Understanding and Prediction of Nano-physical Properties for Polymers Based on Combinatorial Method

• Project/Area Number: 18685014
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Polymer chemistry
• Research Institution: Kyushu University
• Principal Investigator: TANAKA Keiji Kyushu University, 大学院・工学研究院, 教授 (20325509)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000); Fiscal Year 2008: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000); Fiscal Year 2007: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2006: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
• Keywords: 高分子薄膜・表面 / コンビナトリアル手法 / 高分子ナノ物性 / 階層的ダイナミクス / 表面・界面・超薄膜 / 走査プローブ顕微鏡 / 中性子反射率測定 / 動的粘弾性測定 / 時空間分解蛍光測定 / 時空間分解能光測定

Research Abstract

ナノテクノロジーの発展に伴いデバイスの微細化、すなわち、素材料の微細化が急速に進行している。高分子材料においても例外ではなく、厚さ100nm以下の高分子膜が幅広い分野で使用されるようになってきた。本研究では、ナノサイズの高分子材料で観測される特異な分子鎖熱運動性の発現機構とその支配因子を明らかにした。

Research Products

• [Journal Article] Interfacial Mobility of Polymers on Inorganic Solids (2009)
  • Author(s): K. Tanaka, 他5名
  • Journal Title: J. Phys. Chem. B. 113 (14) Pages: 4571-4577
  • Peer Reviewed
• [Journal Article] Non-solvents Cause Swelling at the Interface with Poly (methyl Methacrylate) Films (2008)
  • Author(s): K. Tanaka, Y. Fujii, H. Atarashi, M. Hino, T. Nagamura
  • Journal Title: Langmuir 24(1) Pages: 296-301
  • Peer Reviewed
• [Journal Article] Simultaneous Imaging for Surface and Internal Structure of Polymer Blend Thin Films (2008)
  • Author(s): H. Sugihara, K. Oya, H. Murase, K. Akabori, K. Tanaka, T. Kajiyama, A. Takahara
  • Journal Title: Appl. Suff. Sci. 254(10) Pages: 3180-3183
  • Peer Reviewed
• [Journal Article] Entanglement Effect on Film Retention of Poly (methyl methacrylate) in Methanol (2008)
  • Author(s): Y. Fujii, H. Atarashi, T. Nagamura, K. Tanaka
  • Journal Title: Chem. Lett. 37(3) Pages: 326-327
  • NAID: 10021078665
  • Peer Reviewed
• [Journal Article] Model Analysis of Scanning Viscoelasticity Microscopy and Its Applications to Polymer Surfaces (2008)
  • Author(s): K. Akabori, K. Tanaka, H. Murase, A. Takahara, T. Kajiyama
  • Journal Title: J Soc. Rheology Japan 36(2) Pages: 87-92
  • NAID: 10025542126
  • Peer Reviewed
• [Journal Article] Surface Depth Analysis for Fluorinated Block Copolymer Films by X-ray Photoelectron Spectroscopy Using C60 Cluster Ion Beam (2008)
  • Author(s): K. Tanaka, N. Sanada, M. Hikita, T. Nakamura, T. Kajiyama, A. Takahara
  • Journal Title: Appl. Surface Sci. 254(17) Pages: 5435-5438
  • Peer Reviewed
• [Journal Article] Directional Affinity of Short Peptides for Synthetic Polymers (2008)
  • Author(s): T. Date, K. Tanaka, T. Nagamura, T Serizawa
  • Journal Title: Chem. Mater. 20(14) Pages: 4536-4538
  • Peer Reviewed
• [Journal Article] Surface Depth Analysis for Fluorinated Block Copolymer Films by X-ray Photoelectron Spectroscopy Using C_<60> Cluster Ion Beam (2008)
  • Author(s): K.Tanaka, 他5名
  • Journal Title: Appl. Surface Sci 254(17) Pages: 5435-5438
  • Peer Reviewed
• [Journal Article] Directional Affinity of Short Peptides for Synthetic Polymers (2008)
  • Author(s): T. Date, K. Tanaka, 他2名
  • Journal Title: Chem. Mater. 20 (14)
  • Peer Reviewed
• [Journal Article] Substrate Effect on Mechanical Relaxation of Polystyrene in Ultrathin Films (2007)
  • Author(s): K. Akabori, K. Tanaka, A. Takahara, T. Kajiyama, T. Nagamura
  • Journal Title: Eur Phys. J. Special Topics 141 Pages: 173-180
  • Peer Reviewed
• [Journal Article] Graft Polymerization Initiated by Photo-sensitizer Segregated at Surface of Polymer Film Upon Ultraviolet Irradiation (2007)
  • Author(s): H. Atarashi, K. Akabori, A. Tanaka, M. Ozawa, K. Tanaka, T. Nagamura
  • Journal Title: Chem. Lett. 36(6) Pages: 808-809
  • NAID: 130004722760
  • Peer Reviewed
• [Journal Article] Surface and Interfacial Segregation in Blends of Polystyrene with Functional End Groups and Deuterated Polystyrene (2007)
  • Author(s): D. Kawaguchi, K. Tanaka, N. Torikai, A. Takahara, T. Kajiyama
  • Journal Title: Langmuir 23(13) Pages: 7269-7275
  • Peer Reviewed
• [Journal Article] ポリスチレン超薄膜中における階層的分子運動特性 (2007)
  • Author(s): 立石洋平、赤堀敬一、田中敬二、長村利彦
  • Journal Title: 奇分子論文棄 64(7) Pages: 429-436
  • Peer Reviewed
• [Journal Article] Effects of Static and Dynamic Forces on Surface Viscoelastic Response of Polymer Films in Scanning Viscoelasticity Microscopy (2007)
  • Author(s): K. Akabori, K. Tanaka, N. Satomi, T. Nagamura, A. Takahara, T. Kajiyama
  • Journal Title: Polymer J. 39(7) Pages: 684-689
  • NAID: 10019524272
  • Peer Reviewed
• [Journal Article] Kinetics of Photo-induced E to Z Isomerization for Azobenzene in Films ; Thickness, Molecular Weight and Temperature Effects (2007)
  • Author(s): Y. Tateishi, K. Tanaka, T. Nagamura
  • Journal Title: J Phys. Chem. B. 111(27) Pages: 7761-7766
  • Peer Reviewed
• [Journal Article] Chain Conformation Effect on Molecular Motion at Surface in Poly(methyl Methacrylate) Films (2007)
  • Author(s): Y. Fujii, K. Akabori, K. Tanaka, T. Nagamura
  • Journal Title: Polymer J. 39(9) Pages: 928-934
  • NAID: 10019860781
  • Peer Reviewed
• [Journal Article] A Novel Structural Analysis for A Cylinder-forming Block Copolymer Thin Film Using Neutron Reflectivity Aided by Transmission Electron Microtomography (2007)
  • Author(s): K. Niihara, U. Matsuwaki, N. Torikai, H. Atarashi, K. Tanaka, H. Jinnai
  • Journal Title: Macromolecules 40(19) Pages: 6940-6946
  • Peer Reviewed
• [Journal Article] Gas Sorption into Surface of Poly (methyl methacrylate) Films at Atmospheric Pressure (2007)
  • Author(s): Y. Fujii, H. Atarashi, N. Yamada, N. Torikai, T. Nagamura, K. Tanaka
  • Journal Title: Polymer J. 39(12) Pages: 1290-1294
  • NAID: 10020285569
  • Peer Reviewed
• [Journal Article] Graft Polymerization Initiated by Photo-sensitizer Segregated at Surface of Polymer Film Upon Uitraviolet Irradiation (2007)
  • Author(s): H, Atarashi・K, Akabori・A, Tanaka・M, Ozawa・K, Tanaka・T, Nagamura
  • Journal Title: Cehm, Lett. 36(6) Pages: 808-809
  • Peer Reviewed
• [Journal Article] Effects of Static and Dynamic Forces on Surface Viscoelastic Response of Polymer Films in Scanning Viscoelasticity Microscopy (2007)
  • Author(s): K, Akabori・K, Tanaka・N, Satomi・T, Nagamura・A, Takahara・T, Kajiyama
  • Journal Title: Polym. J. 39(7) Pages: 684-689
  • NAID: 10019524272
  • Peer Reviewed
• [Journal Article] Kinetics of Photo-induced E to Z Isomerization for Azobenzene in Films: Thickness, Molecular Weight and Temperature Effects (2007)
  • Author(s): Y, Tateishi・K, Tanaka・T, Nagamura
  • Journal Title: J. Phys. Chem. B. 111(27) Pages: 7761-7766
  • Peer Reviewed
• [Journal Article] Substrate Effect on Mechanical Relaxation of Polystyrene in Ultrathin Films (2007)
  • Author(s): K.Akabori, K.Tanaka, A.Takahara, T.Kajiyama, T.Nagamura
  • Journal Title: Eur. Phys. J. Special Topics 141 Pages: 173-180
• [Journal Article] 束縛場における高分子のガラス転移 (2006)
  • Author(s): 田中敬二
  • Journal Title: 高分子論文 63(8) Pages: 539-547
  • NAID: 10019295961
  • Peer Reviewed
• [Journal Article] Time- and Space-resolved Fluorescence Study on Interfacial Mobility of Polymers (2006)
  • Author(s): K. Tanaka, Y. Tsuchimura, K. Akabori, F. Ito, T. Nagamura
  • Journal Title: Appl. Phys. Lett. 89(6)
  • Peer Reviewed
• [Journal Article] Study of the Glass Transition Temperature of Polymer Surface by Coarse-grained Molecular Dynamics Simulation (2006)
  • Author(s): H. Morita, K. Tanaka, T. Kajiyama, T. Nishi, M. Doi
  • Journal Title: Macromolecules 39(18) Pages: 6233-6237
  • Peer Reviewed
• [Journal Article] A Test of MIEZE - Reflectometer for Study of Surface and Interface (2006)
  • Author(s): M. Hino, M. Kitaguchi, H. Hayashida, Y. Kawabata, S. Tasaki, T. Ebisawa, D. Yamazaki, R. Maruyama, K. Tanaka, N. Torikai, R. Inoue, T. Kanaya
  • Journal Title: Physica B 385-386 Pages: 1125-1127
  • Peer Reviewed
• [Journal Article] Relation between the Adhesion Strength and Interfacial Width for Symmetric Polystyrene Bilayers (2006)
  • Author(s): K. Akabori, D. Baba, K. Koguchi, K. Tanaka, T. Nagamura
  • Journal Title: J. Polym. Sci. B : Polym. Phys. 44(24) Pages: 3598-3604
  • Peer Reviewed
• [Journal Article] Comparison of Interdiffusion Behavior between Cyclic and Linear Polystyrenes with High Molecular Weights (2006)
  • Author(s): D.Kawaguchi, K.Masuoka, A.Takano, K.Tanaka, T.Nagamura, N.Torikai, R.M.Dalgliesh, S.Langridge, Y.Matsushita
  • Journal Title: Macromolecules 39 Pages: 5180-5182
• [Journal Article] 束縛場における高分子のガラス転移 (2006)
  • Author(s): 田中敬二
  • Journal Title: 高分子論文集 63 Pages: 539-547
  • NAID: 10019295961
• [Journal Article] Time- and Space-resolved Fluorescence Study on Interfacial Mobility of Polymers (2006)
  • Author(s): K.Tanaka, Y.Tsuchimura, K.Akabori, F.Ito, T.Nagamura
  • Journal Title: Appl. Phys. Lett. 89
• [Journal Article] Study of the Glass Transition Temperature of Polymer Surface by Coarse-grained Molecular Dynamics Simulation (2006)
  • Author(s): H.Morita, K.Tanaka, T.Kajiyama, T.Nishi, M.Doi
  • Journal Title: Macromolecules 39 Pages: 6233-6237
• [Journal Article] Relation between the Adhesion Strength and Interfacial Width for Symmetric Polystyrene Bilayers (2006)
  • Author(s): K.Akabori, D.Baba, K.Koguchi, K.Tanaka, T.Nagamura
  • Journal Title: J. Polym. Sci. B : Polym. Phys. 44 Pages: 3598-360
• [Presentation] Glass Transition Temperature of Polystyrene at Interfaces with Inorganic Substrates by Time-and Space-Resolved Fluorescence Spectroscopy (2008)
  • Author(s): K. Tanaka, 他4名
  • Organizer: The XVth International Congress on Rheology, The Society of Rheology 80^<th> Annual Meeting
  • Place of Presentation: California, USA
  • Year and Date: 2008-08-05
• [Presentation] 走査プローブ顕微鏡による液体界面の高分子物性評価 (2008)
  • Author(s): 田中敬二、藤井義久、長村利彦
  • Organizer: 日本顕微鏡学会第64回学術講演会
  • Place of Presentation: 京都
• [Presentation] Anomalous Swelling of Polymer at Interfaces with Non-solvents (2008)
  • Author(s): K. Tanaka, Y. Fujii, M. Hino, T. Nagamura
  • Organizer: International Symposium on Non-Equilibrium Soft Matter
  • Place of Presentation: Kyoto
• [Presentation] 水とポリメタクリル酸メチル膜界面の凝集構造と分子運動特性 (2008)
  • Author(s): 田中敬二、藤井義久、新 史紀、日野正裕、長村利彦
  • Organizer: 繊維学会年次大会
  • Place of Presentation: 東京
• [Presentation] Glass Transition Temperature of Polystyrene at Interfaces with Inorganic Substrates by Time-and Space-Resolved Fluorescence Spectroscopy (2008)
  • Author(s): K. Tanaka, Y. Tateishi, T. Nagamura, H. Morita, M. Doi
  • Organizer: The XVth International Congress on Rheology, The Society of Rheology 80th Annual Meeting
  • Place of Presentation: California
• [Presentation] Density Profiles of Poly (methylMethacrylate) at Non-solvent Interfaces (2008)
  • Author(s): K. Tanaka, M. Hino, T. Nagamura
  • Organizer: International Symposium on Polymer Physics
  • Place of Presentation: Fukuoka
• [Presentation] 光を用いた高分子薄膜・表面・界面の構造と物性評価-水界面における高分子鎖の凝集構造と分子鎖熱運動性- (2008)
  • Author(s): 田中敬二、長村利彦
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪
• [Presentation] Glass Transition Temperature of Polystyrenes at Inorganic Solid Interfaces by Time-and Space-Resolved Fluorescence Spectroscopy (2008)
  • Author(s): K. Tanaka, Y. Tateishi, Y. Okada, H. Morita, M. Doi, T. Nagamura
  • Organizer: Japan-Korea Polymer Young Scientist Symposium
  • Place of Presentation: Niigata
• [Presentation] Local Conformation of Poly (methyl methacrylate) at the Water Interface (2008)
  • Author(s): K. Tanaka, Y. Tateishi, T. Nagamura
  • Organizer: 2nd Japan-Korea Joint Seminar 2008 and International Symposium
  • Place of Presentation: Tokyo
• [Presentation] Aggregation States of Poly (methyl Methacrylate) at the Water Interface (2008)
  • Author(s): K. Tanaka, Y. Tateishi, T. Nagamura
  • Organizer: The 3rd International Symposium on Polymer Science
  • Place of Presentation: Nagoya
• [Presentation] Aggregation Structure of Polymers at Interfaces with Non-solvents (2008)
  • Author(s): K. Tanaka
  • Organizer: The 3rd Taiwan-Japan Workshop on Neutron Scattering of Bio-Materials and Soft-Matters for Nanotechnology nad Biotechnology
  • Place of Presentation: Kyoto
• [Presentation] Swelling of Poly(methy1 methacrylate) at the Interface with Non-Solvents (2007)
  • Author(s): k, Tanaka・Y, Fujii・M, Hino・T, Nagamura
  • Organizer: The 10th Pacific Polymer Conference
  • Place of Presentation: Kobe
• [Book] 15章異種固体におけるガラス転移温度 (2009)
  • Author(s): 田中敬二、長村利彦
  • Publisher: 高分子表面・界面分析法の新展開、西岡利勝監修、シーエムシー出版
• [Book] 高分子表面・界面分析法の新展開、15章異種固体におけるガラス転移温度 (2009)
  • Author(s): 田中敬二、長村利彦
  • Total Pages: 11
  • Publisher: (株) シーエムシー出版
• [Book] 第5章高分子の物性、5-5表面物性 (2006)
  • Author(s): 田中敬二
  • Publisher: 基礎高分子禅学、川口春馬編集委員長・高分子学会編、東京化学同人
• [Book] 20章表面の高分子鎖ダイナミクス評価 (2006)
  • Author(s): 田中敬二
  • Publisher: 機能物質の集積膜と応用展開、関隆広監修、シーエムシー出版
• [Book] 第5編生体を越えるものづくり、第3章ナノファイバー解析の必須技術、第1節2ナノ力学物性 (2006)
  • Author(s): 田中敬二
  • Publisher: ファイバースーパーバイオミメティックス-近未来創造テクノロジー、本宮達也監修、NTS
• [Book] III編高分子加工の基礎研究、2.走査フォース顕微鏡による高分子のナノ構造・物性解析 (2006)
  • Author(s): 高原淳、古賀智之、田中敬二、梶山千里
  • Publisher: Plastics Age Encyclopedia、プラスチックエージ
• [Book] 機能物質の集積膜と応用展開(関 隆広監修) "20章 表面の高分子鎖ダイナミクス評価" (2006)
  • Author(s): 田中敬二
  • Total Pages: 9
  • Publisher: シーエムシー出版
• [Remarks]
  • URL: http://www.cstfkyushu-u.acjp/~tanaka-lab/
• [Patent(Industrial Property Rights)] 表面改質されたポリマー構造体の製造方法 (2008)
  • Inventor(s): 田中敬二, 他5名
  • Industrial Property Rights Holder: 九州大学他1社
  • Filing Date: 2008-04-23
  • Overseas
• [Patent(Industrial Property Rights)] 表面改質されたポリマー構造体の製造方法 (2007)
  • Inventor(s): 田中, 他6名
  • Industrial Property Rights Holder: 九州大学
  • Filing Date: 2007-04-25