Creation of photofunctional hybrid compund film of σ-conjugated polymer and liquid crystal molecule

• Project/Area Number: 18750110
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: Gunma University
• Principal Investigator: HORIUCHI Hiroaki Gunma University, 大学院工学研究科, 助教 (00334136)
• Project Period (FY): 2006 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥3,740,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥240,000); Fiscal Year 2008: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2007: ¥800,000 (Direct Cost: ¥800,000); Fiscal Year 2006: ¥1,900,000 (Direct Cost: ¥1,900,000)
• Keywords: 膜 / 集合体 / 光構造制御 / ポリシラン / 薄膜 / フォトクロミズム / 液晶 / アゾベンゼン

Research Abstract

σ共役高分子であるポリシランは様々な興味深い物性を示すが、それらの物性は主鎖構造に依存する。本課題では、このポリシランの主鎖構造を光によって制御することを試みた。ポリシランの側鎖に液晶性フォトクロミック化合物であるアゾベンゼン誘導体を導入し、光照射を行った。その結果、薄膜状態において、側鎖の光異性化によりポリシラン主鎖構造の変化を誘起することに成功した。また、熱的に逆反応を誘起できることも見いだした。

Research Products

• [Journal Article] Conformational Change of Poly(methylphenylsilane) Induced by the hotoisomerization of Pendant Azobenzene Moiety in the Film State (2008)
  • Author(s): Horiuchi, H.; Fukushima, T.; Zhao, C.; Okutsu, T.; Takigami, S.; Hiratsuka, H
  • Journal Title: J. Photochem. Photobiol A, 198 Pages: 135-143
  • Peer Reviewed
• [Journal Article] Photophysical property of the J-aggregate thin film of an oxacyanine dye prepared by the spin-coating method and enhancement of its photostability by use of polydimethylsilane (2008)
  • Author(s): Tania, K.; Horiuchi, H.; Hiratsuka, H (名, 6番目)
  • Journal Title: J. Photochem. Photobiol A, 199 Pages: 150-155
  • Peer Reviewed
• [Journal Article] Tryptophan Neutral Radical Brings along Photochemical Crystallization (2008)
  • Author(s): Furuta, K.; Tanizawa, Y.; Horiuchi, H.; Hiratsuka, H.; Okutsu, T
  • Journal Title: Chem. Lett 37 Pages: 458-459
  • NAID: 10021079817
  • Peer Reviewed
• [Journal Article] Photochemically induced nucleation of ribonuclease A enhanced by a stable protein dimmer produced from the photochemical reaction of Tyr residual groups (2008)
  • Author(s): Furuta, K.; Horiuchi, H.; Hiratsuka, H., Okutsu, T
  • Journal Title: Cryst. Growth & Des 8 Pages: 1886-1889
  • Peer Reviewed
• [Journal Article] Photophysical Property and Photostability of J-Aggregate Thin Films of Thiacyanine Dyes Prepared by the Spin-Coating Method (2008)
  • Author(s): Tani, K.; Horiuchi, H.; Hiratsuka H(他4名, 6番目)
  • Journal Title: J. Phys. Chem B, 112 Pages: 836-844
  • Peer Reviewed
• [Journal Article] Photophysical Property of the J-aggregate Thin Film of an Oxacyanine Dye Prepared by the Spin-coating Method and Enhancement of its Photostability by Use of Polydimethylsilane (2008)
  • Author(s): K. Tani, K. Matsuzaki, Y Kodama, M. Fukita, T. Kodaira, H. Horiuchi, T. Okutsu, H. Hiratsuka
  • Journal Title: J. Photochem. Photobiol., A 199 Pages: 150-155
  • Peer Reviewed
• [Journal Article] Conformational Change of Poly(methylphenylsilane) Induced by the hotoisomerization of Pendant Azobenzene Moiety in the Film State (2008)
  • Author(s): H. Horiuchi, T. Fukushima, C. Zhao, T. Okutsu, S. Takigami H. Hiratsuka
  • Journal Title: J. Photochem. Photobiol., A 198 Pages: 135-143
  • Peer Reviewed
• [Journal Article] Tryptophan Neutral Radical Brings along Photochemical Crystallization (2008)
  • Author(s): K. Furuta, Y. Tanizawa, H. Horiuchi, H. Hiratsuka, T. Okutsu
  • Journal Title: Chem. Lett 37 Pages: 458-459
  • NAID: 10021079817
  • Peer Reviewed
• [Journal Article] Photochemically induced nucleation of ribonuclease A enhanced by a stable protein dimmerproduced from the photochemical reaction of Tyr residual groups (2008)
  • Author(s): K. Furuta, H. Horiuchi, H. Hiratsuka, T. Okutsu
  • Journal Title: Cryst. Growth & Des. 8 Pages: 1886-1889
  • Peer Reviewed
• [Journal Article] Conformational Change of Poly (methylphenylsilane) Induced by the hotoisomerization of Pendant Azobenzene Moiety in the Film State (2008)
  • Author(s): Horiuclu, H.; Fukushima, T, ; Zhao, C.; Okutsu, T.; Takigami, S.; Hiratsuka, H.
  • Journal Title: J. Photochem. Photobiol., A: Chem. (印刷中)
  • Peer Reviewed
• [Journal Article] Photophysical Property and Photostability of J-Aggregate Thin Films of Thiacyanine Dyes Prepared by the Spin-Coating Method (2008)
  • Author(s): Tani, K; Ito, C.; Hanawa, Y.; Uchida, M.; Otaguro, K; Horiuchi, H.; Hiratsuka, H.
  • Journal Title: J. Phys. Chem. B 112(3) Pages: 836-844
  • Peer Reviewed
• [Journal Article] Tryptophan Neutral Radical Brings along Photochemical Crystallizatio (2008)
  • Author(s): Furuta, K; Tanizawa, Y.; Horiuchi, H.; Hiratsuka, H.; Okutsu, T.
  • Journal Title: Chem. Lett. 37(4) Pages: 458-459
  • Peer Reviewed
• [Journal Article] Photochemically induced nucleation of ribonuclease A enhanced by a stable protein dimmer produced from the photochemical reaction of Tyr residual groups (2008)
  • Author(s): Furuta, K; Horiuchi, H.; Hiratsuka, H., Okutsu, T.
  • Journal Title: Cryst. Growth & Des. (印刷中)
  • Peer Reviewed
• [Journal Article] Photochemically induced nucleation in supersaturated and undersaturated thaumatin solutions (2008)
  • Author(s): Okutsu, T.; Sugiyama, K.; Furuta, K.; Watanebe, L; Mori, H.; Obi, K.; Horota, K.; Horiuchi, H.; Sazaki, G.; Veesler, S.; Hiratsuka, H.
  • Journal Title: J. Phys. Chem. B 112(3) Pages: 836-844
  • Peer Reviewed
• [Journal Article] Excited-state property of 1-(4-cyanophenyl)-2-(4- methoxyphenyl)-1,1,2,2-tetramethyldisilane (2007)
  • Author(s): Hiratsuka, H.; Horiuchi, H(他7名, 2番目)
  • Journal Title: Chem. Lett 36 Pages: 1168-1169
  • NAID: 10019846042
  • Peer Reviewed
• [Journal Article] Detection of Covalent-bonded Dimer in Photochemically Induced Crystallization of Protein (2007)
  • Author(s): Furuta, K.; Okutsu, T.; Horiuchi, H(他6名, 5番目)
  • Journal Title: Chem. Lett 36 Pages: 714-715
  • NAID: 130004424753
  • Peer Reviewed
• [Journal Article] Enhancement of light-induced nucleation of lysozyme in the presence of polyethylene glycol (PEG) 4000 (2007)
  • Author(s): Okutsu, T.; Horiuchi, H.; Hiratsuka, H(他6名, 8番目)
  • Journal Title: Chem. Lett 36 Pages: 338-339
  • NAID: 10018523241
  • Peer Reviewed
• [Journal Article] Dual phosphorescence and excited state dynamics of p-bromotoluene (2007)
  • Author(s): Okutsu, T.; Horiuchi H.; Hiratsuka, H(他4名, 5番目)
  • Journal Title: J. Photochem. Photobiol A 186 Pages: 229-233
  • Peer Reviewed
• [Journal Article] Excited-state property of 1-(4-cyanophenyl)-2-(4-methoxyphenyl)-1, 1, 2, 2-tetramethyldisilane (2007)
  • Author(s): Hiratsuka, H.; Horiuchi. H.; Takanoha, Y.; Matsumoto, H.; Yoshihara, T; Okutsu, T.; Negishi, K.; Kyushin, S.; Matsumoto, H.
  • Journal Title: Chem. Lett. 36(9) Pages: 1168-1169
  • NAID: 10019846042
  • Peer Reviewed
• [Journal Article] Detection of covalent-bonded dimer in photochemically induced crystallization of protein (2007)
  • Author(s): Furuta, K.; Okutsu, T.; Sazaki, G.; Yoshizaki, L; Horiuchi. H.; Shimizu, T.; Yamamoto, M.; Tanaka, Y.; Hiratsuka, H.
  • Journal Title: Chem. Lett. 36(6) Pages: 714-715
  • NAID: 130004424753
  • Peer Reviewed
• [Journal Article] Enhancement of light-induced nucleation of lysozyme in the presence of polyethylene glycol (PEG) 4000 (2007)
  • Author(s): Okutsu, T.; Sato, M.; Furuta, K.; Fujinaga, Y.; Horota, K.; Obi, K.; Horiuchi, H.; Hiratsuka, H.
  • Journal Title: Chem. Lett. 36(2) Pages: 338-339
  • NAID: 10018523241
  • Peer Reviewed
• [Journal Article] Dual phosphorescence and excited state dynamics of p-bromotoluene (2007)
  • Author(s): Okutsu, T.; Ishihara, A.; Kounose, N.; Horiuchi, H.; Suzuki, T.; Ichimura, T.; Hiratsuka, H.
  • Journal Title: J. Photochem. Photobiol., A 186(2-3) Pages: 229-233
  • Peer Reviewed
• [Journal Article] Dual phosphorescence and excited state dynamics of p-bromotoluene (2007)
  • Author(s): T.Okutsu, A.Ishihara, N.Kounose, H.Horiuchi, T.Suzuki, T.Ichimura, H.Hiratsuka
  • Journal Title: J.Photochem.Photobiol.A 186 Pages: 229-233
• [Journal Article] Enhancement of Light-induced Nucleation in the Presence of Polyethylene Glycol (PEG) 4000 (2007)
  • Author(s): T.Okutsu, M.Sato, K.Furuta, Y.Fujinaga, K.Horota, K.Obi, H.Horiuchi, H.Hiratsuka
  • Journal Title: Chem.Lett. (in press)
• [Journal Article] Enhancement of singlet oxygen sensitization of tetraphenylporphyrin by silylation (2006)
  • Author(s): Horiuchi, H.; Hiratsuka, H (他5名, 1番目)
  • Journal Title: Chem. Lett 35 Pages: 662-663
  • NAID: 10019163037
  • Peer Reviewed
• [Journal Article] Crystals from light: Photochemically induced nucleation of hen egg-white lysozyme (2006)
  • Author(s): Veesler, S.; Horiuchi, H.; Okutsu, T (他3名, 3番目)
  • Journal Title: Cryst. Growth & Des 6 Pages: 1631-1635
  • Peer Reviewed
• [Journal Article] Thermal Hysteresis and Thickness Dependence of the Molecular Orientation of Poly(di-n-hexylsilane) in the Film State (2006)
  • Author(s): Horiuchi, H(他12名, 1番目)
  • Journal Title: J. Phys. Chem B 110 Pages: 9072-9078
  • Peer Reviewed
• [Journal Article] Photophysical and Photochemical Processes of 9,10-Dihydro-9-silaphenanthrene Derivatives: Photochemical Formation and Electronic Structure of 9-Silaphenanthrenes (2006)
  • Author(s): Hiratsuka, H.; Horiuchi, H(他10名, 2番目)
  • Journal Title: J. Phys. Chem A 110 Pages: 3868-3874
  • Peer Reviewed
• [Journal Article] Yellow-green fluorescence of 5,11- and 5,12-Bis(diisopropylsilyl)naphthacenes (2006)
  • Author(s): Kyushin, S.; Ishikita, Y.; Matsumoto, H.; Horiuchi, H.; Hiratsuka, H
  • Journal Title: Chem. Lett 35 Pages: 64-65
  • NAID: 10016907825
  • Peer Reviewed
• [Journal Article] Thermal Hysteresis and Thickness Dependence of the Molecular Orientation of Poly(di-n-hexylsilane) in the Film State (2006)
  • Author(s): H.Horiuchi, T.Ishihara, S.Tsunoda, D.Morishita, T.Takei, T.Okutsu, T.Seko, H.Sugino, Y.Kawakami, H.Watanabe, M.Abe, S.Takigami, H.Hiratsuka
  • Journal Title: J.Phys.Chem.B 110 Pages: 9072-9078
• [Journal Article] Enhancement of Singlet Oxygen Sensitization of Tetraphenylporphyrin by Silylation (2006)
  • Author(s): H.Horiuchi, T.Tanaka, K.Yoshimura, K.Sato, S.Kyushin, H.Matsumoto, H.Hiratsuka
  • Journal Title: Chem.Lett. 35 Pages: 662-663
  • NAID: 10019163037
• [Journal Article] Yellow-green Fluorescence of 5,11- and 5,12-Bis(diisopropylsilyl)naphthacenes (2006)
  • Author(s): S.Kyushin, Y.Ishikita, H.Matsumoto, H.Horiuchi, H.Hiratsuka
  • Journal Title: Chem.Lett. 35 Pages: 64-65
  • NAID: 10016907825
• [Journal Article] Crystals from light : Photochemically-induced nucleation (2006)
  • Author(s): S.Veesler, K.Furuta, H.Horiuchi, H.Hiratsuka, N.Ferte, T.Okutsu
  • Journal Title: Cryst.Growth ＆ Des. 6 Pages: 1631-1635
• [Journal Article] Effects of the Substituents on 4-Position on the Photon-mode Erasable Photochromic System of 2-Hydroxychalcone Derivatives
  • Author(s): Horiuchi, H(他6名, 1番目)
  • Journal Title: J. Photochem. Photobiol A(印刷中)
  • Peer Reviewed
• [Presentation] シリルポルフィリンの細胞取込過程と光線力学活性 (2009)
  • Author(s): 堀内宏明(他7名, 1番目)
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-27
• [Presentation] 光化学反応による分子間力の制御 (2009)
  • Author(s): 新野見智之・堀内宏明・平塚浩士・奥津哲夫
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-27
• [Presentation] シリルポルフィリンの細胞取込過程と光線力学活性 (2009)
  • Author(s): 堀内宏明・亀谷剛大・吉村公男・久新荘一郎・松本英之・穂坂正博・竹内利行・平塚浩士
  • Organizer: 日本化学会第89春季年会(2009)
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-27
• [Presentation] 光化学反応による分子間力の制御 (2009)
  • Author(s): 新野見智之・堀内宏明・平塚浩士・奥津哲夫
  • Organizer: 日本化学会第89春季年会(2009)
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-27
• [Presentation] オキサゾールおよびチアゾール環を有するモノメチンシアニン色素の耐光性 (2009)
  • Author(s): 吉田貴之・大関太吾郎・小平拓郎・大田黒国彦・堀内宏明・平塚浩士
  • Organizer: 日本化学会第89春季年会(2009)
  • Place of Presentation: 千葉
  • Year and Date: 2009-03-27
• [Presentation] フォトクロミック分子の光誘起結晶成長とモルフォロジー制御 (2008)
  • Author(s): 新野見智之・堀内宏明・平塚浩士・奥津哲夫
  • Organizer: 第2回関東支部大会(2008)
  • Place of Presentation: 群馬
  • Year and Date: 2008-09-19
• [Presentation] 光照射時のポリシランによるシアニン色素薄膜の安定化機構 (2008)
  • Author(s): 石田祥平・堀内宏明・谷克彦・松崎健一・角田欣一・堀田弘樹・橋本拓也・平塚浩士
  • Organizer: 第2回関東支部大会(2008
  • Place of Presentation: 群馬
  • Year and Date: 2008-09-19
• [Presentation] フォトクロミック分子の光誘起結晶成長とモルフォロジー制御 (2008)
  • Author(s): 新野見智之・堀内宏明・平塚浩士・奥津哲夫
  • Organizer: 第2回日本化学会関東支部大会
  • Place of Presentation: 群馬
  • Year and Date: 2008-09-18
• [Presentation] 含ケイ素光増感色素のin vitro の光線力学活性と光物理的性質 (2008)
  • Author(s): 亀谷剛大・堀内宏明(他6名, 2番目)
  • Organizer: 第2回日本化学会関東支部大会
  • Place of Presentation: 群馬
  • Year and Date: 2008-09-18
• [Presentation] 含ケイ素光増感色素のin vitroの光線力学活性と光物理的性質 (2008)
  • Author(s): 亀谷剛大・堀内宏明・平塚浩士
  • Organizer: 第2回関東支部大会(2008)
  • Place of Presentation: 群馬
  • Year and Date: 2008-09-18
• [Presentation] 光照射時のポリシランによるシアニン色素薄膜の安定化機構 (2008)
  • Author(s): 石田祥平・堀内宏明(他6名, 2番目)
  • Organizer: 2008年光化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-13
• [Presentation] 含ケイ素光増感色素の光物理的性質とin vitro の光線力学活性 (2008)
  • Author(s): 亀谷剛大・堀内宏明・(他6名, 2番目)
  • Organizer: 2008年光化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-13
• [Presentation] 非対称シアニン色素J会合体薄膜の耐光性 (2008)
  • Author(s): 大関太吾郎・太田黒国彦・谷克彦・小平拓朗・堀内宏明・平塚浩士
  • Organizer: 2008年光化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-13
• [Presentation] 含ケイ素光増感色素の光物理的性質とin vitroの光線力学活性 (2008)
  • Author(s): 亀谷剛大・堀内宏明・穂坂正博・竹内利之・吉村公男・久新荘一郎・松本英之・平塚浩士
  • Organizer: 2008年光化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-13
• [Presentation] Stabilization of cyanine dye thin film by polysilanes upon photo-irradiition (2008)
  • Author(s): S. Ishida, H. Horiuchi, K. Tani, K. Matsuzaki, K. Tsunoda, H. Hotta, T. Hashimoto, H. Hiratsuka
  • Organizer: Post ISOS XV Symposium
  • Place of Presentation: 群馬
  • Year and Date: 2008-06-09
• [Presentation] Photophysical and photochemical properties of thia-azacyanine dye thin films on quartz plate (2008)
  • Author(s): H. Hiratsuka, H Horiuchi, N. Kusakari, D. Ohzeki, K. Tani, T. Kodaira
  • Organizer: XXII^<nd> IUPAC Symposium On Photochemistry
  • Place of Presentation: 群馬
  • Year and Date: 2008-06-09
• [Presentation] Heavy atom effect of group 14 elements at 9-position in fluorine (2008)
  • Author(s): H. Oshima, N. Kusakari, H. Horiuchi, T. Okutsu, H. Hiratsuka, T. Kondo, Y. Ishihara, J. Takano, M. Oba, K. Nishiyam
  • Organizer: XXII^<nd> IUPAC Symposium On Photochemistry
  • Place of Presentation: 群馬
  • Year and Date: 2008-06-09
• [Presentation] Photophysical and electrochemical properties of phenazasi line derivatives in solution and thin film (2008)
  • Author(s): H. Huang, H. Horiuchi, H. Hiratsuka, T. Kondo, Y. lshihara, J. Takanob, M. Oba, K. Nishiyama
  • Organizer: The 15^<th> International Symposium on Otganosilicon Chemistry
  • Place of Presentation: 住済州島(韓国)
  • Year and Date: 2008-06-01
• [Presentation] Photodynamic Activities of Silicon-containing Photosensitizers in Vitro (2008)
  • Author(s): T. Kameya, H. Horiuchi, M. Hosaka , T. Takeuchi, K. Yoshimura, S. Kyushin, H. Matsumoto, H. Hiratsuka
  • Organizer: The 15^<th> International Symposium on Organosilicon Chemisty
  • Place of Presentation: 住済州島(韓国)
  • Year and Date: 2008-06-01
• [Presentation] Stabilization of cyanine dye thin film by polysilanes upon photo-irradiation (2008)
  • Author(s): Syohei Ishida , Hiroaki Horiuchi, (他6名, 2番目)
  • Organizer: Post ISOS XV Symposiu
  • Place of Presentation: Takasaki
• [Presentation] Photodynamic Activities of Silicon-containing Photosensitizers in Vitro (2008)
  • Author(s): Kameya, Takehiro; Horiuchi, Hiroaki; (他6名, 2番目)
  • Organizer: The 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: Korea
• [Presentation] Donor-Acceptor基を有するdiaryldisilaneの溶液及び固体マトリクス中の光物性 (2008)
  • Author(s): 松本大志・堀内宏明(他5名, 2番目)
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
• [Presentation] 2-Hydroxychalcone 類の光物理・光化学過程の再検討 (2008)
  • Author(s): 岩田健作・堀内宏明・平塚浩士
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
• [Presentation] Donor-Acceptor基を有するdiaryldisilaneの溶液及び固体マイトリクス中の光物性 (2008)
  • Author(s): 松本 大志・堀内 宏明・京免 徹・花屋 実・久新 荘一郎・松本 英之・平塚 浩士
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] 9-sila-, 9-germa-, 9-stanna-fluorenesの光物理過程における重原子効果 (2008)
  • Author(s): 大島 秀文・草刈 伸治・堀内 宏明・奥津 哲夫・平塚 浩士・近藤 智裕・石原 良美・高野 二郎・大場 真・西山 幸三郎
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] 2-Hydroxychalcone類の光物理・光化学過程の再検討 (2008)
  • Author(s): 岩田 健作・堀内 宏明・平塚 浩士
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] 非対称シアニン色素の固体表面上におけるJ会合体薄膜形成と光物性 (2008)
  • Author(s): 大関 太吾郎・小平 拓郎・大田黒 国彦・堀内 宏明・平塚 浩士
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] シアニン色素J会合体の成長と光物性 (2008)
  • Author(s): 中島 聖・小平 拓郎・大田黒 国彦・堀内 宏明・平塚 浩士
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学
• [Presentation] in vitroにおける含ケイ素光増感色素の光線力学活性 (2007)
  • Author(s): 亀谷剛大、堀内宏明(他6名, 2番目)
  • Organizer: 2007年光化学討論会
  • Place of Presentation: 松本
  • Year and Date: 2007-09-28
• [Presentation] 光線力学療法への応用を目指した含ケイ素光増感色素の開発 (2007)
  • Author(s): 堀内宏明、(他7名, 1番目)
  • Organizer: 2007年光化学討論会
  • Place of Presentation: 松本
  • Year and Date: 2007-09-28
• [Presentation] シリル化による光増感色素の高効率化の検討 (2007)
  • Author(s): 堀内宏明(他7名, 1番目)
  • Organizer: 第17回日本光線力学学会学術講演会
  • Place of Presentation: 栃木
  • Year and Date: 2007-06-16
• [Presentation] Donor-Acceptor 基を有するdiaryloligosilaneの励起状態 (2007)
  • Author(s): 松本大志・堀内宏明(他6名, 4番目)
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2007-03-25
• [Presentation] ポリシランによるシアニン色素J会合体薄膜の耐光性の向上 (2007)
  • Author(s): 松崎健一・堀内宏明(他4名, 3番目)
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2007-03-25
• [Presentation] シリル化ポルフィリンによる一重項酸素光増感と光線力学療法への応用 (2007)
  • Author(s): 堀内宏明(他7名, 1番目)
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2007-03-25
• [Presentation] Photodynamic activities of Silicon-containing Photosensitizers in Vitro (2007)
  • Author(s): KAMEYA, Takehiro; HORIUCHI, Hiroaki (他6名, 2番目)
  • Organizer: The 3rd International Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: Gunma
• [Presentation] Enhancement of Photodynamic Activity of Tetraphenylporphyrin Derivatives by Silylation (2007)
  • Author(s): Hiroaki Horiuchi, (他7名, 1番目)
  • Organizer: 1st Asian Silicon Symposium
  • Place of Presentation: Miyagi
• [Presentation] 光線力学療法への応用を目指した含ケイ素光増感色素の開発 (2007)
  • Author(s): 堀内宏明・亀谷剛大・吉村公男・久新荘一郎・松本英之・穂坂正博・竹内利之・平塚浩士
  • Organizer: 光化学討論会
  • Place of Presentation: 信州大学
• [Presentation] Enhancement of Photodynamic Activity of Tetraphenylporphyrin Derivatives by Silylation (2007)
  • Author(s): H. Horiuchi. T. Kameya, M. Hosaka, T. Takeuchi, K. Yoshimura, S. Kyushin, H. Matsumoto, H., Hiratsuka
  • Organizer: 1st Asian Silicon Symposium
  • Place of Presentation: 蔵王
• [Presentation] シリル化による光増感色素の高効率化の検討 (2007)
  • Author(s): 堀内宏明、亀谷剛大、穂坂正博、竹内利行、吉村公男、久新荘一郎、松本英之、平塚浩士
  • Organizer: 光線力学学会
  • Place of Presentation: 鬼怒川
• [Presentation] 9位に高周期14族元素を有するフルオレン誘導体の光物理過程 (2007)
  • Author(s): 大島秀文・草刈伸治・古川恭也・堀内宏明・平塚浩士・西山幸三郎・大場 真
  • Organizer: 光化学討論会
  • Place of Presentation: 信州大学
• [Presentation] in vitroにおける含ケイ素光増感色素の光線力学活性 (2007)
  • Author(s): 亀谷剛大・堀内宏明・穂坂正博・竹内利之・吉村公男・久新荘一郎・松本英之・平塚浩士
  • Organizer: 光化学討論会
  • Place of Presentation: 信州大学
• [Presentation] Photophysics of 9-Sila, 9-Germa, and 9-Stanna-fluorenes-Heavy atom effect- (2007)
  • Author(s): H.Hiratsuka, H.Horiuchi, H.Ohshima, N.Kusakari, Y.Furukawa, T.Okutsu, T.Kondoh, M.Oba, K.Nishiyama
  • Organizer: 1st Asian Silicon Symposium
  • Place of Presentation: 蔵王
• [Presentation] ポリシランによる色素J会合体薄膜の耐光性の向上 (2006)
  • Author(s): 松崎健一・堀内宏明(他4名, 3番目)
  • Organizer: ケイ素化学シンポジウム
  • Place of Presentation: 群馬
  • Year and Date: 2006-11-10
• [Presentation] ポリシランの光構造制御におよぼす置換基効果 (2006)
  • Author(s): 岩田健作・堀内宏明・平塚浩士
  • Organizer: ケイ素化学シンポジウム
  • Place of Presentation: 群馬
  • Year and Date: 2006-11-10
• [Presentation] 光線力学療法に用いる含ケイ素光増感色素の開発 (2006)
  • Author(s): 堀内宏明(他7名, 1番目)
  • Organizer: ケイ素化学シンポジウム
  • Place of Presentation: 群馬
  • Year and Date: 2006-11-10
• [Presentation] Enhancement of Photo-stability of Cyanine J-Aggregates by Polysilane (2006)
  • Author(s): Kenichi Matsuzaki, Hiroaki Horiuchi, (他4名, 3番目)
  • Organizer: The 2nd International Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: Gunma
  • Year and Date: 2006-11-09
• [Presentation] Substituent effects on the photo-control of polysilane conformation (2006)
  • Author(s): Kensaku Iwata, Hiroaki Horiuchi, Hiroshi Hiratsuka
  • Organizer: The 2nd International Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: Gunma
  • Year and Date: 2006-11-09
• [Presentation] Photochemistry of Silylporphyrin as Photosensitizers for Photodynamic Therapy (2006)
  • Author(s): Hiroaki Horiuchi, (他7名, 1番目)
  • Organizer: The 2nd International Symposium on Development of Silicon-based Functional Materials
  • Place of Presentation: Gunma
  • Year and Date: 2006-11-09
• [Presentation] 薄膜状態におけるポリシラン主鎖構造の光制御 (2006)
  • Author(s): 堀内宏明・平塚浩士
  • Organizer: 第55回高分子討論会
  • Place of Presentation: 富山
  • Year and Date: 2006-09-21
• [Presentation] シリル化ポルフィリンによる一重項酸素の光増感 (2006)
  • Author(s): 堀内宏明(他7名, 1番目)
  • Organizer: 2006年光化学討論会
  • Year and Date: 2006-09-10
• [Book] 光機能性高分子材料の新たな潮流 -最新技術とその展望- (2008)
  • Author(s): 堀内宏明, 平塚浩士
  • Publisher: シーエムシー出版
• [Book] 光機能性高分子材料の新たな潮流-最新技術とその展望- (2008)
  • Author(s): 堀内宏明, 平塚浩士
  • Publisher: シーエムシー出版
• [Book] 光機能性高分子材料の新たな潮流(第1章:オリゴシラン、ポリシランの光物性) (2008)
  • Author(s): 堀内宏明、平塚浩士(監修:市村國宏)
  • Total Pages: 16
  • Publisher: (株)シーエムシー出版