今崎雄介・忍久保洋・大須賀篤弘
  • Organizer: 2008年光化学討論会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2008-09-11
• [Presentation] Synthesis of Novel Porphyrins by Organometallic Means (2008)
  • Author(s): H. Shinokubo, A. Osuka
  • Organizer: 8th International Symposium on Functional π-Electron System
  • Place of Presentation: Graz, Austria
  • Year and Date: 2008-07-22
• [Presentation] Synthesis of Novel Porphyrins by Organometallic Means (2008)
  • Author(s): Hiroshi Shinokubo
  • Organizer: 8 th International Symposium on Functional π-Electron Systems
  • Place of Presentation: グラーツ
  • Year and Date: 2008-07-22
• [Presentation] Synthesis of Alkylated Perylene Bisimides and Their Optical Properties (2008)
  • Author(s): S. Nakazono, Y. Imazaki, H. Shinokubo, A. Osuka
  • Organizer: 8th International Symposium on Functional π-Electron Systems
  • Place of Presentation: Graz, Austria
  • Year and Date: 2008-07-21
• [Presentation] Synthesis of Alkylated Perylene Bisimides and Their Optical Properties (2008)
  • Author(s): Satomi Nakazono
  • Organizer: 8 th International Symposium on Functional π-Electron Systems
  • Place of Presentation: グラーツ
  • Year and Date: 2008-07-21
• [Presentation] Synthesis of Novel Porphyrins by Organometallic Means (2008)
  • Author(s): H. Shinokubo, A. Osuka
  • Organizer: XXIII International Conference on Organometallic Chemistry
  • Place of Presentation: Rennes, France
  • Year and Date: 2008-07-14
• [Presentation] Synthesis of Novel Porphyrins by Organometallic Means (2008)
  • Author(s): Hiroshi Shinokubo
  • Organizer: XXIII International Conference on Organometallic Chemistry
  • Place of Presentation: レンヌ
  • Year and Date: 2008-07-14
• [Presentation] Synthesis of Novel Porphyrins by Organometallic Means (2008)
  • Author(s): H. Shinokubo
  • Organizer: Fifth International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Moscow, Russia
  • Year and Date: 2008-07-07
• [Presentation] Reactivity and Biradical Character of Doubly Linked Corrole Dimers (2008)
  • Author(s): S. Hiroto, H. Shinokubo, A. Osuka
  • Organizer: Fifth International Conference on Porphyrins and Phthalocyanins
  • Place of Presentation: Moscow, Russia
  • Year and Date: 2008-07-07
• [Presentation] Reactivity and Biradical Character of Doubly Linked Corrole Dimers (2008)
  • Author(s): S. Hiroto
  • Organizer: Fifth International Conference on Porphyrins and Phthalocyanins
  • Place of Presentation: モスクワ
  • Year and Date: 2008-07-07
• [Presentation] Synthesis of Novel Porphyrins by Organometallic Means (2008)
  • Author(s): Hiroshi Shinokubo
  • Organizer: Fifth International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: モスクワ
  • Year and Date: 2008-07-07
• [Presentation] パラジウム触媒による歪んだオレフィンとの[3+2]環化反応を用いたポルフィリン類縁体の合成と物性 (2008)
  • Author(s): 水村理俊・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
  • Year and Date: 2008-03-30
• [Presentation] オレフィン架橋二重縮環コロールの合成とそのビラジカル性の研究 (2008)
  • Author(s): 廣戸聡・古川貢・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
  • Year and Date: 2008-03-29
• [Presentation] ペリレンビスイミドの高選択的官能基化と機能評価 (2008)
  • Author(s): 中園智美・今崎雄介・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
  • Year and Date: 2008-03-28
• [Presentation] アザインドール置換及びトリアゾール置換ポルフィリン亜鉛錯体の合成と会合挙動 (2008)
  • Author(s): 前田千尋・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
  • Year and Date: 2008-03-27
• [Presentation] パラジウム触媒による臭素化ポルフィリンと歪んだアルケンとの反応 (2007)
  • Author(s): 水村理俊・忍久保洋・大須賀篤弘
  • Organizer: 第54回有機金属化学討論会
  • Place of Presentation: 広島大学
  • Year and Date: 2007-10-28
• [Presentation] Palladium-Catalyzed [3+2] Annulation of meso-Bromoporphyrins with Strained Alkenes (2007)
  • Author(s): 水村理俊
  • Organizer: 第54回有機金属化学討論会
  • Place of Presentation: 広島大学
  • Year and Date: 2007-10-28
• [Presentation] 二重縮環コロールの反応とその生成物の構造 (2007)
  • Author(s): 廣戸聡
  • Organizer: 第38回構造有機化学討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2007-10-28
• [Presentation] 二重縮環コロールの反応とその生成物の構造 (2007)
  • Author(s): 廣戸聡・忍久保洋・大須賀篤弘
  • Organizer: 第37回構造有機化学討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2007-10-27
• [Presentation] ルテニウム触媒を用いたペリレンビスイミドの2,5,8,11位における高選択的官能基化 (2007)
  • Author(s): 中園智美・今崎雄介・忍久保洋・大須賀篤弘
  • Organizer: 第54回有機金属化学討論会
  • Place of Presentation: 広島大学
  • Year and Date: 2007-10-27
• [Presentation] パラジウム触媒を用いた[3+2]環化反応によるメゾ-アザインドール置換ポルフィリン亜鉛錯体の合成及びその自己集合挙動 (2007)
  • Author(s): 前田千尋・忍久保洋・大須賀篤弘
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-26
• [Presentation] パラジウム触媒を用いた[3+2]環化反応によるメゾーアザインドール置換ポルフィリン亜鉛錯体の合成及びその自己集合挙動 (2007)
  • Author(s): 前田千尋
  • Organizer: 第57回錯体化学討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-26
• [Presentation] Palladium-Catalyzed Annulation of meso-Bromoporphyrins with Strained Alkenes Containing Norbornyl Scaffolds (2007)
  • Author(s): M. Mizumura
  • Organizer: 14th IUPAC International Symposium on Organometallic Chemistry Towards Organic Synthesis Aromatic Compounds
  • Place of Presentation: なら100年会館
  • Year and Date: 2007-08-05
• [Presentation] Synthesis of meso-5-Azaindolyl Appended Zn(II) Porphyrin via Pd-Catalyzed Annulation (2007)
  • Author(s): C. Maeda
  • Organizer: 14th IUPAC International Symposium on Organometallic Chemistry Towards Organic Synthesis Aromatic Compounds
  • Place of Presentation: なら100年会館
  • Year and Date: 2007-08-05
• [Presentation] Synthesis of Corrole Derivative through Organometal Catalyzed Reactions (2007)
  • Author(s): S. Hiroto
  • Organizer: 14th IUPAC International Symposium on Organometallic Chemistry Towards Organic Synthesis Aromatic Compounds
  • Place of Presentation: なら100年会館
  • Year and Date: 2007-08-05
• [Presentation] Synthesis of Corrole Derivative through Organometal Catalyzed Reactions (2007)
  • Author(s): S. Hiroto, H. Shinokubo, A. Osuka
  • Organizer: 14th IUPAC Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
  • Place of Presentation: 奈良
  • Year and Date: 2007-08-03
• [Presentation] Synthesis of meso-5-Azaindolyl Appended Zn(II) Porphyrin via Pd-Catalyzed Annulation (2007)
  • Author(s): C. Maeda, H. Shinokubo, A. Osuka
  • Organizer: 4th IUPAC Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
  • Place of Presentation: 奈良
  • Year and Date: 2007-08-03
• [Presentation] Palladium-Catalyzed Annulation of meso-Bromoporphyrins with Strained Alkenes Containing Norbornyl Scaffolds (2007)
  • Author(s): M. Mizumura, H. Shinokubo, A. Osuka
  • Organizer: 4th IUPAC Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
  • Place of Presentation: 奈良
  • Year and Date: 2007-08-03
• [Presentation] Rhodium-Catalyzed Efficient Functionalization of Porphyrins (2007)
  • Author(s): H. Shinokubo
  • Organizer: 14th IUPAC International Symposium on Organometallic Chemistry Towards Organic Synthesis Aromatic Compounds
  • Place of Presentation: なら100年会館
  • Year and Date: 2007-08-03
• [Presentation] Facile Peripheral Functionalization of Porphyrins via Pd-Catalyzed [3+2] Annulation with Alkynes (2007)
  • Author(s): H. Shinokubo
  • Organizer: 12th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: 淡路夢舞台
  • Year and Date: 2007-07-23
• [Presentation] Synthesis and Properties of Doubly Linked Corrole Dimers (2007)
  • Author(s): S. Hiroto
  • Organizer: 12th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: 淡路夢舞台
  • Year and Date: 2007-07-23
• [Presentation] パラジウム触媒による臭素化ポルフィリンとアルケンとの反応 (2007)
  • Author(s): 水村理俊・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 関西大学
  • Year and Date: 2007-03-28
• [Presentation] 二重縮環コロール二量体の合成と性質 (2007)
  • Author(s): 廣戸聡・古川貢・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 関西大学
  • Year and Date: 2007-03-28
• [Presentation] パラジウム触媒による臭素化ポルフィリンとアルキンの[3+2]環化反応 (2007)
  • Author(s): 荒井清治・A. K. Sahoo・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 関西大学
  • Year and Date: 2007-03-27
• [Presentation] 遷移金属触媒によるペリレンビスイミドの位置選択的修飾反応 (2007)
  • Author(s): 今崎雄介・忍久保洋・大須賀篤弘
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 関西大学
  • Year and Date: 2007-03-27
• [Presentation] Facile Peripheral Functionalization of Porphyrins via Pd-Catalyzed [3 + 2] Annulation with Alkynes (2007)
  • Author(s): A. K. Sahoo, S. Arai, S. Mori, H. Shinokubo, A. Osuka
  • Organizer: 12th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: 淡路島
• [Presentation] Synthesis and Properties of Doubly Linked Corrole Dimers (2007)
  • Author(s): S. Hiroto, H. Shinokubo, A. Osuka
  • Organizer: 12th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: 淡路島
• [Presentation] Regioselective borylation of porphyrinoid via C-H bond activation with iridium complex (2006)
  • Author(s): H. Shinokubo, H. Hata, S. Hiroto, A. Osuka
  • Organizer: Fourth International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Rome, Italy
  • Year and Date: 2006-07-02
• [Presentation] Regioselective Direct Borylation of Porphyrinoids with Iridium Catalyst (2006)
  • Author(s): H. Shinokubo, S. Hiroto, H. Hata, A. Osuka
  • Organizer: The 10th International Kyoto Conference on New Aspects of Organic Chemistry
  • Place of Presentation: 京都
• [Presentation] Synthesis of Brominated Directly Fused Diporphyrins through Gold(III)-Mediated Oxidation (2006)
  • Author(s): A. K. Sahoo, H. Shinokubo, A. Osuka
  • Organizer: The 10th International Kyoto Conference on New Aspects of Organic Chemistry
  • Place of Presentation: 京都
• [Presentation] Synthesis and properties of novel corrole derivatives through Ir-catalyzed direct borylation (2006)
  • Author(s): Hiroto, H. Shinokubo, A. Osuka
  • Organizer: The 10th International Kyoto Conference on New Aspects of Organic Chemistry
  • Place of Presentation: 京都
• [Presentation] Synthesis and Biradicaloid Character of Doubly Linked Corrole Dimers (2006)
  • Author(s): S. Hiroto, K. Furukawa, H. Shinokubo, A. Osuka
  • Organizer: 2006 Korea-Japan Symposium on Frontier Photoscience System
  • Place of Presentation: Seoul, Korea
• [Presentation] 二重縮環コロールの合成とビラジカル性についての研究 (2006)
  • Author(s): 廣戸聡・古川貢・忍久保洋・大須賀篤弘
  • Organizer: 第18回基礎有機化学連合討論会
  • Place of Presentation: 九州産業大学
• [Presentation] Ir-catalyzed regioselective borylation of aromatic substituents of porphyrins (2006)
  • Author(s): H. Shinokubo, H. Hata, A. Osuka
  • Organizer: Fourth International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Rome, Italy
• [Presentation] Synthesis and properties of novel corrole derivatives through Ir-catalyzed direct borylation (2006)
  • Author(s): S. Hiroto, H. Shinokubo, A. Osuka
  • Organizer: Fourth International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Rome, Italy
• [Presentation] Synthesis and properties of novel corrole derivatives through Ir-catalyzed direct borylation (2006)
  • Author(s): S. Hiroto, H. Shinokubo, A. Osuka
  • Organizer: The 7th International Symposium on Functional π-Electron System
  • Place of Presentation: 大阪
• [Book] ポルフィリンの周辺官能基化, 檜山爲次郎監修、電子共役系有機材料の創製・機能開発・応用 (2008)
  • Author(s): 忍久保洋
  • Publisher: シーエムシー出版
• [Remarks] ホームページ等
  • URL: http://www.apchem.nagoya-u.ac.jp/hshino/index.html
• [Remarks]
  • URL: http://www.apchem.nagoya-u.acjp/hshino/sub/research/research.html